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    • 24. 发明授权
    • Grafted copolymers highly absorbent to aqueous electrolyte solutions
    • 接枝共聚物对水性电解质溶液具有高吸收性
    • US5412052A
    • 1995-05-02
    • US241319
    • 1994-05-11
    • Iqbal AhmedHenry L. Hsieh
    • Iqbal AhmedHenry L. Hsieh
    • A61L15/24A61L15/62C08F8/44C08F285/00C08F255/00C08F265/00C08F267/00C08F273/00
    • C08F285/00A61L15/24A61L15/62C08F8/44
    • The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions. The graft copolymer is formed by the graft polymerizing an effective amount of each of the following components together to provide a highly absorbent copolymer:(a) graft polymerizing onto a first polymer selected from the group consisting of polypropylene, polyethylene and other polyolefins, and at least one comonomer selected from the group consisting of acrylamide, methacrylamide, acrylonitrile, acrylic acid, methacrylic acid, alkali salts of acrylic acid, alkali salts of methacrylic acid, 3-methacrylamidopropyltrimethylamine, 2-acrylamido-2-methylpropane sulfonic acid, alkali salts of 2-acrylamido-2-methylpropane sulfonic acid, 2-methacryloyloxyethane sulfonic acid, alkali salts of 2-methacryloyloxyethane sulfonic acid, and any combination of two or more thereof; and(b) graft polymerizing therewith an ampholytic ion pair monomer comprising(i) an ammonium cation 3-methacrylamidopropyltrimethylammonium and(ii) a sulfonate anion selected from the group consisting of 2-acrylamido-2-methylpropane sulfonate, 2-methacryloyloxyethane sulfonate, vinyl sulfonate, styrene sulfonate and any combination of thereof.
    • 本发明提供对水性电解质溶液具有高吸收性的接枝共聚物。 接枝共聚物通过将有效量的以下各组分接枝聚合在一起形成,以提供高吸收性共聚物:(a)接枝聚合到选自聚丙烯,聚乙烯和其它聚烯烃的第一种聚合物上, 至少一种选自丙烯酰胺,甲基丙烯酰胺,丙烯腈,丙烯酸,甲基丙烯酸,丙烯酸的碱金属盐,甲基丙烯酸的碱金属盐,3-甲基丙烯酰胺基丙基三甲基胺,2-丙烯酰胺基-2-甲基丙烷磺酸, 2-丙烯酰胺基-2-甲基丙磺酸,2-甲基丙烯酰氧基乙磺酸,2-甲基丙烯酰氧基乙磺酸的碱金属盐,以及它们的两种或多种的任意组合; 其包括(i)铵阳离子3-甲基丙烯酰胺基丙基三甲基铵和(ii)选自2-丙烯酰胺基-2-甲基丙磺酸盐,2-甲基丙烯酰氧基乙烷磺酸盐,乙烯基醚的磺酸盐阴离子的两性离子对单体的接枝聚合 磺酸盐,苯乙烯磺酸盐及其任何组合。
    • 25. 发明授权
    • Grafted copolymers highly absorbent to aqueous electrolyte solutions
    • 接枝共聚物对水性电解质溶液具有高吸收性
    • US5357000A
    • 1994-10-18
    • US53038
    • 1993-04-26
    • Iqbal AhmedHenry L. Hsieh
    • Iqbal AhmedHenry L. Hsieh
    • A61L15/60C08F220/34C08F220/60C08F246/00C08F251/00C08F255/02C08F251/02
    • C08F255/02A61L15/60C08F220/34C08F220/60C08F246/00C08F251/00
    • The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions. The graft copolymer is formed by the graft polymerizing an effective amount of each of the following components together to provide a highly absorbent copolymer:(a) graft polymerizing onto a first polymer selected from the group consisting of polysaccharide, polypropylene, polyethylene and other polyolefins, and at least one comonomer selected from the group consisting of acrylamide, methacrylamide, acrylontrile, acrylic acid, methacrylic acid, alkali salts of acrylic acid, alkali salts of methacrylic acid, 2-methacryloyloxyethyldiethylamine, 2-acrylamido-2-methylpropane sulfonic acid, alkali salts of 2-acrylamido-2-methylpropane sulfonic acid, 2-methacryloxyloxyethane sulfonic acid, alkali salts of 2-methacryloyloxyethane sulfonic acid, and any combination of two or more thereof; and(b) graft polymerizing therewith no ampholytic ion pair monomer comprising(i) an ammonium cation 2-methacryloxyloxyethyldiethylammonium and(ii) a sulfonate anion selected from the group consisting of 2-acrylamido-2-methylpropane sulfonate, 2-methacryloyloxyethane sulfonate, vinyl sulfonate, styrene sulfonate and any combination of thereof.
