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11. 发明授权

US07732501B2 Fullerene based proton conductive materials 有权
公开(公告)号：US07732501B2
公开(公告)日：2010-06-08
申请号：US11551048
申请日：2006-10-19
申请人： Berthold Nuber , Bjoern Pietzak
发明人： Berthold Nuber , Bjoern Pietzak
IPC分类号： C08J5/20
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , C08J5/2225 , C08J5/2262 , C08J2365/00 , H01B1/122 , H01M8/1023 , H01M8/1025 , H01M8/103 , H01M8/1039 , H01M2300/0082 , Y10S977/737
摘要： A fullerene-based proton conductor including a proton conductive functional group connected to the fullerene by an at least partially fluorinated spacer molecule. Also, a polymer including at least two of the proton conductors that are connected by a linking molecule. Further, an electrochemical device employing the polymer as a proton exchange membrane, whereby the device is able to achieve a self-humidifying characteristic.

12. 发明申请

US20100120927A1 FULLERENE BASED PROTON CONDUCTIVE MATERIALS 失效
标题翻译：富勒烯基导电材料
公开(公告)号：US20100120927A1
公开(公告)日：2010-05-13
申请号：US12652346
申请日：2010-01-05
申请人： Berthold Nuber , Bjoern Pietzak
发明人： Berthold Nuber , Bjoern Pietzak
IPC分类号： C08J5/22
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , C08J5/2225 , C08J5/2262 , C08J2365/00 , H01B1/122 , H01M8/1023 , H01M8/1025 , H01M8/103 , H01M8/1039 , H01M2300/0082 , Y10S977/737
摘要： A fullerene-based proton conductor including a proton conductive functional group connected to the fullerene by an at least partially fluorinated spacer molecule. Also, a polymer including at least two of the proton conductors that are connected by a linking molecule. Further, an electrochemical device employing the polymer as a proton exchange membrane, whereby the device is able to achieve a self-humidifying characteristic.
摘要翻译：一种基于富勒烯的质子导体，其包括通过至少部分氟化的间隔分子与富勒烯连接的质子传导性官能团。此外，包含由连接分子连接的至少两个质子导体的聚合物。此外，使用该聚合物作为质子交换膜的电化学装置，由此该装置能够实现自加湿特性。

13. 发明申请

US20070087247A1 FULLERENE BASED PROTON CONDUCTIVE MATERIALS 有权
标题翻译：富勒烯基导电材料
公开(公告)号：US20070087247A1
公开(公告)日：2007-04-19
申请号：US11551079
申请日：2006-10-19
申请人： Berthold Nuber , Bjoern Pietzak
发明人： Berthold Nuber , Bjoern Pietzak
IPC分类号： H01M8/10
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , C08J5/2225 , C08J5/2262 , C08J2365/00 , H01B1/122 , H01M8/1023 , H01M8/1025 , H01M8/103 , H01M8/1039 , H01M2300/0082 , Y10S977/737
摘要： A fullerene-based proton conductor including a proton conductive functional group connected to the fullerene by an at least partially fluorinated spacer molecule. Also, a polymer including at least two of the proton conductors that are connected by a linking molecule. Further, an electrochemical device employing the polymer as a proton exchange membrane, whereby the device is able to achieve a self-humidifying characteristic.
摘要翻译：一种基于富勒烯的质子导体，其包括通过至少部分氟化的间隔分子与富勒烯连接的质子传导性官能团。此外，包含由连接分子连接的至少两个质子导体的聚合物。此外，使用该聚合物作为质子交换膜的电化学装置，由此该装置能够实现自加湿特性。

