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11. 发明公开

EP0036054A3 Oxygen-curable mercapto-functional organosilicon-organic compound compositions possessing rapid surface reaction and method of forming higher molecular weight products therefrom 失效
标题翻译：负责快速表面反应的氧可熔融的功能性有机有机化合物组合物和形成高分子量产物的方法
公开(公告)号：EP0036054A3
公开(公告)日：1981-10-07
申请号：EP80304331
申请日：1980-12-02
申请人： DOW CORNING CORPORATION
发明人： Homan, Gary Rex
IPC分类号： C08L83/08 , C08K03/18 , C08K05/56 , C08K05/09 , C08J03/24 , D21H01/40 , H01B03/46 , C08L83/10 , C08L81/04 , C08K05/37
CPC分类号： C08L83/10 , C08G75/14 , C08K3/18 , C08K5/56 , H01R4/2445 , H01R4/245 , C08L83/08
摘要： Compositions which are stable in the absence of oxygen are formed by mixing the following substantially in the absence of oxygen:
(A) 100 parts by weight of at least one mercapto-functional organosilicon-organic copolymer or mixtures of at least two different types of components selected from the following three types: the above copolymers, mercapto- functional organic compounds free of silicon atoms and mercapto-functional organosilicon compounds wherein all three types contain an average of at leasttwo mercapto groups per molecule; (B) 0-200 parts byweight of at least one filler; (C) a catalytic amount, preferably from 0.1 to 6 parts by weight, of an iron carbonyl catalyst selected from the group consisting of Fe(CO) 5 , Fe 2 (CO) 9 , Fe 3 (CO) 12 , dicyclopentadienyldiiron tetracarbonyl, butadieneiron tricarbonyl and cyclohexadieneiron tricarbonyl; and (D) 0.1-6 parts by weight of an acid, such as 2-ethylhexanoic acid, which meets a particular set of criteria.
The compositions polymerize or cure to form higher molecular weight products at room temperature upon exposure to oxygen. These compositions are especially useful as coatings such as for paper or as electrical insulation because they possess a rapid rate of surface cure. Elastomeric sealant compositions can be prepared which rapidly become tack-free at the surface and are less prone to surface contamination by foreign matter such as dust during cure.
摘要翻译：在不存在氧的情况下稳定的组合物通过以下方式形成：基本上在不存在氧的情况下混合以下物质：（A）100重量份的至少一种巯基官能的有机硅 - 有机共聚物或至少两种不同类型的组分的混合物选自以下三种类型：上述共聚物，不含硅原子的巯基官能的有机化合物和巯基官能的有机硅化合物，其中所有三种类型每分子含有至少两个巯基平均值; （B）0-200重量份的至少一种填料; （C）催化量，优选0.1至6重量份的选自Fe（CO）5，Fe 2（CO）9，Fe 3（CO）12，四羰基二环戊二烯基二铁，三羰基二苯基铁和环己二烯三羰基; 和（D）0.1-6重量份满足特定标准的酸，如2-乙基己酸。组合物在暴露于氧气时，在室温下聚合或固化形成较高分子量的产物。这些组合物特别可用作涂层，例如纸或电绝缘，因为它们具有快速的表面固化速率。可以制备弹性体密封剂组合物，其在表面快速变得无粘性，并且在固化期间不易受外来物质如灰尘的表面污染。

12. 发明申请

WO1999014766A1 MOISTURE-CURABLE ELECTRICALLY-INSULATING RESIN 审中-公开
标题翻译：水分可固化电绝缘树脂
公开(公告)号：WO1999014766A1
公开(公告)日：1999-03-25
申请号：PCT/US1997016210
申请日：1997-09-16
申请人： MINNESOTA MINING AND MANUFACTURING COMPANY , STEPPUTTIS, Manfred , XU, Frank, Y. , BARUCHA, Dieter
发明人： MINNESOTA MINING AND MANUFACTURING COMPANY
IPC分类号： H01B03/46
CPC分类号： H01B3/427 , H01B3/46
摘要： The invention refers to a low-toxicity moisture-curable resin comprising at least one polymer (A) having an organic backbone and at least one silicon-containing end group having at least one hydroxyl or hydrolyzable group, whereby said organic polymer is crosslinkable through formation of siloxane bonds, at least one curing catalyst (B), at least one molecular sieve (C), and water (D), wherein the amounts of (C) and (D) are selected so that the cured resin has an insulation resistance, Ri, of at least 10,000 MOhm.
摘要翻译：本发明涉及一种含有至少一种具有有机骨架的聚合物（A）和至少一个具有至少一个羟基或可水解基团的至少一个含硅端基的低毒性可湿固化树脂，其中所述有机聚合物可通过形成交联的硅氧烷键，至少一种固化催化剂（B），至少一种分子筛（C）和水（D），其中选择（C）和（D）的量使得固化树脂具有绝缘电阻，Ri，至少为10,000MWhm。

