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    • 11. 发明申请
    • Cerium based phosphor materials for solid-state lighting applications
    • 用于固态照明应用的铈基磷光体材料
    • US20070159066A1
    • 2007-07-12
    • US11541708
    • 2006-10-02
    • Anthony CheethamRonan Le Toquin
    • Anthony CheethamRonan Le Toquin
    • H01J1/62H01J63/04
    • C09K11/7721C09K11/0883H01L33/502H05B33/14Y02B20/181
    • A luminescent cerium (Ce) doped compound emitting bright red light, comprising a calcium silicate nitride ternary system, such as CaSiN2δOδ:Ce3+, that crystallizes in a face-centered cubic unit cell with a lattice parameter of ˜a=14.88 Å. The Ce doped compound can be used for white light applications either: (i) to enhance the light quality of the system based on a blue LED with a yellow or green phosphor, (ii) as an orange phosphor in combination with a blue LED and a green phosphor, or (iii) as a red phosphor in a setup comprising a ultraviolet (UV) LED and red, green and blue (RGB) phosphors. Substitution of smaller elements on the Ca site or larger elements on the Si site leads to a decrease of the emission wavelength towards the yellow or orange region.
    • 发射亮红光的发光铈(Ce)掺杂化合物,其包含硅酸钙氮化物三元体系,例如CaSi 2 O 3·3O 3:Ce 3+ SUP>,其在具有〜a = 14.88Å的晶格参数的面心立方晶胞中结晶。 Ce掺杂的化合物可以用于白光应用:(i)基于具有黄色或绿色磷光体的蓝色LED来提高系统的光质,(ii)作为橙色荧光粉与蓝色LED组合,以及 绿色荧光体,或(iii)在包括紫外线(UV)LED和红色,绿色和蓝色(RGB))荧光体的设置中的红色荧光体。 在Ca位置上取代更小的元素或Si位点上的较大元素导致朝向黄色或橙色区域的发射波长的减小。