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11. 发明公开

EP0105727A3 Hydrocarbon soluble catalyst supports and resultant polymerization catalysts 失效
标题翻译：碳氢化合物催化剂支持和生物聚合催化剂
公开(公告)号：EP0105727A3
公开(公告)日：1985-05-29
申请号：EP83305888
申请日：1983-09-29
申请人： E.I. DU PONT DE NEMOURS AND COMPANY
发明人： Gessell, Donald Earl
IPC分类号： C08F10/00 , C08F04/62 , C08F04/02
CPC分类号： C08F10/00 , C08F4/6367 , C08F4/02
摘要： A method is provided for preparing hydrocarbon soluble magnesium siloxide supports comprising contacting such supports with sufficient aluminium alkoxide or organic ethers to render the supports hydrocarbon soluble. Thereafter the supports are contacted with a transition metal compound and halogenated to obtain polymerization catalysts.

12. 发明公开

EP0101615A3 Supported polyolefin catalyst components and methods of making and using the same 失效
标题翻译：支持的聚烯烃催化剂组分及其制备和使用方法
公开(公告)号：EP0101615A3
公开(公告)日：1984-10-10
申请号：EP83108174
申请日：1983-08-18
申请人： PHILLIPS PETROLEUM COMPANY
发明人： Agapiou, Agapios , Allan, John Leslie Hugh , Jacobson, Felix I.
IPC分类号： C08F10/00 , C08F04/62
CPC分类号： C08F10/00 , C08F4/6381 , C08F4/6355 , C08F4/638
摘要： A method of producing a polymerization catalyst component suitable for use in the polymerization of alpha-olefins, which method comprises forming an active component by co-comminuting an inorganic Lewis acid, a first organic electron donor, a support base selected from the group consisting of the Group IIA & IIIA salts and the salts of the multivalent metals of the first transition series with the exception of copper, and a polymerization active tri-, tetra-, or penta-valent transition metal compound of a Group IVB-VIB metal, and heating the active component in an inert hydrocarbon solvent to produce the polymerization catalyst component. The active component can be heated in the inert hydrocarbon solvent in the presence of an additional polymerization active tri-, tetra-, or penta- valent transition metal compound of a group IVB-VIB metal. In addition, a second organic electron donor may be incorporated in the active component.

13. 发明公开

EP0102895A3 Copolymerization of ethylene and 1-hexene in a fluidized bed 失效
标题翻译：乙烯和1-HEXENE在流化床中的共聚
公开(公告)号：EP0102895A3
公开(公告)日：1984-04-11
申请号：EP83401691
申请日：1983-08-22
申请人： BP Chimie Société Anonyme
发明人： Morterol, Frédéric , Vidal, Jean Louis
IPC分类号： C08F210/16 , C08F02/34 , C08F04/62
CPC分类号： C08F210/16 , Y10S526/901 , Y10S526/903 , Y10S526/904 , C08F2/34 , C08F4/6355 , C08F210/14 , C08F2500/03 , C08F2500/09

14. 发明公开

EP0072035A3 Process for producing polyolefins 失效
标题翻译：生产聚烯烃的方法
公开(公告)号：EP0072035A3
公开(公告)日：1984-02-22
申请号：EP82107293
申请日：1982-08-11
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Baba, Kazuo , Wakatsuki, Kizuku , Sato, Toshimi , Hikasa, Tadashi
IPC分类号： C08F10/00 , C08F04/62
CPC分类号： C08F10/00 , C08F4/6355
摘要： A process for producing a polyolefin, which comprises polymerizing an olefin in the presence of a catalyst system comprising
(a) a solid catalyst component obtained by supporting a titanium compound and/or a vanadium compound on a solid product derived from the reaction of a phenol, an aromatic carboxylate ester, and a solid reaction product of an organomagnesium compound and an aryloxyaluminium compound represented by the general formula Al(OR 1 ) 3 , wherein R' represents an aryl group having 6 to 20 carbon atoms, and (b) an organoaluminium compound.

