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11. 发明申请

US20100087597A1 WATER/OIL REPELLENT COMPOSITION, METHOD FOR PRODUCTION THEREOF, AND ARTICLE 有权
标题翻译：水/油组合物，其生产方法和文章
公开(公告)号：US20100087597A1
公开(公告)日：2010-04-08
申请号：US12570893
申请日：2009-09-30
申请人： Minako Shimada , Kazunori Sugiyama , Yuuichi Oomori
发明人： Minako Shimada , Kazunori Sugiyama , Yuuichi Oomori
IPC分类号： C08F2/32 , C08K5/05 , C08K5/09 , C08K5/06
CPC分类号： D06M15/277 , C08F214/18 , C08F220/24 , C08F220/34 , C08F2220/1891 , D06M15/248 , D06M15/256 , D06M15/263 , D06M2200/11 , D06M2200/12
摘要： To provide a water/oil repellent composition which can give water/oil repellency to a surface of an article and has excellent durability (wash durability and heavy-rain durability), a method for producing such a composition, and an article which has water/oil repellency and is less susceptible to deterioration of water/oil repellency when it is washed or in heavy rain.A water/oil repellent composition which comprises a copolymer having polymerized units derived from monomer (a) and polymerized units derived from monomer (b), wherein the proportion of the polymerized units derived from the monomer (b) is 30 to 80 mol % in the total of the polymerized units derived from the monomer (a) and the polymerized units derived from the monomer (b). Monomer (a) is a compound represented by the formula: (Z-Y)nX; wherein Z is a C1-6 perfluoroalkyl group or the like; Y is a bivalent organic group or the like; n is 1 or 2; and X is a polymerizable unsaturated group; and monomer (b) is a (meth)acrylate having no polyfluoroalkyl group and having an C20-30 alkyl group.
摘要翻译：本发明提供一种斥水斥油剂组合物，其能够对制品的表面赋予斥水斥油性，并且具有优异的耐久性（耐洗涤耐久性和耐雨性），制造这种组合物的方法以及具有水/ 拒油性，并且在洗涤或大雨时不易受到拒水/斥油性的损害。含有衍生自单体（a）的聚合单元和源自单体（b）的聚合单元的共聚物的斥水斥油剂组合物，其中衍生自单体（b）的聚合单元的比例为30〜80摩尔％衍生自单体（a）的聚合单元和衍生自单体（b）的聚合单元的总和。单体（a）是由下式表示的化合物：（Z-Y）n X; 其中Z为C1-6全氟烷基等; Y是二价有机基团等; n为1或2; X为可聚合不饱和基团; 单体（b）是不具有多氟烷基且具有C20-30烷基的（甲基）丙烯酸酯。

12. 发明申请

US20110071248A1 COPOLYMER, METHOD FOR ITS PRODUCTION, AND WATER/OIL REPELLENT COMPOSITION 审中-公开
标题翻译：共聚物，其生产方法和水/油组合物
公开(公告)号：US20110071248A1
公开(公告)日：2011-03-24
申请号：US12958906
申请日：2010-12-02
申请人： Kazunori Sugiyama , Toyomichi Shimada , Nobuyuki Otozawa , Yuuichi Oomori , Minako Shimada
发明人： Kazunori Sugiyama , Toyomichi Shimada , Nobuyuki Otozawa , Yuuichi Oomori , Minako Shimada
IPC分类号： C08F214/18 , C08L27/12 , C08F220/24
CPC分类号： C08F214/18 , C08F214/202 , C08F214/222 , C08F216/1408 , C08F220/26 , C08F220/36 , C08F220/58 , C08F222/10 , C08F2220/1891 , C08F214/08
摘要： To provide a copolymer which is capable of providing an article surface with a dynamic water repellency and which has extremely excellent washing durability of water repellency and oil repellency, while placing little burden on the environment; a method for its production; and a water/oil repellent composition.A copolymer comprising structural units of the monomer (a) and structural units of the monomer (b), wherein the total of the content of structural units based on the monomer (a) and the content of structural units based on the monomer (b) is at least 85 mass % of all structural units (100 mass %), and the molar ratio ((a)/(b)) of the content of structural units based on the monomer (a) to the content of structural units based on the monomer (b) is from 0.12 to 3; and a water/oil repellent composition containing such a copolymer. Monomer (a): a compound represented by (Z—Y)n—X, wherein Z is a C1-6 polyfluoroalkyl group or the like, Y is a bivalent organic group or a single bond, n is 1 or 2, and when n is 1, and X is a polymerizable unsaturated group. Monomer (b): a halogenated olefin.
摘要翻译：为了提供一种共聚物，其能够提供具有动态拒水性的物品表面，并且在环境上施加很小的负担的情况下具有非常优异的防水性和拒油性的洗涤耐久性。一种生产方法; 和斥水斥油剂组合物。包含单体（a）的结构单元和单体（b）的结构单元的共聚物，其中基于单体（a）的结构单元的含量和基于单体（b）的结构单元的含量的总和基于单体（a）的结构单元的含量与基于单体（a）的结构单元的含量相比，所有结构单元（100质量％）的至少85质量％和结构单元的含量（（a）/（b）单体（b）为0.12〜3; 和含有这种共聚物的斥水斥油剂组合物。单体（a）：由（Z-Y）n -X表示的化合物，其中Z为C1-6多氟烷基等，Y为二价有机基团或单键，n为1或2，当 n为1，X为可聚合不饱和基团。单体（b）：卤代烯烃。

