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21. 发明申请

US20060207477A1 Method for pigmenting semi-crystalline plastics with phthalocyanine pigments in a non-warping manner 失效
标题翻译：以非翘曲的方式用酞菁颜料着色半晶体塑料的方法
公开(公告)号：US20060207477A1
公开(公告)日：2006-09-21
申请号：US10569112
申请日：2004-08-07
申请人： Matthias Ganschow , Carsten Plueg , Hans Joachim Metz
发明人： Matthias Ganschow , Carsten Plueg , Hans Joachim Metz
IPC分类号： C08K5/00
CPC分类号： C09B67/0019
摘要： The invention relates to a method for pigmenting semi-crystalline plastics with phthalocyanine pigments in a non-warping manner. Said method is characterised by the use of a phthalocyanine pigment that has been heated as a suspension in an organic solvent in the presence of a dicarboxylic acid or a dixarboxylic acid salt to a temperature of at least 80° C. The invention also relates to a phthalocyanine pigment produced in this way.
摘要翻译：本发明涉及一种以非翘曲的方式将酞菁颜料着色的半结晶塑料的方法。所述方法的特征在于使用在二羧酸或二甲酸盐存在下作为悬浮液在有机溶剂中加热至至少80℃的酞菁颜料。本发明还涉及一种以这种方式生产的酞菁颜料。

22. 发明授权

US5041571A Process of producing anthraquinones in one step 失效
标题翻译：一步生产蒽醌的方法
公开(公告)号：US5041571A
公开(公告)日：1991-08-20
申请号：US503490
申请日：1990-03-29
申请人： Mohammad Aslam , Hans-Joachim Metz
发明人： Mohammad Aslam , Hans-Joachim Metz
IPC分类号： B01J27/12 , C07B61/00 , C07C46/00 , C07C50/16 , C07C50/18
CPC分类号： C07C50/18 , C07C46/00 , C07C50/16 , C07C2103/24
摘要： A process for the preparation of anthraquinone compounds comprises reaction of phthalic anhydride with a benzene derivative in a reaction mixture containing HF and BF.sub.3 as catalyst at a first temperature up to about 30.degree. C. and, subsequently, at an elevated temperature.

23. 发明授权

US08703865B2 Method for production of polymer-encapsulated pigments 有权
标题翻译：聚合物包封颜料的生产方法
公开(公告)号：US08703865B2
公开(公告)日：2014-04-22
申请号：US11587879
申请日：2005-04-21
申请人： Matthias Ganschow , Hans Joachim Metz , Ulrike Rohr , Karl-Heinz Schweikart , Katharina Landfester
发明人： Matthias Ganschow , Hans Joachim Metz , Ulrike Rohr , Karl-Heinz Schweikart , Katharina Landfester
IPC分类号： C08F2/32 , C04B14/00
CPC分类号： C09D17/003 , C09B67/0013
摘要： The invention relates to a method for production of an aqueous dispersion of polymer-encapsulated pigments characterized in that (a) an aqueous pigment dispersion, containing at least one organic pigment (P) at least one surfactant (T), and water is prepared,(b) a monomer miniemulsion stabilized by a hydrophobic organic compound with a water solubility at 20° C. of not more than 5×10−5 g/l, is prepared from a polymerizable monomer (M) and at least one surfactant (T), in water, (c) a monomer pigment emulsion is prepared, whereby the aqueous pigment dispersion from (a) and the monomer miniemulsion from (b) are mixed and homogenized, and (d) the pigment-containing monomer miniemulsion from (c) is polymerized in the presence of a polymerization initiator and/or by heat, whereupon an encapsulation of the pigment with the polymer thus formed occurs.
摘要翻译：本发明涉及一种生产聚合物包封颜料的水分散体的方法，其特征在于（a）制备含有至少一种有机颜料（P）至少一种表面活性剂（T）的水性颜料分散体和水，（b）由可聚合单体（M）和至少一种表面活性剂（T）制备由20℃下的水溶性为5×10-5g / l以下的疏水性有机化合物稳定的单体细乳液），在水中，（c）制备单体颜料乳液，由此将来自（a）的水性颜料分散体和（b）的单体细乳液混合并均化，和（d）含颜料的单体细乳液从（c ）在聚合引发剂和/或通过热的存在下聚合，由此发生颜料与如此形成的聚合物的包封。

