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21. 发明申请

US20070191517A1 Acrylic pressure sensitive adhesive composition 审中-公开
标题翻译：丙烯酸压敏胶组合物
公开(公告)号：US20070191517A1
公开(公告)日：2007-08-16
申请号：US11506217
申请日：2006-08-18
申请人： Sang-ki Chun , Dong-han Kho , Suk-ky Chang , Jae-Seung Oh , Byoung-bae Lee
发明人： Sang-ki Chun , Dong-han Kho , Suk-ky Chang , Jae-Seung Oh , Byoung-bae Lee
IPC分类号： C08K5/50 , B32B7/12
CPC分类号： C09J133/02 , C08K5/0008 , C08L33/02 , C08L2666/28
摘要： An acrylic adhesive composition comprising a room temperature eutectic salt prepared by mixing a metal salt represented by the formula (1) below and an alkali metal cation with a compound having an amide group represented by the formula (2) below: M+X31 (YOmRf)n (1) where M is an alkali metal cation and Rf is a perfluoroalkane group having 1-4 carbon atoms; where R1 is hydrogen, an alkyl group having 1-10 carbon atoms, an alkenyl group having 2-10 carbon atoms or an aryl or alaryl group having 6-10 carbon atoms; R2 is hydrogen, halogen, an alkyl group having 1-10 carbon atoms, an alkenyl group having 2-10 carbon atoms or an aryl or alaryl group having 6-10 carbon atoms; X is carbon or nitrogen; and n is 0-6.
摘要翻译：一种丙烯酸类粘合剂组合物，其包含通过将由下式（1）表示的金属盐与碱金属阳离子与下式（2）表示的具有酰胺基的化合物混合而制备的室温共晶盐： -formulae description =“In-line Formulas”end =“lead”？> M + + / / / / />>> 其中M是碱金属阳离子，R < f是具有1-4个碳原子的全氟烷烃基; 其中R 1是氢，具有1-10个碳原子的烷基，具有2-10个碳原子的烯基或具有6-10个碳原子的芳基或芳芳基; R 2是氢，卤素，具有1-10个碳原子的烷基，具有2-10个碳原子的烯基或具有6-10个碳原子的芳基或芳基; X是碳或氮; n为0-6。

22. 发明授权

US07247595B2 Supported metallocene catalyst and olefin polymerization using the same 有权
标题翻译：负载金属茂催化剂和烯烃聚合使用相同
公开(公告)号：US07247595B2
公开(公告)日：2007-07-24
申请号：US11289623
申请日：2005-11-30
申请人： Bun-Yeoul Lee , Jae-Seung Oh , Joo-Eun Lee , Do-Hoon Lee
发明人： Bun-Yeoul Lee , Jae-Seung Oh , Joo-Eun Lee , Do-Hoon Lee
IPC分类号： B01J31/00 , C07F17/00
CPC分类号： B01J31/2295 , B01J2231/12 , B01J2531/46 , B01J2531/48 , C07B2200/11 , C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/02 , C08F110/02 , C08F4/65925 , C08F2500/03 , C08F2500/18
摘要： A metallocene compound represented by the following Chemical Formula 1: wherein M is a transition metal of Group 4; Cp denotes a cyclopentadienyl ring unsubstituted or substituted by hydrogen, alkyl, cycloalkyl, aryl, alkenyl, alkylaryl, arylalkyl or arylalkenyl radicals; Qs, which are the same or different, are halogen radicals, alkyl, alkenyl, aryl, alkylaryl, or arylakyl radicals having 1 to 20 carbon atoms, or alkylidene radicals having 1 to 20 carbon atoms; A′ is methoxymethyl, t-butoxymethyl, tetrahydropyranyl, tetrahydrofuranyl, 1-ethoxyethyl, 1-methyl-1-methoxyethyl, or t-butyl; and a is an integer of 4 to 8. The metallocene compounds in this invention can be strongly supported on the inorganic support, and the supported catalyst of this invention allows for an olefin polymerization process without any fouling in the reactor, and produces a polymer with better morphology and bulk density.
摘要翻译：由以下化学式1表示的茂金属化合物：其中M是第4族的过渡金属; Cp表示未被取代或被氢，烷基，环烷基，芳基，烯基，烷基芳基，芳基烷基或芳基烯基取代的环戊二烯基环; 具有1〜20个碳原子的卤素基团，烷基，链烯基，芳基，烷基芳基或芳基烷基，或碳原子数1〜20的亚烷基的Q相同或不同。 A'是甲氧基甲基，叔丁氧基甲基，四氢吡喃基，四氢呋喃基，1-乙氧基乙基，1-甲基-1-甲氧基乙基或叔丁基; a为4〜8的整数。本发明中的茂金属化合物可以强力负载在无机载体上，本发明的负载型催化剂允许在反应器中没有任何结垢的烯烃聚合反应，并产生具有更好的形态和体积密度。

