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11. 发明申请

WO2008127742A2 METHODS FOR MANUFACTURING SUPPORTED CATALYST FROM A POROUS SUPPORT AND A NANOCATALYST SOLUTION 审中-公开
标题翻译：从多孔支持和纳米级解决方案制造支持的催化剂的方法
公开(公告)号：WO2008127742A2
公开(公告)日：2008-10-23
申请号：PCT/US2008/050016
申请日：2008-01-02
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , ZHOU, Zhenhua , WU, Zhihua , ZHOU, Bing
发明人： ZHOU, Zhenhua , WU, Zhihua , ZHOU, Bing
IPC分类号： C01B15/029 , B01J21/10 , B01J21/04 , B01J21/06 , B01J21/08 , B01J21/12 , B01J21/16 , B01J29/06 , B01J31/06 , B01J31/02
CPC分类号： C01B15/029 , B01J21/08 , B01J23/44 , B01J35/0013 , B01J35/023 , B01J37/0207 , B01J37/0211 , B01J37/0213 , B01J37/10 , B01J37/18
摘要： Supported catalysts are manufactured from a pretreated porous support material and a nanocatalyst solution of catalyst nanoparticles. The porous support material is pre-treated with a gaseous solvent (e.g., steam or alcohol) to protect the support material from cracking during impregnation of the nanocatalyst solution. The supported catalysts have more uniform size, lower attrition of metals during manufacturing and use, and improved distributions of metal loading compared to catalysts manufactured using known techniques. Hydrogen peroxide manufactured from such catalysts is less likely to be contaminated with catalyst metal.
摘要翻译：负载催化剂由预处理的多孔载体材料和催化剂纳米颗粒的纳米催化剂溶液制成。多孔支撑材料用气态溶剂（例如蒸汽或醇）进行预处理，以保护支撑材料在浸渍纳米催化剂溶液期间不会开裂。负载催化剂在制造和使用过程中具有更均匀的尺寸，更低的金属磨损，以及与使用已知技术制造的催化剂相比，金属负载的分布改善。由这种催化剂制造的过氧化氢不太可能被催化剂金属污染。

12. 发明申请

WO2008036743A3 SUPPORTED NICKEL CATALYSTS HAVING HIGH NICKEL LOADING AND HIGH METAL DISPERSION AND METHODS OF MAKING SAME 审中-公开
公开(公告)号：WO2008036743A3
公开(公告)日：2008-03-27
申请号：PCT/US2007/078896
申请日：2007-09-19
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , REYES, Clementine , FRANSSON, Martin , TREVINO, Horacio , ZHOU, Bing
发明人： REYES, Clementine , FRANSSON, Martin , TREVINO, Horacio , ZHOU, Bing
IPC分类号： B01J23/00 , B01J23/40
摘要： Supported nickel catalyst having high nickel loading and dispersion are manufactured using a dispersing agent. The dispersing agent molecules include at least one functional group that bonds with the nickel atoms and influences nanoparticle formation. The support material is loaded with at least about 5% nickel, more preferably at least about 8%, and most preferably at least about 12% by weight of the total catalyst. Catalysts manufactured using the organic dispersing agents and loaded with the foregoing amounts of nickel have metal dispersions greater than about 5% as measured by hydrogen adsorption, more preferably greater than about 10%, and most preferably greater than about 15%.

13. 发明申请

WO2007109457A3 STABLE CONCENTRATED METAL COLLOIDS AND METHODS OF MAKING SAME 审中-公开
公开(公告)号：WO2007109457A3
公开(公告)日：2007-09-27
申请号：PCT/US2007/063874
申请日：2007-03-13
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , PARASHER, Sukesh , ZHANG, Cheng , RUETER, Michael, A. , ZHOU, Bing
发明人： PARASHER, Sukesh , ZHANG, Cheng , RUETER, Michael, A. , ZHOU, Bing
IPC分类号： B01J13/00 , B01J23/40 , B01J23/42 , B01J23/44 , C01B15/029
摘要： A method for manufacturing stable concentrated colloids containing metal nanoparticles in which the colloid is stabilized by adding a base. This allows the metal particles to be formed in higher concentration without forming larger agglomerates and/or precipitating. The method of manufacturing the stable colloidal metal nanoparticles of the present invention generally includes (i) providing a solution comprising a plurality of metal atoms, (ii) providing a solution comprising a plurality of organic agent molecules, each organic agent molecule comprising at least one functional group capable of bonding to the metal atoms, (iii) reacting the metal atoms in solution with the organic agent molecules in solution to form a mixture comprising a plurality of complexed metal atoms, (iv) reducing the complexed metal atoms in the mixture using a reducing agent to form a plurality of nanoparticles, and (v) adding an amount of a base to the mixture, thereby improving the stability of the nanoparticles in the mixture. The base may be added before or after forming the nanoparticles.

