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11. 发明申请

WO2008100786A1 ENERGY INTEGRATED PROCESSES FOR MAKING DETERGENT RANGE ALKYLBENZENES 审中-公开
标题翻译：用于制造洗涤剂烷基苯的能源综合工艺
公开(公告)号：WO2008100786A1
公开(公告)日：2008-08-21
申请号：PCT/US2008/053335
申请日：2008-02-07
申请人： UOP LLC , SOHN, Stephen, W. , RILEY, Mark G.
发明人： SOHN, Stephen, W. , RILEY, Mark G.
IPC分类号： C07C2/64 , C07C15/107
CPC分类号： C07C15/107 , C07C6/126 , Y02P20/125
摘要： Integrated, energy efficient process for making detergent range alkylbenzenes, heavies coproduced during the alkylation of benzene with olefin using a solid, acidic catalyst are transalkylated. Spent benzene (136) from regeneration of the solid, acidic catalyst used for alkylation ( 1 12) provides at least 50 percent of the benzene provided for the transalkylation (168). The integrated processes thus reduce the load on the benzene distillation assembly ( 138) used in the alkylbenzene refining system (138, 144, 150).
摘要翻译：用于制备洗涤剂范围烷基苯的综合的能量高效方法，在使用固体，酸性催化剂的烯烃烷基化烷基化过程中共同生成的重质烃被转烷基化。用于烷基化的固体酸性催化剂（112）中再生的苯（136）提供至少50％的用于烷基转移的苯（168）。综合过程因此降低了在烷基苯精制系统（138,144,150）中使用的苯蒸馏组件（138）上的负荷。

12. 发明申请

WO2008055116A1 PROCESS AND APPARATUS FOR ALKYLATION OF AROMATIC COMPOUND WITH ALIPHATIC MONO-OLEFIN COMPOUND OF 8 TO 18 CARBON ATOMS 审中-公开
标题翻译： 8至18个碳原子的芳烃单烯烃化合物的芳族化合物的烷基化方法和装置
公开(公告)号：WO2008055116A1
公开(公告)日：2008-05-08
申请号：PCT/US2007/082878
申请日：2007-10-29
申请人： UOP LLC , RILEY, Mark G.
发明人： RILEY, Mark G.
IPC分类号： C07C2/56
CPC分类号： C07C2/66 , C07C15/107
摘要： Continuous processes for monoalkylating aromatic compound with an aliphatic feedstock comprising aliphatic olefin of 8 to 18 carbon atoms per molecule are effected using at least 3 reaction zones (104, 106a, 106b) in series, each containing solid alkylation catalyst with effluent cooling between reaction zones (104, 106a, 106b), each of which reaction zones is supplied a portion of the fresh aliphatic feedstock, such that the Reaction Zone Delta T in each reaction zone (104, 106a, 106b) is less than 15°C. The overall aromatic compound to olefin molar ratio is less than 20:1. The alkylation product has desirable linearity and low amounts of dimers, dealkylated compounds and diaryl compounds even though a low aromatic compound to olefin molar ratio is used.
摘要翻译：使用包含至少3个串联的反应区（104,106a，106b），每分子含有8至18个碳原子的脂肪族烯烃的单烷基化芳族化合物的连续方法，其中每个含有固体烷基化催化剂，在反应区域（104,106a，106b），其中每个反应区被供应一部分新鲜脂肪族原料，使得每个反应区（104,106a，106b）中的反应区Delta T小于15℃。总的芳族化合物与烯烃的摩尔比小于20:1。尽管使用低芳族化合物与烯烃的摩尔比，烷基化产物具有所需的线性和低二聚体，脱烷基化合物和二芳基化合物的量。

13. 发明申请

WO2011008311A1 PROCESS FOR USING LAYERED SPHERE CATALYSTS WITH HIGH ACCESSIBILITY INDEXES 审中-公开
标题翻译：使用具有高可接受性指数的层状球形催化剂的方法
公开(公告)号：WO2011008311A1
公开(公告)日：2011-01-20
申请号：PCT/US2010/027082
申请日：2010-03-12
申请人： UOP LLC , GAJDA, Gregory J. , GLOVER, Bryan K. , NEGIZ, Antoine , RILEY, Mark G. , SENETAR, John J. , HOLMGREEN, Erik M.
发明人： GAJDA, Gregory J. , GLOVER, Bryan K. , NEGIZ, Antoine , RILEY, Mark G. , SENETAR, John J. , HOLMGREEN, Erik M.
IPC分类号： C07C2/10 , C07C5/09 , C07C4/06 , C07C11/04 , B01J35/08
CPC分类号： C07C7/163 , B01J21/04 , B01J23/40 , B01J23/44 , B01J23/50 , B01J23/58 , B01J23/66 , B01J35/002 , B01J35/008 , B01J37/0221 , C07C7/167 , C10G45/40 , Y02P20/52 , C07C11/04
摘要： A process and catalyst for use in the selective hydrogenation of acetylene to ethylene is presented. The catalyst comprises a layered structure, wherein the catalyst has an inner core and an outer layer of active material. The catalyst further includes a metal deposited on the outer layer, and the catalyst is formed such that the catalyst has an accessibility index between 3 and 500.
摘要翻译：提出了一种用于将乙炔选择性氢化成乙烯的方法和催化剂。催化剂包括层状结构，其中催化剂具有内核和活性材料的外层。催化剂还包括沉积在外层上的金属，并且形成催化剂使得催化剂的可接近指数在3和500之间。

