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11. 发明授权

US5792810A Curable coating composition including compound having carbamate and hydroxyl functionality 失效
标题翻译：可固化涂料组合物，包括具有氨基甲酸酯和羟基官能团的化合物
公开(公告)号：US5792810A
公开(公告)日：1998-08-11
申请号：US698524
申请日：1996-08-15
申请人： Gregory G. Menovcik , John D. McGee , Walter H. Ohrbom , Brian D. Bammel , Todd A. Seaver , John W. Rehfuss
发明人： Gregory G. Menovcik , John D. McGee , Walter H. Ohrbom , Brian D. Bammel , Todd A. Seaver , John W. Rehfuss
IPC分类号： C09D161/20 , C08G71/00 , C09D167/04 , C09D201/00 , C09D201/02 , C09D201/06 , C08J3/00 , C08K3/20 , C08L51/00 , C08L75/00
CPC分类号： C09D201/025 , C08G71/00 , C09D167/04 , C09D201/02 , C09D201/06 , Y10T428/31551
摘要： A curable coating composition is described comprising (A) a compound comprising carbamate or urea and hydroxyl functional groups that is the reaction product of (1) a compound comprising a carbamate or urea group or a group that can be converted to a carbamate or urea group, and an active hydrogen group that is reactive with a lactone or a hydroxy carboxylic acid, and (2) a lactone or a hydroxy carboxylic acid, (B) a compound comprising at least one group that is reactive with carbamate and at least one group that is reactive with hydroxyl, or a plurality of groups that are reactive with both carbamate and hydroxyl.
摘要翻译：描述了可固化涂料组合物，其包含（A）包含氨基甲酸酯或脲的化合物和羟基官能团，其是（1）包含氨基甲酸酯或脲基团的化合物或可转化为氨基甲酸酯或脲基团的基团的反应产物和与内酯或羟基羧酸反应的活性氢基，和（2）内酯或羟基羧酸，（B）至少一种与氨基甲酸酯反应的基团和至少一个基团其与羟基反应，或多个与氨基甲酸酯和羟基反应的基团。

12. 发明授权

US06423788B1 Curable coating composition 失效
标题翻译：可固化涂料组合物
公开(公告)号：US06423788B1
公开(公告)日：2002-07-23
申请号：US08686929
申请日：1995-10-06
申请人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Paul J. Harris , John W. Rehfuss
发明人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Paul J. Harris , John W. Rehfuss
IPC分类号： C09D17300
CPC分类号： C09D201/02 , C08G71/00 , C09D167/04 , C09D201/025 , Y10T428/31551
摘要： A curable coating composition is described comprising (A) a carbamate- or urea-functional compound that is the reaction product of a mixture comprising (1) a compound comprising a carbamate or urea group or a group that can be converted to carbamate or urea, and a hydroxyl functional group that is the reaction product of (a) a compound comprising a carbamate or urea group or a group that can be converted to a carbamate or urea group, and an active hydrogen group that is reactive with a lactone ring or a hydroxy carboxylic acid, and (b) a lactone or a hydroxy carboxylic acid, and (2) a compound that is reactive with hydroxyl groups on a plurality of molecules of compound (A)(1), but that is not reactive with the carbamate or urea groups on compound (A)(1), (B) a compound comprising a plurality of groups that are reactive with carbamate or urea.
摘要翻译：描述了可固化涂料组合物，其包含（A）氨基甲酸酯或脲官能化合物，其为包含（1）包含氨基甲酸酯或脲基团的化合物或可转化为氨基甲酸酯或脲的基团的混合物的反应产物，和作为（a）包含氨基甲酸酯或脲基的化合物或可以转化为氨基甲酸酯或脲基的基团的反应产物的羟基官能团以及与内酯环或羟基羧酸和（b）内酯或羟基羧酸，和（2）与多个化合物（A）（1）分子上的羟基反应但不与氨基甲酸酯反应的化合物或化合物（A）（1）上的脲基，（B）包含与氨基甲酸酯或脲反应的多个基团的化合物。

