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21. 发明授权

KR101957362B1 이산화탄소 흡수제 및 그 제조방법, 이를 이용한 이산화탄소 포집방법 有权
公开(公告)号：KR101957362B1
公开(公告)日：2019-03-14
申请号：KR1020110109891
申请日：2011-10-26
申请人： 한국전력공사
发明人： 위영호 , 류청걸 , 이중범 , 엄태형
IPC分类号： B01J20/30 , B01J20/34

22. 发明公开

KR1020150036864A 고체 이산화탄소 흡수제 조성물 및 이를 함유하는 고체 이산화탄소 흡수제 审中-实审
标题翻译：固体吸附剂组合物，用于从化石燃料燃烧中除去二氧化碳，并含有固体吸附剂
公开(公告)号：KR1020150036864A
公开(公告)日：2015-04-08
申请号：KR1020130115820
申请日：2013-09-30
申请人： 한국전력공사
发明人： 엄태형 , 류청걸 , 이중범 , 백점인 , 김경숙
IPC分类号： B01D53/14 , B01D53/62 , B01D53/81 , B01D53/96
CPC分类号： B01J20/043 , B01D53/62 , B01D53/81 , B01D53/82 , B01D53/83 , B01D53/96 , B01D2253/104 , B01D2253/106 , B01D2253/112 , B01D2253/1124 , B01D2253/25 , B01D2257/504 , B01D2258/0283 , B01D2259/40088 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/2803 , B01J20/3204 , B01J20/3236 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： 본발명은이산화탄소를제거하기위한고체이산화탄소흡수제조성물로서, 활성물질, 지지체, 및무기결합제를포함하고, 상기지지체는알루미늄화합물및 2종이상의 4가금속산화물을포함하는고체이산화탄소흡수제조성물에관한것이다.
摘要翻译：本发明涉及一种用于除去二氧化碳的固体二氧化碳吸收剂组合物，其包含：活性物质; 支持者和无机粘合剂，其中所述载体包括铝化合物和两种或更多种四价金属氧化物。

23. 发明公开

KR1020150009796A 탈황제 제조용 원료 조성물 및 이를 이용해 제조된 탈황제 审中-实审
标题翻译：用于原材料制造的脱硫和固体脱硫分离原料
公开(公告)号：KR1020150009796A
公开(公告)日：2015-01-27
申请号：KR1020130084160
申请日：2013-07-17
申请人： 한국전력공사
发明人： 백점인 , 류청걸 , 위영호 , 제갈성 , 이중범 , 엄태형 , 최동혁
IPC分类号： B01D53/48 , B01D53/81
CPC分类号： B01D53/81 , B01D53/52 , B01D2257/30 , B01D2257/304
摘要： 본 발명은 황화수소와 같은 황화합물 가스를 함유하는 가스로부터 황 성분을 고온에서 제거하는 유동층 탈황공정에 적용할 고체 탈황제 제조용 원료 조성물, 이의 제조방법 및 이를 이용하여 제조된 고체 탈황제에 관한 것이다. 본 발명에 따른 고체 탈황제 제조용 원료 조성물은 활성성분인 산화 아연 40 내지 60 중량부, 비표면적을 제공하기 위한 지지체로 보에마이트를 7 내지 25 중량부, 하이드로탈사이트(Mg-Al double-layered hydroxide) 10 내지 20 중량부, 마그네시아 1 내지 4 중량부, 강도 향상을 위한 무기결합제로 벤토나이트와 칼슘실리케이트의 혼합물을 8 내지 22 중량부, 및 재생증진제인 산화니켈 5 내지 8 중량부로 구성된다. 본 발명은 상기 원료 조성물로 만든 슬러리를 분무건조법으로 성형하고 소성시켜 제조함으로써, 형상, 입자크기 및 분포를 비롯한 물성이 고온 건식 유동층 탈황 공정에 적용하기에 적합하고, 황 흡수능이 뛰어나며, 특히 내마모도가 향상된 재생가능한 고체 탈황제를 제공한다.
摘要翻译：本发明涉及用于制造固体脱硫吸附剂的原料组合物，其应用于流化床脱硫方法，用于将其中包含硫化合物如硫化氢在内的高温下的硫成分从含气体中除去，固体脱硫吸附剂。根据本发明的固体脱硫吸附剂的制造原料组合物包含40-60重量份氧化锌，活性成分，7-25重量份勃姆石作为提供比表面积的支持物，10-20 重量份的水滑石（Mg-Al双层氢氧化物），1-4重量份的氧化镁，8-22重量份的膨润土和硅酸钙的混合物作为无机粘合剂，以提高强度，5 -8重量份的氧化镍，再生增强剂。本发明提供了可再生固体脱硫吸附剂，其中包括形状，粒度和分布的物理性质适用于高温干流化床脱硫方法，并且硫吸收性能优异，特别是耐磨性通过以喷雾干燥法形成用原料组合物制造的浆料并进行增塑而制造。

