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11. 发明授权

US4921540A Corrosion inhibiting pigments based on zinc silicate their production and their use 失效
标题翻译：基于硅酸锌的防腐颜料的生产及其用途
公开(公告)号：US4921540A
公开(公告)日：1990-05-01
申请号：US26694
申请日：1987-03-13
申请人： Manfred Gawol , Gerhard Adrian
发明人： Manfred Gawol , Gerhard Adrian
IPC分类号： C09C1/04 , C09C1/28 , C09D5/08
CPC分类号： C09C1/28 , C01P2004/61
摘要： Corrosion inhibiting pigments on the basis of zinc silicate are produced from 35-65% by weight of ZnO, 15-35% by weight of SiO.sub.2, 5-20% by weight of B.sub.2 O.sub.3, and 1-20% by weight of WO.sub.3 which can be entirely or partly substituted by, MoO.sub.3 and/or SnO.sub.2 wherein the amount of zinc silicate, boron oxide and, if necessary, the other metal oxides or their hydrates singly or in a combination thereof is such that the entire combination with the zinc silicate and the boron oxide contains at least one of the oxides WO.sub.3, MoO.sub.3 and/or SnO.sub.2 in amounts bringing the balance to 100%. The pigments can be manufactured by dry mixing of the components, melting for 1-3 hours at 1100.degree. C.-1400.degree. C. and subsequent grinding to desired fineness.
摘要翻译： PCT No.PCT / EP86 / 00505 Sec。 371日期1987年3月13日 102（e）日期1987年3月13日PCT申请日1986年8月28日PCT公布。第WO87 / 01714号公报日期：1987年3月26日。以硅酸锌为基础的防腐颜料为35-65重量％的ZnO，15-35重量％的SiO 2，5-20重量％的B 2 O 3和1-20 可以完全或部分地被MoO 3和/或SnO 2代替的WO 3的重量％，其中硅酸锌，氧化硼和必要时，其它金属氧化物或其水合物的量单独或组合使用的量使得与硅酸锌和氧化硼的全部组合含有使余量为100％的量的至少一种氧化物WO 3，MoO 3和/或SnO 2。颜料可以通过干混合组分制造，在1100℃-1400℃下熔融1-3小时，随后研磨成所需的细度。

12. 发明授权

US4400365A Method for the manufacture of aluminum zinc phosphate hydrates or basic aluminum zinc phosphate hydrates 失效
标题翻译：制造磷酸铝锌水合物或碱式磷酸铝锌水合物的方法
公开(公告)号：US4400365A
公开(公告)日：1983-08-23
申请号：US326184
申请日：1981-12-01
申请人： Wigo Haacke , Gerhard Adrian , Manfred Gawol , Rainer Henbach , 37
发明人： Wigo Haacke , Gerhard Adrian , Manfred Gawol , Rainer Henbach , 37
IPC分类号： C01B25/45 , C09C1/00 , C09C1/04 , C09C1/40 , C09D5/08 , C01B15/16 , C01B25/26
CPC分类号： C09C1/40 , C01B25/45 , C09D5/084 , C01P2002/08
摘要： Aluminum zinc phosphate hydrates or basic aluminum zinc phosphate hydrates are manufactured by reacting 1 mole of aluminum hydrogen phosphate with from 2.4 to 4 moles of zinc oxide, if necessary with the addition of up to 0.4 moles of alkali aluminate or the equivalent quantity of alkali hydroxide. A 50% by weight acidic aluminum hydrogen phosphate solution is preferably used for the reaction which is carried out at an elevated temperature in the range from 30.degree. to 80.degree. C. The aluminum zinc phosphate hydrates produced by the method are useful anti-corrosion pigments for use in paints.
摘要翻译：磷酸铝锌水合物或碱式磷酸铝锌水合物通过使1摩尔磷酸氢铝与2.4至4摩尔氧化锌反应制备，如果需要，加入高达0.4摩尔碱金属铝酸盐或等量的碱金属氢氧化物。优选使用50重量％酸式磷酸氢铝溶液进行反应，该反应在30℃至80℃的高温下进行。通过该方法生产的磷酸铝锌水合物是有用的防腐颜料用于油漆。