    • 本发明提供对水性电解质溶液具有高吸收性的接枝共聚物。 接枝共聚物通过将有效量的以下各组分接枝聚合在一起形成,以提供高吸收性共聚物:(a)接枝聚合到选自多糖,聚丙烯,聚乙烯和其它聚烯烃的第一聚合物上, 和至少一种选自丙烯酰胺,甲基丙烯酰胺,丙烯腈,丙烯酸,甲基丙烯酸,丙烯酸的碱金属盐,甲基丙烯酸的碱金属盐,2-甲基丙烯酰氧基乙基二乙胺,2-丙烯酰胺基-2-甲基丙烷磺酸,碱金属的共聚单体 2-丙烯酰胺基-2-甲基丙磺酸的盐,2-甲基丙烯酰氧基乙烷磺酸,2-甲基丙烯酰氧基乙磺酸的碱金属盐,以及它们的两种或多种的任意组合; 包括(i)铵阳离子2-甲基丙烯酰氧基乙基二乙基铵和(ii)选自2-丙烯酰胺基-2-甲基丙磺酸盐,2-甲基丙烯酰氧基乙烷磺酸盐,乙烯基乙烯基醚的磺酸盐阴离子的(ii) 磺酸盐,苯乙烯磺酸盐及其任何组合。
    • 26. 发明授权
    • Grafted copolymers highly absorbent to aqueous electrolyte solutions
used in diapers and paper towels
    • 接枝共聚物对尿布和纸巾中使用的水性电解质溶液具有高吸收性
    • US5331021A
    • 1994-07-19
    • US126279
    • 1993-09-24
    • Iqbal AhmedHenry L. Hsieh
    • Iqbal AhmedHenry L. Hsieh
    • A61L15/60C08F220/34C08F220/60C08F246/00C08F251/00C08F255/02A61F13/15A61F13/20D21F11/00D21H11/00
    • C08F255/02A61L15/60C08F220/34C08F220/60C08F246/00C08F251/00
    • The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions. The graft copolymer is formed by the graft polymerizing an effective amount of each of the following components together to provide a highly absorbent copolymer:(a) graft polymerizing onto a first polymer selected from the group consisting of polysaccharide, polypropylene, polyethylene and other polyolefins, and at least one comonomer selected from the group consisting of acrylamide, methacrylamide, acrylonitrile, acrylic acid, methacrylic acid, alkali salts of acrylic acid, alkali salts of methacrylic acid, 2-methacryloyloxyethyldimethylamine, 2-acrylamido-2-methylpropane sulfonic acid, alkali salts of 2-acrylamido-2-methylpropane sulfonic acid, 2-methacryloyloxyethane sulfonic acid, alkali salts of 2-methacryloyloxyethane sulfonic acid, and any combination of two or more thereof; and(b) graft polymerizing therewith an ampholytic ion pair monomer comprising(i) an ammonium cation 2-methacryloyloxyethyldimethylammonium and(ii) a sulfonate anion selected from the group consisting of 2-acrylamido-2-methylpropane sulfonate, 2-methacryloyloxyethane sulfonate, vinyl sulfonate, styrene sulfonate and any combination of thereof.
