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    • 12. 发明授权
    • Soluble trisazo dyestuffs containing a 2-phenyl-benzimidazolyl,
-benzoxazolyl or -benzthiazolyl middle component
    • US4144231A
    • 1979-03-13
    • US795435
    • 1977-05-10
    • Wolfgang BauerJoachim Ribka
    • Wolfgang BauerJoachim Ribka
    • C09B35/376D06P1/06C09B35/36
    • D06P1/06C09B35/376
    • A water soluble trisazo dyestuff of the formula B.sub.1 --N.dbd.N--Z-N.dbd.N-M-N.dbd.N-B.sub.2 is useful for dyeing substances containing nitrogen or hydroxyl wherein M is ##STR1## B.sub.1 and B.sub.2 are the same or different and are selected from the group consisting of ##STR2## 2,4-dihydroxy-3-quinolyl and 2,6-diamino-5-pyridyl; Z is ##STR3## X is --O-- or --S--; R.sub.1 is hydrogen, alkyl having 1 to 4 carbon atoms, phenyl or benzyl; R.sub.3 is hydrogen, chloro or alkyl or alkoxy having 1 to 4 carbon atoms;R.sub.4 is hydrogen chloro, alkyl or alkoxy having 1 to 4 carbon atoms, hydroxy, alkanoylamino having 1 to 4 carbon atoms, benzoylamino, naphthoylamino, oxalylamino, carboxyalkylamino having 2 to 5 carbon atoms, sulphoalkylamino having 1 to 4 carbon atoms or oxyalkylamino having 1 to 4 carbon atoms;R.sub.5 is hydrogen or alkyl having 1 to 8 carbon atoms; R.sub.6 is --CN, --COOH, --CONH.sub.2 or --SO.sub.3 H; R.sub.7 is hydrogen, or alkyl having 1 to 4 carbon atoms, R.sub.8 is hydrogen phenyl or phenyl substituted with a methyl, nitro, chloro or sulpho; R.sub.9 is methyl, carboxyl or alkoxycarbonyl having 2 to 5 carbon atoms; R.sub.10 is hydrogen, methyl, methoxy, chloro, --COOH or --SO.sub.3 H;E is a hydroxyl, amino, alkylamino having 1 to 4 carbon atoms, phenylamino, naphthylamino, benzoylamino, naphthoylamino, alkanoylamino having 2 to 5 carbon atoms, carboxyalkylamino having 2 to 5 carbon atoms, sulphoalkylamino having 1 to 4 carbon atoms, hydroxyalkylamino having 1 to 4 carbon atoms dialkylamino having 1 to 4 carbon atoms in each alkyl;E' is hydrogen or the same or a different member of the group of substituents standing for E;R.sub.11, r.sub.12 and R.sub.13 are alkyl or alkoxy having 1 to 4 carbon atoms, carboxyl, sulpho, chloro, bromo, nitro or methoxycarbonyl; R.sub.14 and R.sub.15 are hydrogen, methyl, ethyl, methoxy, ethoxy or chloro; with the proviso that at least one of M, B.sub.1 and B.sub.2 includes a sulpho substituent.
    • 16. 发明专利
    • PHOTOSENSITIVE BODY
    • JPH01235958A
    • 1989-09-20
    • JP6451788
    • 1988-03-16
    • MINOLTA CAMERA KK
    • UEDA HIDEAKI
    • C09B35/36C09B35/376C09B35/38G03G5/06
    • PURPOSE:To obtain the photosensitive body which has the excellent whole electrostatic characteristics, especially, the excellent sensitivity, and is improved the spectral sensitivity at a long wavelength region by forming the photosensitive layer contg. a specified azo pigment on an electroconductive supporting body. CONSTITUTION:The photosensitive layer contg. the polyazo pigment shown by formula Cp-N=N-A-N=N-Ar1-N=N-Cp is formed on the electroconductive supporting body. In the formula, A is an aromatic heterocyclic ring group having carbonyl group (except at fluorene ring) which may be substd., Ar1 is aryl group which may be substd., Cp is a coupler residual group having a phenolic hydroxyl group. Thus, the photosensitive body which has the excellent whole electrophotographic characteristics, especially the excellent sensitivity and repeatedly stability is obtd., and the sensitivity of the sensitive body at the long wavelength region is improved.
    • 19. 发明专利
    • FR2352039B1
    • 1980-12-12
    • FR7715331
    • 1977-05-18
    • CASSELLA AG
    • C09B35/376D06P1/06C09B35/36D06P1/02D06P3/02D06P3/58
    • A water soluble trisazo dyestuff of the formula B1-N=N-Z-N=N-M-N=N-B2 is useful for dyeing substances containing nitrogen or hydroxyl wherein M is B1 and B2 are the same or different and are selected from the group consisting of +TR 2,4-dihydroxy-3-quinolyl and 2,6-diamino-5-pyridyl; Z is +tr X is -O- or -S-; R1 is hydrogen, alkyl having 1 to 4 carbon atoms, phenyl or benzyl; R3 is hydrogen, chloro or alkyl or alkoxy having 1 to 4 carbon atoms; R4 is hydrogen chloro, alkyl or alkoxy having 1 to 4 carbon atoms, hydroxy, alkanoylamino having 1 to 4 carbon atoms, benzoylamino, naphthoylamino, oxalylamino, carboxyalkylamino having 2 to 5 carbon atoms, sulphoalkylamino having 1 to 4 carbon atoms or oxyalkylamino having 1 to 4 carbon atoms; R5 is hydrogen or alkyl having 1 to 8 carbon atoms; R6 is -CN, -COOH, -CONH2 or -SO3H; R7 is hydrogen, or alkyl having 1 to 4 carbon atoms, R8is hydrogen phenyl or phenyl substituted with a methyl, nitro, chloro or sulpho; R9 is methyl, carboxyl or alkoxycarbonyl having 2 to 5 carbon atoms; R10 is hydrogen, methyl, methoxy, chloro, -COOH or -SO3H; E is a hydroxyl, amino, alkylamino having 1 to 4 carbon atoms, phenylamino, naphthylamino, benzoylamino, naphthoylamino, alkanoylamino having 2 to 5 carbon atoms, carboxyalkylamino having 2 to 5 carbon atoms, sulphoalkylamino having 1 to 4 carbon atoms, hydroxyalkylamino having 1 to 4 carbon atoms dialkylamino having 1 to 4 carbon atoms in each alkyl; E' is hydrogen or the same or a different member of the group of substituents standing for E; R11, R12 and R13 are alkyl or alkoxy having 1 to 4 carbon atoms, carboxyl, sulpho, chloro, bromo, nitro or methoxycarbonyl; R14 and R15 are hydrogen, methyl, ethyl, methoxy, ethoxy or chloro; with the proviso that at least one of M, B1 and B2 includes a sulpho substituent.