24. 发明公开

KR1020130034434A 재생증진제를 포함하는 건식 이산화탄소 흡수제 및 그 제조 방법 审中-实审
标题翻译：含有可再生干燥剂的添加剂及其制备方法
公开(公告)号：KR1020130034434A
公开(公告)日：2013-04-05
申请号：KR1020110098436
申请日：2011-09-28
申请人： 한국전력공사
发明人： 이중범 , 류청걸 , 엄태형 , 김경숙 , 백점인 , 최동혁 , 위영호
IPC分类号： B01J20/02 , B01J20/30 , B01J2/04 , B01D53/14
CPC分类号： B01D53/02 , B01D2253/112 , B01D2257/504 , B01J20/041 , B01J20/043 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/28004 , B01J20/3021 , B01J20/305 , B01J20/3078 , B01J20/3085 , Y02C10/06 , Y02C10/08 , B01J20/02 , B01D53/14 , B01J2/04 , B01J20/0203 , B01J20/30
摘要： PURPOSE: A carbon dioxide absorbing composition, a slurry composition comprising the same, a carbon dioxide absorbing agent and a method of the same are provided to be required for the average size of circular shape and distribution, packing density and abrasion resistance, be mass produced due to a dispersing technology and reduce the cost of production due to higher production yields. CONSTITUTION: A carbon dioxide absorbing composition comprises an active substance, a supporting body and an enhancer for re-growth. The enhancer for re-growth comprises more than two substances from a group made up of titania, zirconia, α - alumina, sulfuric acid vanadium and manganese oxide. The active substance is chosen among a group made up of alkali metal oxide, alkaline earth metal oxide, alkali metal carbonate, alkaline-earth metal carbonate, alkali metal bicarbonate, alkaline earth metal bicarbonate and a precursor of the former substances. The amount of the active substance is 5-80 by weight for the absorbing composition 100 by weight. The supporting body is chosen among a group made up of alumina, magnesia, silica, a clay group and hydrotalcite. The slurry composition comprises the absorbing composition and a liquid. A method of manufacturing the carbon dioxide absorbing composition comprises the following steps. The slurry composition is manufactured after being dried to make the composition solid(20). The solid composition is dried and plasticized(30). [Reference numerals] (10) Step of manufacturing slurry using solid raw material; (20) Step of primarily manufacturing an absorber by spray-drying and molding the manufactured slurry; (30) Step of manufacturing a final absorber by drying and plasticizing the primarily manufactured absorber;
摘要翻译：目的：提供二氧化碳吸收组合物，包含该二氧化碳吸收剂的浆料组合物，二氧化碳吸收剂及其制备方法，以便大规模生产圆形平均尺寸和分布，包装密度和耐磨性由于分散技术，由于生产成本较高，降低了生产成本。构成：二氧化碳吸收组合物包含活性物质，支持体和用于再生长的增强剂。用于再生长的增强剂包括由二氧化钛，氧化锆，α-氧化铝，硫酸钒和氧化锰组成的组中的两种以上的物质。活性物质选自由碱金属氧化物，碱土金属氧化物，碱金属碳酸盐，碱土金属碳酸盐，碱金属碳酸氢盐，碱土金属碳酸氢盐和前体物质的前体组成的组中。对于吸收组合物100，活性物质的量按重量计为5-80。支撑体选自由氧化铝，氧化镁，二氧化硅，粘土和水滑石组成的组中。浆料组合物包含吸收组合物和液体。制备二氧化碳吸收组合物的方法包括以下步骤。将浆料组合物在干燥后制成固体成分（20）。将固体组合物干燥并增塑（30）。（附图标记）（10）使用固体原料制造浆料的步骤; （20）通过喷雾干燥和成型制造的浆料来主要制造吸收体的步骤; （30）通过干燥和塑化主要制造的吸收体来制造最终吸收体的步骤;