    • 本发明提供对水性电解质溶液具有高吸收性的接枝共聚物。 接枝共聚物通过将有效量的以下各组分接枝聚合在一起形成,以提供高吸收性共聚物:(a)接枝聚合到选自多糖,聚丙烯,聚乙烯和其它聚烯烃的第一聚合物上, 和至少一种选自丙烯酰胺,甲基丙烯酰胺,丙烯腈,丙烯酸,甲基丙烯酸,丙烯酸的碱金属盐,甲基丙烯酸的碱金属盐,2-甲基丙烯酰氧基乙基二甲基胺,2-丙烯酰胺基-2-甲基丙烷磺酸,碱金属的共聚单体 2-丙烯酰氨基-2-甲基丙烷磺酸的盐,2-甲基丙烯酰氧基乙烷磺酸,2-甲基丙烯酰氧基乙烷磺酸的碱金属盐,以及其两种或多种的任意组合; 其包括(i)铵阳离子2-甲基丙烯酰氧基乙基二甲基铵和(ii)选自2-丙烯酰胺基-2-甲基丙磺酸盐,2-甲基丙烯酰氧基乙烷磺酸盐,乙烯基乙烯基醚的磺酸盐阴离子的两性离子对单体的接枝聚合 磺酸盐,苯乙烯磺酸盐及其任何组合。
    • 27. 发明授权
    • Grafted copolymers highly absorbent to aqueous electrolyte solutions
    • 接枝共聚物对水性电解质溶液具有高吸收性
    • US5290871A
    • 1994-03-01
    • US65829
    • 1993-05-21
    • Iqbal AhmedHenry L. Hsieh
    • Iqbal AhmedHenry L. Hsieh
    • A61L15/60C08F220/34C08F220/60C08F246/00C08F251/00C08F255/02C08F255/00C08F265/00C08F267/00C08F273/00
    • C08F255/02A61L15/60C08F220/34C08F220/60C08F246/00C08F251/00
    • The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions. The graft copolymer is formed by the graft polymerizing an effective amount of each of the following components together to provide a highly absorbent copolymer:(a) graft polymerizing onto a first polymer selected from the group consisting of polysaccharide, polypropylene, polyethylene and other polyolefins, and at least one comonomer selected from the group consisting of acrylamide, methacrylamide, acrylonitrile, acrylic acid, methacrylic acid, alkali salts of acrylic acid, alkali salts of methacrylic acid, 2-methacryloyloxyethyldimethylamine, 2-acrylamido-2-methylpropane sulfonic acid, alkali salts of 2-acrylamido-2-methylpropane sulfonic acid, 2-methacryloyloxyethane sulfonic acid, alkali salts of 2-methacryloyloxyethane sulfonic acid, and any combination of two or more thereof; and(b) graft polymerizing therewith an ampholytic ion pair monomer comprising(i) an ammonium cation2-methacryloyloxyethyldimethylammonium and(ii) a sulfonate anion selected from the group consisting of 2-acrylamido-2-methylpropane sulfonate, 2-methacryloyloxyethane sulfonate, vinyl sulfonate, styrene sulfonate and any combination of thereof.
