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11. 发明授权

US5228896A Cyclohexenone oxime ethers, their preparation, intermediates for their preparation and their use as herbicides 失效
标题翻译： CYCLOHEXENONE OXIME ETHERS，他们的准备工作，中间体的制备及其作为除草剂的使用
公开(公告)号：US5228896A
公开(公告)日：1993-07-20
申请号：US697040
申请日：1991-05-08
申请人： Ulf Misslitz , Norbert Meyer , Juergen Kast , Norbert Goetz , Albrecht Harreus , Thomas Kuekenhoehner , Bruno Wuerzer , Helmut Walter , Karl-Otto Westphalen , Matthias Gerber
发明人： Ulf Misslitz , Norbert Meyer , Juergen Kast , Norbert Goetz , Albrecht Harreus , Thomas Kuekenhoehner , Bruno Wuerzer , Helmut Walter , Karl-Otto Westphalen , Matthias Gerber
IPC分类号： C07D213/30 , A01N43/10 , A01N43/16 , A01N43/18 , A01N43/36 , A01N43/40 , A01P13/00 , C07D207/32 , C07D207/333 , C07D307/38 , C07D307/42 , C07D333/16 , C07D333/28 , C07D405/12 , C07D407/12 , C07D409/12
CPC分类号： C07D207/333 , A01N43/10 , A01N43/16 , A01N43/36 , A01N43/40 , C07D307/42 , C07D333/16 , C07D333/28 , C07D405/12 , C07D407/12 , C07D409/12
摘要： Cyclohexenone oxime ethers of the formula I ##STR1## (R.sup.1 =C.sub.1 -C.sub.6 -alkyl; A=substituted or unsubstituted alkylene or alkenylene;Z=a 5-membered or 6-membered heteroaromatic structure;X=substituted or unsubstituted amino, nitro, cyano, halogen, alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, substituted or unsubstituted benzyloxycarbonyl and phenyl;n=0 to 3, or 1 to 4 where Z is halogen-substituted pyridyl; andR.sup.2 =alkoxyalkyl or alkylthioalkyl; substituted or unsubstituted cycloalkyl or cycloalkenyl; a substituted or unsubstituted 5-membered saturated heterocyclic structure which contains one or two hetero atoms; a substituted or unsubstituted 6-membered or 7-membered saturated or mono- or diunsaturated heterocyclic structure containing one or two hetero atoms; a substituted or unsubstituted 5-membered heteroaromatic structure containing one to three hetero atoms; substituted or unsubstituted phenyl or pyridyl)and their agriculturally useful salts and esters of C.sub.1 -C.sub.10 -carboxylic acids and inorganic acids.The compounds are suitable as herbicides.
摘要翻译：式I的环己烯酮肟醚（I）（R1 = C1-C6-烷基; A =取代或未取代的亚烷基或亚烯基; Z = 5元或6元杂芳族结构; X =取代或未取代的氨基硝基，氰基，卤素，烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，羧基，C 1 -C 4烷氧基羰基，取代或未取代的苄氧羰基和苯基; n = 0至3或1至4，其中Z为卤素取代的吡啶基; R2 =烷氧基烷基或烷硫基烷基;取代或未取代的环烷基或环烯基;取代或未取代的含有一个或两个杂原子的5元饱和杂环结构; 或含有一个或两个杂原子的未取代的6元或7元饱和或单或二不饱和杂环结构;具有一至三个杂原子的取代或未取代的5元杂芳族结构;取代或未取代的苯基或吡啶基）及其农业有用的C 1 -C 10 - 羧酸和无机酸的盐和酯。该化合物适用作除草剂。

