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11. 发明申请

WO2017205112A1 HIGH CHARGE DENSITY METALLOALUMINOPHOSPHOSILICATE MOLECULAR SIEVES MeAPSO-83 审中-公开
标题翻译：高电荷密度金属铝氧磷酸硅分子筛MeAPSO-83
公开(公告)号：WO2017205112A1
公开(公告)日：2017-11-30
申请号：PCT/US2017/032873
申请日：2017-05-16
申请人： UOP LLC
发明人： LEWIS, Gregory J.
IPC分类号： B01J27/182 , B01J29/85 , B01J31/02 , C01B39/54 , C10G11/05 , C10G35/095
摘要： A new family of crystalline microporous metalloalumino(gallo)phosphosilicates designated MeAPSO-83 has been synthesized. These metalloalumino(gallo)phosphosilicates are represented by the empirical formula of: R p+ rA + mM 2+ wExPSiyOz where A is an alkali metal such as potassium, R is an quaternary ammonium cation such as ethyltrimethylammonium, M is a divalent metal such as Zn and E is a trivalent framework element such as aluminum or gallium. This family of metalloalumino(gallo)phosphosilicate materials are stabilized by combinations of alkali and quaternary ammonium cations, enabling unique, high charge density compositions. The MeAPSO-83 family of materials have the BPH topology and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.
摘要翻译：合成了称为MeAPSO-83的新型结晶微孔金属铝（gallo）磷硅酸盐。这些金属铝（羰基）磷硅酸盐由经验式表示：其中A是碱金属，例如作为钾，R是季铵阳离子如乙基三甲基铵，M是二价金属如Zn，E是三价骨架元素如铝或镓。这种金属铝（镓）磷硅酸盐材料系列通过碱金属和季铵阳离子的组合来稳定化，从而能够实现独特的高电荷密度组合物。 MeAPSO-83系列材料具有BPH拓扑结构，并具有催化性能，用于进行各种烃转化过程和分离性质，以分离至少一种组分。

12. 发明申请

WO2017151845A1 HIGH CHARGE DENSITY SILICOMETALLOPHOSPHATE MOLECULAR SIEVES 审中-公开
标题翻译：高电荷密度硅分子筛分子筛
公开(公告)号：WO2017151845A1
公开(公告)日：2017-09-08
申请号：PCT/US2017/020328
申请日：2017-03-02
申请人： UOP LLC
发明人： LEWIS, Gregory J. , KNIGHT, Lisa M.
IPC分类号： B01J27/182 , B01J29/85 , B01J31/02 , C01B39/54 , C10G11/05 , C10G35/095
摘要： A new family of crystalline microporous high charge density silicometallophosphates has been synthesized. These silicometallophosphate are represented by the empirical formula of: R p+ r M m + E x PSi y O z where M is an alkali metal such as potassium, R is any quaternary ammonium cation such as ethyltrimethylammonium and E is a trivalent framework element such as aluminum or gallium. This family of high charge density silicometallophosphate molecular sieves has catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.
摘要翻译：已经合成了一族新的结晶性微孔高电荷密度硅铝磷酸盐。这些硅铝磷酸盐由以下经验式表示：R + P + M + M + M + E×M + 其中M是碱金属如钾，R是任何季铵阳离子如乙基三甲基铵，E是三价骨架元素如铝或镓。这种高电荷密度硅铝磷酸盐分子筛族具有用于进行各种烃转化过程和用于分离至少一种组分的分离性质的催化性质。

