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    • 13. 发明申请
    • HIGH PURITY TABLETED ALPHA-ALUMINA CATALYST SUPPORT
    • WO2022268348A1
    • 2022-12-29
    • PCT/EP2021/083130
    • 2021-11-26
    • BASF SE
    • WALSDORFF, ChristianCHOI, Sung YeunKARPOV, AndreyAMAKAWA, KazuhikoDUYCKAERTS, Nicolas
    • B01J21/04B01J23/50B01J23/68B01J35/10B01J35/02B01J37/00B01J37/08C01F7/02C07D301/10C04B35/111C01F7/44B01J23/688B01J35/1009B01J35/1038B01J35/1042B01J35/108B01J37/0009B01J37/0018B01J37/0072
    • A catalyst support comprising at least 85 wt.-% of alpha-alumina and having a pore volume of at least 0.40 mL/g, as determined by mercury porosimetry, and a BET surface area of 0.5 to 5.0 m2/g, wherein the catalyst support is a tableted catalyst support comprising, based on the total weight of the catalyst support, less than 500 ppmw of potassium. The invention moreover relates to a process for producing a tableted alpha- alumina catalyst support, which comprises i) forming a free-flowing feed mixture comprising i-a) at least one aluminum compound which is thermally convertible to alpha-alumina, the aluminum compound comprising a transition alumina and/or an alumina hydrate; and i-b) 30 to 120 wt.-%, relative to i-a), of a pore-forming material; ii) tableting the free-flowing feed mixture to obtain a compacted body; and iii) heat treating the compacted body at a temperature of at least 1100 °C, to obtain the tableted alpha-alumina catalyst support. The invention further relates to a compacted body obtained by tableting a free-flowing feed mixture which comprises, relative to the total weight of the free-flowing feed mixture, a) at least one aluminum compound which is thermally convertible to alpha-alumina, the aluminum compound comprising a transition alumina and/or an alumina hydrate; and b) 30 to 120 wt.-%, relative to a), of a pore- forming material. The invention moreover relates to a shaped catalyst body for producing ethylene oxide by gas-phase oxidation of ethylene, comprising at least 12 wt.-% of silver, relative to the total weight of the catalyst, deposited on the tableted alpha-alumina catalyst support. The invention also relates to a process for producing ethylene oxide by gas-phase oxidation of ethylene, comprising reacting ethylene and oxygen in the presence of the shaped catalyst body. The invention allows for the use of specific pore- forming materials that are particularly suitable for obtaining an advantageous pore structure while allowing for a catalyst support having high purity.