14. 发明申请

WO2007001418A3 MULTICOMPONENT NANOPARTICLES FORMED USING A DISPERSING AGENT 审中-公开
公开(公告)号：WO2007001418A3
公开(公告)日：2007-01-04
申请号：PCT/US2005/037545
申请日：2005-10-19
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , ZHOU, Bing , PARASHER, Sukesh , RUETER, Michael
发明人： ZHOU, Bing , PARASHER, Sukesh , RUETER, Michael
IPC分类号： B01J23/00
摘要： Nanoparticles include a plurality of two or more dissimilar components selected from the group of noble metals, base transition metals, alkali earth metals, and rare earth metals and/or different groups of the periodic table of elements. The two or more dissimilar components are dispersed using a dispersing agent such that the nanoparticles have a substantially uniform distribution of the two or more dissimilar components. The dispersing agents can be poly functional small organic molecules, polymers, or oligomers, or salts of these. The molecules of the dispersing agent bind to the particle atoms to overcome same-component attractions, thereby allowing dissimilar components to form heterogeneous manoparticles. Dissimular components such as iron and platinum can be complexed using the dispersing agent to form sbstantially uniform heterogeneous nanoparticles. The nanoparticles can be used alone or applied to a support. At least a portion of the dispersing agent can be removed by reduction and/or oxidation.

15. 发明申请

WO2009088544A2 FUNCTIONALIZATION OF CARBON NANOSPHERES BY SEVERE OXIDATIVE TREATMENT 审中-公开
标题翻译：通过严格氧化处理对碳纳米管的功能化
公开(公告)号：WO2009088544A2
公开(公告)日：2009-07-16
申请号：PCT/US2008/079403
申请日：2008-10-09
申请人： HEADWATERS TECHNOLOGY INNOVATION, LLC , ZHANG, Cheng , ZHOU, Bing
发明人： ZHANG, Cheng , ZHOU, Bing
IPC分类号： D02G3/02 , C01B31/00 , B01J19/10 , C08K3/04
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/05 , C01B32/18 , Y10T428/2918
摘要： Carbon nanostructures are formed from a carbon precursor and catalytic templating nanoparticles and are treated with a severe oxidative agent to introduce oxygen-containing functional groups to the surface of the graphitic material. Methods for manufacturing carbon nanostructures generally include (1) forming a precursor mixture that includes a carbon precursor and a plurality of catalytic templating particles, (2) carbonizing the precursor mixture to form an intermediate carbon material including carbon nanostructures, amorphous carbon, and catalytic metal, (3) purifying the intermediate carbon material by removing at least a portion of the amorphous carbon and optionally at least a portion of the catalytic metal, and (4) treating the intermediate carbon material with a severe oxidative treatment to increase surface functionalization. Examples of oxidative treatments include (i) a mixture of nitric acid and sulfuric acid, (ii) a solution of hydrogen peroxide, or (iii) a mixture of sulfuric acid and hydrogen peroxide.
摘要翻译：碳纳米结构由碳前体和催化模板纳米颗粒形成，并用严重的氧化剂处理以将含氧官能团引入石墨材料的表面。制造碳纳米结构的方法通常包括（1）形成包含碳前体和多个催化模板颗粒的前体混合物，（2）将前体混合物碳化以形成包括碳纳米结构，无定形碳和催化金属的中间碳材料（3）通过除去至少一部分无定形碳和任选的至少一部分催化金属来纯化中间碳材料，和（4）用严格的氧化处理来处理中间碳材料以增加表面官能度。氧化处理的实例包括（i）硝酸和硫酸的混合物，（ii）过氧化氢溶液，或（iii）硫酸和过氧化氢的混合物。