14. 发明申请

WO2011025867A1 ION EXCHANGE MEMBRANES 审中-公开
标题翻译：离子交换膜
公开(公告)号：WO2011025867A1
公开(公告)日：2011-03-03
申请号：PCT/US2010/046777
申请日：2010-08-26
申请人： SIEMENS PTE. LTD. , LIN, Juchui, Ray , GU, George, Y.
发明人： LIN, Juchui, Ray , GU, George, Y.
IPC分类号： B01D61/00
CPC分类号： B01D61/44 , B01D67/0006 , B01D69/02 , B01D69/10 , B01D71/82 , B01D2323/30 , B01D2325/20 , B01D2325/26 , B01D2325/42 , C08J5/2225 , C08J5/2243 , C08J5/2275 , C08J2323/06 , C08J2327/16 , Y02A20/134 , Y02P20/57
摘要： Highly energy efficient electrodialysis membranes having low operating costs and a novel process for their manufacture are described herein. The membranes are useful in the desalination of water and purification of waste water. They are effective in desalination of seawater due to their low electrical resistance and high permselectivity. These membranes are made by a novel process which results in membranes significantly thinner than prior art commercial electrodialysis membranes. The membranes are produced by polymerizing one or more monofunctional ionogenic monomers with at least one multifunctional monomer in the pores of a porous substrate.
摘要翻译：本文描述了具有低操作成本的高效能电渗析膜和用于其制造的新颖方法。该膜可用于脱盐水和净化废水。它们由于其低电阻和高选择性而具有对海水淡化的有效性。这些膜通过新技术制成，其导致膜比现有技术的商业电渗析膜显着更薄。膜通过在多孔基材的孔中聚合一种或多种单官能离子型单体与至少一种多官能单体而制备。

15. 发明申请

WO2017043592A1 塩化アルカリ電解用イオン交換膜の製造方法および塩化アルカリ電解装置の製造方法审中-公开
标题翻译：用于碱性氯离子电解的离子交换膜的生产方法和碱性氯化物电解装置的生产方法
公开(公告)号：WO2017043592A1
公开(公告)日：2017-03-16
申请号：PCT/JP2016/076495
申请日：2016-09-08
申请人：旭硝子株式会社
发明人：曽我　環 , 西尾　拓久央 , 山木　泰 , 金子　隆之
IPC分类号： C25B13/08 , C08J5/22 , C25B1/46 , C25B9/00
CPC分类号： C08J5/2293 , C08J5/22 , C08J5/2225 , C08J2300/102 , C08J2300/105 , C25B1/34 , C25B1/46 , C25B9/00 , C25B13/08
摘要：塩化アルカリを電解する際の電流効率およびアルカリ耐性が高い塩化アルカリ電解用イオン交換膜を効率よく製造できる方法の提供。　カルボン酸型官能基に変換できる基を有する含フッ素ポリマー（Ａ'）を含む前駆体層（Ｃ'）を有するイオン交換膜前駆体膜を、アルカリ金属水酸化物、水溶性有機溶媒および水を含むアルカリ水溶液に浸漬して、カルボン酸型官能基に変換できる基を加水分解処理してカルボン酸型官能基に変換することによって、カルボン酸型官能基を有する含フッ素ポリマー（Ａ）を含む層（Ｃ）１２を有する塩化アルカリ電解用イオン交換膜１を製造する方法であって；水溶性有機溶媒の濃度が、アルカリ水溶液（１００質量％）中、１～６０質量％であり、含フッ素ポリマー（Ａ）におけるカルボン酸型官能基を有する構成単位の割合が１４．００～１４．５０モル％であり；層（Ｃ）１２における比抵抗が３．０×１０３～２５．０×１０３ Ω・ｃｍである。
摘要翻译：提供一种可以有效地生产碱性氯化物电解中具有高电流效率和高耐碱性的碱金属氯化物电解用离子交换膜的方法。该方法制造用于碱金属氯化物电解的离子交换膜1，具有包含具有羧酸官能团的含氟聚合物（A）的层（C）12，其通过以下方式制备：将离子交换膜前体膜浸入碱性水溶液包含碱金属氢氧化物，水溶性有机溶剂和水的溶液，所述离子交换膜前体膜具有含有具有羧酸官能团的可取代基的含氟聚合物（A'）的前体层（C'）; 并水解羧酸官能团可取代的基团并用羧酸官能团代替。在碱性水溶液（100质量％）中，水溶性有机溶剂浓度为1质量％〜60质量％。含氟聚合物（A）中具有羧酸官能团的结构单元的比例为14.00〜1.40摩尔％。层（C）12中的电阻率为3.0×10 3〜25.0×10 3Ω·cm。