15. 发明公开

EP0073662A3 Olefin polymerization catalyst 失效
标题翻译： OLEFIN聚合催化剂
公开(公告)号：EP0073662A3
公开(公告)日：1983-04-13
申请号：EP82304526
申请日：1982-08-26
申请人： Standard Oil Company
发明人： Arzoumanidis, Gregory Gerasimos , Tovrog, Benjamin Samuel
IPC分类号： C08F10/00 , C08F04/62 , C08F02/34
CPC分类号： C08F10/06 , Y10S526/904 , C08F4/6552 , C08F4/6492
摘要： A propylene polymerization catalyst comprises (a) a titanium-containing component formed by reducing titanium tetrachloride with an aluminium alkyl, optionally contacting the resulting recduced solid with a pretreatment amount of alpha-olefin monomer under polymerization conditions, and reacting the resulting product with a Lewis base complexing agent and additional titanium tetrachloride, and (b) an alkyl aluminium halide having a halogen/aluminium atomic ratio between 0.89 and 0.98 and preferably between 0.92 and 0.98.

16. 发明公开

EP0055864A3 Catalyst, method for making and use of same for polymerizing olefins 失效
标题翻译：催化剂，用于制备和使用聚合烯烃的方法
公开(公告)号：EP0055864A3
公开(公告)日：1982-08-04
申请号：EP81110848
申请日：1981-12-30
申请人： PHILLIPS PETROLEUM COMPANY
发明人： McDaniel, Max Paul , Johnson, Marvin Merrill
IPC分类号： C08F10/00 , C08F04/62 , C08F04/02
CPC分类号： C08F10/00 , C08F4/025 , C08F4/69
摘要： In one embodiment of this invention, a chromium component is supported on a silica/aluminum orthophosphate combination and used with an organometal cocatalyst. In accordance with other embodiments of the invention, the silica/phosphate combination for a chromium catalyst support is produced by either impregnating a silica xerogel with aluminum phosphate or boron phosphate, precipitating aluminum phosphate in the presence of a silica hydrogel, or physically mixing silica and aluminum phosphate xerogels. The resulting catalysts are capable of producing high melt flow olefin polymers and exhibit high activity. The resulting polymers have many unusual and desirable characteristics, such as high density and good environmental stress crack resistance.

17. 发明公开

EP0032307A3 Catalyst component 失效
标题翻译：催化剂组分
公开(公告)号：EP0032307A3
公开(公告)日：1982-03-03
申请号：EP80304676
申请日：1980-12-22
申请人： IMPERIAL CHEMICAL INDUSTRIES PLC
发明人： Hartshorn, Angus John , Jones, Eric
IPC分类号： C08F10/00 , C08F04/62
CPC分类号： C08F10/00 , C08F4/6555 , C08F4/6346 , C08F4/6355 , C08F4/6383 , C08F4/6385
摘要： A component for an olefin polymerisation catalyst which component is the product of treating a particulate support material with (a) an organomagnesium compound, (b) a transition metal compound of Groups IVA, VA or ViA, e.g. bis-butoxy titanium dichloride, (c) a pacifying agent, e.g. HCl and (d) optionally an aluminium compound, e.g. ethyl aluminium dichloride, an organometallic compound, e.g. zirconium tetrabenzyl, a halogenating agent e.g. carbon tetrachloride, or a Lewis Base compound, e.g. ethyl benzoate.
摘要翻译：用于烯烃聚合催化剂的组分，其组分是用（a）有机镁化合物处理颗粒载体材料的产物，（b）IVA族，VA族或VIA族的过渡金属化合物，例如。二氯化二丁氧基钛，（c）安抚剂，例如 HCl和（d）任选的铝化合物，例如乙基二氯化铝，有机金属化合物，例如四苄基锆，卤化剂如四氯化碳，或路易斯碱化合物，例如苯甲酸乙酯。

18. 发明公开

EP0004533A3 Catalyst, process for its preparation and its use for the polymerization of 1-olefins 失效
标题翻译：催化剂，其制备方法及其用于1-烯烃聚合的方法
公开(公告)号：EP0004533A3
公开(公告)日：1979-12-12
申请号：EP79100142
申请日：1979-01-18
申请人： HOECHST AKTIENGESELLSCHAFT
发明人： Gutweiler, Klemens, Dr.
IPC分类号： C08F10/00 , C08F04/62
CPC分类号： C08F10/00 , C08F4/69
摘要： Durch Umsetzen eines auf einem Siliciumdioxid enthaltenden Träger fixierten Chromatesters mit einer aluminiumorganischen Verbindung in Abwesenheit eines ungesättigten pomyerisierbaren Kohlenwasserstoffs und nachfolgendes Aktivieren mit weiterer aluminiumorganischer Verbindung erhält man einen Katalysator für die Polymerisation von 1-Olefinen. Bei der Umsetzung fallen keine Waschflüssigkeiten an, die wieder aufbereitet werden müßten. Der Katalysator liefert ein Polymeres mit breiter Molgewichtsverteilung in hoher Ausbeute, welches wenig hochmwlekulare Anteile enthält, so daß die aus diesem Polymeren hergestellten Folien praktisch stippenfrei sind.

