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21. 发明授权

KR100511754B1 난연성 열가소성 수지 조성물 有权
公开(公告)号：KR100511754B1
公开(公告)日：2005-08-31
申请号：KR1020020062449
申请日：2002-10-14
申请人： 제일모직주식회사
发明人： 홍상현 , 안성희 , 유영식
IPC分类号： C08K5/5399
摘要： 본 발명의 난연성 열가소성 수지 조성물은 (A) 고무 변성 스티렌계 수지 100 중량부; (B) 하기 화학식으로 표시되는 고리형 포스파젠 올리고머 화합물 1 내지 10 중량부; 및 (C) 방향족 인산 에스테르 화합물 1 내지 10 중량부로 이루어지는 것을 특징으로 한다.

(상기 식에서 R
1 은 알킬기, 아릴기, 알킬 치환 아릴기, 아르알킬기, 알콕시기, 아릴옥시기, 아미노기 또는 히드록시기로부터 임의적으로 선택된 치환기를 나타내며; k와 m은 0 또는 1에서 10 까지의 정수이며; R
2 는 C
6-30 디옥시아릴 또는 알킬 치환된 C
6-30 디옥시아릴기 유도체이며; n은 수평균 중합도로서 n의 평균값은 0.3 내지 3임).

22. 发明授权

KR100508870B1 난연성 열가소성 수지 조성물 失效
公开(公告)号：KR100508870B1
公开(公告)日：2005-08-17
申请号：KR1020020088248
申请日：2002-12-31
申请人： 제일모직주식회사
发明人： 홍상현 , 안성희 , 이병도 , 김중현 , 이준영
IPC分类号： C08L25/08 , C08L55/02 , C08L71/12 , C08K9/10
摘要： 본 발명의 난연성 열가소성 수지 조성물은 (A) 열가소성 수지 100 중량부; (B) 하기 화학식 1로 표시되는 디알킬 펜타에리트리톨 디포스포네이트를 폴리스티렌 수지로 피복시킨 캡슐화 인계 화합물 1-50 중량부; 및 (C) 불소화 폴리올레핀계 수지 0∼5 중량부로 이루어진다.
[화학식 1]

상기 식에서 R은 C
1-4 의 알킬기이다.

23. 发明授权

KR100505317B1 난연성 열가소성 수지 조성물 失效
公开(公告)号：KR100505317B1
公开(公告)日：2005-08-02
申请号：KR1020030053858
申请日：2003-08-04
申请人： 제일모직주식회사
发明人： 안성희 , 양재호 , 홍상현 , 배수학 , 유영식
IPC分类号： C08K5/5333
CPC分类号： C08L51/04 , C08F279/02 , C08K5/523 , C08K5/5357 , C08L9/00 , C08L9/02 , C08L25/06 , C08L25/10 , C08L71/12 , C08L71/123 , C08L2205/03 , C08L2666/02 , C08L2666/14 , C08L2666/04
摘要： 본 발명에 따른 난연성 열가소성 수지 조성물은 (A) 고무강화 폴리스티렌 수지 20∼90 중량부, (B) 폴리페닐렌 에테르 수지 10∼80 중량부, (C) 상기 구성성분 (A)+(B)로 이루어진 기초수지 100 중량부에 대하여, 고리형 알킬 포스포닉산 화합물 0.1∼30 중량부, 및 (D) 상기 구성성분 (A)+(B)로 이루어진 기초수지 100 중량부에 대하여, 방향족 인산 에스테르계 화합물 0∼25 중량부로 이루어지는 것을 특징으로 한다.