23. 发明申请

US20070099090A1 Secondary battery comprising eutectic mixture and preparation method thereof 有权
标题翻译：包含共晶混合物的二次电池及其制备方法
公开(公告)号：US20070099090A1
公开(公告)日：2007-05-03
申请号：US11586607
申请日：2006-10-26
申请人： Jae Seung Oh , Shin Jung Choi , Byoung Bae Lee , Jae Duk Park , Ji Won Park
发明人： Jae Seung Oh , Shin Jung Choi , Byoung Bae Lee , Jae Duk Park , Ji Won Park
IPC分类号： H01M10/40
CPC分类号： H01M10/0525 , H01M4/131 , H01M4/1391 , H01M4/525 , H01M10/0565 , H01M10/0566 , H01M10/4235 , Y02E60/122
摘要： Disclosed is a secondary battery comprising a cathode, an anode, a separator and an electrolyte, wherein the electrolyte comprises a eutectic mixture formed of: (a) an amide group-containing compound, and (b) an ionizable lithium salt, and the anode comprises a metal or metal oxide having a potential vs. lithium potential (Li/Li+) within electrochemical window of the eutectic mixture. An electrolyte for a secondary battery comprising the eutectic mixture is also disclosed. Since the secondary battery uses a eutectic mixture as an electrolyte in combination with an anode having a potential vs. lithium potential (Li/Li+) within the electrochemical window of the eutectic mixture, it solves the problems occurring in a conventional battery using a eutectic mixture as an electrolyte, such problems including decomposition of an electrolyte and degradation of the quality of a battery. Also, due to the thermal and chemical stability, high conductivity and a broad electrochemical window of a eutectic mixture, it is possible to improve the quality as well as safety of a battery.
摘要翻译：公开了包括阴极，阳极，隔膜和电解质的二次电池，其中电解质包括由以下物质形成的共晶混合物：（a）含酰胺基化合物和（b）可电离锂盐，阳极包括在共晶混合物的电化学窗口内具有电位与锂电位（Li / Li + +）的金属或金属氧化物。还公开了包含共晶混合物的二次电池用电解质。由于二次电池在共晶混合物的电化学窗口内使用共晶混合物作为电解质与具有电位与锂电位（Li / Li + SUP +）的阳极组合，因此解决了发生的问题在使用共晶混合物作为电解质的常规电池中，存在电解质分解和电池质量劣化等问题。此外，由于热和化学稳定性，高导电性和共晶混合物的宽电化学窗口，可以提高电池的质量和安全性。