19. 发明公开

EP0105728A3 High efficiency catalysts for varying olefin polymer molecular weight distribution 失效
标题翻译：改进烯烃聚合物分子量分布的高效催化剂
公开(公告)号：EP0105728A3
公开(公告)日：1985-06-12
申请号：EP83305889
申请日：1983-09-29
申请人： E.I. DU PONT DE NEMOURS AND COMPANY
发明人： Gessell, Donald Earl
IPC分类号： C08F10/00 , C08F04/62
CPC分类号： C08G77/398 , C07F7/0836 , C08F10/00 , C08F4/636
摘要： Catalysts having high efficiency in preparing olefin polymers while controlling molecular weight distribution are disclosed. The catalysts utilise magnesium siloxide supports and the product polymer molecular weight distribution can be controlled by the catalyst preparation.
摘要翻译：公开了在控制分子量分布的同时在制备烯烃聚合物方面具有高效率的催化剂。催化剂采用硅氧化硅载体，产物聚合物分子量分布可通过催化剂制备进行控制。

20. 发明公开

EP0067607A3 A catalyst for polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：EP0067607A3
公开(公告)日：1983-09-14
申请号：EP82302811
申请日：1982-06-01
申请人： Asahi Kasei Kogyo Kabushiki Kaisha
发明人： Ikegami, Tadashi , Takaya, Katsuhiko , Yoneda, Haruyuki
IPC分类号： C08F10/00 , C08F04/62
CPC分类号： C08F10/00 , C08F4/69
摘要： A catalyst suitable for use in the polymerization of olefins is disclosed. This catalyst contains:
[A] a solid catalyst component obtained by calcining a reaction product of (a) at least one compound selected from an amine compound, a phosphoric acid amide, a hydrocarbyloxy compound of titanium, vanadium, hafnium or zirconium, and a germanium compound having the general formula:
wherein (i) R 1 , R 2 and R 3 are each independently a hydrocarbon group having 1 through 10 carbon atoms, and R 4 is a hydrogen atom, a halogen atom, a -OH group, or a -OGeR 1 R 2 R 3 group, or (ii) R 1 , R 2 , R 3 and R 4 are each independently -OR s wherein R 5 is a hydrocarbon group having 1 through 10 carbon atoms, or a halogen atom. and a tin compound having the general formula:
wherein R', R 2 and R 3 are the same as defined above and R 6 is a halogen atom, or -OH group, with (b) at least one chromium compound, said reaction product being supported on an inorganic oxide carrier; and [B] an organometallic compound component selected from the following groups (1) through (5):
(1) a hydrocarbon-soluble organomagnesium component having the general formula:
wherein M is an element selected from aluminum, boron, beryllium, zinc and lithium; R 7 and R 8 are the same or different hydrocarbon groups having 1 to 20 carbon atoms; X and Y are the same or different groups selected from OR 9 OSiR 10 R 11 R 12 , NR 13 ,R 14 , or SR 15 wherein R 9 , R'°, R 11 , R 12 , R 13 , and R" are each independently a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms and R 15 is a hydrocarbon group having 1 to 20 carbon atoms; a is zero or greater than zero, β is greater than zero and p, q, r, and s are each zero or greater than zero and both p and q are not zero at the same time and have the relationship p + q + r + s = m" + 2 β wherein m has a valency of M; (2) an organoaluminum component obtained by reacting (i) one mole of a trialkylaluminum compound with (ii) 0.1 to 2 moles of a carbinol having 1 to 10 carbon atoms, 0.1 to 5 moles of a silanol or siloxane, or a mixture thereof; (3) a component comprising said hydrocarbon-soluble organomagnesium component (1) and said organo- aluminum component (2); (4) a component comprising said hydrocarbon-soluble organomagnesium component (1) and an organoboron, organozinc, or organolithium compound; and (5) a component comprising said organo-aluminum component (2) and an organoboron, organozinc, or organolithium compound.

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