14. 发明申请

WO2009048761A2 LAYERED ZEOLITIC CATALYST FOR IMPROVED LINEARITY IN DETERGENT ALKYLATION 审中-公开
标题翻译：用于改进线性的层状杀虫剂
公开(公告)号：WO2009048761A2
公开(公告)日：2009-04-16
申请号：PCT/US2008/078213
申请日：2008-09-30
申请人： UOP LLC , JAN, Deng-Yang , RILEY, Mark G.
发明人： JAN, Deng-Yang , RILEY, Mark G.
IPC分类号： C07C15/107 , B01J29/00
CPC分类号： C07C2/66 , C07C2529/18 , C07C2529/70 , C07C15/107
摘要： A process is disclosed wherein a layered catalyst is used for the alkylation of benzene with a substantially linear olefin. The layered catalyst allows for shifting the operating conditions to increase the alkylation of benzene, while reducing the amount of isomerization of the alkyl group. This is important for increasing the quality of the alkylbenzene by increasing the linearity of the alkylbenzene.
摘要翻译：公开了一种方法，其中层状催化剂用于用基本上线性的烯烃烷基化苯。层状催化剂允许转变操作条件以增加苯的烷基化，同时减少烷基的异构化量。这对于通过增加烷基苯的线性来提高烷基苯的质量是重要的。

15. 发明申请

WO2011008310A1 LAYERED SPHERE CATALYSTS WITH HIGH ACCESSIBILITY INDEXES 审中-公开
标题翻译：具有高可达性指数的层状球形催化剂
公开(公告)号：WO2011008310A1
公开(公告)日：2011-01-20
申请号：PCT/US2010/027075
申请日：2010-03-12
申请人： UOP LLC , GAJDA, Gregory J. , GLOVER, Bryan K. , NEGIZ, Antoine , RILEY, Mark G. , SENETAR, John J. , HOLMGREEN, Erik M.
发明人： GAJDA, Gregory J. , GLOVER, Bryan K. , NEGIZ, Antoine , RILEY, Mark G. , SENETAR, John J. , HOLMGREEN, Erik M.
IPC分类号： B01J23/70 , B01J23/38 , B01J23/78 , B01J35/08 , C07C5/05
CPC分类号： B01J23/40 , B01J23/44 , B01J23/58 , B01J23/66 , B01J35/002 , B01J35/008 , B01J35/023 , B01J37/0205 , B01J37/0221 , B01J37/0242 , B01J37/08 , B01J37/18 , C07C7/163 , C07C7/167 , C10G45/40 , Y02P20/52 , C07C11/04
摘要： A process and catalyst for use in the selective hydrogenation of acetylene to ethylene is presented. The catalyst comprises a layered structure, wherein the catalyst has an inner core and an outer layer of active material. The catalyst further includes a metal deposited on the outer layer, and the catalyst is formed such that the catalyst has an accessibility index between 3 and 500.
摘要翻译：提出了一种用于将乙炔选择性氢化成乙烯的方法和催化剂。催化剂包括层状结构，其中催化剂具有内核和活性材料的外层。催化剂还包括沉积在外层上的金属，并且形成催化剂使得催化剂的可接近指数在3和500之间。

16. 发明申请

WO2010074798A1 LAYERED SPHERE CATALYSTS WITH HIGH ACCESSIBILITY INDEXES 审中-公开
标题翻译：具有高可达性指数的层状球形催化剂
公开(公告)号：WO2010074798A1
公开(公告)日：2010-07-01
申请号：PCT/US2009/061576
申请日：2009-10-22
申请人： UOP LLC , GAJDA, Gregory J. , GLOVER, Bryan K. , NEGIZ, Antoine , RILEY, Mark G. , SENETAR, John J. , HOLMGREEN, Erik M.
发明人： GAJDA, Gregory J. , GLOVER, Bryan K. , NEGIZ, Antoine , RILEY, Mark G. , SENETAR, John J. , HOLMGREEN, Erik M.
IPC分类号： B01J23/72 , B01J35/08 , C07C5/09 , C07C11/04
CPC分类号： B01J35/023 , B01J23/50 , B01J23/52 , B01J23/58 , B01J23/622 , B01J23/8926 , B01J35/002 , B01J35/008 , B01J37/0221 , B01J37/0242 , C07C5/09 , C07C2523/62 , C07C2523/66 , C07C2523/89 , Y02P20/52 , C07C11/04
摘要： A process and catalyst for use in the selective hydrogenation of acetylene to ethylene is presented. The catalyst comprises a layered structure, wherein the catalyst has an inner core and an outer layer of active material. The catalyst further includes a metal deposited on the outer layer, and the catalyst is formed such that the catalyst has an accessibility index between 3 and 500.
摘要翻译：提出了一种用于将乙炔选择性氢化成乙烯的方法和催化剂。催化剂包括层状结构，其中催化剂具有内核和活性材料的外层。催化剂还包括沉积在外层上的金属，并且形成催化剂使得催化剂的可接近指数在3和500之间。

