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11. 发明授权

US08039545B2 Functionalized polymers 有权
标题翻译：官能化聚合物
公开(公告)号：US08039545B2
公开(公告)日：2011-10-18
申请号：US12254284
申请日：2008-10-20
申请人： Yuan-Yong Yan
发明人： Yuan-Yong Yan
IPC分类号： C08C19/25 , C08C19/22 , C08F8/30 , C08K3/36 , C08L23/36
CPC分类号： C08C19/44 , C08C19/30 , C08L19/006
摘要： A functionalized polymer includes a polymer chain and a terminal group linked to the chain through a functionality that contains one or more urethane groups. The functionalized polymer can be provided by reacting a nucleophile with a polymer having terminal iso(thio)cyanate functionality which, in turn, can be provided by reacting a terminally active polymer with a polyiso(thio)cyanate. Even polymers that contain substantial amounts of styrene mer can be used in the described process.
摘要翻译：官能化聚合物包括聚合物链和通过包含一个或多个氨基甲酸酯基的官能团与链连接的端基。官能化聚合物可以通过使亲核试剂与具有末端异（硫代）氰酸酯官能团的聚合物反应来提供，其又可以通过使末端活性聚合物与多异（硫代）氰酸酯反应来提供。即使是含有大量苯乙烯聚合物的聚合物也可用于所述方法中。

12. 发明授权

US07999029B2 Polyhedral-modified polymer 有权
标题翻译：多面体改性聚合物
公开(公告)号：US07999029B2
公开(公告)日：2011-08-16
申请号：US11666853
申请日：2005-11-02
申请人： Yuan-Yong Yan , Jason Poulton , Takayuki Yako , Xiaorong Wang , Hao Wang , Michelle A. Cottrell
发明人： Yuan-Yong Yan , Jason Poulton , Takayuki Yako , Xiaorong Wang , Hao Wang , Michelle A. Cottrell
IPC分类号： C08L51/10 , C08K3/04
CPC分类号： C08L19/006 , C08C19/44 , C08F291/00 , C08K3/013 , C08L15/00 , C08L51/10
摘要： A macromolecule including a polymer and a polyhedral radical chemically bonded to a terminus of the polymer provides numerous processing and performance advantages. Further functionalization of this macromolecule also is described as being advantageous in certain circumstances. Methods of providing, functionalizing, and utilizing the macromolecule also are provided.
摘要翻译：化学键合到聚合物末端的聚合物和多面体基团的大分子提供许多加工和性能优点。这种大分子的进一步官能化也被描述为在某些情况下是有利的。还提供了提供，功能化和利用大分子的方法。

13. 发明授权

US07884160B2 Non-spherical nanoparticles made from living triblock polymer chains 有权
标题翻译：由活性三嵌段聚合物链制成的非球形纳米颗粒
公开(公告)号：US07884160B2
公开(公告)日：2011-02-08
申请号：US11641514
申请日：2006-12-19
申请人： Xiaorong Wang , Mindaugas Rackaitis , Victor J. Foltz , Edward D. Kelley , Yuan-Yong Yan
发明人： Xiaorong Wang , Mindaugas Rackaitis , Victor J. Foltz , Edward D. Kelley , Yuan-Yong Yan
IPC分类号： B32B27/00 , C08L53/02 , C08L21/00
CPC分类号： C08F297/04 , B82Y30/00 , C08F257/02 , C08F285/00 , C08K2201/011 , C08L21/00 , C08L53/02 , C09D153/02 , C08L2666/24 , C08L2666/02
摘要： The present invention provides polymeric nanoparticles comprising triblock and optionally diblock copolymer chains. The architecture of the polymeric nanoparticles may be controlled, resulting in nanoparticles having non-spherical shapes. The present invention also provides a method of preparing the polymeric nanoparticles and a rubber article such as a tire manufactured from a formulation comprising the polymer nanoparticles.
摘要翻译：本发明提供了包含三嵌段和任选的二嵌段共聚物链的聚合物纳米颗粒。可以控制聚合物纳米颗粒的结构，导致具有非球形形状的纳米颗粒。本发明还提供了制备聚合物纳米颗粒的方法和由包含聚合物纳米颗粒的制剂制成的橡胶制品，例如轮胎。