25. 发明公开

KR1020120033461A 산소공여입자 및 그 제조방법 有权
标题翻译：氧气载体及其制造方法
公开(公告)号：KR1020120033461A
公开(公告)日：2012-04-09
申请号：KR1020100094980
申请日：2010-09-30
申请人： 한국전력공사
发明人： 백점인 , 류청걸 , 이중범 , 류정호 , 엄태형
IPC分类号： C01B13/14 , B01J20/28 , B01J20/06 , B01J20/32
CPC分类号： B01J20/3204 , B01J20/06 , B01J20/28004 , B01J20/28011 , B01J20/28059 , B01J20/305 , B01J20/3236 , F23C2900/99008 , Y02E20/346 , C01B13/14
摘要： PURPOSE: Oxygen donating particles and a method for manufacturing the same are provided to improve the reactivity of the oxygen donating particles and to be adequate to a fluid bed process. CONSTITUTION: Oxygen donating particles include active materials containing metal oxide and a support. The support includes hydrotalcite or the mixture of gamma alumina and the hydrotalcite. The metal oxide contains one or more selected from a group including copper-based, nickel-based, iron-based, manganese-based, and cobalt-based oxides. A composition for the oxygen donating particles include 50-80 parts by weight of the metal oxide, 10-45 parts by weight of the gamma alumina, and 5-50 parts by weight of the hydrotalcite. A method for manufacturing the oxygen donating particles includes the following: the composition is mixed with a solvent(S10); homogenized slurry is obtained(S20); the slurry is sprayed and dried to form solid particles(S30); and the solid particles are dried and plasticized to obtain eth oxygen donating particles(S40).
摘要翻译：目的：提供给氧颗粒及其制造方法，以改善供氧颗粒的反应性并适于流化床工艺。构成：供氧颗粒包括含有金属氧化物和载体的活性物质。载体包括水滑石或γ氧化铝和水滑石的混合物。金属氧化物含有选自铜系，镍系，铁系，锰系，钴系氧化物中的一种以上。供氧颗粒的组合物包括50-80重量份的金属氧化物，10-45重量份的γ-氧化铝和5-50重量份的水滑石。供氧粒子的制造方法包括：将该组合物与溶剂混合（S10）; 得到均质浆料（S20）; 将浆料喷雾并干燥以形成固体颗粒（S30）; 并将固体颗粒干燥和塑化以获得供氧颗粒（S40）。

26. 发明公开

KR1020120028046A 탈황제 및 그 제조방법 无效
标题翻译：脱硫分离器及其制造方法
公开(公告)号：KR1020120028046A
公开(公告)日：2012-03-22
申请号：KR1020100090006
申请日：2010-09-14
申请人： 한국전력공사
发明人： 류청걸 , 위영호 , 이중범 , 백점인 , 엄태형 , 류정호
IPC分类号： B01J20/16 , B01J20/02 , B01D53/48 , B01D53/28
CPC分类号： B01J20/28011 , B01D53/02 , B01D2253/104 , B01D2253/106 , B01D2253/112 , B01D2253/25 , B01D2257/30 , B01J20/0244 , B01J20/10 , B01J20/28004 , B01J20/2803 , B01J20/3028 , B01J20/3042 , B01J20/3078 , B01J20/3085 , B01J2220/42 , B01J2220/56
摘要： PURPOSE: A desulfurizing agent and a method for preparing the same are provided to improve abrasion resistance characteristic, heat resistance characteristic, and desulfurizing capability of the desulfurizing agent. CONSTITUTION: A composition for a desulfurizing agent contains desulfurizing active components, a support, and inorganic binder. The support contains alumina and calcium silicate. The inorganic binder contains one or more of bentonite, boehmite, or palygorskite. The active components are one or more selected form zinc sulfite, zinc sulfate, zinc hydroxide, zinc carbonate, zinc acetate, and zinc nitrate. The support contains 5-30 parts by weight of alumina and 1-30 parts by weight of calcium silicate. The inorganic binder contains 1-10 parts by weight of bentonite, 2-20 weight% of boehmite, or 1-10 parts by weight of palygorskite.
摘要翻译：目的：提供脱硫剂及其制备方法，以提高脱硫剂的耐磨性，耐热特性和脱硫能力。构成：用于脱硫剂的组合物含有脱硫活性成分，载体和无机粘合剂。载体含有氧化铝和硅酸钙。无机粘合剂含有一种或多种膨润土，勃姆石或坡缕石。活性组分是选自亚硫酸锌，硫酸锌，氢氧化锌，碳酸锌，乙酸锌和硝酸锌中的一种或多种。载体含有5-30重量份的氧化铝和1-30重量份的硅酸钙。无机粘合剂含有1-10重量份的膨润土，2-20重量％的勃姆石，或1-10重量份的坡缕石。