13. 发明授权

US06841619B2 Compound and coating compositions for adhesion to olefinic substrates 失效
标题翻译：用于粘附到烯烃底物的化合物和涂料组合物
公开(公告)号：US06841619B2
公开(公告)日：2005-01-11
申请号：US09907207
申请日：2001-07-17
申请人： John D. McGee , Daniel Blickberndt , Craig Schang , Walter H. Ohrbom , Keri Krueger
发明人： John D. McGee , Daniel Blickberndt , Craig Schang , Walter H. Ohrbom , Keri Krueger
IPC分类号： C08J7/04 , C08G63/00 , C08G63/08 , C08G65/26 , C08L53/00 , C08L71/02 , C09D5/00 , C09D7/12 , C09D153/00 , C09D161/28 , C09D201/00 , C09J5/02 , C08J3/00 , C08K3/04 , C08L67/02 , B32B31/20
CPC分类号： C08L71/02 , C08G63/00 , C08L53/005 , C09D5/002 , C09D7/65 , C09D201/00 , Y10T428/31909 , Y10T428/31913 , Y10T428/31917 , C08L2666/04 , C08L2666/24
摘要： The present invention provides an olefin-based block copolymer that has an olefin block that is substantially saturated and at least one (poly)ester or (poly)ether block. The olefin-based block copolymer of the invention can be prepared by reacting a liquid hydroxyl-functional, saturated or substantially saturated olefin polymer with a chain-extension reagent that is reactive with hydroxyl groups and will polymerize in a head-to-tail arrangement of monomer units. The olefin-based block copolymer of the invention can be used to prepare an adhesion promoter that provides excellent adhesion of subsequent coating layers to olefinic substrates like TPO and superior properties as compared to previously used adhesion promoters containing chlorinated polyolefins. Alternatively, the olefin-based copolymers of the invention can be used as an additive in a curable coating composition to provide excellent adhesion to olefinic substrates like TPO, even when used in very minor amounts compared to the amounts required for previously known agents.
摘要翻译：本发明提供一种具有基本上饱和的烯烃嵌段和至少一种（多）酯或（聚）醚嵌段的烯烃基嵌段共聚物。本发明的烯烃基嵌段共聚物可以通过使液体羟基官能的饱和或基本上饱和的烯烃聚合物与与羟基反应的链延长试剂反应来制备，并且将以头 - 尾排列的方式聚合单体单元。与先前使用的含有氯化聚烯烃的粘合促进剂相比，本发明的烯烃基嵌段共聚物可用于制备粘合促进剂，其对随后的涂层提供与TPO等烯烃基材的优异粘附性和优异的性能。或者，本发明的烯烃基共聚物可用作可固化涂料组合物中的添加剂，以提供与诸如TPO的烯烃基材的优异粘合性，即使以与先前已知的试剂所需量相比非常小的量使用。

14. 发明授权

US06300414B1 Additive for coating compositions for adhesion to TPO substrates 失效
标题翻译：用于粘附到TPO基材上的涂料组合物的添加剂
公开(公告)号：US06300414B1
公开(公告)日：2001-10-09
申请号：US09143156
申请日：1998-08-28
申请人： John D. McGee , Daniel Blickberndt , Craig Schang , Walter H. Ohrbom , Keri Krueger
发明人： John D. McGee , Daniel Blickberndt , Craig Schang , Walter H. Ohrbom , Keri Krueger
IPC分类号： C08L6702
CPC分类号： C08L71/02 , C08G63/00 , C08L53/005 , C09D5/002 , C09D7/65 , C09D201/00 , Y10T428/31909 , Y10T428/31913 , Y10T428/31917 , C08L2666/04 , C08L2666/24
摘要： The present invention provides an olefin-based block copolymer that has an olefin block that is substantially saturated and at least one (poly)ester or (poly)ether block. The olefin-based block copolymer of the invention can be prepared by reacting a liquid hydroxyl-functional, saturated or substantially saturated olefin polymer with a chain-extension reagent that is reactive with hydroxyl groups and will polymerize in a head-to-tail arrangement of monomer units. The olefin-based block copolymer of the invention can be used to prepare an adhesion promoter that provides excellent adhesion of subsequent coating layers to olefinic substrates like TPO and superior properties as compared to previously used adhesion promoters containing chlorinated polyolefins. Alternatively, the olefin-based copolymers of the invention can be used as an additive in a curable coating composition to provide excellent adhesion to olefinic substrates like TPO, even when used in very minor amounts compared to the amounts required for previously known agents.
摘要翻译：本发明提供一种具有基本上饱和的烯烃嵌段和至少一种（多）酯或（聚）醚嵌段的烯烃基嵌段共聚物。本发明的烯烃基嵌段共聚物可以通过使液体羟基官能的饱和或基本上饱和的烯烃聚合物与与羟基反应的链延长试剂反应来制备，并且将以头 - 尾排列的方式聚合单体单元。与先前使用的含有氯化聚烯烃的粘合促进剂相比，本发明的烯烃基嵌段共聚物可用于制备粘合促进剂，其对随后的涂层提供与TPO等烯烃基材的优异粘附性和优异的性能。或者，本发明的烯烃基共聚物可用作可固化涂料组合物中的添加剂，以提供与诸如TPO的烯烃基材的优异粘合性，即使以与先前已知的试剂所需量相比非常小的量使用。