14. 发明申请

US20090326176A1 NOVEL MULTIFUNCTIONAL INITIATORS FOR ANIONIC POLYMERIZATION AND POLYMERS THEREFROM 审中-公开
标题翻译：用于阴离子聚合的新型多功能发射体及其聚合物
公开(公告)号：US20090326176A1
公开(公告)日：2009-12-31
申请号：US12344653
申请日：2008-12-29
申请人： Yuan-Yong Yan
发明人： Yuan-Yong Yan
IPC分类号： C08F4/48 , C07F1/02 , C08G73/00
CPC分类号： C08F4/488 , B60C1/00 , C07C211/65 , C08C19/44 , C08F36/06 , C08G73/0213 , C08L9/06
摘要： The embodiments of the invention relate to a multifunctional lithiated amine-containing compound comprising at least two molecules of lithiated amine in a molecule of the compound. In one embodiment, the compound has a formula where x is an integer of 1 or more, Q is (a) an element selected from the group consisting of O, S, N, P and Si or (b) an alkylene group having from 1 to 20 methylene groups, and R1 and R2 are the same or different and are selected from the group consisting of alkyls, cycloalkyls and aralkyls containing from 1 to 20 carbon atoms. In another embodiment, the compound comprises cyclic lithio amines and has a formula: where x is 1 or more, R3, R4 and R5 are the same or different and represent alkylene groups containing from 3 to 20 carbon atoms.
摘要翻译：本发明的实施方案涉及在化合物的分子中包含至少两个锂化胺分子的多官能含锂化胺化合物。在一个实施方案中，该化合物具有其中x为1或更大的整数的式，Q为（a）选自O，S，N，P和Si的元素或（b） 1至20个亚甲基，R 1和R 2相同或不同，并且选自含有1至20个碳原子的烷基，环烷基和芳烷基。在另一个实施方案中，该化合物包含环状硫代胺并具有下式：其中x为1或更多，R 3，R 4和R 5相同或不同，并且表示含有3至20个碳原子的亚烷基。

15. 发明授权

US07517936B2 Curable sealant composition 有权
标题翻译：可固化的密封剂组合物
公开(公告)号：US07517936B2
公开(公告)日：2009-04-14
申请号：US10552122
申请日：2004-04-02
申请人： Takayuki Yako , Jason T. Poulton , Yuan-Yong Yan
发明人： Takayuki Yako , Jason T. Poulton , Yuan-Yong Yan
IPC分类号： C08C19/25 , C08F36/04 , C08L9/00
CPC分类号： C08C19/44 , C09J115/00
摘要： A curable sealant composition is provided. The composition includes a polymer including at least conjugated dime contributed monomer units in a backbone of the polymer and terminal groups including silicon. The composition also includes additional sealant ingredients selected from the group consisting of plasticizers, filler, reinforcing agents, modifiers, curing catalysts/hardeners, stabilizers, and mixtures thereof.
摘要翻译：提供可固化的密封剂组合物。该组合物包括在聚合物的主链和至少包括硅的末端基团中至少包含缀合的珠粒贡献的单体单元的聚合物。该组合物还包括选自增塑剂，填料，增强剂，改性剂，固化催化剂/硬化剂，稳定剂及其混合物的另外的密封剂成分。

16. 发明申请

US20080146745A1 POLYMERS FUNCTIONALIZED WITH PROTECTED OXIME COMPOUNDS 有权
标题翻译：具有保护的氧化物的聚合物
公开(公告)号：US20080146745A1
公开(公告)日：2008-06-19
申请号：US11955437
申请日：2007-12-13
申请人： Steven Luo , Yuan-Yong Yan , Jason T. Poulton , Eiju Suzuki
发明人： Steven Luo , Yuan-Yong Yan , Jason T. Poulton , Eiju Suzuki
IPC分类号： C08C19/22 , C08C19/25 , C08C19/20
CPC分类号： C08C19/44 , C08L9/00 , C08L19/006 , C08L2666/08
摘要： A method for preparing a functionalized polymer, the method comprising the steps of (i) polymerizing conjugated diene monomer by employing a lanthanide-based catalyst to form a reactive polymer, and (ii) reacting the reactive polymer with a protected oxime compound.
摘要翻译：一种制备官能化聚合物的方法，所述方法包括以下步骤：（i）通过使用镧系元素基催化剂聚合共轭二烯单体以形成反应性聚合物，和（ii）使反应性聚合物与受保护的肟化合物反应。