16. 发明申请

US20180237925A1 PRODUCTION METHOD FOR ION EXCHANGE MEMBRANE FOR ALKALI CHLORIDE ELECTROLYSIS, AND PRODUCTION METHOD FOR ALKALI CHLORIDE ELECTROLYSIS APPARATUS 审中-公开
公开(公告)号：US20180237925A1
公开(公告)日：2018-08-23
申请号：US15908999
申请日：2018-03-01
申请人： Asahi Glass Company,Limited
发明人： Tamaki CHINSOGA , Takuo Nishio , Yasushi Yamaki , Takayuki Kaneko
IPC分类号： C25B1/46 , C08J5/22 , C25B13/08 , C25B9/18
CPC分类号： C25B1/46 , C08F214/26 , C08J5/22 , C08J5/2225 , C08J5/225 , C08J2327/24 , C25B9/08 , C25B9/18 , C25B13/08
摘要： To provide a method capable of efficiently producing an ion exchange membrane for alkali chloride electrolysis which has high current efficiency, little variation in current efficiency and high alkaline resistance. This is a method for producing an ion exchange membrane 1 having a layer (C) 12 containing a fluorinated polymer (A) having carboxylic acid type functional groups, by immersing an ion exchange membrane precursor film having a precursor layer (C′) containing a fluorinated polymer (A′) having groups convertible to carboxylic acid type functional groups, in an aqueous alkaline solution comprising an alkali metal hydroxide, a water-soluble organic solvent and water, wherein the proportion of structural units having carboxylic acid type functional groups in the fluorinated polymer (A) is from 13.0 to 14.50 mol %; in the layer (C) 12, the value of resistivity is from 4.0×103 to 25.0×103 Ω·cm, and the variation in resistivity is at most 4.0×103 Ω·cm, and the concentration of the water-soluble organic solvent is from 1 to 60 mass % in the alkaline aqueous solution.

17. 发明授权

US09318764B2 Proton conducting polymer membrane, membrane-electrode assembly using same, and polymer electrolyte fuel cell 有权
标题翻译：质子导电聚合物膜，使用其的膜 - 电极组件和聚合物电解质燃料电池
公开(公告)号：US09318764B2
公开(公告)日：2016-04-19
申请号：US14007241
申请日：2012-04-13
申请人： Toru Tanaka , Katsutoshi Suzuki , Haruhiko Komoriya , Arata Takahashi , Saori Itabashi
发明人： Toru Tanaka , Katsutoshi Suzuki , Haruhiko Komoriya , Arata Takahashi , Saori Itabashi
IPC分类号： H01M8/10 , H01B1/12 , C08J5/22
CPC分类号： H01M8/1039 , C08J5/2225 , H01B1/122 , H01M8/1011 , H01M8/1023 , H01M8/1037 , H01M8/1053 , Y02E60/523 , Y10T156/10
摘要： Disclosed is a proton conducting polymer membrane formed by laminating a plurality of solid electrolyte membranes. This proton conducting polymer membrane is one prepared by laminating at least one layer of a solid electrolyte membrane formed by using a resin having a bis(perfluoroalkanesulfonyl)methide group in the chemical structure. This solid electrolyte membrane has a superior proton conductivity without transmitting the fuel (methanol or hydrogen).
摘要翻译：公开了通过层叠多个固体电解质膜形成的质子传导性聚合物膜。该质子传导性聚合物膜是通过层叠通过在化学结构中使用具有双（全氟烷基磺酰基）甲硅烷基的树脂形成的至少一层固体电解质膜而制备的。该固体电解质膜在不传输燃料（甲醇或氢）的情况下具有优异的质子传导性。