15. 发明授权

US5994479A Curable coating compositions containing blends of carbamate-functional compounds 失效
标题翻译：含有氨基甲酸酯官能化合物的混合物的可固化涂料组合物
公开(公告)号：US5994479A
公开(公告)日：1999-11-30
申请号：US997317
申请日：1997-12-23
申请人： Marvin L. Green , John D. McGee , Brian D. Bammel , Danielle A. Regulski , Walter H. Ohrbom
发明人： Marvin L. Green , John D. McGee , Brian D. Bammel , Danielle A. Regulski , Walter H. Ohrbom
IPC分类号： C08G18/40 , C08G18/80 , C09D5/02 , C09D5/03 , C09D161/20 , C09D175/00 , C09D201/02 , C08G8/28 , C08G59/14 , C08L63/00 , C08L67/04
CPC分类号： C09D161/20 , C08G18/8077 , C09D201/025 , Y10T428/31551
摘要： The present invention provides a curable coating composition comprising(a) a first component comprising at least two functional groups, at least one of which is a carbamate or urea group that is the reaction product of:(1) a hydroxyl group that is the result of a ring-opening reaction between an epoxy group and an organic acid group, and(2) cyanic acid or a carbamate or urea group;(b) a curing agent having a plurality of functional groups that are reactive with component (a), and(c) a second component having functional groups that are reactive with component (a) or component (b) or both components (a) and (b).
摘要翻译：本发明提供一种可固化涂料组合物，其包含（a）包含至少两个官能团的第一组分，其中至少一个为氨基甲酸酯或脲基，其为：（1）作为结果的羟基的反应产物的环氧基和有机酸基之间的开环反应，和（2）氰酸或氨基甲酸酯或脲基; （b）具有多个与组分（a）反应的官能团的固化剂，和（c）具有与组分（a）或组分（b）或两种组分（a）反应的官能团的第二组分）和（b）。

16. 发明授权

US6040062A Aqueous coating compositions for environmental etch resistant coatings 失效
标题翻译：用于环境耐蚀涂层的水性涂料组合物
公开(公告)号：US6040062A
公开(公告)日：2000-03-21
申请号：US867547
申请日：1997-06-02
申请人： John D. McGee , Donald H. Campbell , John W. Rehfuss
发明人： John D. McGee , Donald H. Campbell , John W. Rehfuss
IPC分类号： C08L51/00 , C08G18/80 , C08G81/02 , C08L51/06 , C09D151/00 , C09D151/06 , C09D161/20 , C09D201/02 , B32B27/00 , B05D3/02 , C08L33/02
CPC分类号： C09D201/025 , C08G18/8077 , C08G81/021 , C09D161/20 , Y10S525/902
摘要： Environmental etch resistant coatings are described. The coatings are derived from aqueous, curable coating compositions comprising:(a) a carbamate-functional grafted acrylic polymer that comprises the reaction product of a first acrylic polymer and a second acrylic polymer, with at least one of the first and second acrylic polymers having groups that impart water dispersibility to the grafted acrylic polymer, and at least one of the first and second acrylic polymers having carbamate functionality; and(b) a second component comprising a compound having a plurality of functional groups that are reactive with the carbamate functionality.
摘要翻译：描述了耐环境蚀刻涂层。所述涂层衍生自含水可固化涂料组合物，其包含：（a）包含第一丙烯酸类聚合物和第二丙烯酸类聚合物的反应产物的氨基甲酸酯官能的接枝丙烯酸类聚合物，所述第一和第二丙烯酸类聚合物中的至少一种具有赋予接枝丙烯酸类聚合物水分散性的基团，以及具有氨基甲酸酯官能团的第一和第二丙烯酸类聚合物中的至少一种; 和（b）第二组分，其包含具有多个与氨基甲酸酯官能团反应的官能团的化合物。

17. 发明授权

US5639554A Method for highly etch resistant flexible coating 失效
标题翻译：高耐蚀性柔性涂层的方法
公开(公告)号：US5639554A
公开(公告)日：1997-06-17
申请号：US434966
申请日：1995-05-04
申请人： John D. McGee , Brian D. Bammel , John W. Rehfuss
发明人： John D. McGee , Brian D. Bammel , John W. Rehfuss
IPC分类号： C09D4/02 , B05D7/00 , C08L33/06 , C09D133/06 , C09D157/04 , C09D201/02 , C09D201/08 , B05D1/36 , B05D7/24
CPC分类号： B05D7/53 , C09D133/062 , C09D157/04 , C09D201/025 , C08L2205/02 , C08L33/062 , Y10T428/31551
摘要： A coating composition including a first component comprising a compound having appended thereto more than one carbamate functional group, and further including a second component reactive with said carbamate groups, which is a substituted acrylamide compound. The composition is useful as a clearcoating composition in a color-plus-clear composite coating.
摘要翻译：一种涂料组合物，其包含第一组分，其包含具有多于一个氨基甲酸酯官能团的化合物，并且还包含与作为取代的丙烯酰胺化合物的所述氨基甲酸酯基反应的第二组分。该组合物可用作彩色 - 透明复合涂层中的透明涂层组合物。