13. 发明申请

WO1994027298A1 POLYMER COMPOSITION AND ELECTRICAL WIRE INSULATION 审中-公开
标题翻译：聚合物组合物和电线绝缘
公开(公告)号：WO1994027298A1
公开(公告)日：1994-11-24
申请号：PCT/GB1994001042
申请日：1994-05-16
申请人： RAYCHEM LIMITED , DURSTON, David, John
发明人： RAYCHEM LIMITED
IPC分类号： H01B03/46
CPC分类号： H01B3/46 , H01B3/421 , Y10T428/2929 , Y10T428/2938 , Y10T428/2947 , Y10T428/2958 , Y10T428/2962
摘要： Polymer blend for insulating electrical wires comprises a first polymer (polyester) having an inherent L.O.I. not higher than 21 % and up to 40 % by weight of a polyimide-siloxane (PIS) copolymer. Preferred polyesters are polybutylene terephthalate or polyester-ester block copolymers. Preferred wire constructions have core insulation layer of polyethylene or polyester overlaid with jacket of the polyester/PIS copolymer blend.
摘要翻译：用于绝缘电线的聚合物共混物包括具有固有的L.O.I的第一聚合物（聚酯）。不高于21％和至多40重量％的聚酰亚胺 - 硅氧烷（PIS）共聚物。优选的聚酯是聚对苯二甲酸丁二醇酯或聚酯酯嵌段共聚物。优选的导线结构具有覆盖有聚酯/ PIS共聚物共混物的护套的聚乙烯或聚酯的芯绝缘层。

14. 发明申请

WO1998025277A1 ENAMELLED METALLIC WIRES 审中-公开
标题翻译：金属擦亮WIRES
公开(公告)号：WO1998025277A1
公开(公告)日：1998-06-11
申请号：PCT/DE1997002781
申请日：1997-11-28
申请人： FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V , WOLTER, Herbert , STORCH, Werner , DEICHMANN, Karl
发明人： FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V
IPC分类号： H01B03/46
CPC分类号： C09D183/00 , C08G77/22 , H01B3/308 , H02K3/30 , Y10T428/29 , Y10T428/2907 , Y10T428/2936 , Y10T428/2955
摘要： Enamelled metallic wires are coated with one or several electrically insulating enamel layers. At least one of the electrically insulating enamel layers is composed of an organically modified silicic acid (hetero)polycondensate obtained by partial or total hydrolytic condensation of one or several silicium compounds capable of being hydrolytically condensed and optionally other elements from the group formed by B, A1, P, Sn, Pb, the transition metals, the lanthanides and the actinides, and/or is composed of precondensates derived from the above-mentioned compounds, optionally in the presence of a catalyst and/or a solvent, under the effect of water and humidity.
摘要翻译：本发明涉及一种金属漆包线用清漆中的一个或多个电绝缘层，其中，所述清漆的电绝缘层中的至少一个（杂）缩聚物是有机改性的二氧化硅，其已经通过硅以及任选的其它一种或多种可水解缩合化合物的部分或完全水解缩合得到的选自B，A1，P，锡，铅，过渡金属，镧系元素和锕系元素，元件和/或从上述gennanten化合物的预缩合衍生的，任选地在催化剂和/或通过水和湿气的作用的溶剂的存在下，

15. 发明申请

WO1998010433A1 MEDICAL ELECTRICAL LEAD AND REINFORCED SILICONE ELASTOMER COMPOSITIONS USED THEREIN 审中-公开
标题翻译：医用电导线和加固硅胶弹性体组合物
公开(公告)号：WO1998010433A1
公开(公告)日：1998-03-12
申请号：PCT/US1997014804
申请日：1997-08-25
申请人： MEDTRONIC, INC.
发明人： MEDTRONIC, INC. , PAULSEN, Mark, J. , MILLER, Jennifer, P. , EBERT, Michael, J.
IPC分类号： H01B03/46
CPC分类号： C08K9/06 , H01B3/28 , H01B3/46 , Y10T428/31663 , A61L31/06 , C08L83/04
摘要： A medical electrical lead and a reinforced silicone elastomer used therein. The silicone elastomer used therein is preferably made from a novel silica reinforced polysiloxane material, which after vulcanization by cross-linking exhibits improved mechanical properties. The medical electrical lead features an electrode at a distal end thereof, a connector at a proximal end thereof and an elongated electrical conductor extending between the electrode and the connector, the conductor in electrical contact with the electrode at a distal end and in electrical contact with the connector at a proximal end, the conductor comprised of a plurality of wires or wire bundles wound in a multifilar coil configuration.
摘要翻译：其中使用医用电线和增强硅酮弹性体。其中使用的硅氧烷弹性体优选由新型二氧化硅增强聚硅氧烷材料制成，其在通过交联硫化后显示出改善的机械性能。医疗电引线在其远端具有电极，在其近端处具有连接器，并且在电极和连接器之间延伸的细长电导体，导体在远端处与电极电接触并与电极接触所述连接器在近端处，所述导体包括以多线圈构造缠绕的多根线或线束。

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