13. 发明申请

WO2014209655A1 MANGANESE OXIDE-BASED AND METALLOMANGANESE OXIDE-BASED ION-EXCHANGERS FOR REMOVING MERCURY (+2) IONS FROM LIQUID STREAMS 审中-公开
标题翻译：用于从液相中除去汞（+2）离子的基于氧化物和氧化镁的氧化物基离子交换器
公开(公告)号：WO2014209655A1
公开(公告)日：2014-12-31
申请号：PCT/US2014/042509
申请日：2014-06-16
申请人： UOP LLC
发明人： LEWIS, Gregory J. , JAKUBCZAK, Paulina , MARTE, Julio C.
IPC分类号： C02F1/42 , C02F1/62
CPC分类号： C02F1/42 , B01J20/02 , B01J39/10 , C02F1/281 , C02F2001/425 , C02F2101/20 , C02F2103/10
摘要： A process for removing Hg 2+ ions from a liquid stream is disclosed. The process involves contacting the liquid stream with specified ion-exchangers based on manganese oxides and metallomanganese oxides of the form A n+ w M 3+ x Mn 1-x O 2 where A can be cations such as Na + or Mg 2+ , M 3+ can be metals such as Fe 3+ or Co 3+ , and the TIC, the theoretical ion exchange capacity per framework metal atom, varies from 0.08 to 0.25. These ion-exchangers are particularly effective in removing Hg 2+ ions from aqueous streams even in the presence of Mg 2+ and Ca 2+ ions.
摘要翻译：公开了从液体流中除去Hg 2+离子的方法。该方法包括使液体流与基于氧化锰和形式为An + wM3 + xMn1-xO2的金属锰氧化物的特定离子交换剂接触，其中A可以是阳离子如Na +或Mg2 +，M3 +可以是金属如Fe3 +或Co3 +，并且 TIC，每个骨架金属原子的理论离子交换能力从0.08变化到0.25。即使在Mg2 +和Ca2 +离子存在下，这些离子交换剂也特别有效地从水流中除去Hg2 +离子。

14. 发明公开

EP4221859A2 PROCESS FOR REMOVING IONS FROM BODILY FLUIDS 审中-实审
公开(公告)号：EP4221859A2
公开(公告)日：2023-08-09
申请号：EP21926038.7
申请日：2021-09-29
申请人： UOP LLC
发明人： LUPTON, Francis Stephen , LEWIS, Gregory J. , HODGES, James M. , JAKUBCZAK, Paulina , SYLEJMANI-REKALIU, Mimoza , SHEETS, William
IPC分类号： B01D15/36 , B01J20/10 , B01J45/00 , A61K47/50 , A61P39/04

15. 发明公开

EP2925436A1 METALLOPHOSPHATE MOLECULAR SIEVES, METHOD OF PREPARATION AND USE 有权
标题翻译：金属磷酸盐分子筛，制备和使用方法
公开(公告)号：EP2925436A1
公开(公告)日：2015-10-07
申请号：EP13858307.5
申请日：2013-11-25
申请人： UOP LLC
发明人： LEWIS, Gregory J. , KNIGHT, Lisa M. , JAKUBCZAK, Paulina , STANCZYK, Justin E.
IPC分类号： B01J27/14 , B01J31/02 , B01J27/18 , B01J27/182 , B01J29/82 , C01B25/26 , C01B39/54 , C07C5/22 , C07C2/66 , C07F15/00 , C07F15/02 , C10G11/02 , C10G35/06 , C10G47/20 , C01B39/46
CPC分类号： C10G47/20 , B01J31/02 , C01B37/08 , C01B39/54 , C07C1/20 , C07C2/66 , C07C5/22 , C07C2529/84 , C07F19/00 , C10G11/05 , C10G35/065 , C10G49/08 , C10G50/00 , C07C11/02 , C07C15/02
摘要： A new family of crystalline microporous metallophosphates designated AlPO-67 has been synthesized. These metallophosphates are represented by the empirical formula R
+
r M
m
2+ EP
x Si
y O
z where R is an organoammonium cation such as the ETMA
+ or DEDMA
+ , M is a framework metal alkaline earth or transition metal of valence 2+, and E is a trivalent framework element such as aluminum or gallium. The AlPO-67 compositions exhibit the LEV framework topology and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component. The materials may be used as a catalytic composite for hydrocarbon conversions or may be used to separate at least one component from a mixture.
摘要翻译：已经合成了一种称为AlPO-67的结晶微孔金属磷酸盐的新家族。这些金属磷酸盐由经验式R + rM m 2 + EP xSi y O z表示，其中R是有机铵阳离子如ETMA +或DEDMA +，M是骨架金属碱土或2+价过渡金属，E 是三价骨架元素，如铝或镓。 AlPO-67组合物表现出LEV骨架拓扑结构并具有用于进行各种烃转化过程和用于分离至少一种组分的分离性质的催化性质。该材料可以用作烃转化的催化复合材料，或者可以用来从混合物中分离至少一种组分。