24. 发明授权

US06506919B1 Metallocene compounds and their use for olefin polymerization 有权
标题翻译：茂金属化合物及其在烯烃聚合中的应用
公开(公告)号：US06506919B1
公开(公告)日：2003-01-14
申请号：US09914717
申请日：2001-08-31
申请人： Jae-Seung Oh , Bun-Yeoul Lee , Joo-Eun Lee , Do-Hoon Lee
发明人： Jae-Seung Oh , Bun-Yeoul Lee , Joo-Eun Lee , Do-Hoon Lee
IPC分类号： C07F1700
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65912 , C08F4/65916 , C08F4/65922 , C08F110/02 , Y10S526/943 , C08F4/65925 , C08F4/6592
摘要： The present invention relates to a metallocene compound and the olefin polymerization using the same, particularly to a metallocene compound and the olefin polymerization using this compound on which supported catalysts are easily prepared by the reaction of the ligand containing —(CR12)a—O—SiRbYc ligand (wherein each Y, which can be the same as or different from other Y, is a hydrogen, halogen, alkoxy, aryloxy, amide, or silyloxy radical, each R1, which can be the same as or different from other R1, is a hydrogen radical, or an alkyl, cycloalkyl, aryl, alkenyl, alkylaryl, arylalkyl, or arylalkenyl radical having from 1 to 40 carbon atoms, each R, which can be the same as or different from other R, is an alkyl, cycloalkyl, aryl, alkenyl, alkylaryl, arylalkyl, or arylalkenyl radical having from 1 to 40 carbon atoms, a is an integral number from 1 to 40, c is 1, 2, or 3, and the sum of b and c is 3) with a support. Furthermore, the present invention relates to a supported metallocene catalyst using this metallocene compound and the olefin polymerization using the same. The metallocene compounds in this invention have superior characteristics in the preparation of supported catalyst due to the high reactivity with the support and minimal side reactions during the anchoring process. In addition, the olefin polymerization process employing the supported catalyst in this invention proceeds without fouling in the reactor, and the morphology and bulk density of the polymer produced are better than that produced by the conventional method.
摘要翻译：本发明涉及茂金属化合物和使用该茂金属化合物的烯烃聚合，特别涉及茂金属化合物和使用该化合物的烯烃聚合，其上通过含有 - （CR12）aO-SiRbYc配体的配体的反应容易地制备负载型催化剂（其中每个可以与其它Y相同或不同的Y是氢，卤素，烷氧基，芳氧基，酰胺或甲硅烷氧基，每个可以与其它R 1相同或不同的R 1是氢原子或具有1至40个碳原子的烷基，环烷基，芳基，烯基，烷基芳基，芳基烷基或芳基烯基，每个R可以与其它R相同或不同，是烷基，环烷基，芳基，具有1至40个碳原子的烯基，烷基芳基，芳基烷基或芳基烯基，a为1至40的整数，c为1,2或3，b和c之和为3）。此外，本发明涉及使用该金属茂化合物的负载金属茂催化剂和使用其的烯烃聚合。本发明中的茂金属化合物由于与载体的高反应性和锚固过程中的极少副反应而在制备负载型催化剂方面具有优异的特性。此外，在本发明中使用负载型催化剂的烯烃聚合方法在反应器中不污染地进行，并且所生产的聚合物的形态和体积密度比通过常规方法产生的更好。

25. 发明授权

US06469113B1 Method for producing supported metallocene catalyst and olefin polymerization process using the same 有权
标题翻译：制备负载型茂金属催化剂的方法及使用其的烯烃聚合方法
公开(公告)号：US06469113B1
公开(公告)日：2002-10-22
申请号：US09445647
申请日：1999-12-09
申请人： Bun-Yeoul Lee , Jae-Seung Oh
发明人： Bun-Yeoul Lee , Jae-Seung Oh
IPC分类号： C08F4656
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F110/02 , Y10S526/943 , C08F4/65916 , C08F2500/03
摘要： The present invention relates to a method for producing supported metallocene catalyst and an olefin polymerization process using same, and more particularly to a method for manufacturing supported metallocene catalyst by reacting metallocene catalyst having an alkoxysilane group at a part of a ligand with a support having a highly reactive siloxane group at the surface, and the olefin polymerization process using the same.
摘要翻译：本发明涉及一种负载型茂金属催化剂的制造方法和使用该催化剂的烯烃聚合方法，更具体地说，涉及通过使配位体的一部分具有烷氧基硅烷基的茂金属催化剂与具有烷氧基硅烷的载体在表面具有高反应性的硅氧烷基团，而使用其的烯烃聚合方法也是如此。

26. 发明授权

US06355742B1 Method of recycling cocatalyst for olefin polymerization conducted with metallocene catalyst 有权
标题翻译：用茂金属催化剂进行烯烃聚合的助催化剂再循环方法
公开(公告)号：US06355742B1
公开(公告)日：2002-03-12
申请号：US09445667
申请日：1999-12-09
申请人： Jae-Seung Oh , Bun-Yeoul Lee
发明人： Jae-Seung Oh , Bun-Yeoul Lee
IPC分类号： C08F206
CPC分类号： C08F6/02 , Y10S526/943 , C08L23/00
摘要： A method of recycling a cocatalyst for olefin polymerization conducted with a metallocene catalyst is provided. In the method, olefinic monomers are polymerized using a supported catalyst and cocatalyst. The supported catalyst is prepared by covalent bonding a catalyst with a support and the cocatalyst is dissolved in a suspension. The cocatalyst is separated from the resulting suspension after polymerization, and the separated cocatalyst is reused for subsequent polymerization.
摘要翻译：提供了一种使用茂金属催化剂进行烯烃聚合的助催化剂再循环方法。在该方法中，烯烃单体使用负载型催化剂和助催化剂进行聚合。载体催化剂通过将催化剂与载体共价键合制备，并将助催化剂溶解在悬浮液中。在聚合后将助催化剂与所得悬浮液分离，并将分离的助催化剂再次用于随后的聚合。