24. 发明授权

US07655300B2 Transparent zeolite-polymer hybrid material with tunable properties 有权
标题翻译：具有可调谐性质的透明沸石 - 聚合物杂化材料
公开(公告)号：US07655300B2
公开(公告)日：2010-02-02
申请号：US11823975
申请日：2007-06-29
申请人： Hans Joachim Metz , Gion Calzaferri , André Devaux , Stephane Suarez , Andreas Kunzmann
发明人： Hans Joachim Metz , Gion Calzaferri , André Devaux , Stephane Suarez , Andreas Kunzmann
IPC分类号： B32B5/16
CPC分类号： C09C1/405 , B82Y30/00 , C01P2004/64 , C08K9/06 , C08K9/10 , C09C3/12 , Y10T428/1064 , Y10T428/254 , Y10T428/31663
摘要： The invention is about the preparation of novel highly transparent zeolite-doped polymer and zeolites monolayers.External coating of the zeolite crystals by covalently linked functionalized alkoxysilane derivatives allows for an efficient dispersion of the nano zeolite particles into an organic liquid monomer; the following co-polymerisation process leads to a hard, insoluble and transparent material containing said zeolites. Optical properties such as colour, refractive index, Abbe number or photochromism can be fine tuned by simply changing zeolite loading, while transparency is maintained.
摘要翻译：本发明涉及新型高度透明的沸石掺杂聚合物和沸石单层的制备。通过共价连接的官能化烷氧基硅烷衍生物对沸石晶体的外部涂层允许纳米沸石颗粒有效分散到有机液体单体中; 以下共聚过程导致含有所述沸石的硬的，不溶的和透明的材料。光学性质如颜色，折射率，阿贝数或光致变色可以通过简单地改变沸石负载来微调，同时保持透明度。

25. 发明授权

US07285663B2 β-Isoindigo coloring agent 失效
标题翻译： β-Isoindigo着色剂
公开(公告)号：US07285663B2
公开(公告)日：2007-10-23
申请号：US10542529
申请日：2003-12-13
申请人： Heino Heckmann , Hans Joachim Metz
发明人： Heino Heckmann , Hans Joachim Metz
IPC分类号： C07D403/10 , C09D11/02 , C09B7/02
CPC分类号： C07D401/14 , C07D209/44 , C07D403/14 , C07D405/14 , C09B57/04
摘要： The invention relates to a compound of general formula (I) in which C represents an alicyclic or heterocyclic group having C2v symmetry, and B represents ortho-C6-C18-arylene. The invention also relates to a method for producing this compound and to the use thereof as a coloring agent for coloring or pigmenting organic or inorganic high-molecular or low-molecular, particularly high-molecular, organic materials.
摘要翻译：本发明涉及通式（I）的化合物，其中C表示具有C 2对称性的脂环族或杂环基，B表示邻-C 6 -C 亚磺酰基。本发明还涉及一种生产该化合物的方法及其用作着色剂或着色剂的有机或无机高分子或低分子特别是高分子有机材料的着色剂

26. 发明授权

US07029818B2 Use of coated pigment granules in electrophotographic toners and developers, powder coatings and inkjet inks 失效
公开(公告)号：US07029818B2
公开(公告)日：2006-04-18
申请号：US10004601
申请日：2001-11-01
申请人： Ulrike Rohr , Ruediger Baur , Hans-Joachim Metz , Andreas Stohr
发明人： Ulrike Rohr , Ruediger Baur , Hans-Joachim Metz , Andreas Stohr
IPC分类号： G03G9/08
CPC分类号： C09D11/322 , C09D5/035 , G03G9/08782 , G03G9/09 , G03G9/0906 , G03G9/091 , G03G9/0912 , G03G9/0914 , G03G9/0916 , G03G9/0918 , G03G9/092 , G03G9/0926 , G03G9/122
摘要： The present invention relates to the use of wax-coated pigment granules as colorants in electrophotographic toners and developers, powder coating materials, inkjet inks, electret fibers, and color filters, wherein the coated pigment granules have a particle size of between 0.05 and 5 mm and a wax content of from 1 to 50% by weight, based on the overall weight of the coated pigment granules.

27. 发明授权

US07014699B2 Oxalkylation products produced from epoxides and amines and their use in pigment preparations 失效
标题翻译：由环氧化物和胺生产的烷基化产物及其在颜料制剂中的应用
公开(公告)号：US07014699B2
公开(公告)日：2006-03-21
申请号：US10469363
申请日：2002-02-26
申请人： Martin Alexander Winter , Hans Joachim Metz , Andreas Harz , Andreas Pfrengle
发明人： Martin Alexander Winter , Hans Joachim Metz , Andreas Harz , Andreas Pfrengle
IPC分类号： C04B14/00 , B01F17/00 , C08G73/00 , C08G65/26 , C08L63/02
CPC分类号： C09D11/326 , C08G59/50 , C08G65/2603 , C08G65/2618 , C08G65/3324 , C08G65/3344 , C08G2650/34 , C09B67/0085 , C09D11/03 , C09D17/001 , Y10S516/905 , Y10S516/92
摘要： The invention relates to addition compounds of formula (1): in which: n is a number from 1 to 10; R1 and R2 are identical or different and are each a hydrogen atom or a saturated or unsaturated aliphatic radical having 1 to 4 carbon atoms; R3 and R4 are identical or different and are each a hydrogen atom or alkyl having 1 to 3 carbon atoms, and the bridge member (R3+R4) is in each case positioned ortho or meta in relation to the phenolic oxygen atom; Z represents a group —CH2—CH2—, —CH2—CH(CH3)—, —CH(CH3)—CH2— or a combination thereof; s is number from 1 to 200; B represents hydrogen, —CO—CH═CH—COOM, —COCH(SO3M)CH2COOM, —CO—CH2—CH(SO3M)—COOM, —SO3M, —SO2M and/or —PO3MM, whereby M is preferably a cation selected from the group Li+, Na+, K+, NH4+, HO—CH2—CH2—NH3+, (HO—CH2—CH2—)2NH2+ or (HO—CH2—CH2—)3NH+; and Y is a radical of an amine. The inventive addition compounds are used as dispersing agents of solids, for example, pigments, particularly in aqueous media.
摘要翻译：本发明涉及式（1）的加成化合物：其中：n为1至10的数; R 1和R 2相同或不同，各自为氢原子或具有1至4个碳原子的饱和或不饱和脂族基团; R 3和R 4相同或不同，并且各自为氢原子或具有1至3个碳原子的烷基，并且桥构件（R 3）在各种情况下，相对于酚氧原子定位为邻位或间隔; Z表示基团-CH 2 CH 2 -CH 2 - ， - CH 2 -CH（CH 3 3） - ，-CH（CH 3 CH 3）-CH 2 - 或其组合; s从1到200; B表示氢，-CO-CH-CH-COOM，-COCH（SO 3 M）CH 2 COOM，-CO-CH 2 -CH（SO 3 M）-COOM，-SO 3 M，-SO 2 M和/或-PO 3 < M，其中M优选为选自Li +，Na +，H +，NH 4的阳离子 HO-CH 2 -CH 2 -NH 2 N 3 - ， - - - - - （HO-CH 2 -CH 2 - ）2 NH 2 N + 或（HO-CH 2 -CH 2 - ）3 NH 2 + Y是胺的基团。本发明的加成化合物用作固体的分散剂，例如颜料，特别是在水性介质中。