16. 发明公开

EP2867166A1 METALLOPHOSPHATE MOLECULAR SIEVES, METHOD OF PREPARATION AND USE 有权
标题翻译： METALLOPHOSPHAT分子筛，方法生产和使用
公开(公告)号：EP2867166A1
公开(公告)日：2015-05-06
申请号：EP13808484.3
申请日：2013-05-15
申请人： UOP LLC
发明人： LEWIS, Gregory J. , KNIGHT, Lisa M. , JAKUBCZAK, Paulina , STANCZYK, Justin E.
IPC分类号： C01B39/54 , C01B37/08 , B01J29/85
CPC分类号： C01B39/54 , B01J29/83 , B01J29/84 , B01J29/85 , B01J2229/38 , B01J2229/40 , C01B37/06 , C01B37/065 , C01B37/08 , C10G2/33 , C10G3/48 , C10G11/04 , C10G29/205 , C10G45/04 , C10G45/60 , C10G47/12 , C10G50/00 , Y02P30/20
摘要： A new family of crystalline microporous metallophosphates designated AlPO-59 has been synthesized. These metallophosphates are represented by the empirical formula R
+
r M
m
2+ EP
x Si
y O
z where R is an organoammonium cation such as the ETMA
+ , M is a framework metal alkaline earth or transition metal of valence 2+, and E is a trivalent framework element such as aluminum or gallium. The AlPO-59 compositions are characterized by a new unique ABC-6 net structure and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.

17. 发明申请

WO2017205114A1 HIGH CHARGE DENSITY METALLOALUMINOPHOSPHOSILICATE MOLECULAR SIEVES 审中-公开
标题翻译：高电荷密度金属铝氧磷酸盐分子筛
公开(公告)号：WO2017205114A1
公开(公告)日：2017-11-30
申请号：PCT/US2017/032882
申请日：2017-05-16
申请人： UOP LLC
发明人： LEWIS, Gregory J.
IPC分类号： C01B39/54 , C01B37/08 , B01J29/84
摘要： A new family of crystalline microporous metalloalumino(gallo)phosphosilicate molecular sieves has been synthesized and are designated high charge density (HCD) MeAPSOs. These metalloalumino(gallo)phosphosilicate are represented by the empirical formula of: Rp+rA+mM2+wExPSiyOz where A is an alkali metal such as potassium, R is at least one quaternary ammonium cation such as ethyltrimethylammonium, M is a divalent metal such as Zn and E is a trivalent framework element such as aluminum or gallium. This family of metalloalumino(gallo)phosphosilicate materials are stabilized by combinations of alkali and quaternary ammonium cations, enabling unique, high charge density compositions. The HCD MeAPSO family of materials have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.
摘要翻译：已经合成了一族新的结晶微孔金属铝（镓）磷硅酸盐分子筛，并将其命名为高电荷密度（HCD）MeAPSO。这些金属铝（羰基）磷硅酸盐由经验式表示：Rp + rA + mM2 + wExPSiyOz其中A是碱金属如钾，R是至少一个季铵阳离子如乙基三甲基铵，M是二价金属如 Zn和E是三价骨架元素，例如铝或镓。这种金属铝（镓）磷硅酸盐材料系列通过碱金属和季铵阳离子的组合来稳定化，从而能够实现独特的高电荷密度组合物。 HCD MeAPSO系列材料具有用于进行各种烃转化过程和用于分离至少一种组分的分离性质的催化性质。

18. 发明申请

WO2017151864A1 HIGH CHARGE DENSITY SILICOMETALLOPHOSPHATE MOLECULAR SIEVES SAPO-69 审中-公开
标题翻译：高电荷密度硅磷酸盐分子筛SAPO-69
公开(公告)号：WO2017151864A1
公开(公告)日：2017-09-08
申请号：PCT/US2017/020366
申请日：2017-03-02
申请人： UOP LLC
发明人： LEWIS, Gregory J. , KNIGHT, Lisa
IPC分类号： B01J27/182 , B01J29/85 , B01J31/02 , C01B39/54 , C10G11/05 , C10G35/095
摘要： A new family of crystalline microporous silicometallophosphate designated SAPO-69 has been synthesized. These silicometallophosphate are represented by the empirical formula of: R p+ r M m + E x PSi y O z where M is an alkali metal such as potassium, R is an organoammonium cation such as ethyltrimethylammonium and E is a trivalent framework element such as aluminum or gallium. The SAPO-69 family of materials represent the first phosphate-based molecular sieves to have the OFF topology and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.
摘要翻译：已经合成了一种称为SAPO-69的结晶微孔硅磷酸盐的新家族。这些硅铝磷酸盐由以下经验式表示：R + P + M + M + M + E×M + 其中M是碱金属如钾，R是有机铵阳离子如乙基三甲基铵，E是三价骨架元素如铝或镓。 SAPO-69系列材料代表了第一种具有OFF拓扑结构的磷酸盐基分子筛，并具有用于进行各种烃转化过程和用于分离至少一种组分的分离性质的催化性质。