12. 发明授权

US5080708A Isoxazole(isothiazole)-5-carboxamides 失效
标题翻译：异佛唑（异噻唑）-5-羧酰胺
公开(公告)号：US5080708A
公开(公告)日：1992-01-14
申请号：US337640
申请日：1989-04-13
申请人： Wolfgang Freund , Thomas Kuekenhoehner , Gerhard Hamprecht , Bruno Wuerzer , Karl-Otto Westphalen , Norbert Meyer , Hans Theobald
发明人： Wolfgang Freund , Thomas Kuekenhoehner , Gerhard Hamprecht , Bruno Wuerzer , Karl-Otto Westphalen , Norbert Meyer , Hans Theobald
IPC分类号： A01N43/80 , A01N43/84 , A01N55/00 , A01N57/24 , C07D261/18 , C07D275/02 , C07D275/03 , C07D413/04 , C07D413/12 , C07D417/12
CPC分类号： C07D275/03 , A01N43/80 , A01N43/84 , A01N55/00 , A01N57/24 , C07D261/18 , C07D413/04 , C07D413/12 , C07D417/12
摘要： Isoxazole(isothiazole)-5-carboxamides of the formula ##STR1## where X is oxygen or sulfur,R.sup.1 is hydrogen, substituted or unsubstituted alkyl, alkoxy, substituted or unsubstituted cycloalkyl, a 5- or 6-membered heterocyclic radical having one or two heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen, and which may be substituted, or substituted or unsubstituted phenyl, orR.sup.2 is formyl, 4,5-dihydrooxazol-2-yl or a radical of the formula COYR.sup.5 or CONR.sup.6 R.sup.7, whereY is oxygen or sulfur,R.sup.5 ishydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted alkenyl, haloalkenyl, substituted or unsubstituted alkynyl,cycloalkyl,cycloalkenyl,substituted or unsubstituted phenyl,a 5- or 6-membered heterocyclic radical having one or two heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen,cycloalkanimino, phthalimido, succinimido, or a radical ##STR2## R.sup.3 and R.sup.4 have the meanings defined herein, or their agriculturally acceptable salts possess herbicidal activity.
摘要翻译：其中X是氧或硫，R 1是氢，取代或未取代的烷基，烷氧基，取代或未取代的环烷基，具有一个或两个的5-或6-元杂环基的异噻唑（异噻唑）-5-甲酰胺，选自氧，硫和氮的杂原子，并且其可以被取代，或取代或未取代的苯基，或R 2是甲酰基，4,5-二氢恶唑-2-基或式COYR 5或CONR 6 R 7的基团，其中 Y是氧或硫，R5是氢，取代或未取代的烷基，取代或未取代的烯基，卤代烯基，取代或未取代的炔基，环烷基，环烯基，取代或未取代的苯基，具有一个或两个杂原子的5-或6-元杂环基选自氧，硫和氮，环亚烷基亚氨基，邻苯二甲酰亚氨基，琥珀酰亚胺基或自由基，CH 2 CH（OH）CH 2（OH）等，R 3和R 4具有本文定义的含义或其农业超可接受的盐具有除草活性。