27. 发明授权

US06340728B1 Method for olefin polymerization with recycling of co-catalyst 有权
标题翻译：烯烃聚合方法与辅助催化剂的再循环
公开(公告)号：US06340728B1
公开(公告)日：2002-01-22
申请号：US09494711
申请日：2000-01-31
申请人： Jae-Seung Oh , Bun-Yeoul Lee , Yoon-Hyeun Oum , Tai-Ho Park
发明人： Jae-Seung Oh , Bun-Yeoul Lee , Yoon-Hyeun Oum , Tai-Ho Park
IPC分类号： C08F214
CPC分类号： C08F10/00 , C08F4/65925 , C08F6/02 , C08F110/06 , Y02P20/584 , C08L23/00 , C08F4/65912 , C08F4/65916 , C08F2500/18
摘要： Disclosed are catalyst preparation olefin polymerization processes with the recycling of a co-catalyst. According to the olefin polymerization process activated single-site catalysts are prepared by contacting supported single-site pre-catalyst with an organic solvent containing co-catalyst. The activated single-site catalysts are separated from co-catalysts dissolved in an organic solvent and the olefin polymerization is conducted using the separated single-site catalysts with one or more olefinic monomers. The separated co-catalysts is reused by recycling the organic solvent containing the separated co-catalysts and contacting them with the supported single-site pre-catalysts. The olefin polymerization process of the present invention enables recycling expensive co-catalyst for subsequent olefin polymerization and accordingly the total amount of co-catalyst required can be significantly reduced.
摘要翻译：公开了催化剂制备烯烃聚合方法与助催化剂的再循环。根据烯烃聚合方法，活化的单中心催化剂是通过将负载的单部位预催化剂与含有助催化剂的有机溶剂接触来制备的。将活化的单中心催化剂与溶于有机溶剂中的助催化剂分离，并使用分离的单中心催化剂与一种或多种烯属单体进行烯烃聚合。分离的助催化剂通过再循环含有分离的助催化剂的有机溶剂并将其与负载的单位点预催化剂接触来再利用。本发明的烯烃聚合方法使得可以再循环昂贵的助催化剂用于随后的烯烃聚合，因此可显着降低所需的助催化剂的总量。

28. 发明授权

US06255417B1 Process for the preparation of olefinic polymers using metallocene catalyst 失效
标题翻译：使用茂金属催化剂制备烯烃聚合物的方法
公开(公告)号：US06255417B1
公开(公告)日：2001-07-03
申请号：US09077278
申请日：1998-05-27
申请人： Jae-Seung Oh , Tai-Ho Park , Bun-Yeoul Lee , Sang-Won Jeong
发明人： Jae-Seung Oh , Tai-Ho Park , Bun-Yeoul Lee , Sang-Won Jeong
IPC分类号： C08F206
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65922 , C08F110/02 , Y10S526/943 , C08F2/06
摘要： An improved process of preparing a olefinic polymer of the type in which an olefinic monomer is polymerized alone or with a comonomer in a hydrocarbon solvent using a metallocene catalyst of formula (I) in the presence of a cocatalyst; wherein the improvement comprises: preparing the olefinic polymer in an aliphatic hydrocarbon solvent using a modified metallocene catalyst which is obtained by introducing at least one C5-20 alkyl substituent into the &pgr;-ligand, the alkylene bridge or silicon bridge of the metallocene catalyst of formula (I): L1L2MX2 (I) wherein, M is Ti, Zr or Hf; X is a halogen, or a C1-3 alkyl group; and L1 and L2 are each a &pgr;-ligand selected from the group consisting of cyclopentadienyl, indenyl, fluorenyl and derivatives thereof, and are optionally linked together by a C1-4 alkylene bridge optionally substituted with a C1-3 hydrocarbyl group or by a silicon bridge optionally substituted with a C1-3 hydrocarbyl group.
摘要翻译：在助催化剂存在下，使用式（I）的茂金属催化剂制备其中烯烃单体单独或与烃溶剂中的共聚单体聚合的烯烃聚合物的改进方法; 其中所述改进包括：使用改性金属茂催化剂在脂族烃溶剂中制备烯属聚合物，所述改性金属茂催化剂是通过将至少一个C 5-20烷基取代基引入式配体中的金属茂催化剂的亚胺桥或硅桥，（I）：其中，M为Ti，Zr或Hf; X为卤素或C 1-3烷基; 和L 1和L 2各自为选自环戊二烯基，茚基，芴基及其衍生物的π-配位体，并且任选地被任选被C 1-3烃基取代的C 1-4亚烷基桥基或通过硅桥任选地被C 1-3烃基取代。