13. 发明授权

US11820671B2 Solid body having dyeing properties 有权
公开(公告)号：US11820671B2
公开(公告)日：2023-11-21
申请号：US16637292
申请日：2018-08-09
申请人： Heubach GmbH
发明人： Dieter Lieske , Maria Kubica , Stephan Blöss
IPC分类号： C01G45/00 , C01B19/00 , C09C1/02 , C09C1/04 , C09C1/22
CPC分类号： C01G45/006 , C01B19/002 , C09C1/02 , C09C1/04 , C09C1/22 , C01P2002/52
摘要： The invention relates to a solid body of a compound of formula Zn1-t-eTtEeO1-yYy, wherein the compound has a wurtzite structure and wherein T represents one or more transition metals, selected from one or more of Mn, Cd, Cr, Fe, Co and Ni; E represents one or more alkaline earth metals, selected from one or more of Be, Mg, Ca, Sr and Ba; Y represents one or more chalcogens, selected from S, Se, Te; tis a value in the region of 0 to

14. 发明申请

US20120160130A1 TINTING SYSTEM FOR PRODUCING A DEFINED NUMBER OF SHADES OF A PAINT READY FOR USE, INCLUDING ASSOCIATED COMPONENTS 审中-公开
标题翻译：用于生产用于使用的准备好的编号的定影系统的调色系统，包括相关组件
公开(公告)号：US20120160130A1
公开(公告)日：2012-06-28
申请号：US13375678
申请日：2010-06-01
申请人： Rainer Heubach
发明人： Rainer Heubach
IPC分类号： C09D1/00 , G09B19/00
CPC分类号： C09B67/0097 , B05C17/0103 , B05C17/0116 , B44D3/003 , B44D3/08 , C08K3/013 , C08K3/22 , C08K3/30 , C08K5/0041 , C09D7/41 , C09D7/61 , C09D7/80 , C09D17/00
摘要： A tinting system for producing a defined number of shades of a paint ready for use characterized by: (a) a dye set, (b) a color identification means, and (c) plurality of metering means for accommodating a shade component, and a brightening component. Each metering means being designed to manually meter the respective dye component and to exactly reproduce the number of shades defined by the color identification means.
摘要翻译：一种着色系统，用于制造准备使用的油漆的规定数量的阴影，其特征在于：（a）染料组，（b）颜色识别装置，和（c）多个用于容纳遮光部件的计量装置，以及增亮组分。每个计量装置被设计成手动地测量相应的染料成分并准确地再现由颜色识别装置限定的色调数量。