13. 发明授权

US5211737A 4-arryl-2-haloimidazole-5-carboxylic esters, the preparation and use thereof 失效
标题翻译： 4-芳基-2-卤代咪唑-5-羧酸酯的制备和应用
公开(公告)号：US5211737A
公开(公告)日：1993-05-18
申请号：US666483
申请日：1991-03-06
申请人： Ulrich Wriede , Gerhard Hamprecht , Hermann Koehler , Thomas Kuekenhoehner , Bruno Wuerzer , Karl-Otto Westphalen
发明人： Ulrich Wriede , Gerhard Hamprecht , Hermann Koehler , Thomas Kuekenhoehner , Bruno Wuerzer , Karl-Otto Westphalen
IPC分类号： A01N25/32 , C07D233/90
CPC分类号： A01N25/32 , C07D233/90
摘要： 4-Aryl-2-haloimidazole-5-carboxylic esters of the general formula Ia and Ib ##STR1## where R.sup.1 is C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl,R.sub.2 is C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl,Hal is chlorine or bromine,n is 0 to 3,x is C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, C.sub.1 -C.sub.4 -haloalkylthio, cyano, nitro, carbo-C.sub.1 -C.sub.4 -alkoxy, N,N-di-C.sub.1 -C.sub.4 -alkylcarbamoyl and/or halogen,processes for their manufacture, and their use in herbicidal agents as safeners in combination with at least one herbicidal active ingredient from the group consisting ofa) 2-(4-heteroaryloxy)- or 2-(4-aryloxy)-phenoxyacetic acid or -propionic acid derivatives andb) cyclohexenone derivatives.
摘要翻译：其中R 1是C 1 -C 6 - 烷基，C 3 -C 6 - 烯基或C 3 -C 6 - 炔基，R 2是（C 1 -C 6） - 烷基，C 3 -C 6 - 烯基或C 3 -C 6炔基的4-芳基-2-卤代咪唑-5-羧酸酯 C 1 -C 6 - 烷基，C 3 -C 6 - 烯基或C 3 -C 6炔基，Hal为氯或溴，n为0至3，x为C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4 - 烷氧基， C 1 -C 4 - 卤代烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4烷基亚磺酰基，C 1 -C 4烷基磺酰基，C 1 -C 4卤代烷硫基，氰基，硝基，C 1 -C 4 - 烷氧基，N， C4-烷基氨基甲酰基和/或卤素，其制备方法和它们在除草剂中的用途作为安全剂与至少一种除草活性成分组合，所述除草活性成分包括a）2-（4-杂芳氧基） - 或2-（4 - 芳氧基） - 苯氧基乙酸或 - 丙酸衍生物，和b）环己烯酮衍生物。

14. 发明授权

US5205854A Isoxazole(isothiazole)-5-carboxamides 失效
标题翻译：异恶唑（异噻唑）-5-甲酰胺
公开(公告)号：US5205854A
公开(公告)日：1993-04-27
申请号：US764214
申请日：1991-09-23
申请人： Wolfgang Freund , Thomas Kuekenhoehner , Gerhard Hamprecht , Bruno Wuerzer , Karl-Otto Westphalen , Norbert Meyer , Hans Theobald
发明人： Wolfgang Freund , Thomas Kuekenhoehner , Gerhard Hamprecht , Bruno Wuerzer , Karl-Otto Westphalen , Norbert Meyer , Hans Theobald
IPC分类号： A01N43/80 , A01N43/84 , A01N55/00 , A01N57/24 , C07D261/18 , C07D275/02 , C07D275/03 , C07D413/04 , C07D413/12 , C07D417/12
CPC分类号： C07D275/03 , A01N43/80 , A01N43/84 , A01N55/00 , A01N57/24 , C07D261/18 , C07D413/04 , C07D413/10 , C07D417/12
摘要： Isoxazole(isothiazole)-5-carboxamides, having herbicidal activity, of the formula ##STR1## where X is oxygen or sulfur,R.sup.1 is hydrogen, substituted or unsubstituted alkyl, alkoxy, substituted or unsubstituted cycloalkyl, a 5- or 6-membered heterocyclic radical having one or two heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen, and which may be substituted, or substituted or unsubstituted phenyl, orR.sup.2 is formyl, 4,5-dihydrooxazol-2-yl or a radical of the formula COYR.sup.5 or CONR.sup.6 R.sup.7.
摘要翻译：具有除草活性的具有除草活性的异噻唑（异噻唑）-5-甲酰胺，其中X是氧或硫，R1是氢，取代或未取代的烷基，烷氧基，取代或未取代的环烷基，5-或6-元杂环具有一个或两个选自氧，硫和氮的杂原子的基团，并且其可以被取代或取代或未取代的苯基，或R 2是甲酰基，4,5-二氢恶唑-2-基或式 COYR5或CONR6R7。