16. 发明申请

WO2009032798A1 HYDROGEN STORAGE USING POROUS CARBON NANOSPHERES 审中-公开
标题翻译：氢存储使用多孔碳纳米管
公开(公告)号：WO2009032798A1
公开(公告)日：2009-03-12
申请号：PCT/US2008/074906
申请日：2008-08-29
申请人： HEADWATERS TECHNOLOGY INNOVATION, LLC , ZHOU, Bing , ZHANG, Cheng
发明人： ZHOU, Bing , ZHANG, Cheng
IPC分类号： B22F1/00 , B82B1/00 , B82B3/00
CPC分类号： C01B3/0021 , B82Y30/00 , F17C11/005 , Y02E60/325 , Y10S420/90 , Y10S977/70 , Y10S977/84 , Y10T29/49826 , Y10T428/2991
摘要： Hydrogen is stored by adsorbing the hydrogen to a carbon nanomaterial that includes carbon nanospheres. The carbon nanospheres are multi- walled, hollow carbon nanostructures with a maximum diameter in a range from about 10 nm to about 200 nm. The nanospheres have an irregular outer surface and an aspect ratio of less than 3: 1. The carbon nanospheres can store hydrogen in quantities of at least 1.0% by weight.
摘要翻译：通过将氢吸附到包括碳纳米球的碳纳米材料上来储存氢。碳纳米球是多壁的中空碳纳米结构，其最大直径在约10nm至约200nm的范围内。纳米球具有不规则的外表面和小于3:1的纵横比。碳纳米球可以以至少1.0重量％的量存储氢。

17. 发明申请

WO2008042670A1 METHODS FOR MANUFACTURING BI-METALLIC CATALYSTS HAVING A CONTROLLED CRYSTAL FACE EXPOSURE 审中-公开
标题翻译：用于制造具有受控晶体面暴露的双金属催化剂的方法
公开(公告)号：WO2008042670A1
公开(公告)日：2008-04-10
申请号：PCT/US2007/079555
申请日：2007-09-26
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , ZHOU, Zhenhua , WU, Zhihua , ZHANG, Cheng , ZHOU, Bing
发明人： ZHOU, Zhenhua , WU, Zhihua , ZHANG, Cheng , ZHOU, Bing
IPC分类号： B01J23/02
CPC分类号： C01B15/029 , B01J23/44 , B01J35/0013 , B01J37/0203 , B01J37/0211 , B01J37/18
摘要： Improved bi-metallic nanocatalysts are manufactured using a control agent to produce nanoparticles having a controlled crystal face exposure. The bi-metallic nanocatalyst particles are manufactured in a two-step process. In a first step, nanocatalyst particles are manufactured using the control agent and the primary metal atoms. The primary metal atoms and the control agent are reacted to form complexed metal atoms. The complexed metal atoms are then allowed or caused to form nanoparticles. The nanoparticles formed in the first step using the control agent have a desired crystal face exposure. In a second step, the secondary metal atoms are deposited on the surface of the primary metal nanoparticles. The secondary catalyst atoms maintain the same crystal face exposure as the primary metal nanoparticles.
摘要翻译：使用控制剂制备改进的双金属纳米催化剂以产生具有受控晶面曝光的纳米颗粒。双金属纳米催化剂颗粒以两步法制备。在第一步中，使用控制剂和主要金属原子制造纳米催化剂颗粒。使主要金属原子和控制剂反应形成络合的金属原子。然后允许或引起络合的金属原子形成纳米颗粒。使用控制剂在第一步中形成的纳米颗粒具有所需的晶面曝光。在第二步中，二次金属原子沉积在一次金属纳米粒子的表面上。二次催化剂原子保持与主要金属纳米颗粒相同的晶面暴露。