27. 发明公开

KR1020090027294A 순환공정에 의한 혼합가스 중의 산성가스 분리 및 흡수제 재생 장치 및 그 방법 有权
标题翻译：通过回收系统的混合气体的酸性气体和用于分离酸性气体和用于再生吸收剂的方法和方法
公开(公告)号：KR1020090027294A
公开(公告)日：2009-03-17
申请号：KR1020070092398
申请日：2007-09-12
申请人： 한국전력공사
发明人： 장경룡 , 엄희문 , 류청걸 , 심재구 , 김준한 , 임현수
IPC分类号： B01J20/04 , B01J20/00 , B01D53/14
CPC分类号： Y02C10/06 , B01D53/1425 , B01D2252/10
摘要： An absorbent, a system and a method for separation of the acid gas and reproduction of the absorbent are provided to improve regeneration of the absorbent by improving a thermal regenerative process conspicuously. A system for separation of acid gas in mixed gas and reproduction of an absorbent includes a CO2 absorptive tower(10), a sodium carbonate decomposition bath(20), a NaOH electrolytic bath(30) and a hydrochloric acid making device(40). The CO2 absorptive tower generates a sodium carbonate by reacting NaOH with flowed mixing gas including acid gas. The sodium carbonate decomposition bath generates NaCl by reacting the sodium carbonate with an HCl solution. The NaOH electrolytic bath generates the NaOH, hydrogen, and chlorine.
摘要翻译：提供用于分离酸性气体的吸收剂，系统和方法以及吸收剂的再现，以通过明显改善热再生过程来改善吸收剂的再生。用于分离混合气体中的酸性气体和再生吸收剂的系统包括CO 2吸收塔（10），碳酸钠分解浴（20），NaOH电解浴（30）和制盐装置（40）。 CO2吸收塔通过使NaOH与含有酸性气体的流动混合气体反应生成碳酸钠。碳酸钠分解浴通过使碳酸钠与HCl溶液反应而产生NaCl。 NaOH电解槽产生NaOH，氢和氯。

28. 发明授权

KR100426497B1 유동층용 고온건식 아연계 탈황제 및 그 제조방법과탈황제 제조용 슬러리 有权
标题翻译： 유동층용고온건식아연계탈황제및그제조방법과탈황제제조슬러리
公开(公告)号：KR100426497B1
公开(公告)日：2004-04-14
申请号：KR1020010067537
申请日：2001-10-31
申请人： 한국전력공사
发明人： 류청걸 , 이중범 , 안달홍 , 김종진
IPC分类号： B01J20/06
摘要： PURPOSE: Provided are a zinc oxide-based desulfurizing agent with proper shape, grain size and distribution, strong abrasion resistance and high desulfurizing efficiency, thereby being applicable to a fluidized-bed desulfurization process, a method for fabricating the same, and slurry used for fabricating the agent. CONSTITUTION: The desulfurizing agent is consisted of zinc oxide or zinc oxide precursor 40-60 wt%, regeneration improving agent 4-10 wt% selected from transition metal oxides, a transition metal sulfides, and precursors thereof, a supporting structure of diatomaceous earth 15-50 wt%, and inorganic binder 5-41 wt%, wherein Abrasion Index (AI) of the desulfurizing agent is less than 90%. The method comprises the steps of (a) preparing desulfurizing agent ingredients (raw materials) including zinc oxide or zinc oxide precursor 40-60 wt%, regeneration improving agent 4-10 wt% selected from transition metal oxides, a transition metal sulfides, and precursors thereof, a supporting structure of diatomaceous earth 15-50 wt%, and inorganic binder 5-41 wt%, (b) adding acid or base to the desulfurizing agent raw material to adjust pH thereof and wet-grinding the raw material, (c) adding dispersing agent, organic binder and antifoaming agent to the grinded raw material to obtain raw material slurry, (d) spray drying the slurry to obtain granular type desulfurizing agent, (e) calcining the granular type desulfurizing agent.
摘要翻译：用途：提供一种具有适当形状，粒度和分布，耐磨性强，脱硫效率高的氧化锌基脱硫剂，适用于流化床脱硫工艺及其制备方法和用于制造药剂。构成：脱硫剂由氧化锌或氧化锌前体40-60％，再生改进剂4-10％，选自过渡金属氧化物，过渡金属硫化物及其前体，硅藻土的支撑结构15 -50重量％，无机粘合剂5-41重量％，其中脱硫剂的磨损指数（AI）小于90％。该方法包括以下步骤：（a）制备包含氧化锌或氧化锌前体40-60重量％的脱硫剂成分（原料），选自过渡金属氧化物，过渡金属硫化物和4-10重量％再生改进剂的再生改进剂其前体，硅藻土的支撑结构为15-50重量％，无机粘结剂为5-41重量％，（b）向脱硫剂原料中加入酸或碱调节其pH值并湿磨原料，（ c）在研磨后的原料中加入分散剂，有机粘结剂和消泡剂，得到原料浆，（d）喷雾干燥得到粒状脱硫剂，（e）煅烧粒状脱硫剂。