13. 发明申请

US20110196067A1 WATER/OIL REPELLENT COMPOSITION AND METHOD FOR ITS PRODUCTION 审中-公开
标题翻译：水/油组合物及其生产方法
公开(公告)号：US20110196067A1
公开(公告)日：2011-08-11
申请号：US13088445
申请日：2011-04-18
申请人： Nobuyuki OTOZAWA , Yuuichi Oomori , Minako Shimada , Toyomichi Shimada
发明人： Nobuyuki OTOZAWA , Yuuichi Oomori , Minako Shimada , Toyomichi Shimada
IPC分类号： C09D133/16 , C09D163/00
CPC分类号： C08F214/06 , C09D127/06 , C09D129/10 , C09K3/18 , D06M15/248 , D06M15/256 , D06M15/263 , D06M15/277 , D06M15/29 , D06M15/347 , D06M2200/11 , D06M2200/12
摘要： To provide a water/oil repellent composition which is capable of imparting sufficient dynamic water repellency and post-air-drying water repellency to the surface of an article and which presents a low environmental impact, and a method for its production.A water/oil repellent composition which comprises a copolymer having structural units based on the following monomer (a), structural units based on the following monomer (b) and structural units based on the following monomer (c), and a medium, wherein the molar ratio of the structural units based on the monomer (a) to the structural units based on the monomer (b) (i.e. (a)/(b)) is at least 1: monomer (a): vinyl chloride; monomer (b): a vinyl ether having no polyfluoroalkyl group and having a crosslinkable functional group; and monomer (c): a monomer having a polyfluoroalkyl group.
摘要翻译：本发明提供一种斥水斥油剂组合物及其制造方法，其能够赋予制品表面充分的动态拒水性和空气后干燥性拒水性。包含具有基于以下单体（a）的结构单元的共聚物，基于以下单体（b）的结构单元和基于以下单体（c）的结构单元）和介质的斥水斥油剂组合物，其中，基于单体（a）的结构单元与基于单体（b）（即（a）/（b））的结构单元的摩尔比为至少1：单体（a）：氯乙烯; 单体（b）：不具有多氟烷基且具有交联性官能团的乙烯基醚; 和单体（c）：具有多氟烷基的单体。

