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    • 21. 发明申请
    • Block copolymer composition for overmolding any nylon
    • 用于包覆成型任何尼龙的嵌段共聚物组合物
    • US20050197447A1
    • 2005-09-08
    • US11072817
    • 2005-03-04
    • Jiren GuKrishna Venkataswamy
    • Jiren GuKrishna Venkataswamy
    • C08F8/00C08K3/00C08L23/04C08L51/00C08L53/02C09D123/04C09D151/00C09D153/02
    • C08F8/00C08K3/00C08L23/04C08L51/00C08L53/02C09D123/04C09D151/00C09D153/02
    • A thermoplastic elastomer (TPE) for overmolding (OM) a nylon substrate with an overmolded layer consists essentially of an inert filler, a plasticizer, preferably a mineral oil, and chosen combinations of ingredients from the following: (i) a functionalized “high rubber” SHDS (styrene-hydrogenated diene-styrene) having a functionality of 1%, the “small end blocks” together present in an amount in the range from about 8-25% by weight; (ii) hydrogenated SDS or SHDS block copolymer having polystyrene endblocks and a polymerized vinyl aromatic monomer in the poly(conjugated diene) midblock, the polystyrene endblocks together present in an amount in the range from 20-30% by weight of the block copolymer, excluding weight of the polystyrene in the polydiene midblock; (iii) a functionalized “high rubber” SHDS having a functionality of >1% but
    • 用于包覆成型(OM)的具有包覆成型层的尼龙基底的热塑性弹性体(TPE)主要由惰性填料,增塑剂,优选矿物油组成,以及选自下列成分的组合:(i)官能化的“高橡胶 功能性为1%的SHDS(苯乙烯 - 氢化二烯 - 苯乙烯),“小端嵌段”的量一般为约8-25重量% (ii)在聚(共轭二烯)中间嵌段中具有聚苯乙烯端嵌段和聚合的乙烯基芳族单体的氢化SDS或SHDS嵌段共聚物,聚苯乙烯端嵌段一起以嵌段共聚物的20-30重量% 不包括聚二烯中间嵌段中聚苯乙烯的重量; (iii)具有> 1%但<2%的官能度的官能化“高橡胶”SHDS,“小端嵌段”一起存在于约8-25重量%的范围内; (iv)0-30重量%的组合物,官能化聚烯烃(F3),具有2至4个碳原子的烯烃; (v)0-15重量%的组合物,氢化非官能化氢化聚苯乙烯 - 聚(共轭二烯) - 聚苯乙烯(SHDS)嵌段共聚物; 和(vi)增加组合物使用寿命的添加剂。
    • 22. 发明授权
    • Olefinic slip-coating for automotive weatherseals
    • 用于汽车耐候密封胶的含油涂层
    • US06368700B1
    • 2002-04-09
    • US09393731
    • 1999-09-10
    • Krishna VenkataswamyAngela Marie Person
    • Krishna VenkataswamyAngela Marie Person
    • B32B702
    • B32B7/02B32B27/08B32B27/32B32B2307/536B32B2307/712B32B2323/10B32B2605/08B60J10/17C08L23/0815C08L23/10C08L23/16C08L51/06C08L75/00C08L75/04C08L2205/03C08L2205/04C08L2205/22C09D123/10Y10T428/24777Y10T428/24802Y10T428/24983C08L2666/24C08L2666/20C08L2666/02
    • A weatherseal or belt-line seal for a vehicle is formed by extrusion of an olefin-based thermoplastic elastomer or vulcanizate (first TPV) as an elongate body of arbitrary length and cross-section. The cross-section is adapted for use in a particular location in the opening of a structure to be protected against wind and rain, for example around the glass of a window in a vehicle's door, or around the opening (at the periphery) in which the door is closed, so as to present at least one sealing surface against which the glass or door may be abutted to provide a seal against the elements. A slip-coating is co-extruded onto one or more longitudinal sealing surfaces of the body; the slip-coating contains a novel compatibilizer which allows thermoplastic polyurethane (TPU) to be chemically bonded to a graft copolymer of polypropylene (PP) and a compound having two anhydride groups. The reaction product of the grafted PP and the TPU effects a thermal bond with the sealing surface of the body. The slip-coating has a combination of softness and abrasion resistance which are uniquely suited for the purpose of the weatherseal.
    • 用于车辆的耐候密封带或带状线密封件是通过挤出作为任意长度和横截面的细长体的烯烃类热塑性弹性体或硫化橡胶(第一TPV)形成的。 横截面适用于要防止风雨的结构的开口中的特定位置,例如在车辆门的窗户玻璃周围或围绕开口(在周边)处,其中 门关闭,以便呈现至少一个密封表面,玻璃或门可抵靠该密封表面以抵靠元件提供密封。 滑动涂层共挤出到主体的一个或多个纵向密封表面上; 滑移涂层含有一种新颖的相容剂,其允许热塑性聚氨酯(TPU)与聚丙烯(PP)和具有两个酸酐基团的化合物的接枝共聚物化学键合。 接枝PP和TPU的反应产物与本体的密封面发生热粘合。 滑爽涂层具有柔软性和耐磨性的组合,其特别适用于耐候密封胶的目的。