19. 发明申请

WO2014085281A1 SILICOMETALLOPHOSPHATE MOLECULAR SIEVES, METHOD OF PREPARATION AND USE 审中-公开
标题翻译：硅烷基磷酸酯分子筛，制备和使用方法
公开(公告)号：WO2014085281A1
公开(公告)日：2014-06-05
申请号：PCT/US2013/071565
申请日：2013-11-25
申请人： UOP LLC
发明人： LEWIS, Gregory J. , KNIGHT, Lisa M. , JAKUBCZAK, Paulina , STANCZYK, Justin E.
IPC分类号： B01J27/14 , B01J31/02 , B01J27/18 , B01J27/182 , B01J29/82 , C01B25/26 , C01B39/54 , C07C5/22 , C07C2/66 , C07F15/00 , C07F15/02 , C10G11/02 , C10G35/06 , C10G47/20 , C01B39/46
CPC分类号： C10G47/20 , C01B39/54 , C07C1/20 , C07C2/66 , C07C2529/82 , C10G11/05 , C10G35/065 , C10G49/08 , C10G50/00 , C07C15/02 , C07C11/02
摘要： A new family of crystalline microporous metallophosphates designated MAPSO-64 has been synthesized. These metallophosphates are represented by the empirical formula R+rMmn+EPxSiyOz where R is an organoammonium cation such as ETMA+ or DEDMA+, M is a divalent metal such as an alkaline earth or transition metal, and E is a framework element such as aluminum or gallium. The microporous MAPSO-64 compositions BPH topology and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.
摘要翻译：已经合成了名为MAPSO-64的新型结晶微孔金属磷酸盐系列。这些金属磷酸盐由经验式R + rMmn + EPxSiyOz表示，其中R是有机铵阳离子如ETMA +或DEDMA +，M是二价金属如碱土金属或过渡金属，E是骨架元素如铝或镓。微孔MAPSO-64组合物BPH拓扑结构，并且具有用于进行各种烃转化方法和用于分离至少一种组分的分离性质的催化性质。

20. 发明申请

WO2014085279A1 METALLOPHOSPHATE MOLECULAR SIEVES, METHOD OF PREPARATION AND USE 审中-公开
标题翻译：金属磷酸酯分子筛，制备和使用方法
公开(公告)号：WO2014085279A1
公开(公告)日：2014-06-05
申请号：PCT/US2013/071562
申请日：2013-11-25
申请人： UOP LLC
发明人： LEWIS, Gregory J. , KNIGHT, Lisa M. , JAKUBCZAK, Paulina , STANCZYK, Justin E.
IPC分类号： B01J27/14 , B01J31/02 , B01J27/18 , B01J27/182 , B01J29/82 , C01B25/26 , C01B39/54 , C07C5/22 , C07C2/66 , C07F15/00 , C07F15/02 , C10G11/02 , C10G35/06 , C10G47/20 , C01B39/46
CPC分类号： C10G47/20 , B01J31/02 , C01B37/08 , C01B39/54 , C07C1/20 , C07C2/66 , C07C5/22 , C07C2529/84 , C07F19/00 , C10G11/05 , C10G35/065 , C10G49/08 , C10G50/00 , C07C11/02 , C07C15/02
摘要： A new family of crystalline microporous metallophosphates designated AlPO-67 has been synthesized. These metallophosphates are represented by the empirical formula R + r M m 2+ EP x Si y O z where R is an organoammonium cation such as the ETMA + or DEDMA + , M is a framework metal alkaline earth or transition metal of valence 2+, and E is a trivalent framework element such as aluminum or gallium. The AlPO-67 compositions exhibit the LEV framework topology and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component. The materials may be used as a catalytic composite for hydrocarbon conversions or may be used to separate at least one component from a mixture.
摘要翻译：已经合成了一系列名为AlPO-67的结晶微孔金属磷酸盐系列。这些金属磷酸盐由经验式R + rMm 2 + EPxSiyOz表示，其中R是有机铵阳离子，例如ETMA +或DEDMA +，M是价键2+的骨架金属碱土金属或过渡金属，E是三价骨架元素，例如铝或镓。 AlPO-67组合物表现出LEV框架拓扑结构，并且具有用于进行各种烃转化方法和用于分离至少一种组分的分离性能的催化性质。这些材料可以用作烃转化的催化复合物，或者可以用于从混合物中分离出至少一种组分。

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