24. 发明公开

KR1020050015167A 난연성 열가소성 수지 조성물 失效
标题翻译：阻燃剂热塑性树脂组合物，使用环烷基磷酸作为阻燃剂
公开(公告)号：KR1020050015167A
公开(公告)日：2005-02-21
申请号：KR1020030053858
申请日：2003-08-04
申请人： 제일모직주식회사
发明人： 안성희 , 양재호 , 홍상현 , 배수학 , 유영식
IPC分类号： C08K5/5333
CPC分类号： C08L51/04 , C08F279/02 , C08K5/523 , C08K5/5357 , C08L9/00 , C08L9/02 , C08L25/06 , C08L25/10 , C08L71/12 , C08L71/123 , C08L2205/03 , C08L2666/02 , C08L2666/14 , C08L2666/04
摘要： PURPOSE: Provided is a flame retardant thermoplastic resin composition which mixes cyclic alkyl phosphonic acid as flame retardant with blend of rubber reinforced polystyrene resin and polyphenylene ether resin so that it shows excellent flame retardancy, with keeping thermal resistance. CONSTITUTION: The flame retardant thermoplastic resin composition comprises the components of: 100wt% of basic resin which is composed of 20-90wt% of rubber reinforced polystyrene resin and 10-80wt% of polyphenylene ether resin; 0.1-30wt% of cyclic alkyl phosphonic acid; and 0-25wt% of aromatic phosphoric ester compound.
摘要翻译：目的：提供将环状烷基膦酸作为阻燃剂与橡胶增强聚苯乙烯树脂和聚苯醚树脂的混合物混合的阻燃性热塑性树脂组合物，其具有优异的阻燃性，同时保持耐热性。构成：阻燃热塑性树脂组合物包含：由20-90重量％的橡胶增强聚苯乙烯树脂和10-80重量％的聚苯醚树脂组成的100重量％的碱性树脂; 0.1-30wt％环烷基膦酸; 和0-25重量％的芳族磷酸酯化合物。

25. 发明授权

KR100430890B1 내충격성및성형성이우수한열가소성수지조성물 失效
公开(公告)号：KR100430890B1
公开(公告)日：2004-10-12
申请号：KR1019980062768
申请日：1998-12-31
申请人： 제일모직주식회사
发明人： 안경현 , 김성국 , 정종훈 , 안성희
IPC分类号： C08L55/02 , C08L25/04
摘要： PURPOSE: A thermoplastic resin composition having a good shock resistance and a plasticity is provided which is mixed with a butadiene based rubber graft copolymer and nonlinear acrylonitrilstyrene copolymer resin having a crosslinking point, so it manufactures large plastic goods and is used for various utilities of structural material. CONSTITUTION: A thermoplastic resin composition having a good shock resistance and plasticity is composed of 20-50 wt.pts. of graft copolymer(11) which is made by a copolymerization of rubber copolymer(B) with cyanovinyl compound(A) and aliphaticvinyl compound(S) or (A), (S) and monomer(E), wherein the weight average molecular weight of copolymer(II) is 120,000-600,000. The copolymerized weight average molecular weight is more 18,000 by containing 0.01-3 wt.pts. of the composition composed of 1-99 wt% of multifunctional mercaptan and 99-1 wt% of vinyl benzene based compound, and contains an ingredient(II-1) having more 0.6 of intrinsic viscosity. The graft copolymer(I) is composed of 20-80 wt% of graft copolymer(I-1) having 0.1-0.2 micrometer of particle size and 80-20 wt% of graft copolymer(I-2) having 0.28-0.40 micrometer of particle size.
摘要翻译：目的：提供一种具有良好耐冲击性和可塑性的热塑性树脂组合物，其与具有交联点的丁二烯基橡胶接枝共聚物和非线性丙烯腈 - 苯乙烯共聚物树脂混合，因此它制造大型塑料制品并用于各种结构用途材料。构成：具有良好耐冲击性和可塑性的热塑性树脂组合物由20-50重量份组成。（B）与氰乙烯基化合物（A）和脂族乙烯基化合物（S）或（A），（S）和单体（E）共聚制得的接枝共聚物（11），其中重均分子量的共聚物（II）为120,000-600,000。通过含有0.01-3wt.pts，共聚重均分子量为18,000。由1-99重量％多官能硫醇和99-1重量％乙烯基苯基化合物组成的组合物，并且含有特性粘度大于0.6的成分（II-1）。接枝共聚物（I）由粒径为0.1-0.2微米的接枝共聚物（I-1）20-80重量％和接枝共聚物（I-2）为0.28-0.40微米的接枝共聚物（I-2）80-20重量％粒度。

