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    • 15. 发明专利
    • 1,8-NAPTHALENEDICARBOXIMIDES AS ANTIDOTES
    • CA2030129A1
    • 1991-05-30
    • CA2030129
    • 1990-11-16
    • SAUPE THOMASMEYER NORBERTPLATH PETERSCHIRMER ULRICHWUERZER BRUNOWESTPHALEN KARL OTTOPATSCH MANFREDPFISTER JUERGEN
    • SAUPE THOMASMEYER NORBERTPLATH PETERSCHIRMER ULRICHWUERZER BRUNOWESTPHALEN KARL-OTTOPATSCH MANFREDPFISTER JUERGEN
    • A01N25/32A01N39/02A01N39/04A01N43/42C07D221/14C07D401/12C07D405/12C07D409/12C07D471/06
    • 1,8-Naphthalanedicarbox-imides of the formula Ia I where R1 to R4 are each H, halogen, OH, SH, CN, SCN, NO2, alkyl which may be halogenated, alkenyl, alkynyl, cycloalkyl, cycloalkoxy, NH2, alkylamino, dialkylamino, aminoalkyl, alkylaminoalkyl, dialkylaminoalkyl, alkoxy, alkylthio, alkoxyalkyl, alkylthioalkyl, alkylcarbonyl, alkylcarbonyloxy, alkoxycarbonyl, COOH, hydroxycarbonylalkyl, hydroxycarbonylalkoxy, hydroxycarbonylalkylthio, SO3H, alkylsulfinyl, alkylsulfonyl, alkoxysulfonyl, SO2NH2, alkylaminosulfonyl, dialkylaminosulfonyl, unsubstituted or substituted NHNH2, C6H5, phenylalkyl, naphthyl, naphthylalkyl, hetaryl, hetarylalkyl, phenoxy, naphthyloxy, phenylthio, naphthylthio, phenoxycarbonyl, naphthyloxycarbonyl, phenylcarbonyl, naphthylcarbonyl, phenylcarbonyloxy, naphthylcarbonyloxy, phenylalkoxy, naphthylalkoxy, hetarylalkoxy, phenylsulfinyl, naphthylsulfinyl, hetarylsulfinyl, phenylsulfonyl, naphthylsulfonyl, hetarylsulfonyl, phenoxysulfonyl, naphthyloxysulfonyl or hetaryloxysulfonyl, where all aryl moieties may carry further substituents; X is an unsubstituted or substituted alkylene chain; R5 is H, CN, alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, alkoxyoarbonyl, acetyl, cycloalkyl, benzoyl, naphthoyl, hetaroyl, C6H5, naphthyl, phenylalkyl, naphthylalkyl, hetaryl or hetarylalkyl, where the aryl moieties of the six last-mentioned radicals may carry further substituents; R6 is H, CN, alkyl which may be halogenated, alkoxy, alkoxyalkyl, diazolylmethyl, triazolylmethyl, alkoxycarbonyl, furyl, tetrahydrofuryl, thienyl, tetrahydropyranyl, tetrahydrothiopyranyl, dihydropyranyl or dihydrothiopyranyl; R6 is C6H5 if R5 is H, CH3 or CH3CO; R5 and R6, together with the common carbon atom, form a cycloalkyl radical or an unsubstituted or substituted 5-membered or 6-membered ring which may be unsaturated and may contain O or S as hetero atoms, and Y and Z are each O and S, with the exception of compounds in which R3 and R4 are simultaneously H, and, where R1 to R4 are each an acidic group, the planttolerated salts of Ia, and herbicides which contain the 2-(4-hetaryloxy)- or 2-(4-aryloxy)-phenoxyacetic acid or -propionic acid derivatives and/or cyclohexenone derivatives as herbicidal active ingredients and 1,8naphthalenedicarboximides Ia and/or Ib Ib where R7 is an organic radical and may have different meanings, and/or Ic Ic and, in the case of acidic terminal groups, the planttolerated salts of Ia and/or Ib and/or Ic as antidotes.
    • 16. 发明专利
    • SUBSTITUED 1,8-NAPHTHYRIDINES, THEIR PREPARATION AND THEIR USE AS ANTIDOTES
    • CA2011538A1
    • 1990-09-11
    • CA2011538
    • 1990-03-06
    • SAUPE THOMASSCHAEFER PETERMEYER NORBERTWUERZER BRUNOWESTPHALEN KARL OTTO
    • SAUPE THOMASSCHAEFER PETERMEYER NORBERTWUERZER BRUNOWESTPHALEN KARL-OTTO
    • A01N25/32A01N43/90C07D471/04
    • O.Z. 0050/40631 Substituted 1,8-naphthyridines of the general formula I I, where: R1 is mercapto, benzylthio, sulfonyl, amino or NR2R3, where R2 is C1-C12-alkyl, C3-C6-alkenyl, C3-C8-cycloalkyl, substituted or unsubstituted phenyl or phenyl-(C1-C3)-alkyl, or a group -?-A, where A is C1-C8-alkyl, substituted or unsubstituted phenyl, or is amino, alkyl- or dialkylamino where each alkyl radical is of 1 to 6 carbon atoms, phenylamino, morpholino or piperidyl, and R3 is hydrogen, C1-C12-alkyl or C3-C8-cycloalkyl, or R2 and R3 are bonded to one another to form a saturated or unsaturated 5-membered or 6-membered heterocyclic structure which, in addition to the nitrogen atom to which they are bonded, may contain a further heteroatom such as oxygen or nitrogen; hydroxyl, mercapto, halogen or XR4, where X is oxygen or sulfur and R4 is C1-C12-alkyl, C1-C4-alkoxycarbonyl-(C1-C4)-alkyl, C5-C8-cycloalkyl, or substituted or unsubstituted phenyl or phenyl-C1-C3-alkyl, R5 and R7 are each hydrogen, C1-C12-alkyl, C3-C8-cycloalkyl, substituted or unsubstituted phenyl or phenyl-(C1-C3)-alkyl, hydroxyl, halogen, mercapto, C1-C4-alkoxy, C1-C4-alkylthio, amino, mono- or dialkylamino where each alkyl is of 1 to 6 carbon atoms, substituted or unsubstituted phenoxy or phenylthio, halo (Cl-C3)-alkyl, C1-C4-alkoxy-(C1-C3)-alkyl, C1-C4-alkylthio- (C1-C3)-alkyl, amino-(C1-C3)-alkyl, C1-C4-acyloxy, substituted or unsubstituted hydrazino, cyano and thiocyanato, and O.Z. 0050/40631 R5 is hydrogen, C1-C12-alkyl, C3-C8-cycloalkyl, substituted or unsubstituted phenyl or phenyl-(C1-C3)-alkyl, halogen, halo (C1-C3)-alkyl, Cl-C4-alkoxy-(C1-C3)-alkyl, C1-C4-alkylthio- (C1-C3)-alkyl, amino-(C1-C3)-alkyl, carboxyl or C1-C4-alkoxy-carbonyl, their plant-tolerated salts, processes for their manufacture, and their use as safeners.