15. 发明授权

US07824487B2 Rutile-based pigment and a method for the production thereof 失效
标题翻译：金红石型颜料及其制造方法
公开(公告)号：US07824487B2
公开(公告)日：2010-11-02
申请号：US11676804
申请日：2007-02-20
申请人： Rainer Heubach
发明人： Rainer Heubach
IPC分类号： C09C1/36 , C01G23/00 , C01G27/00 , C01G23/02 , C01G23/047
CPC分类号： C09C1/0084 , B02C17/16 , B02C17/20 , B02C17/22 , C01P2002/30 , C01P2002/52 , C01P2004/51 , C01P2004/53 , C01P2004/62 , C01P2004/80 , C01P2006/80 , C09C1/0096 , C09C1/34 , C09C1/36 , C09C1/3623 , C09C3/041
摘要： The invention covers a fine-particle, brilliant and strongly hiding rutile-based pigment that is devoid of any metal or reactive metal compounds relevant to mill abrasion detectable by application technology but whose particle-size in terms of particle diameters ranges from 50 to 1000 nm, for mono-, bi-, tri- or oligo-modal size distribution and a primary maximum ranges from 230 to 400 nm, wherein optionally for a bi- or poly-modal frequency distribution, a secondary maximum is less than 25% of the primary maximum between 400 and 1000 nm. The process for producing said pigment comprises treating an inorganic mixed-phase rutile structured oxide pigment by high-speed grinding in suspension in a ball grinding mill provided with a mechanically and chemically resistant coating until said particle-size and a substantially isometric rounded particle shape are attained. The invention optionally provides for viscosity adjustment and surface conditioning of the pigment. The inventive pigment differs from prior art by improved gloss, low whiteness or reduced whitening, relatively high hue saturation, by extremely high hiding power which had been unattainable in said class of products up to now and exhibits a low photoactivity with respect to known fine-particle rutiles. In practice neither abrasivity nor interaction of possible grinding residues with an application matrix are observed.
摘要翻译：本发明涵盖了微粒，辉光和强烈隐藏的金红石型颜料，其没有任何金属或反应性金属化合物，其与通过应用技术可检测的研磨磨损相关，但是其粒径在粒径范围为50至1000nm ，对于单，双，三或寡模态尺寸分布，并且初级最大值范围为230-400nm，其中任选地对于双模或多模式频率分布，二次最大值小于初级最大值在400和1000 nm之间。制备所述颜料的方法包括：将无机混合相金红石结构氧化物颜料通过在具有机械和耐化学腐蚀性涂层的球磨机中悬浮高速研磨直到所述颗粒尺寸和基本上等长的圆形颗粒形状达到了本发明任选地提供颜料的粘度调节和表面调节。本发明的颜料与现有技术不同，通过改善光泽度，低白度或减少白度，相对较高的色相饱和度，通过迄今为止在所述类别的产品中无法实现的极高的遮盖力，并且相对于已知的细小颜料显示出低的光活性，颗粒金红石。实际上，不会观察到可能研磨残留物与应用基质的磨损性和相互作用。

16. 发明授权

US4412658A Method and a device for manufacturing partially oxidized lead dust 失效
标题翻译：方法和制造部分氧化铅粉尘的装置
公开(公告)号：US4412658A
公开(公告)日：1983-11-01
申请号：US253532
申请日：1981-04-13
申请人： Rainer Heubach , Reinhard Marx , Dieter Hauke
发明人： Rainer Heubach , Reinhard Marx , Dieter Hauke
IPC分类号： H01M4/56 , B02C17/00 , B02C17/18 , C01G21/02 , H01M4/57
CPC分类号： B02C17/00 , B02C17/18 , C01G21/02 , H01M4/57 , C01P2006/12
摘要： In a process and a device for manufacturing partially oxidized lead dust from lead pieces, the natural pile of dissociated coarse and fine material formed in a rotating drum is mechanically disturbed by radially extending guide plates in the interior of a drum which plates are arranged in pairs and displaced toward each other by 180.degree. in the direction of the circumference of the drum and the individual plates of each pair of plates are spaced axially apart, by which arrangement the efficiency of the process and the product quality are greatly improved.
摘要翻译：在用于从铅片制造部分氧化的铅粉尘的工艺和装置中，形成在旋转鼓中的解离的粗细和细材料的天然绒头由鼓的内部的径向延伸的引导板机械地扰乱，所述导板在成对布置并且在鼓的圆周方向上彼此相对移动180度，并且每对板的各个板轴向间隔开，通过该布置，工艺的效率和产品质量得到极大的改善。