29. 发明授权

US09954253B2 Electrolyte having eutectic mixture and nitrile compound, and electrochemical device containing the same 有权
公开(公告)号：US09954253B2
公开(公告)日：2018-04-24
申请号：US12854505
申请日：2010-08-11
申请人： Ji-Won Park , Byoung-Bae Lee , Jae-Seung Oh , Dong-Su Kim , Hyo-Jin Lee , Yeon-Suk Hong
发明人： Ji-Won Park , Byoung-Bae Lee , Jae-Seung Oh , Dong-Su Kim , Hyo-Jin Lee , Yeon-Suk Hong
IPC分类号： H01M6/18 , H01M6/04 , H01M6/16 , H01G9/004 , H01M10/0569 , H01M10/052 , H01M10/0567 , H01G11/56
CPC分类号： H01M10/0569 , H01G11/56 , H01M10/052 , H01M10/0567 , H01M2300/0025 , Y02E60/13
摘要： Disclosed is an electrolyte comprising (a) a eutectic mixture of an amide compound represented by the following chemical formula 1 or 2 and an ionizable lithium salt; and (b) a nitrile compound. The eutectic mixture and the nitrile compound in the electrolyte contribute to excellent thermal and chemical stability and sufficiently low viscosity and high ion conductivity. The electrolyte can be usefully applied as an electrolyte of electrochemical devices.

30. 发明授权

US09017879B2 Electrolyte having eutectic mixture and electrochemical device containing the same 有权
标题翻译：具有共晶混合物的电解质和含有该共晶混合物的电化学装置
公开(公告)号：US09017879B2
公开(公告)日：2015-04-28
申请号：US12813000
申请日：2009-01-09
申请人： Ji-Won Park , Byoung-Bae Lee , Jae-Seung Oh , Shin-Jung Choi , Jae-Duk Park , Dong-Su Kim , Hyo-Jin Lee
发明人： Ji-Won Park , Byoung-Bae Lee , Jae-Seung Oh , Shin-Jung Choi , Jae-Duk Park , Dong-Su Kim , Hyo-Jin Lee
IPC分类号： H01M10/0564 , H01M10/0525
CPC分类号： H01M10/0564 , H01M10/0525 , H01M2300/0085 , H01M2300/0091 , Y02E60/122
摘要： An electrolyte includes a eutectic mixture comprising (a) an alkoxy alkyl group-containing amide compound having a specific chemistry formula 1 or 2: wherein each of X, R, R1, R2, m and n is defined; and (b) an ionizable lithium salt. The eutectic mixture-containing electrolyte exhibits excellent high temperature stability as well as inherent characteristics of eutectic mixtures, including excellent thermal and chemical stability, thus contributing to improved high temperature stability and decreased lowest limit of electrochemical window. The electrolyte is useful in electrochemical devices comprising various anode materials.
摘要翻译：电解质包括共晶混合物，其包含（a）具有特定化学式1或2的含烷氧基烷基的酰胺化合物：其中X，R，R 1，R 2，m和n各自定义; 和（b）可电离的锂盐。含共晶混合物的电解质表现出优异的高温稳定性以及共晶混合物的固有特性，包括优异的热和化学稳定性，从而有助于提高高温稳定性和降低电化学窗口的最低限度。电解质可用于包含各种阳极材料的电化学装置中。

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