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11. 发明授权

US06630610B2 Method of producing fluorinated organic compounds 有权
标题翻译：氟化有机化合物的制备方法
公开(公告)号：US06630610B2
公开(公告)日：2003-10-07
申请号：US09800126
申请日：2001-03-06
申请人： Charles F. Swain , Stephen A. Cottrell , Clifford Scott Riegel , Curtis A. Brescher
发明人： Charles F. Swain , Stephen A. Cottrell , Clifford Scott Riegel , Curtis A. Brescher
IPC分类号： C07C1700
CPC分类号： C07C17/206 , C07B39/00 , C07C19/08
摘要： A process for producing a fluorinated organic compound comprising: (a) reacting an organic starting material with a fluorination agent in the presence of a liquid fluorination catalyst under conditions which are effective to vaporize one or more chlorinated organic by-products and to produce a gaseous product stream containing said fluorinated organic compound and said one or more chlorinated organic by-products; and (b) recovering said fluorinated organic compound from said product stream, and a system for performing the aforementioned process and recovering the chlorinated by-product.
摘要翻译：一种氟化有机化合物的制备方法，包括：（a）在有效蒸发一种或多种氯化有机副产物并产生气态的条件下，在液体氟化催化剂存在下使有机原料与氟化剂反应含有所述氟化有机化合物和所述一种或多种氯化有机副产物的产物流; 和（b）从所述产物流中回收所述含氟有机化合物，以及用于进行上述方法并回收氯化副产物的体系。

12. 发明授权

US06339178B1 Synthesis of 1,1,1-trifluoroethane by fluorination of 1-chloro-1, 1-difluoroethane 有权
标题翻译：通过氟化1-氯-1,1-二氟乙烷合成1,1,1-三氟乙烷
公开(公告)号：US06339178B1
公开(公告)日：2002-01-15
申请号：US09929502
申请日：2000-06-22
申请人： Andre Lantz , Sylvain Perdrieux , Dominique Garrait , Laurent Wendlinger
发明人： Andre Lantz , Sylvain Perdrieux , Dominique Garrait , Laurent Wendlinger
IPC分类号： C07C1700
CPC分类号： C07C17/206 , Y02P20/582 , C07C19/08
摘要： The subject of the invention is the manufacture of 1,1,1-trifluoroethane by fluorination or 1-chloro-1,1-difluoroethane with anhydrous hydrofluoric acid. The reaction is carried out in the liquid phase and in the presence of a fluorination catalyst.
摘要翻译：本发明的主题是通过氟化或1-氯-1,1-二氟乙烷与无水氢氟酸制备1,1,1-三氟乙烷。反应在液相中并在氟化催化剂的存在下进行。

13. 发明授权

US06235951B1 Method for producing 1,1,1,3,3-pentafluoropropane 失效
标题翻译：制备1,1,1,3,3-五氟丙烷的方法
公开(公告)号：US06235951B1
公开(公告)日：2001-05-22
申请号：US08752879
申请日：1996-11-20
申请人： Fuyuhiko Sakyu , Satoshi Yoshikawa , Yasuo Hibino , Yoshihiko Gotoh , Ryouichi Tamai
发明人： Fuyuhiko Sakyu , Satoshi Yoshikawa , Yasuo Hibino , Yoshihiko Gotoh , Ryouichi Tamai
IPC分类号： C07C1700
CPC分类号： C07C19/08 , C07C17/00 , C07C17/087 , C07C17/37 , C07C21/18 , C07C19/10
摘要： The present invention relates to a method for producing 1,1,1,3,3-pentafluoropropane. This method includes the steps of (a) adding hydrogen fluoride to 1-chloro-3,3,3-trifluoropropene in the presence of an addition catalyst to obtain 1,1,1,3-tetrafluoro-3-chloropropane; and (b) disproportionating the 1,1,1,3-tetrafluoro-3-chloropropane into the 1,1,1,3,3-pentafluoropropane and 1,1,1-trifluoro-3,3-dichloropropane, in the presence of a disproportionation catalyst. This method is a useful method for producing 1,1,1,3,3-pentafluoropropane in an industrial scale, because its steps (a) and (b) are respectively superior in selectivity and yield. According to the invention, 1-chloro-3,3,3-trifluoropropene may be produced by a method including a step of reacting 1,1,1,3,3-pentachloropropane with hydrogen fluoride in a gas phase in the presence of a fluorination catalyst. This method is useful, because yield of 1-chloro-3,3,3-trifluoropropene is high.
摘要翻译：本发明涉及一种生产1,1,1,3,3-五氟丙烷的方法。该方法包括以下步骤：（a）在加成催化剂存在下，向1-氯-3,3,3-三氟丙烯中加入氟化氢，得到1,1,1,3-四氟-3-氯丙烷; 和（b）在存在下将1,1,1,3-四氟-3-氯丙烷歧化成1,1,1,3,3-五氟丙烷和1,1,1-三氟-3,3-二氯丙烷的歧化催化剂。由于其步骤（a）和（b）分别优选选择性和产率，所以该方法是以工业规模生产1,1,1,3,3-五氟丙烷的有用方法。根据本发明，1-氯-3,3,3-三氟丙烯可以通过包括以下步骤制备的方法：使1,1,1,3,3-五氯丙烷与氟化氢在气相中在氟化催化剂。该方法是有用的，因为1-氯-3,3,3-三氟丙烯的产率高。