17. 发明申请

WO2010139694A3 TINTING SYSTEM FOR PRODUCING A DEFINED NUMBER OF SHADES OF A PAINT READY FOR USE, INCLUDING ASSOCIATED COMPONENTS 审中-公开
标题翻译：着色用于生产用途画完颜色的阴影的确定的号码，包括相关的组件
公开(公告)号：WO2010139694A3
公开(公告)日：2011-04-07
申请号：PCT/EP2010057645
申请日：2010-06-01
申请人： HEUBACH GMBH , HEUBACH RAINER
发明人： HEUBACH RAINER
IPC分类号： B24D15/00 , C09B67/00
CPC分类号： C09B67/0097 , B05C17/0103 , B05C17/0116 , B44D3/003 , B44D3/08 , C08K3/013 , C08K3/22 , C08K3/30 , C08K5/0041 , C09D7/41 , C09D7/61 , C09D7/80 , C09D17/00
摘要： The invention relates to a dye set and a color identification means. A main concept of the invention is to combine the dye set and the color identification means into a tinting system for producing a defined number of shades of a paint ready for use. The tinting system according to the invention is characterized by: (a) a dye set according to the invention, (b) a color identification means according to the invention, and (c) a first metering means for accommodating the substrate component, a second metering means in each case for accommodating each shade component, and a third metering means for accommodating the brightening component, each metering means being designed to manually meter the respective dye component and to exactly reproduce the number of shades defined by the color identification means. The invention further relates to a method for producing a paint ready for use using the described tinting system and to the use of in particular syringes to provide a paint ready for use.
摘要翻译：本发明涉及一种着色剂组和彩色识别装置。本发明的主要思想是将染料组组合并在用于生产一个所定义的准备喷漆的色调的数目的调色系统的颜色识别装置。根据本发明的着色系统的特征在于：（a）一种Farbmitteisatz根据本发明，（b）一种颜色识别装置根据本发明的和（c）第一计量装置，用于接收基底部件，在第二计量装置，用于接收每个颜色分量和一个第三计量每一种情况下用于接收的Aufhellkomponente，每个计量装置被设计为相应的着色剂成分的手动分配和通过颜色识别号的装置定义的颜色的准确再现。本发明还涉及一种方法，用于生产准备漆用上述着色系统和用于提供即用涂料中使用特别是注射器。

18. 发明申请

WO2006021354A3 RUTILE-BASED PIGMENT AND A METHOD FOR THE PRODUCTION THEREOF 审中-公开
标题翻译：颜料ON金红石基地和生产方法
公开(公告)号：WO2006021354A3
公开(公告)日：2007-04-12
申请号：PCT/EP2005008892
申请日：2005-08-16
申请人： HEUBACH GMBH , HEUBACH RAINER
发明人： HEUBACH RAINER
IPC分类号： C09C3/04 , B02C17/20 , B02C17/22 , C09C1/00 , C09C1/34
CPC分类号： C09C1/0084 , B02C17/16 , B02C17/20 , B02C17/22 , C01P2002/30 , C01P2002/52 , C01P2004/51 , C01P2004/53 , C01P2004/62 , C01P2004/80 , C01P2006/80 , C09C1/0096 , C09C1/34 , C09C1/36 , C09C1/3623 , C09C3/041
摘要： The invention relates to a fine-particle, bright and high-coating rutile-based pigment which is characterised in that it is devoid of any metal or reactive metal compounds relevant to mill abrasion detectable by application technology but whose grain-size in terms of particle diameters ranges from 50 to 1000 nm, for mono-, bi-, tri- or oligo-modal size distribution and a primary maximum ranges from 230 to 400 nm, wherein optionally for a bi- or poly-modal frequency distribution, a secondary maximum is less than 25 % of the primary maximum between 400 and 1000 nm. The method for producing said pigment consists in treating an organic mixed-phase rutile structured oxide pigment by high-speed grinding in suspension in a ball grinding mill provided with a mechanically and chemically resistant coating until said grain-size and a substentially isometric rounded particle shape are attained. According to the invention, means for viscosity adjustment and surface conditioning of the pigment are also provided. The inventive pigment differs from prior art by improved brightness, low whiteness or low lightness, relatively high hue saturation and by extremely high covering power which is not obtainable in said class of products up to now and exhibits a low photoactivity with respect to known fine-particle rutiles. In practice no abrasivity, neither interaction of possible grinding residues with an application matrix is observed.
摘要翻译：公开了一种细颗粒，明亮，且高遮盖颜料金红石基。这是其特征在于，它示出了反应性金属或作为其结果铣刀的磨损的金属化合物的任何应用程序相关的内容，但用50和1000纳米和单 - ，二，三或230之间的Hauptma ximum的oligomodal频率分布和之间的粒径的粒径分布包括400纳米，任选地具有400和1000之间的主要最大纳米以双峰或多峰的频率分布的发生低于25％的次级最大值。用于制造这样的颜料的方法，其特征在于，直到上述的粒度分布给予和几乎等距圆形，与由高性能研磨金红石结构的无机混合相氧化物颜料在悬浮液进行处理以化学和机械抗拉内衬搅拌球磨机已设置的粒子。助剂以调整本发明的颜料的粘度和表面调节是在这种情况下任选地提供。如上所述的颜料的特征在于，在由改进的光泽度，减少的白度或白化少，相对较高的色饱和度，以及现有技术的非常高的，以前没有在这个类遮盖力的使用，而在相对于所述细碎金红石根据现有技术的低光活性相同出。此外，还有在实践中无不良磨损并没有与应用矩阵中的任何咖啡渣滓的互动。