29. 发明授权

KR102020950B1 산업폐기물을 이용한 산소공여입자 및 그 제조방법 有权
公开(公告)号：KR102020950B1
公开(公告)日：2019-09-16
申请号：KR1020130000402
申请日：2013-01-02
申请人： 한국전력공사
发明人： 김경숙 , 최미화 , 류청걸 , 양석란 , 백점인 , 이중범 , 엄태형
IPC分类号： C01G49/02 , C01G53/04 , B01J2/02 , B01D53/62

30. 发明授权

KR101790066B1 촉진수성가스전환 반응 공정용 촉매 및 그 제조 방법 有权
标题翻译：加速水煤气变换反应过程的催化剂及其生产方法
公开(公告)号：KR101790066B1
公开(公告)日：2017-10-26
申请号：KR1020100094732
申请日：2010-09-29
申请人： 한국전력공사
发明人： 이중범 , 류청걸 , 김경숙 , 제갈성 , 양석란 , 백점인 , 엄태형 , 류정호 , 최동혁
IPC分类号： B01J21/06 , B01J23/02 , B01J23/72 , B01J37/00 , B01J35/10 , C01B3/16
CPC分类号： C01B3/16 , B01J21/066 , B01J23/02 , B01J23/72 , B01J35/1014 , B01J35/1019 , C01B2203/1076 , C01B2203/1082 , C01B2203/1094 , Y02P20/52
摘要： 본발명은산화구리, 산화아연및 산화세리움으로이루어진그룹으로부터선택된하나이상의활성성분; 지지체, 무기결합제및 산화칼슘, 산화바륨, 산화스트론튬, 산화마그네슘, 산화지르코늄및 바륨티타니아로이루어진그룹으로부터선택된하나이상의촉진제를포함하는수성가스전환반응촉매및 그제조방법에관한것이다. 본발명에따른촉매는충진밀도및 내마모도등의물리적특성, CO 전환율이우수하여이산화탄소를효과적으로포집, 분리할수 있다. 또한, 분무기술을적용함으로대량생산이용이하고, 생산수율이높아비용발생이적기때문에석탄가스화복합발전, 연료전지, 석탄액화공정, 화합물생산공정등에저비용연소전 CO회수기술로사용할수 있다.
摘要翻译：本发明涉及包含至少一种选自氧化铜，氧化锌和氧化铈的活性成分的组合物; 和至少一种选自碳酸钙，氧化钡，氧化锶，氧化镁，氧化锆和氧化钡的促进剂及其制备方法。根据本发明的催化剂可以由于诸如填充密度和耐磨性的物理性质以及CO转化而有效地捕获和分离二氧化碳。此外，它是可能的，因为使用大量生产的通过施加喷涂技术的，并且提高生产量更少成本的煤气化复合发电，燃料电池，低成本，预燃烧CO恢复技术，诸如煤的液化方法，该化合物的生产过程。

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