14. 发明授权

US06225514B1 Ring halogenation of aromatic compounds 失效
标题翻译：芳香族化合物的环卤化
公开(公告)号：US06225514B1
公开(公告)日：2001-05-01
申请号：US09547385
申请日：2000-04-11
申请人： Charles M. Cook , Michael C. Hausladen , Michael C. Savidakis , Michael J. Fifolt
发明人： Charles M. Cook , Michael C. Hausladen , Michael C. Savidakis , Michael J. Fifolt
IPC分类号： C07C1700
CPC分类号： C07C17/12 , B01J23/00 , B01J27/053 , C07B39/00 , C07C67/307 , C07C25/06 , C07C25/02 , C07C69/76
摘要： Disclosed is a method of halogenating the ring of an aromatic compound. The aromatic compound is contacted with a halogenating agent in the presence of a heterogeneous catalyst. The catalyst is the calcination reaction product of: (A) 51 to 99 wt % of a support which comprises at least one inorganic oxide or hydroxide of at least one metal that is at least divalent and forms a metal-to-oxygen matrix during calcination; and (B) 1 to 49 wt % of at least one dopant which comprises a compound that places an element that is at least divalent, bonded to oxygen atoms, into said matrix during said calcination, resulting in the formation of an acidic solid.
摘要翻译：公开了一种卤化芳族化合物的环的方法。芳香族化合物在多相催化剂存在下与卤化剂接触。催化剂是以下的煅烧反应产物：（A）51至99重量％的载体，其包含至少一种至少一种至少二价金属的无机氧化物或氢氧化物，并且在煅烧期间形成金属对氧基质 ; 和（B）1至49重量％的至少一种掺杂剂，其包括在所述煅烧期间将与氧原子键合的至少二价的元素放置到所述基质中的化合物，导致形成酸性固体。

15. 发明授权

US06222079B1 Method of increasing certain isomeric ratios in chlorinating substituted benzenes 失效
标题翻译：提高氯化取代苯中某些异构体比例的方法
公开(公告)号：US06222079B1
公开(公告)日：2001-04-24
申请号：US09429156
申请日：1999-10-28
申请人： Dean R. Lagerwall , Pravin M. Khandare , Hang-Chang Bobby Chen , Mark F. Lechner
发明人： Dean R. Lagerwall , Pravin M. Khandare , Hang-Chang Bobby Chen , Mark F. Lechner
IPC分类号： C07C1700
CPC分类号： C07C25/02 , C07C17/12
摘要： Disclosed is a method of increasing the percentage of certain isomers made when di or tri-substituted benzenes are chlorinated in the presence of a Friedel-Crafts catalyst. The use of about 0.001 to about 1 wt % a cocatalyst during chlorination alters the isomeric ratio of the product mixture. In particular, the percentage of the 2,5-isomer is increased when said substituted benzene is ortho or meta-substituted, the percentage of the 3,4-isomer is increased when said substituted benzene is para-substituted, and the percentage of the 2,4,5-isomer is increased when said substituted benzene is 2,4-disubstituted, 3,4-disubstituted, or 2,5-disubstituted.
摘要翻译：公开了当在Friedel-Crafts催化剂存在下将二或三取代的苯氯化时产生的某些异构体的百分比提高的方法。在氯化期间使用约0.001至约1重量％的助催化剂改变产物混合物的异构体比例。特别地，当所述取代的苯为邻位或间位取代时，2,5-异构体的百分比增加，当所述取代的苯为对位取代时，3,4-异构体的百分比增加，当所述取代的苯是2,4-二取代的，3,4-二取代的或2,5-二取代的时，2,4,5-异构体增加。