15. 发明授权

US5276160A Preparation of 3-carbamoylisoxazole-4-carboxylic esters by selective amidation 失效
标题翻译：通过选择性酰胺化制备3-氨基甲酰基异恶唑-4-羧酸酯
公开(公告)号：US5276160A
公开(公告)日：1994-01-04
申请号：US35660
申请日：1993-03-23
申请人： Volker Maywald , Thomas Kuekenhoehner , Gerhard Hamprecht
发明人： Volker Maywald , Thomas Kuekenhoehner , Gerhard Hamprecht
IPC分类号： C07D261/18 , C07D413/04 , C07D261/08
CPC分类号： C07D261/18
摘要： Abstract of the Disclosure: 3-Carbamoylisoxazole-4-carboxylic esters of the formula I ##STR1## where R.sup.1 is hydrogen, alkyl, cycloalkyl, phenyl or a 5- to 6-membered heterocyclic radical, it being possible for the organic radicals to carry substituents which are inert under the reaction conditions;R.sup.2 is alkyl, cycloalkyl, benzyl or C.sub.1 -C.sub.3 -alkenyl;R.sup.3 is hydrogen, alkyl or cycloalkyl andR.sup.4 is an aliphatic or cycloaliphatic radical or unsubstituted or substituted phenyl, or R.sup.4 together with R.sup.3 is a 4- to 7-membered alkylene chain which can be interrupted by oxygen, sulfur or N-methyl, are prepared by selective amidation of an isoxazole-3,4-dicarboxylic diester of the formula II ##STR2## where R.sup.2 has the meanings of R.sup.2 and is identical to or different from R.sup.2.
摘要翻译：本发明摘要：式I的3-氨基甲酰异恶唑-4-羧酸酯其中R 1是氢，烷基，环烷基，苯基或5-至6-元杂环基，有机基团可能携带在反应条件下为惰性的取代基; R2是烷基，环烷基，苄基或C1-C3-烯基; R3是氢，烷基或环烷基，R4是脂族或脂环族基团或未取代或取代的苯基，或R4与R3一起可以被氧，硫或N-甲基中断的4至7元亚烷基链，通过选择性酰胺化式II的异恶唑-3,4-二羧酸二酯，其中R 2具有R 2的含义并且与R 2相同或不同。

16. 发明授权

US5264580A Preparation of isoxazole-3,4-dicarboxylic acid derivatives 失效
标题翻译：异恶唑-3,4-二羧酸衍生物的制备
公开(公告)号：US5264580A
公开(公告)日：1993-11-23
申请号：US39573
申请日：1993-03-23
申请人： Volker Maywald , Thomas Kuekenhoehner , Peter Muenster , Stefan Stahl
发明人： Volker Maywald , Thomas Kuekenhoehner , Peter Muenster , Stefan Stahl
IPC分类号： C07D261/18 , C97D261/08
CPC分类号： C07D261/18
摘要： A process for preparing isoxazole-3,4-dicarboxylic acid derivatives of the formula I ##STR1## where R.sup.1 is hydrogen, alkyl, cycloalkyl or phenyl, or a 5- to 6-membered heterocyclic radical, and the organic radicals can have substituents which are inert under the reaction conditions;R.sup.2 is hydrogen, alkyl, cycloalkyl, benzyl or C.sub.3 -C.sub.6 -alkenyl;A is NR.sup.3 R.sup.4 where R.sup.3 is hydrogen or an aliphatic or cycloaliphatic radical and R.sup.4 is an aliphatic or cycloaliphatic radical or unsubstituted or substituted phenyl, or R.sup.3 forms together with R.sup.4 a 4- to 7-membered alkylene chain which can be interrupted by oxygen, sulfur or N-methyl, or is OR.sup.5 where R.sup.5 is alkyl, cycloalkyl, benzyl or alkenyl;by deprotonation of a CH-acid compound of the formula II ##STR2## using a base and reacting with hydroximyl chlorides of the formula III ##STR3## wherein a magnesium alcoholate of the formula IVMg(OR.sup.6 ).sub.2 IVwhere R.sup.6 is an aliphatic or cycloaliphatic radical is used for the deprotonation.
摘要翻译：制备式I的异恶唑-3,4-二羧酸衍生物，其中R1是氢，烷基，环烷基或苯基，或5-至6-元杂环基，并且有机基团可以具有取代基在反应条件下是惰性的; R2是氢，烷基，环烷基，苄基或C3-C6-烯基; A是NR 3 R 4，其中R 3是氢或脂族或脂环族基团，R 4是脂族或脂环族基团或未取代或取代的苯基，或R 3与R 4一起形成可被氧，硫中断的4-至7-元亚烷基链或N-甲基，或是OR 5，其中R 5是烷基，环烷基，苄基或烯基; 通过使用碱将式II II的CH-酸化合物去质子化，并与式III的氢氯化物反应，其中式IV的醇镁盐（OR 6）2 IV，其中R 6是脂肪族或脂环族基团用于去质子化。

