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11. 发明授权

US4670363A Non-aqueous electrochemical cell 失效
标题翻译：非水电化学电池
公开(公告)号：US4670363A
公开(公告)日：1987-06-02
申请号：US910694
申请日：1986-09-22
申请人： Thomas A. Whitney , Donald L. Foster
发明人： Thomas A. Whitney , Donald L. Foster
IPC分类号： H01M6/16 , H01M10/052 , H01M10/0567 , H01M10/0569 , H01M10/36 , H01M6/14
CPC分类号： H01M10/0569 , H01M10/052 , H01M10/0567 , H01M6/164 , H01M6/168
摘要： An improved nonaqueous electrolyte and electrochemical cell containing same, wherein the electrolyte is comprised of a salt complexed by a tertiary amine and an aromatic organic solvent, the improvement being the addition of a solvent having a dielectric constant greater than 20 which provides an electrolyte having a conductivity sufficient to support current densities greater than 1 mA/cm.sub.2.
摘要翻译：一种改进的非水电解质和包含其的电化学电池，其中电解质由与叔胺和芳族有机溶剂络合的盐组成，改进之处在于加入介电常数大于20的溶剂，其提供电解质，其具有电导率足以支持大于1mA / cm2的电流密度。

12. 发明授权

US4104450A Alkali metal batteries having electrolytes including alkali metal salts of complex anions containing heteroatom substituents in organic solvent 失效
标题翻译：具有电解质的碱金属电池，包括在有机溶剂中含有杂原子取代基的复合阴离子的碱金属盐
公开(公告)号：US4104450A
公开(公告)日：1978-08-01
申请号：US827133
申请日：1977-08-24
申请人： Thomas A. Whitney , Lawrence P. Klemann
发明人： Thomas A. Whitney , Lawrence P. Klemann
IPC分类号： H01M6/16 , H01M10/0568 , H01M6/14
CPC分类号： H01M10/0568 , H01M6/162 , H01M6/166
摘要： An electrochemical cell is described which has an alkali metal anode, a cathode and a non-aqueous electrolyte which includes:(a) an organic solvent selected from the group consisting of inertly substituted and unsubstituted ethers, esters, sulfones, organic sulfites, organic sulfates, organic nitrites and organic nitro compounds; and,(b) electrolytically active alkali metal salts including alkali metal complex anion salts having the formula:ZMR.sub.x Q.sub.ywherein Z is an alkali metal, M is a metal selected from the group consisting of Zn, Cd, B, Al, Ga, In, Tl, Sn (stannous), P and As, the Rs are certain organic radicals, the Qs are certain heteroatom substituents, x is zero or a positive integer, and y is a positive integer, subject to the proviso that the sum of x plus y is equal to one plus the valence of the metal M. Preferred are the cells having an alkali metal anode, a transition metal chalcogenide active cathode, and an electrolyte as described.
摘要翻译：描述了具有碱金属阳极，阴极和非水电解质的电化学电池，其包括：

13. 发明授权

US4085138A Process for optical resolution of crude trans-1,2-cyclohexanediamine 失效
标题翻译：粗反式-1,2-环己二胺的光学拆分方法
公开(公告)号：US4085138A
公开(公告)日：1978-04-18
申请号：US711138
申请日：1976-08-03
申请人： Thomas A. Whitney
发明人： Thomas A. Whitney
IPC分类号： C07C87/38 , C07C87/40
CPC分类号： C07C51/367
摘要： Crude trans-1,2-cyclohexanediamine (DACH) contained in a mixture of amines derived as a by-product from the manufacture of 1,6-hexanediamine (HDA) or any other synthesis process crude by-product stream may be directly resolved into its optical isomers by using a mixture of tartaric acid and a second acid selected from the group consisting of C.sub.1 to C.sub.8 carboxylic acids and HCl, without first separating the DACH in high purity from the mixed amine component by-product stream. Alternatively, racemic DACH may be separated from a crude mixed amine component by-product stream by use of oxalic, sulfuric and/or nitric acids. This racemic product may then be optically resolved by techniques known in the art.
摘要翻译：衍生自制备1,6-己二胺（HDA）或任何其他合成方法粗副产物流的副产物的胺混合物中所含的粗反式1,2-环己烷二胺（DACH）可直接分解为其光学异构体通过使用酒石酸和选自C1至C8羧酸和HCl的第二种酸的混合物，而不首先将高纯度的DACH与混合的胺组分副产物流分离。或者，外消旋DACH可以通过使用草酸，硫酸和/或硝酸与粗混合胺组分副产物流分离。然后可以通过本领域已知的技术光学拆分外消旋产物。

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