26. 发明授权

KR100448163B1 난연성 열가소성 수지 조성물 有权
标题翻译： 난연성열가소성수지조성물
公开(公告)号：KR100448163B1
公开(公告)日：2004-09-10
申请号：KR1020020038306
申请日：2002-07-03
申请人： 제일모직주식회사
发明人： 홍상현 , 양재호 , 안성희 , 배수학 , 장영길
IPC分类号： C08L25/08 , C08L51/04 , C08L71/12 , C08K5/527
摘要： PURPOSE: A flame retardant thermoplastic resin composition is provided, to improve the impact strength and the heat resistance with using a small amount of a flame retardant. CONSTITUTION: The thermoplastic resin composition comprises (A) 40-90 parts by weight of a styrene-based resin comprising (a1) 10-60 wt% of the styrene-containing graft copolymer resin prepared by graft polymerizing 10-60 wt% of a rubber component and (a2) 40-90 wt% of a styrene-acrylonitrile copolymer resin whose acrylonitrile content is 0.5-10 wt%, and 0-20 wt% of a rubber component; (B) 5-60 parts by weight of a polyphenylene ether resin; and (C) 2-30 parts by weight of a cyclic alkyl phosphonic acid compound based on 100 parts by weight of (A)+(B). Preferably the cyclic alkyl phosphonic acid compound is represented by the formula 1, wherein R1 and R2 are independently an alkyl group of C1-C4; and x is 0 or 1.
摘要翻译：目的：提供阻燃热塑性树脂组合物，通过使用少量阻燃剂来提高冲击强度和耐热性。本发明的热塑性树脂组合物包含：（A）40-90重量份的苯乙烯基树脂，其包含（a1）10-60重量％的通过接枝聚合10-60重量％的（a2）40〜90重量％的丙烯腈含量为0.5〜10重量％的苯乙烯 - 丙烯腈共聚物树脂和0〜20重量％的橡胶组分; （B）5-60重量份聚苯醚树脂; 和（C）基于100重量份的（A）+（B），2-30重量份的环烷基膦酸化合物。优选环状烷基膦酸化合物由式1表示，其中R 1和R 2独立地为C 1 -C 4的烷基; 并且x是0或1。

27. 发明公开

KR1020040059912A 난연성 열가소성 수지 조성물 有权
标题翻译：耐火热塑性树脂组合物
公开(公告)号：KR1020040059912A
公开(公告)日：2004-07-06
申请号：KR1020020086417
申请日：2002-12-30
申请人： 제일모직주식회사
发明人： 홍상현 , 안성희 , 양재호 , 배수학 , 유영식
IPC分类号： C08L51/04
CPC分类号： C08L51/04 , C08F212/08 , C08J2300/22 , C08K5/5357 , C08L25/12 , C08L2201/02
摘要： PURPOSE: Provided is a flame resistant thermoplastic resin composition, which has excellent stability against fire and flame resistance, and is environmental-friendly due to the absence of halogen-containing flame retardant compounds. CONSTITUTION: The flame resistant thermoplastic resin composition comprises: (A) 100 parts by weight of a rubber-modified styrene-based resin composed of (a1) 20-100 wt% of a graft copolymer resin obtained by graft polymerization of 5-65 wt% of a rubbery polymer, 30-95 wt% of an aromatic vinyl monomer, 0-20 wt% of a monomer which can be copolymerized with the aromatic vinyl monomer and 0-15 wt% of a monomer for supplementing processability and heat resistance, and (a2) 0-80 wt% of a copolymer resin obtained by copolymerization of 60-90 wt% of an aromatic vinyl monomer, 10-40 wt% of a monomer which can be copolymerized with the aromatic vinyl monomer and 0-30 wt% of a monomer for supplementing processability and heat resistance; and (B) 15-40 parts by weight of a cyclic alkyl phosphonic acid compound.
摘要翻译：目的：提供耐火耐火性优异的耐火热塑性树脂组合物，由于不存在含卤阻燃化合物，因此环保。构成：耐火性热塑性树脂组合物包含：（A）100重量份的由（a1）20-100重量％的接枝共聚物树脂（a）将5-65重量份的接枝聚合得到的橡胶改性苯乙烯类树脂％的橡胶状聚合物，30-95重量％的芳族乙烯基单体，0-20重量％的可与芳族乙烯基单体共聚的单体和0-15重量％的用于补充加工性和耐热性的单体，和（a2）0-80重量％的通过共聚60-90重量％的芳族乙烯基单体，10-40重量％的可与芳族乙烯基单体共聚的单体和0-30重量％用于补充加工性和耐热性的单体的％; 和（B）15-40重量份的环烷基膦酸化合物。