17. 发明授权

US5201935A Cyclohexenone derivatives 失效
标题翻译：环己烯酮衍生物
公开(公告)号：US5201935A
公开(公告)日：1993-04-13
申请号：US934304
申请日：1992-08-26
申请人： Dieter Kolassa , Juergen Kasi , Thomas Kuekenhoehner , Norbert Meyer , Karl-Otto Westphalen , Bruno Wuerzer
发明人： Dieter Kolassa , Juergen Kasi , Thomas Kuekenhoehner , Norbert Meyer , Karl-Otto Westphalen , Bruno Wuerzer
IPC分类号： A01N43/10 , A01N43/14 , A01N43/50 , A01N43/74 , A01N43/80 , A01N43/82 , C07D261/04 , C07D261/08 , C07D271/06 , C07D271/10 , C07D333/22 , C07D413/04
CPC分类号： C07D271/06 , A01N43/10 , A01N43/14 , A01N43/50 , A01N43/74 , A01N43/80 , A01N43/82 , C07D261/04 , C07D261/08 , C07D271/10 , C07D333/22 , C07D413/04
摘要： Cyclohexenone derivatives of the general formula I ##STR1## where the substituents have the following meanings: R.sup.1 substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, phenyl, benzyl or thenyl;R.sup.2 substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl or phenyl;R.sup.3 hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.10 -alkylcarbonyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.4 -trialkylsilyl, C.sub.1 -C.sub.4 -dialkylphosphonyl, C.sub.1 -C.sub.4 -dialkylthiophosphonyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenylcarbonyl, C.sub.3 -C.sub.6 -alkynyl orsubstituted or unsubstituted benzoyl- or phenylsulfonyl;R.sup.4 hydrogen, cyano, halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxycarbonyl;A a substituted or unsubstituted C.sub.1 -C.sub.4 -alkylene chain in which a methylene group may be replaced by an oxygen or sulfur atom;m 0 or 1;B a 5-membered mono- or diunsaturated heterocycle containing up to 2 nitrogen atoms and/or up to one oxygen or sulfur atom;substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkynyl;C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.3 -C.sub.6 -alkenyloxy or C.sub.3 -C.sub.6 -alkynyloxy;n 1, 2 or 3;Y not denoting hydrogen when m is 0, B is isoxazol-5-yl and X is 3-(C.sub.3 -C.sub.6 -cycloalkyl),and environmentally acceptable salts thereof, processes for their manufacture, and their use as herbicidal agents.
摘要翻译：通式I的环己烯酮衍生物，其中取代基具有以下含义：R 1取代或未取代的C 1 -C 6 - 烷基，C 3 -C 6 - 烯基或C 3 -C 6 - 炔基，苯基，苄基或异丁基; R2取代或未取代的C1-C6-烷基，C3-C6-烯基，C3-C6-炔基或苯基; R3，C1-C6-烷基，C1-C10-烷基羰基，C1-C6-烷基磺酰基，C1-C4-三烷基甲硅烷基，C1-C4-二烷基膦酰基，C1-C4-二烷基硫代膦酰基，C3-C6-烯基，C3-C6-烯基羰基，C 3 -C 6炔基或取代或未取代的苯甲酰基或苯基磺酰基; R 4氢，氰基，卤素，C 1 -C 6 - 烷基或C 1 -C 6 - 烷氧基羰基; 取代或未取代的C1-C4亚烷基链，其中亚甲基可被氧或硫原子代替; m 0或1; B是含有至多2个氮原子和/或至多一个氧原子或硫原子的5元单或二不饱和杂环; 取代或未取代的C 1 -C 6 - 烷基，C 2 -C 6 - 烯基或C 2 -C 6 - 炔基; C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 3 -C 6 - 烯氧基或C 3 -C 6 - 炔氧基; n 1，2或3; 当m为0时，Y不表示氢，B为异唑-5-基，X为3-（C 3 -C 6 - 环烷基）及其环境可接受的盐，其制备方法及其作为除草剂的用途。