16. 发明授权

US06794551B2 Process for producing propargyl bromide 有权
标题翻译：产生炔丙基溴的方法
公开(公告)号：US06794551B2
公开(公告)日：2004-09-21
申请号：US10231571
申请日：2002-08-30
申请人： Christopher L. Mero , Hassan Y. Elnager , Robert C. Herndon, Jr.
发明人： Christopher L. Mero , Hassan Y. Elnager , Robert C. Herndon, Jr.
IPC分类号： C07C1700
CPC分类号： C07C17/16 , C07C21/22
摘要： This invention provides a process of producing propargyl bromide in the absence of a base. The process comprises: A) bringing together in a reaction zone under an inert atmosphere and in the absence of a base and in the presence of an inert diluent, a feed of phosphorus tribromide and a separate feed of propargyl alcohol thereby forming a reaction mixture; B) while mechanically agitating the mixture being formed in A), maintaining the temperature of the mixture in the range of about 0° C. to about 25° C. to form a product mixture, and then C) raising the temperature of the product mixture to a temperature in the range of about 40° C. to about 60° C. while stirring the product mixture for a ride period of at least about 2.5 hours. Such process can be conducted as a batch process, as a semi-batch process, or as a continuous process.
摘要翻译：本发明提供了在不存在碱的情况下生产炔丙基溴的方法。该方法包括：A）在惰性气氛下和不存在碱的情况下，在惰性稀释剂存在下，在反应区中一起加入三溴化磷的进料和炔丙醇的单独进料，从而形成反应混合物; B）同时机械搅拌在A）中形成的混合物，将混合物的温度保持在约0℃至约25℃的范围内以形成产物混合物，然后C）提高产物混合物的温度在约40℃至约60℃的温度范围内，同时搅拌产物混合物至少约2.5小时的运行时间。该方法可以作为间歇方法进行，作为半间歇方法，或作为连续过程。

17. 发明授权

US06720464B2 Production and use of octafluoropropane 失效
标题翻译：生产和使用八氟丙烷
公开(公告)号：US06720464B2
公开(公告)日：2004-04-13
申请号：US10111773
申请日：2002-04-29
申请人： Hiromoto Ohno , Toshio Ohi
发明人： Hiromoto Ohno , Toshio Ohi
IPC分类号： C07C1700
CPC分类号： C07C19/08 , C07C17/087 , C07C17/10 , C07C17/206 , C07C17/21 , C07C17/38 , C07C17/383
摘要： Octafluoropropane is produced by a process comprising a step (1) of reacting hexafluoropropene with hydrogen fluoride in a gas phase at a temperature of from 150 to 450° C. in the presence of a fluorination catalyst to obtain 2H-heptafluoropropane and a step (2) of reacting 2H-heptafluoropropane obtained in step (1) with fluorine gas in a gas phase at a temperature of from 250 to 500° C. in the absence of a catalyst to obtain octafluoropropane. High-purity octafluoropropane is obtained which can be used in a process for producing a semiconductor device.
摘要翻译：八氟丙烷是通过在氟化催化剂的存在下，在150〜450℃的温度下，使六氟丙烯与氟化氢反应的工序（1）制造的，得到2H-七氟丙烷和步骤（2 ）在步骤（1）中获得的2H-七氟丙烷与氟气在气相中在250-500℃的温度下在不存在催化剂的情况下反应，得到八氟丙烷。得到高纯度八氟丙烷，可用于制造半导体器件的方法。