17. 发明授权

EP2616176B1 METHOD FOR CONTROLLING 2-PHENYL ISOMER CONTENT OF LINEAR ALKYLBENZENE 有权
标题翻译：控制直链烷基苯2-苯基异构体含量的方法
公开(公告)号：EP2616176B1
公开(公告)日：2018-01-17
申请号：EP11825708.8
申请日：2011-09-08
申请人： UOP LLC
发明人： RILEY, Mark G. , JAN, Deng-Yang , SOHN, Stephen W.
IPC分类号： B01J29/80 , B01J29/08 , C07C2/66 , C07C15/02
CPC分类号： C07C2/66 , B01J29/085 , B01J29/088 , B01J29/18 , B01J29/50 , B01J29/60 , B01J29/70 , B01J29/7007 , B01J29/7034 , B01J29/7038 , B01J29/80 , B01J37/0009 , B01J2229/42 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C2529/80 , C07C15/107
摘要： A method for controlling 2-isomer content in linear alkylbenzene obtained by alkylating benzene with olefins and catalyst used in the method.

18. 发明授权

EP2828237B1 PRODUCTION OF ALKANE SULFONATES 有权
标题翻译：烷烃磺酸盐的生产
公开(公告)号：EP2828237B1
公开(公告)日：2017-11-01
申请号：EP13763547.0
申请日：2013-03-12
申请人： UOP LLC
发明人： RILEY, Mark G. , SOHN, Stephen W.
IPC分类号： C07C309/04 , C07C303/06
CPC分类号： C07C303/06 , C07C309/04 , C07C309/20
摘要： A process for the production of olefin sulfonates is presented. The process comprising generating olefins from normal alkanes through a dehydrogenation unit to produce a mixture of alkanes and alkenes. The mixture is sulfonated to react the olefins and generate olefin sulfonates. The olefin sulfonates are separated from the normal alkanes to produce a product stream, with the normal alkanes recycled to the dehydrogenation unit.

19. 发明授权

EP2077984B1 PROCESSES FOR PRODUCING ALKYLBENZENES OVER SOLID ACID CATALYST AT LOW BENZENE TO OLEFIN RATIOS AND LOW HEAVIES MAKE 有权
标题翻译：用于生产烷基苯OVER固体酸催化剂在低苯与烯烃比和产生了严重的成分的比例很低
公开(公告)号：EP2077984B1
公开(公告)日：2011-03-30
申请号：EP07863626.3
申请日：2007-10-29
申请人： UOP LLC
发明人： RILEY, Mark G. , JAN, Deng-Yang , SOHN, Stephen W.
IPC分类号： C07C15/00
CPC分类号： C07C2/66 , C07C2529/08 , C07C15/107
摘要： The alkylation of aromatic compound with acyclic mono-olefin is effected at low aromatic compound to mono-olefin ratios with reduced co-production of heavies. In the processes a small crystal, acidic FAU molecular sieve is used as a catalyst under alkylation conditions. This invention also relates to catalysts containing small crystal, acidic FAU molecular sieve and at least one other acidic catalytic component.

20. 发明申请

WO2015065629A1 REMOVAL OF LIGHT ALKYLATED AROMATICS FROM THE HEAVY ALKYLATED AROMATICS STREAM 审中-公开
标题翻译：从重型碱性芳香族流体中去除光碱性芳族化合物
公开(公告)号：WO2015065629A1
公开(公告)日：2015-05-07
申请号：PCT/US2014/057713
申请日：2014-09-26
申请人： UOP LLC
发明人： SOHN, Stephen W. , RILEY, Mark G. , MOORE, Michael A.
IPC分类号： C07C7/00 , C07C4/02 , C07C15/06
CPC分类号： C07C6/06 , C07C2/64 , C07C6/126 , C07C303/20 , C10G29/205 , C10G53/02 , C10G2400/30 , C07C309/30 , C07C15/02
摘要： A process for increasing the production of monoalkylbenzenes is presented. The process includes utilizing a transalkylation process to convert dialkylbenzenes to monoalkylbenzenes. The feed to the transalkylation process has alkylated toluenes and alkylated ethylbenzenes and other alkylated aromatics having small alkyl groups with less than 8 carbons removed to improve the efficiency of the transalkylation process. The recycled dialkylbenzenes and a portion of the recycled benzene are converted to monoalkylbenzenes.
摘要翻译：提出了增加单烷基苯生产的方法。该方法包括利用烷基转移方法将二烷基苯转化为单烷基苯。烷基转移方法的进料具有烷基化甲苯和烷基化乙基苯，并且除去具有小于8个碳的小烷基的其它烷基化芳族化合物以提高烷基转移过程的效率。再循环的二苯基苯和一部分再循环的苯被转化为单烷基苯。

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