18. 发明授权

US5034047A Cyclohexenone derivatives and their use as herbicides 失效
标题翻译：环己烯酮衍生物及其作为除草剂的用途
公开(公告)号：US5034047A
公开(公告)日：1991-07-23
申请号：US572357
申请日：1990-08-24
申请人： Dieter Kolassa , Juergen Kast , Thomas Kuekenhoehner , Norbert Meyer , Karl-Otto Westphalen , Bruno Wuerzer
发明人： Dieter Kolassa , Juergen Kast , Thomas Kuekenhoehner , Norbert Meyer , Karl-Otto Westphalen , Bruno Wuerzer
IPC分类号： A01N43/10 , A01N43/14 , A01N43/50 , A01N43/74 , A01N43/80 , A01N43/82 , C07D261/04 , C07D261/08 , C07D271/06 , C07D271/10 , C07D333/22 , C07D413/04
CPC分类号： C07D271/06 , A01N43/10 , A01N43/14 , A01N43/50 , A01N43/74 , A01N43/80 , A01N43/82 , C07D261/04 , C07D261/08 , C07D271/10 , C07D333/22 , C07D413/04
摘要： Cyclohexenone derivatives of the general formula I ##STR1## where the substituents have the following meanings: R.sup.1 : substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, phenyl, benzyl or thenyl;R.sup.2 : substituted or unsubstituted C.sub.1 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl or phenyl;R.sup.3 : hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.10 -alkylcarbonyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.4 -trialkylsilyl, C.sub.1 -C.sub.4 -dialkylphosphonyl, C.sub.1 -C.sub.4 -dialkylthiophosphonyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenylcarbonyl, C.sub.3 -C.sub.6 -alkynyl or substituted or unsubstituted benzoyl- or phenylsulfonyl;R.sup.4 : hydrogen, cyano, halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxycarbonyl;A: a substituted or unsubstituted C.sub.1 -C.sub.4 -alkylene chain in which a methylene group may be replaced by an oxygen or sulfur atom;m: 0 or 1;B: a 5-membered mono- or diunsaturated heterocycle containing up to 2 nitrogen atoms and/or up to one oxygen or sulfur atom; substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkynyl; C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.3 -C.sub.6 -alkenyloxy or C.sub.3 -C.sub.6 -alkynyloxy;n: 1, 2 or 3;Y: not denoting hydrogen when m is O, B is isoxazol-5-yl and X is 3-(C.sub.3 -C.sub.6 -cycloalkyl),and environmentally acceptable salts thereof, processes for their manufacture, and their use as herbicidal agents.
摘要翻译：通式I的环己烯酮衍生物，其中取代基具有以下含义：R 1：取代或未取代的C 1 -C 6 - 烷基，C 3 -C 6 - 烯基或C 3 -C 6 - 炔基，苯基，苄基或异丁基; R2：取代或未取代的C1-C6-烯基，C3-C6-烯基，C3-C6-炔基或苯基; R3：氢，C1-C6-烷基，C1-C10-烷基羰基，C1-C6-烷基磺酰基，C1-C4-三烷基甲硅烷基，C1-C4-二烷基膦酰基，C1-C4-二烷基硫代膦酰基，C3-C6-烯基，C3-C6- 烯基羰基，C 3 -C 6炔基或取代或未取代的苯甲酰基或苯基磺酰基; R4：氢，氰基，卤素，C1-C6-烷基或C1-C6-烷氧基羰基; A：取代或未取代的亚甲基可被氧或硫原子代替的C 1 -C 4 - 亚烷基链; m：0或1; B：含有至多2个氮原子和/或至多一个氧或硫原子的5元单或二不饱和杂环; 取代或未取代的C 1 -C 6 - 烷基，C 2 -C 6 - 烯基或C 2 -C 6 - 炔基; C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 3 -C 6 - 烯氧基或C 3 -C 6 - 炔氧基; n：1,2或3; Y：当m为O时不表示氢，B为异唑-5-基，X为3-（C 3 -C 6环烷基），其环保可接受的盐，其制备方法及其作为除草剂的用途。