28. 发明授权

KR100433570B1 난연성 열가소성 수지조성물 有权
标题翻译：阻燃热塑性树脂组合物
公开(公告)号：KR100433570B1
公开(公告)日：2004-06-02
申请号：KR1020010062556
申请日：2001-10-11
申请人： 제일모직주식회사
发明人： 안성희 , 장영길 , 양재호 , 홍상현
IPC分类号： C08L55/02
摘要： 본발명의난연성열가소성수지조성물은 (A) (a) 고무성분이 10 내지 68 중량부이고, 고무성분을제외하고불포화니트릴계단량체함량이 18 내지 65 중량%인스티렌함유그라프트공중합체수지 20-90 중량% 및 (a) 불포화니트릴계단량체함량이 18 내지 65 중량%인스티렌함유공중합체수지 10-80 중량%로구성된고무변성스티렌계수지 40-100 중량부; (B) 폴리페닐렌에테르수지 0-60 중량부; (C) 상기기초수지 (A) + (B) 100 중량부에대하여방향족인산에스테르 1-30 중량부; 및 (D) 유기타이타니움화합물 0.01-20 중량부로이루어진다.
摘要翻译：本发明（A）的（a）橡胶成分为10〜68重量份的橡胶组分和含苯乙烯接枝共聚物树脂的不饱和腈单体含量，20-18份（重量）至65％，除此以外的阻燃热塑性树脂组合物 90％（重量），和（a）的18％至65％的不饱和腈单体含量（重量）的含苯乙烯的共聚物的树脂，橡胶改性的由40〜100重量份，按重量计10-80％的苯乙烯树脂; （B）0至60重量份的聚苯醚树脂; （C）基于100重量份的基础树脂（A）+（B），1-30重量份的芳族磷酸酯; （D）0.01-20重量份的有机钛化合物。

29. 发明公开

KR1020040033384A 난연성 열가소성 수지 조성물 有权
标题翻译：阻燃热塑性树脂组合物
公开(公告)号：KR1020040033384A
公开(公告)日：2004-04-28
申请号：KR1020020062449
申请日：2002-10-14
申请人： 제일모직주식회사
发明人： 홍상현 , 안성희 , 유영식
IPC分类号： C08K5/5399
摘要： PURPOSE: A flame retardant thermoplastic resin composition is provided, to improve flame retardancy, heat resistance, formability and mechanical strength. CONSTITUTION: The thermoplastic resin composition comprises 100 parts by weight of a rubber modified styrene-based resin comprising 20-100 wt% of a graft copolymer resin obtained by graft polymerizing 30-95 wt% of an aromatic vinyl-based monomer and 1-20 wt% of a monomer capable of copolymerizing with the aromatic vinyl-based monomer with 5-65 wt% of a rubber polymer, and 0-80 wt% of a copolymer resin by obtained by copolymerizing 60-90 wt% of an aromatic vinyl-based monomer and 10-40 wt% of a monomer capable of copolymerizing with the aromatic vinyl-based monomer; 1-10 parts by weight of a cyclic phosphazene compound represented by the formula 1; and 1-10 parts by weight of an aromatic phosphate compound represented by the formula 3. In the formula 1, R1 is an alkyl group, an aryl group unsubstituted or substituted with an alkyl group, an arylalkyl group, an alkoxy group, an aryloxy group, an amino group or OH, and the alkoxy and aryloxy group can be substituted with an alkyl, aryl, amino or hydroxyl group; k and m are an integer of 0-10; R2 is a dioxyaryl group unsubstituted or substituted with an alkyl group; and n has an average number of 0.3-3. In the formula 3, R3, R4 and R5 are independently H or an alkyl group of C1-C4; X is an aryl group of C6-C20 unsubstituted or substituted with an alkyl group and is derived from resorcinol, hydroquinol and dialcohol of bisphenol-A; and n is 1-4.
摘要翻译：目的：提供阻燃热塑性树脂组合物，以改善阻燃性，耐热性，成型性和机械强度。构成：热塑性树脂组合物包含100重量份的橡胶改性苯乙烯类树脂，其包含20-100重量％的通过将30-95重量％的芳族乙烯基类单体和1-20重量％的芳族乙烯基类单体接枝聚合而获得的接枝共聚物树脂重量％的能够与芳族乙烯基类单体共聚的单体与5-65重量％的橡胶聚合物，以及0-80重量％的共聚物树脂，通过共聚60-90重量％的芳族乙烯基 - 和能够与芳族乙烯基类单体共聚的单体10〜40重量％ 1-10重量份由式1表示的环状磷腈化合物; 和1-10重量份由式3表示的芳族磷酸酯化合物。在式1中，R 1是烷基，未被取代或被烷基，芳基烷基，烷氧基，芳氧基基团，氨基或OH，烷氧基和芳氧基可以被烷基，芳基，氨基或羟基取代; k和m是0-10的整数; R2是未取代或被烷基取代的二芳基; n的平均数为0.3-3。在式3中，R 3，R 4和R 5独立地为H或C 1 -C 4的烷基; X是未被取代或被烷基取代的C 6 -C 20的芳基，衍生自双酚A的间苯二酚，氢醌和二醇; n为1-4。