18. 发明申请

US20140166488A1 ION EXCHANGE MEMBRANES 审中-公开
标题翻译：离子交换膜
公开(公告)号：US20140166488A1
公开(公告)日：2014-06-19
申请号：US14189097
申请日：2014-02-25
申请人： EVOQUA WATER TECHNOLOGIES PTE. LTD.
发明人： Juchui Ray Lin , George Y. Gu
IPC分类号： B01D61/44
CPC分类号： B01D61/44 , B01D67/0006 , B01D69/02 , B01D69/10 , B01D71/82 , B01D2323/30 , B01D2325/20 , B01D2325/26 , B01D2325/42 , C08J5/2225 , C08J5/2243 , C08J5/2275 , C08J2323/06 , C08J2327/16 , Y02A20/134 , Y02P20/57
摘要： Highly energy efficient electrodialysis membranes having low operating costs and a novel process for their manufacture are described herein. The membranes are useful in the desalination of water and purification of waste water. They are effective in desalination of seawater due to their low electrical resistance and high permselectivity. These membranes are made by a novel process which results in membranes significantly thinner than prior art commercial electrodialysis membranes. The membranes are produced by polymerizing one or more monofunctional ionogenic monomers with at least one multifunctional monomer in the pores of a porous substrate.
摘要翻译：本文描述了具有低操作成本的高效能电渗析膜和用于其制造的新颖方法。该膜可用于脱盐水和净化废水。它们由于其低电阻和高选择性而具有对海水淡化的有效性。这些膜通过新技术制成，其导致膜比现有技术的商业电渗析膜显着更薄。膜通过在多孔基材的孔中聚合一种或多种单官能离子型单体与至少一种多官能单体而制备。

19. 发明授权

US06890676B2 Fullerene based proton conductive materials 失效
标题翻译：富勒烯基质子传导材料
公开(公告)号：US06890676B2
公开(公告)日：2005-05-10
申请号：US10115109
申请日：2002-04-01
申请人： Berthold Nuber , Bjoern Pietzak
发明人： Berthold Nuber , Bjoern Pietzak
IPC分类号： C01B31/02 , H01M8/10
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , C08J5/2225 , C08J5/2262 , C08J2365/00 , H01B1/122 , H01M8/1023 , H01M8/1025 , H01M8/103 , H01M8/1039 , H01M2300/0082 , Y10S977/737
摘要： A fullerene-based proton conductor including a proton conductive functional group connected to the fullerene by an at least partially fluorinated spacer molecule. Also, a polymer including at least two of the proton conductors that are connected by a linking molecule. Further, an electrochemical device employing the polymer as a proton exchange membrane, whereby the device is able to achieve a self-humidifying characteristic.
摘要翻译：一种基于富勒烯的质子导体，其包括通过至少部分氟化的间隔分子与富勒烯连接的质子传导性官能团。此外，包含由连接分子连接的至少两个质子导体的聚合物。此外，使用该聚合物作为质子交换膜的电化学装置，由此该装置能够实现自加湿特性。

20. 发明公开

EP2470290A4 ION EXCHANGE MEMBRANES 审中-公开
标题翻译：离子交换膜
公开(公告)号：EP2470290A4
公开(公告)日：2013-07-03
申请号：EP10812611
申请日：2010-08-26
申请人： SIEMENS PTE LTD
发明人： LIN JUCHUI RAY , GU GEORGE Y
IPC分类号： B01D61/00 , B01D61/42 , B01D67/00 , B01D69/14 , C08J5/22
CPC分类号： B01D61/44 , B01D67/0006 , B01D69/02 , B01D69/10 , B01D71/82 , B01D2323/30 , B01D2325/20 , B01D2325/26 , B01D2325/42 , C08J5/2225 , C08J5/2243 , C08J5/2275 , C08J2323/06 , C08J2327/16 , Y02A20/134 , Y02P20/57
摘要： Highly energy efficient electrodialysis membranes having low operating costs and a novel process for their manufacture are described herein. The membranes are useful in the desalination of water and purification of waste water. They are effective in desalination of seawater due to their low electrical resistance and high permselectivity. These membranes are made by a novel process which results in membranes significantly thinner than prior art commercial electrodialysis membranes. The membranes are produced by polymerizing one or more monofunctional ionogenic monomers with at least one multifunctional monomer in the pores of a porous substrate.

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