19. 发明授权

US4983210A Isoxazolines, their preparation and their use 失效
标题翻译：异恶唑啉，其制备及其用途
公开(公告)号：US4983210A
公开(公告)日：1991-01-08
申请号：US326986
申请日：1989-03-22
申请人： Joachim Rheinheimer , Karl Eicken , Hans Theobald , Thomas Kuekenhoehner , Karl-Otto Westphalen , Bruno Wuerzer , Juergen Frank , Norbert Meyer
发明人： Joachim Rheinheimer , Karl Eicken , Hans Theobald , Thomas Kuekenhoehner , Karl-Otto Westphalen , Bruno Wuerzer , Juergen Frank , Norbert Meyer
IPC分类号： A01N43/80 , C07D261/04 , C07D413/04 , C07D413/12
CPC分类号： C07D413/04 , A01N43/80 , C07D261/04 , C07D413/12
摘要： Isoxazolines of the general formula I ##STR1## where the substituents have the following meanings: R.sup.1 is C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.7 -cycloalkyl, substituted or unsubstituted phenyl, or a saturated or unsaturated 5- or 6-membered heterocycle;R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are hydrogen, C.sub.1 -C.sub.4 -alkyl or benzyl andR.sup.7 is substituted or unsubstituted C.sub.2 -C.sub.6 -alkenyl, C.sub.5 -C.sub.7 -cycloalkenyl, phenyl, naphthyl or thienyl,processes for their manufacture, and their use.
摘要翻译：其中取代基具有以下含义：R 1为C 1 -C 12 - 烷基，C 3 -C 7 - 环烷基，取代或未取代的苯基或饱和或不饱和的5-或6-元杂环; R2，R3，R4，R5和R6是氢，C1-C4烷基或苄基，R7是取代或未取代的C2-C6-烯基，C5-C7-环烯基，苯基，萘基或噻吩基，其制备方法，使用。

20. 发明授权

US5473069A Preparation of isoxazole-4,5-dicarboxylic diesters 失效
标题翻译：异恶唑-4,5-二羧酸二酯的制备
公开(公告)号：US5473069A
公开(公告)日：1995-12-05
申请号：US667134
申请日：1991-03-11
申请人： Thomas Kuekenhoehner , Volker Maywald
发明人： Thomas Kuekenhoehner , Volker Maywald
IPC分类号： C07D261/18 , C07D261/12
CPC分类号： C07D261/18
摘要： The preparation of isoxazole-4,5-dicarboxylic diester of the formula I ##STR1## where R.sup.1 is any organic radical which is inert under the reaction conditions, and R.sup.2 and R.sup.3 are each alkyl, cycloalkyl or benzyl, entails reacting an aldoxime of the formula II ##STR2## with a diester of maleic or fumaric acid, of the formula IIIR.sup.2 OOC--C.dbd.C--COOR.sup.3 (III)where R.sup.2 and R.sup.3 are identical or different and have the abovementioned meanings, in the presence of an aqueous solution of a hypohalite which is present in excess relative to II.
摘要翻译：制备式I（I）的异恶唑-4,5-二羧酸二酯其中R 1是在反应条件下为惰性的任何有机基团，并且R 2和R 3各自为烷基，环烷基或苄基，式II的醛酮肟与式（III）的马来酸或富马酸的二酯反应，其中R 2和R 3相同或不同并具有上述含义，式III化合物R 2 OOC-C = C-COOR 3（III）存在相对于II过量存在的次卤酸盐的水溶液。

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