18. 发明授权

US06653515B2 Synthesis of &agr;, &bgr;, &bgr;-trifluorostyrene via in-situ formation of trifluorovinyl metal halide 失效
标题翻译：通过原位形成三氟乙烯基金属卤化物合成α，β，β-三氟苯乙烯
公开(公告)号：US06653515B2
公开(公告)日：2003-11-25
申请号：US10017485
申请日：2001-12-14
申请人： Charles Stone , Timothy J. Peckham , Donald J. Burton , Anilkumar Raghavanpillai
发明人： Charles Stone , Timothy J. Peckham , Donald J. Burton , Anilkumar Raghavanpillai
IPC分类号： C07C1700
CPC分类号： C07D333/12 , C07B37/04 , C07C17/093 , C07C41/30 , C07C43/225 , C07C201/12 , C07C25/28 , C07C25/24 , C07C22/08 , C07C205/11
摘要： &agr;,&bgr;,&bgr;-Trifluorostyrene and derivatives thereof synthesized in two steps from 1,1,1,2-tetrafluoroethylene. In the first step, 1,1,1,2-tetrafluoroethylene is reacted with a base, a metal salt such as zinc chloride and an optionally amine to form a trifluorovinyl metal complex. In the second step, the trifluorostyrene or derivative is obtained by reacting the trifluorovinyl metal complex with an aryl transfer agent such as, for example, an aryl triflate or an aryl halide, in the presence of a metal catalyst and optionally a coordinating ligand. Both steps may be carried out in one reactor.
摘要翻译： α，β，β-三氟苯乙烯及其衍生物由1,1,1,2-四氟乙烯两步合成。在第一步骤中，1,1,1,2-四氟乙烯与碱，金属盐如氯化锌和任选的胺反应形成三氟乙烯基金属络合物。在第二步中，三氟乙烯或衍生物通过三氟乙烯基金属络合物与芳基转移剂如三氟甲磺酸芳基酯或芳基卤化物在金属催化剂和任选的配位配体的存在下反应而获得。两个步骤可以在一个反应器中进行。

19. 发明授权

US06639115B2 Process for the manufacture of difluoromethane 有权
标题翻译：制备二氟甲烷的方法
公开(公告)号：US06639115B2
公开(公告)日：2003-10-28
申请号：US09761845
申请日：2001-01-18
申请人： Benoit Requieme , Sylvain Perdrieux , Bernard Cheminal , Eric Lacroix , Andre Lantz
发明人： Benoit Requieme , Sylvain Perdrieux , Bernard Cheminal , Eric Lacroix , Andre Lantz
IPC分类号： C07C1700
CPC分类号： C07C17/206 , C07C19/08
摘要： The invention relates to the synthesis of difluoromethane by gas-phase catalytic fluorination of methylene chloride. To lengthen the lifetime of the catalyst the operation is carried out in the presence of chlorine.
摘要翻译：本发明涉及通过二氯甲烷的气相催化氟化合成二氟甲烷。为了延长催化剂的寿命，操作在氯存在下进行。

20. 发明授权

US06610896B2 Process for production of perfluoroalkadienes 有权
标题翻译：生产全氟烷二烯的方法
公开(公告)号：US06610896B2
公开(公告)日：2003-08-26
申请号：US10169076
申请日：2002-07-05
申请人： Jun Miki , Hitoshi Yoshimi , Hirokazu Aoyama
发明人： Jun Miki , Hitoshi Yoshimi , Hirokazu Aoyama
IPC分类号： C07C1700
CPC分类号： C07C17/23 , C07C21/18
摘要： A process for preparing a perfluoroalkadiene compound of formula (I) CF2═CF—(CF2)n-4—CF═CF2 (I) (wherein n is an integer from 4 to 20) by the deiodofluorination of a compound of formula (II) I—(CF2)n—I (II) (wherein n is as defined above), characterised in that said deiodofluorination is conducted in the presence of metallic zinc and a nitrogen-containing organic compound.
摘要翻译：通过式（II）化合物（其中n如上定义）的脱氟氟化制备式（I）的全氟二烯化合物（其中n为4至20的整数）的方法，其特征在于进行所述脱碘在金属锌和含氮有机化合物的存在下。

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