    • 本发明提供对水性电解质溶液具有高吸收性的接枝共聚物。 接枝共聚物通过将有效量的以下各组分接枝聚合在一起形成,以提供高吸收性共聚物:(a)接枝聚合到选自多糖,聚丙烯,聚乙烯和其它聚烯烃的第一聚合物上, 和至少一种选自丙烯酰胺,甲基丙烯酰胺,丙烯腈,丙烯酸,甲基丙烯酸,丙烯酸的碱金属盐,甲基丙烯酸的碱金属盐,2-甲基丙烯酰氧基乙基二甲基胺,2-丙烯酰胺基-2-甲基丙烷磺酸,碱金属的共聚单体 2-丙烯酰氨基-2-甲基丙烷磺酸的盐,2-甲基丙烯酰氧基乙烷磺酸,2-甲基丙烯酰氧基乙烷磺酸的碱金属盐,以及其两种或多种的任意组合; 其包括(i)铵阳离子2-甲基丙烯酰氧基乙基二甲基铵和(ii)选自2-丙烯酰胺基-2-甲基丙磺酸盐,2-甲基丙烯酰氧基乙烷磺酸盐,乙烯基乙烯基醚的磺酸盐阴离子的两性离子对单体的接枝聚合 磺酸盐,苯乙烯磺酸盐及其任何组合。
    • 28. 发明授权
    • Grafted copolymers highly absorbent to aqueous electrolyte solutions
    • 接枝共聚物对水性电解质溶液具有高吸收性
    • US5290870A
    • 1994-03-01
    • US65721
    • 1993-05-21
    • Iqbal AhmedHenry L. Hsieh
    • Iqbal AhmedHenry L. Hsieh
    • A61L15/60C08F220/34C08F220/60C08F246/00C08F251/00C08F255/02C08F255/00C08F265/00C08F267/00C08F273/00
    • C08F255/02A61L15/60C08F220/34C08F220/60C08F246/00C08F251/00
    • The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions. The graft copolymer is formed by the graft polymerizing an effective amount of each of the following components together to provide a highly absorbent copolymer:(a) graft polymerizing onto a first polymer selected from the group consisting of polysaccharide, polypropylene, polyethylene and other polyolefins, and at least one comonomer selected from the group consisting of acrylamide, methacrylamide, acrylonitrile, acrylic acid, methacrylic acid, alkali salts of acrylic acid, alkali salts of methacrylic acid, 3-methacrylamidopropyldimethylamine, 2-acrylamido-2-methylpropane sulfonic acid, alkali salts of 2-acrylamido-2-methylpropane sulfonic acid, 2-methacryloyloxyethane sulfonic acid, alkali salts of 2-methacryloyloxyethane sulfonic acid, and any combination of two or more thereof; and(b) graft polymerizing therewith an ampholytic ion pair monomer comprising(i) an ammonium cation 3-methacrylamidopropyldimethylammonium and(ii) a sulfonate anion selected from the group consisting of 2-acrylamido-2-methylpropane sulfonate, 2-methacryloyloxyethane sulfonate, vinyl sulfonate, styrene sulfonate and any combination of thereof.
    • 本发明提供对水性电解质溶液具有高吸收性的接枝共聚物。 接枝共聚物通过将有效量的以下各组分接枝聚合在一起形成,以提供高吸收性共聚物:(a)接枝聚合到选自多糖,聚丙烯,聚乙烯和其它聚烯烃的第一聚合物上, 和至少一种选自丙烯酰胺,甲基丙烯酰胺,丙烯腈,丙烯酸,甲基丙烯酸,丙烯酸的碱金属盐,甲基丙烯酸的碱金属盐,3-甲基丙烯酰胺基丙基二甲基胺,2-丙烯酰胺基-2-甲基丙磺酸,碱金属的共聚单体 2-丙烯酰氨基-2-甲基丙烷磺酸的盐,2-甲基丙烯酰氧基乙烷磺酸,2-甲基丙烯酰氧基乙烷磺酸的碱金属盐,以及其两种或多种的任意组合; 其包含(i)铵阳离子3-甲基丙烯酰胺丙基二甲基铵和(ii)选自2-丙烯酰胺基-2-甲基丙磺酸盐,2-甲基丙烯酰氧基乙烷磺酸盐,乙烯基乙烯基醚的磺酸盐阴离子的两性离子对单体的接枝聚合 磺酸盐,苯乙烯磺酸盐及其任何组合。