18. 发明授权

US5559195A Coating composition containing carbamate functional and acrylamide functional components 失效
标题翻译：含有氨基甲酸酯官能和丙烯酰胺功能组分的涂料组合物
公开(公告)号：US5559195A
公开(公告)日：1996-09-24
申请号：US361273
申请日：1994-12-21
申请人： John D. McGee , Brian D. Bammel , John W. Rehfuss
发明人： John D. McGee , Brian D. Bammel , John W. Rehfuss
IPC分类号： C09D4/02 , B05D7/00 , C08L33/06 , C09D133/06 , C09D157/04 , C09D201/02 , C09D201/08 , G08F8/00
CPC分类号： B05D7/53 , C09D133/062 , C09D157/04 , C09D201/025 , C08L2205/02 , C08L33/062 , Y10T428/31551
摘要： A coating composition including a first component comprising a compound having appended thereto more than one carbamate functional group, and further including a second component reactive with said carbamate groups, which is a substituted acrylamide compound. The composition is useful as a clearcoating composition in a color-plus-clear composite coating.
摘要翻译：一种涂料组合物，其包含第一组分，其包含具有多于一个氨基甲酸酯官能团的化合物，并且还包含与作为取代的丙烯酰胺化合物的所述氨基甲酸酯基反应的第二组分。该组合物可用作彩色 - 透明复合涂层中的透明涂层组合物。

19. 发明授权

US5726244A Aqueous coating compositions for environmental etch resistant coatings 失效
公开(公告)号：US5726244A
公开(公告)日：1998-03-10
申请号：US513587
申请日：1995-08-10
申请人： John D. McGee , Donald H. Campbell , John W. Rehfuss
发明人： John D. McGee , Donald H. Campbell , John W. Rehfuss
IPC分类号： C08L51/00 , C08G18/80 , C08G81/02 , C08L51/06 , C09D151/00 , C09D151/06 , C09D161/20 , C09D201/02 , C08L33/08
CPC分类号： C09D201/025 , C08G18/8077 , C08G81/021 , C09D161/20 , Y10S525/902 , Y10T428/31855
摘要： Environmental etch resistant coatings are described. The coatings are derived from aqueous, curable coating compositions comprising: (a) a carbamate-functional grafted acrylic polymer that comprises the reaction product of a first acrylic polymer and a second acrylic polymer, with at least one of the first and second acrylic polymers having groups that impart water dispersibility to the grafted acrylic polymer, and at least one of the first and second acrylic polymers having carbamate functionality; and (b) a second component comprising a compound having a plurality of functional groups that are reactive with the carbamate functionality.

20. 发明授权

US08241524B2 Release on demand corrosion inhibitor composition 有权
标题翻译：释放按需腐蚀抑制剂组成
公开(公告)号：US08241524B2
公开(公告)日：2012-08-14
申请号：US12467537
申请日：2009-05-18
申请人： John D. McGee , Thomas S. Smith, II , Brian D. Bammel , Todd R. Bryden
发明人： John D. McGee , Thomas S. Smith, II , Brian D. Bammel , Todd R. Bryden
IPC分类号： C23F11/00
CPC分类号： C09D5/084 , C09D139/04 , C08L2666/02 , C08L2666/04
摘要： Disclosed is a release on demand type corrosion inhibitor composition for a metal substrate formed from only non-electrically conductive film forming copolymer(s); a nitrogen containing functional group X, where the group X comprises a pyridine, a dihydropyridine, a pyrrole, an imidazole, or a mixtures thereof; and a metallate anion. The metallate anion binds to a nitrogen in the functional group X by ion pairing. A localized rise in pH is believed to cause release of the anion via a protonation/deprotonation reaction and the released anion suppresses the corrosion formation. The coating composition includes no electrically conductive polymers.
摘要翻译：公开了一种用于仅由非导电成膜共聚物形成的金属基材的按需型缓蚀剂组合物; 含氮官能团X，其中基团X包括吡啶，二氢吡啶，吡咯，咪唑或其混合物; 和金属盐阴离子。金属离子阴离子通过离子配对结合官能团X中的氮。认为pH的局部升高通过质子化/去质子化反应引起阴离子的释放，释放的阴离子抑制腐蚀形成。涂料组合物不包括导电聚合物。

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