18. 发明申请

WO2008016956A2 METHODS FOR MANUFACTURING ARY-ARYL COUPLED POLYMERS 审中-公开
标题翻译：制备芳族 - 芳族偶联聚合物的方法
公开(公告)号：WO2008016956A2
公开(公告)日：2008-02-07
申请号：PCT/US2007/074922
申请日：2007-08-01
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , LIU, Changkun , ZHOU, Bing
发明人： LIU, Changkun , ZHOU, Bing
IPC分类号： C08G79/02
CPC分类号： C08G61/12 , C08G61/02 , C08G61/123 , C08G61/126 , C08G2261/124 , C08G2261/3142 , C08G2261/3162 , C08G2261/3223 , C08G2261/3243 , C08G2261/3246 , H01L51/0039 , H01L51/0043
摘要： Aryl-aryl coupled polymers are manufactured using a water-soluble noble metal catalyst. The hydrophilicity of the catalyst facilitates the separation of the catalyst from the polymer product. The method can be generally carried out by preparing a reaction medium comprising an aqueous phase and an organic phase. A water-soluble noble metal catalyst is dispersed in the aqueous phase. A base is also dispersed in the aqueous phase. An aryl-aryl coupled polymer is formed in the reaction medium by (i) adding at least one polymerizable monomer to the reaction mixture; and (ii) mixing the aqueous phase with the organic phase to cause polymerization of the monomer through an aryl-aryl coupling reaction. The polymer has a greater solubility in the organic phase than the aqueous phase. Allowing the organic phase to separate from the aqueous phase separates the water soluble catalyst from the polymer. The reaction can be used to manufacture high molecular weight polymers (e.g., at least 10,000 g/mole) with low quantities of residual metal (e.g., less than 20 ppm).
摘要翻译：使用水溶性贵金属催化剂制造芳基 - 芳基偶联聚合物。催化剂的亲水性有利于催化剂与聚合物产物的分离。该方法通常可以通过制备包含水相和有机相的反应介质来进行。水溶性贵金属催化剂分散在水相中。碱也分散在水相中。通过（i）将至少一种可聚合单体加入到反应混合物中，在反应介质中形成芳基 - 芳基偶联聚合物; 和（ii）将水相与有机相混合以引起单体通过芳基 - 芳基偶联反应进行聚合。聚合物在有机相中的溶解度高于水相。让有机相与水相分离，将水溶性催化剂从聚合物中分离出来。该反应可用于制备具有低量残余金属（例如小于20ppm）的高分子量聚合物（例如至少10,000克/摩尔）。

19. 发明申请

WO2007084904A3 METHODS FOR MANUFACTURING FUNCTIONALIZED INORGANIC OXIDES AND POLYMERS INCORPORATING SAME 审中-公开
公开(公告)号：WO2007084904A3
公开(公告)日：2007-07-26
申请号：PCT/US2007/060610
申请日：2007-01-17
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , ZHOU, Bing , LIU, Changkun , REYES, Clementine
发明人： ZHOU, Bing , LIU, Changkun , REYES, Clementine
IPC分类号： B01D15/00 , C02F1/42
摘要： Inorganic oxide substrates axe functionalized with silicon-free organic functionalizing agents. The organic functionalizing agent has a bonding functional group for bonding to the substrate and a functionalizmg moiety that is not bonded to the substrate for imparting a desired functionality to the substrate. The functionalized inorganic oxide substrates are manufactured by selecting a functionalizing agent and reaction conditions that allows the bonding functional group to bond to the inorganic material while leaving the functionalizing moiety available for providing the desired functionality. The functionalized inorganic oxides can be used as filler materials in polymers or to manufacture a supported nanoparticle catalyst.

20. 发明申请

WO2006121553A3 METHODS FOR MANUFACTURING SUPPORTED NANOCATALYSTS AND METHODS FOR USING SUPPORTED NANOCATALYSTS 审中-公开
公开(公告)号：WO2006121553A3
公开(公告)日：2006-11-16
申请号：PCT/US2006/013227
申请日：2006-04-10
申请人： HEADWATERS TECHNOLOGY INNOVATION LLC , REYES, Clementine , PARASHER, Sukesh , ZHOU, Bing
发明人： REYES, Clementine , PARASHER, Sukesh , ZHOU, Bing
IPC分类号： B01J31/00
摘要： Supported nanocatalysts are manufactured by reacting a functionalized support with a plurality of catalyst atoms in the presence of a solvent. Available functional groups on the support material bind to the catalyst atoms and influence nanoparticle formation and/or nanoparticle anchoring. The functionalized support can be manufactured from a support material and a functionalizing agent that has at least two functional groups for bonding individual functionalizing agent molecules both to the support and to the catalyst atoms. Supported palladium nanocatalysts manufactured using the methods of the present invention are particularly useful for performing Heck and Suzuki carbon-carbon coupling reactions.

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