30. 发明授权

KR100396405B1 열가소성 난연성 수지 조성물 失效
标题翻译： 열가소성난연성수지조성물
公开(公告)号：KR100396405B1
公开(公告)日：2003-09-02
申请号：KR1020000081677
申请日：2000-12-26
申请人： 제일모직주식회사
发明人： 장영길 , 장복남 , 안성희 , 배수학
IPC分类号： C08L25/12 , C08L55/02 , C08L71/12 , C08K5/05
摘要： PURPOSE: Provided is a thermoplastic and fire retardant resin composition which has excellent injection releasability, impact resistance, fire retardancy, and fluidity. CONSTITUTION: The composition comprises 100 parts by weight of base resin consisting of the following (A) and (B): (A) 40-95 parts by weight of rubber modified styrene-acrylonitrile copolymer resin consisting of (a1) 20-90 parts by weight of styrene-acrylonitrile graft copolymer resin containing 10-60 wt% of rubber component and 18-50 wt% of acrylonitrile(in components except for the rubber component), (a2) 0-80 parts by weight of styrene-acrylonitrile copolymer resin containing 18-50 wt% of acrylonitrile, and (a3) 5-40 parts by weight of styrene-based resin containing 0-20 wt% of rubber, (B) 60-5 parts by weight of polyphenylene ether resin; (C) 2-30 parts by weight of styrene-acrylonitrile copolymer containing 5-18 wt% of acrylonitrile; (D) 5-30 parts by weight of aromatic phosphate ester compound(formula 1); and (E) 0.05-3 parts by weight of montan wax.
摘要翻译：目的：提供具有优异的注射释放性，耐冲击性，阻燃性和流动性的热塑性和阻燃性树脂组合物。构成：该组合物包含100重量份由下列（A）和（B）组成的基体树脂：（A）40-95重量份橡胶改性苯乙烯 - 丙烯腈共聚物树脂，其由（a1）20-90份（a2）0-80重量份的苯乙烯 - 丙烯腈共聚物（b），所述苯乙烯 - 丙烯腈共聚物树脂包含10-60重量％的橡胶组分和18-50重量％的丙烯腈（除了橡胶组分以外的组分）（a3）5〜40重量份含有0〜20重量％橡胶的苯乙烯系树脂，（B）60〜5重量份聚苯醚树脂，（C）2-30重量份含有5-18重量％丙烯腈的苯乙烯 - 丙烯腈共聚物; （D）5-30重量份芳香族磷酸酯化合物（式1）; 和（E）0.05-3重量份的褐煤蜡。

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