28. 发明授权

US06504045B2 Crystal polymorphs of a yellow disazo colorant, and their preparation 失效
标题翻译：黄色双偶氮染料的晶体多晶型物及其制备方法
公开(公告)号：US06504045B2
公开(公告)日：2003-01-07
申请号：US09952499
申请日：2001-09-13
申请人： Ruediger Jung , Hans-Joachim Metz , Joachim Weber , Martin U. Schmidt , Olaf Schupp , Andreas Wacker
发明人： Ruediger Jung , Hans-Joachim Metz , Joachim Weber , Martin U. Schmidt , Olaf Schupp , Andreas Wacker
IPC分类号： C07C22900
CPC分类号： C09B67/0028 , C09B67/0015
摘要： The invention relates to six new crystal polymorphs, &agr; (alpha), &bgr; (beta), &ggr; (gamma), &dgr; (delta), &zgr; (zeta), and &eegr; (eta), of the disazo colorant of the formula I, having characteristic reflections in the X-ray diffraction spectrum. The novel crystal polymorphs are prepared by treatment in organic solvents.
摘要翻译：本发明涉及式I的双偶氮着色剂的六种新的晶体多晶型物，即α（α），β（β），γ（γ），δ（delta），zeta（zeta）和eta（eta） X射线衍射光谱中的特征反射。通过在有机溶剂中处理制备新型晶体多晶型物。

29. 发明授权

US06485558B1 Process for the preparation of pigment granules 失效
标题翻译：颜料颗粒的制备方法
公开(公告)号：US06485558B1
公开(公告)日：2002-11-26
申请号：US09649532
申请日：2000-08-28
申请人： Hans Joachim Metz , Heinfred Ohleier
发明人： Hans Joachim Metz , Heinfred Ohleier
IPC分类号： C09D1700
CPC分类号： C09B67/0013 , C09B67/0003 , C09B67/0095
摘要： The invention relates to a process for the preparation of pigment granules, which comprises adding a wax or a waxy polymer to an organic pigment during the finish in an organic or aqueous organic medium and spray-drying the aqueous suspension obtained after removal of the organic solvent by steam distillation or washing out with water.
摘要翻译：本发明涉及一种制备颜料颗粒的方法，该方法包括在有机或含水有机介质中将蜡或蜡状聚合物在终涂过程中向有机颜料中加入并喷雾干燥除去有机溶剂后获得的水性悬浮液通过蒸汽蒸馏或用水冲洗。

30. 发明授权

US06207240B1 Laser marking of effect coatings 失效
标题翻译：效果涂层的激光打标
公开(公告)号：US06207240B1
公开(公告)日：2001-03-27
申请号：US09373804
申请日：1999-08-13
申请人： Axel Schoenfeld , Andreas Stohr , Hans Joachim Metz
发明人： Axel Schoenfeld , Andreas Stohr , Hans Joachim Metz
IPC分类号： B05D300
CPC分类号： B41M5/281 , B05D3/06 , B05D5/061 , B44C1/005 , C09K19/00
摘要： The invention relates to a process for generating a marking on an effect coating or molding compound comprising cholesteric liquid-crystalline main-chain or side-group polymers or comprising a combination of main-chain and side-group polymers, which comprises inducing a color change at the irradiated sites of the effect coating or molding compound by laser irradiation.
摘要翻译：本发明涉及一种用于在包含胆固醇液晶主链或侧基聚合物或包含主链和侧基聚合物的组合的效应涂层或模塑料上产生标记的方法，其包括诱导颜色变化通过激光照射在效果涂层或模塑料的照射位置。

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