17. 发明申请

US20080027171A1 Functionalized polymer 有权
标题翻译：官能化聚合物
公开(公告)号：US20080027171A1
公开(公告)日：2008-01-31
申请号：US11880733
申请日：2007-07-24
申请人： Yuan-Yong Yan , Dennis R. Brumbaugh , Steven Luo
发明人： Yuan-Yong Yan , Dennis R. Brumbaugh , Steven Luo
IPC分类号： C08C19/22
CPC分类号： C08C19/44 , C08C19/22 , C08F8/30 , C08K5/24 , C08L15/00
摘要： A polymer includes directly bonded aromatic pendent groups and at least one moiety defined by one of the following formulas >N—N═CR1R2 or —N═N—CR1R2— where R1 and R2 (a) are independently H or a substituted or unsubstituted alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl, allyl, aralkyl, alkaryl, or alkynyl group, or (b) together form a substituted or unsubstituted alkylene, alkenylene, cycloalkylene, cycloalkenylene, or arylene group. The moiety can be attached to the polymer through one or both of the two open bonds and, where it is attached through only one bond, the other bond attaches to a hydrogen atom, i.e., the moiety is at a terminus of the polymer. Such polymers can be used to provide compositions that also include particulate fillers.
摘要翻译：聚合物包括直接键合的芳香族侧基和至少一个由以下式之一定义的部分：<？in-line-formula description =“In-line formula”end =“lead”？>> NN-CR 1 或者-NN-CR 1 R 2 - <βin-line-formula description =“在线公式其中R 1和R 2（a）独立地为H或取代或未取代的烷基，烯基，环烷基，环烯基，芳基，烯丙基，芳烷基，烷芳基或炔基，或（b）一起形成取代或未取代的亚烷基，亚烯基，亚环烷基，亚环烯基或亚芳基。该部分可以通过两个开环中的一个或两个连接到聚合物上，并且其中仅通过一个键连接，另一个键连接到氢原子，即部分位于聚合物的末端。这样的聚合物可用于提供还包括颗粒填料的组合物。

18. 发明申请

US20070293620A1 Polyhedral-Modified Polymer 有权
标题翻译：多面体改性聚合物
公开(公告)号：US20070293620A1
公开(公告)日：2007-12-20
申请号：US11666853
申请日：2005-11-02
申请人： Yuan-Yong Yan , Jason Poulton , Takayuki Yako , Xiaorong Wang , Hao Wang , Michelle Cottrell
发明人： Yuan-Yong Yan , Jason Poulton , Takayuki Yako , Xiaorong Wang , Hao Wang , Michelle Cottrell
IPC分类号： C08L51/10 , C08K3/04 , C08L19/00
CPC分类号： C08L19/006 , C08C19/44 , C08F291/00 , C08K3/013 , C08L15/00 , C08L51/10
摘要： A macromolecule including a polymer and a polyhedral radical chemically bonded to a terminus of the polymer provides numerous processing and performance advantages. Further functionalization of this macromolecule also is described as being advantageous in certain circumstances. Methods of providing, functionalizing, and utilizing the macromolecule also are provided.
摘要翻译：化学键合到聚合物末端的聚合物和多面体基团的大分子提供许多加工和性能优点。这种大分子的进一步官能化也被描述为在某些情况下是有利的。还提供了提供，功能化和利用大分子的方法。

19. 发明申请

US20070083023A1 Use of sulfur containing initiators for anionic polymerization of monomers 有权
标题翻译：含硫引发剂用于单体阴离子聚合的用途
公开(公告)号：US20070083023A1
公开(公告)日：2007-04-12
申请号：US11607690
申请日：2006-12-02
申请人： Terrence Hogan , William Hergenrather , Yuan-Yong Yan , David Lawson
发明人： Terrence Hogan , William Hergenrather , Yuan-Yong Yan , David Lawson
IPC分类号： C08F136/00
CPC分类号： C08C19/44 , B60C1/0016 , C07F1/02 , C08F4/48 , C08F36/04 , C08K3/013 , Y02T10/862 , Y10S152/905 , C08L15/00
摘要： An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.
摘要翻译：提供用于阴离子聚合单体的引发剂，以在聚合物上提供功能性头基。还提供了具有衍生自含硫阴离子引发剂的功能性头基团和任选地作为由使用功能性终止试剂，偶联剂或连接剂引起的附加官能团的聚合物。提出了一种阴离子聚合单体的方法，包括使单体与含硫阴离子引发剂聚合的步骤，以在聚合物上提供功能性头基。还描述了包含功能聚合物和填料的弹性体化合物。还提供了由含有可硫化弹性体化合物的轮胎成分导致的滚动阻力降低的轮胎。

20. 发明授权

US06737470B1 Curable sealant composition 有权
标题翻译：可固化的密封剂组合物
公开(公告)号：US06737470B1
公开(公告)日：2004-05-18
申请号：US10408046
申请日：2003-04-04
申请人： Takayuki Yako , Yuan-Yong Yan , Jason T. Poulton
发明人： Takayuki Yako , Yuan-Yong Yan , Jason T. Poulton
IPC分类号： C08L8316
CPC分类号： C08C19/44 , C09J115/00
摘要： A curable sealant composition is provided. The composition includes a polymer including at least conjugated diene contributed monomer units in a backbone of the polymer and terminal groups including silicon. The composition also includes additional sealant ingredients selected from the group consisting of plasticizers, filler, reinforcing agents, modifiers, curing catalysts/hardeners, stabilizers, and mixtures thereof.
摘要翻译：提供可固化的密封剂组合物。该组合物包括在聚合物的主链中包含至少共轭二烯贡献的单体单元的聚合物和包括硅的末端基团的聚合物。该组合物还包括选自增塑剂，填料，增强剂，改性剂，固化催化剂/硬化剂，稳定剂及其混合物的另外的密封剂成分。

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