19. 发明申请

WO1989008131A1 IMPROVED CHROME YELLOW AND MOLYBDENUM ORANGE PIGMENTS, PROCESS FOR PRODUCING THEM, AND THEIR USE 审中-公开
标题翻译：改良的黄酮和黄原胶，其生产方法及其使用
公开(公告)号：WO1989008131A1
公开(公告)日：1989-09-08
申请号：PCT/EP1989000167
申请日：1989-02-23
申请人： DR. HANS HEUBACH GMBH & CO. KG , RESSLER, Ingrid , ADRIAN, Gerhard , HORN, Walter
发明人： DR. HANS HEUBACH GMBH & CO. KG
IPC分类号： C09C01/20
CPC分类号： C09C1/20 , C09C3/063
摘要： Heat-stable, brilliantly coloured chrome yellow and molybdenum orange pigments possess excellent fastness to temperature, light, weathering, alkalis and acids, high resistance to SO2 and a significantly reduced acid-soluble lead content. The pigments are prepared by applying to chrome yellow and molybdenum orange pigments, previously stabilized in the customary manner with metallic oxides and/or silicic acid, a layer of silicic acid in the form of a dense amorphous envelope of silicic acid, followed by one or more layers of antimony oxide/silicic acid and a final, precipitated layer of aluminium oxide and/or alkaline earth phosphate. These pigments are eminently suitable for pigmentation of plastics, in particular coating substances and moulding materials.

20. 发明申请

WO1987005040A1 NEW ANTICORROSIVE PIGMENTS, PREPARATION AND UTILIZATION THEREOF 审中-公开
标题翻译：新的抗菌色素，其制备和利用
公开(公告)号：WO1987005040A1
公开(公告)日：1987-08-27
申请号：PCT/EP1987000071
申请日：1987-02-13
申请人： DR. HANS HEUBACH GMBH & CO. KG , GAWOL, Manfred , ADRIAN, Gerhard
发明人： DR. HANS HEUBACH GMBH & CO. KG
IPC分类号： C09C03/06
CPC分类号： C09C1/40 , C01P2006/80 , C09C1/00 , C09C1/0003 , C09C1/0081 , C09C1/0084 , C09C1/02 , C09C1/04 , C09C1/22 , C09C1/3692 , C09C3/006 , C09C3/06 , C09C3/063 , C09C3/08 , C09D5/084
摘要： The anticorrosive pigments disclosed contain metal oxides, metal phosphates and/or molybdate based on the metals zinc, aluminium, iron, baryum, strontium, calcium, magnesium and titanium, isolated or associated, contain in addition between 0.03 and 2% by weight of soluble sodium bichromate or an equivalent quantity of potassium bichromate or ammonium bichromate or equivalent quantities of corresponding chromates or chromic acids. Said pigments are prepared by total homogenization of the chromate parts and are used as sizing on ferrous or non-ferrous metal bases.
摘要翻译：所公开的防腐颜料包含金属氧化物，金属磷酸盐和/或钼酸盐，基于分离或相关的金属锌，铝，铁，重金属，锶，钙，镁和钛，还含有0.03-2重量％的可溶重铬酸钠或等量的重铬酸钾或重铬酸铵或等量的相应的铬酸盐或铬酸。所述颜料通过铬酸盐部分的均匀化而制备，并用作铁基或有色金属基体上的施胶。

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