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    • 23. 发明申请
    • METHOD FOR THE EMULSION POLYMERIZATION OF OLEFINS
    • 方法烯烃乳液聚合
    • WO02064638A2
    • 2002-08-22
    • PCT/EP0201467
    • 2002-02-13
    • BASF AGKRISTEN MARC OLIVERCHOWDHRY MUBARIK MAHMOOD
    • KRISTEN MARC OLIVERCHOWDHRY MUBARIK MAHMOOD
    • C08F2/22C08F4/26C08F4/80C08F10/00C08F110/02
    • C08F10/00C08F110/02C08F2/24C08F4/80
    • The invention relates to a method for the emulsion polymerization of one or more olefins by reacting a ligand according to the general formulae (Ia) to (Ic) or a mixture of at least two of the ligands (Ia) to (Ic), wherein M is a metal of the first group of the periodic table of elements or hydrogen, with a metal compound of the general formula (M(L )2 or M(L )2(L )z, wherein M is a transition metal of the 7 to 10 group of the periodic table of elements and preferably nickel, and immediately using the reaction product for the polymerization or copolymerization of olefins in water or in a solvent mixture that contains at least 50 % by volume of water, optionally in the presence of an activator and an emulsifier. The aqueous dispersions of polyolefins such as polyethylene and ethylene copolymerizates obtained according to the inventive method are suitable for applications in the paper industry such as paper coating or surface sizing, paint coatings, raw materials for adhesives, molded foams such as mattresses, textile or leather applications, carpet backings or pharmaceutical applications.
    • 由通式的配位体反应的乳液聚合过程I A至I C,或至少两个的配位体的混合物我一个至I C,其中M <1>是元素或氢的周期表第1族的金属,具有 (<2> L)2或通式M(L <2>)2(L <1>)Z,其中M是组7的的元素并且优选地,镍的周期表第10的过渡金属的M个金属化合物,和立即使用 用于烯烃在水中的聚合或共聚或至少含有50体积%的水,任选地在活化剂和乳化剂的存在下于溶剂混合物中的反应产物。 根据本发明的聚烯烃如聚乙烯和乙烯共聚物的水性分散体适合用于造纸的应用,如纸张涂层或表面施胶,涂清漆,粘合剂原材料,模塑泡沫,如床垫,纺织品和皮革应用,地毯背衬或药物应用的方法获得。