14. 发明申请

US20100048846A1 WATER/OIL REPELLENT COMPOSITION, METHOD FOR PRODUCTION THEREOF, AND ARTICLE 有权
标题翻译：水/油组合物，其生产方法和文章
公开(公告)号：US20100048846A1
公开(公告)日：2010-02-25
申请号：US12607134
申请日：2009-10-28
申请人： Kazunori SUGIYAMA , Kyouichi Kaneko , Yuuichi Oomori
发明人： Kazunori SUGIYAMA , Kyouichi Kaneko , Yuuichi Oomori
IPC分类号： C08F16/24
CPC分类号： D06M15/277 , C08F220/24 , C08F220/36 , C08F238/00 , C08F2220/1891 , C08F2220/286 , C09D133/16 , D06M15/256 , D06M15/263 , D06M15/53 , D06M2200/11 , D06M2200/12
摘要： To provide a water/oil repellent composition which can impart water/oil repellency to a surface of an article without having its texture deteriorated, and has excellent durability against washing and stability, a method for producing such a composition, and an article treated with such a water/oil repellent composition.A water/oil repellent composition which comprises a copolymer having polymerized units derived from monomer (a), polymerized units derived from monomer (b) and polymerized units derived from monomer (c). Here, monomer (a) is a compound represented by the formula: (Z—Y)nX; wherein Z is a C1-6 perfluoroalkyl group or the like; Y is a bivalent organic group or a single bond; n is 1 or 2; and X is a polymerizable unsaturated group; monomer (b) is a (meth)acrylate having no Rf group and having a C12-18 alkyl group; and monomer (c) is monomer (c1) having no Rf group and having a blocked isocyanate group or monomer (c2) having no Rf group and having at least two polymerizable unsaturated groups.
摘要翻译：提供一种斥水斥油剂组合物，其能够赋予制品表面无斥水性，而不会使织物变质，并且具有优异的耐洗涤耐久性和稳定性，制备这种组合物的方法和用这种方法处理的制品斥水斥油剂组合物。包含具有衍生自单体（a）的聚合单元，衍生自单体（b）的聚合单元和源自单体（c）的聚合单元）的共聚物的斥水斥油剂组合物。这里，单体（a）为下式所示的化合物：（Z-Y）n X; 其中Z为C1-6全氟烷基等; Y是二价有机基团或单键; n为1或2; X为可聚合不饱和基团; 单体（b）是不具有Rf基且具有C12-18烷基的（甲基）丙烯酸酯; 单体（c）是不具有Rf基且具有封端异氰酸酯基的单体（c1）或不具有Rf基且具有至少两个可聚合不饱和基团的单体（c2）。

15. 发明授权

US08791218B2 Water/oil repellent composition, method for production thereof, and article 有权
标题翻译：斥水斥油剂组合物，其制造方法和制品
公开(公告)号：US08791218B2
公开(公告)日：2014-07-29
申请号：US12607134
申请日：2009-10-28
申请人： Kazunori Sugiyama , Kyouichi Kaneko , Yuuichi Oomori
发明人： Kazunori Sugiyama , Kyouichi Kaneko , Yuuichi Oomori
IPC分类号： C08F16/24
CPC分类号： D06M15/277 , C08F220/24 , C08F220/36 , C08F238/00 , C08F2220/1891 , C08F2220/286 , C09D133/16 , D06M15/256 , D06M15/263 , D06M15/53 , D06M2200/11 , D06M2200/12
摘要： To provide a water/oil repellent composition which can impart water/oil repellency to a surface of an article without having its texture deteriorated, and has excellent durability against washing and stability, a method for producing such a composition, and an article treated with such a water/oil repellent composition. A water/oil repellent composition which comprises a copolymer having polymerized units derived from monomer (a), polymerized units derived from monomer (b) and polymerized units derived from monomer (c). Here, monomer (a) is a compound represented by the formula: (Z—Y)nX; wherein Z is a C1-6 perfluoroalkyl group or the like; Y is a bivalent organic group or a single bond; n is 1 or 2; and X is a polymerizable unsaturated group; monomer (b) is a (meth)acrylate having no Rf group and having a C12-18 alkyl group; and monomer (c) is monomer (c1) having no Rf group and having a blocked isocyanate group or monomer (c2) having no Rf group and having at least two polymerizable unsaturated groups.
摘要翻译：提供一种斥水斥油剂组合物，其能够赋予制品表面无斥水性，而不会使织物变质，并且具有优异的耐洗涤耐久性和稳定性，制备这种组合物的方法和用这种方法处理的制品斥水斥油剂组合物。包含具有衍生自单体（a）的聚合单元，衍生自单体（b）的聚合单元和源自单体（c）的聚合单元）的共聚物的斥水斥油剂组合物。这里，单体（a）为下式所示的化合物：（Z-Y）n X; 其中Z为C1-6全氟烷基等; Y是二价有机基团或单键; n为1或2; X为可聚合不饱和基团; 单体（b）是不具有Rf基且具有C12-18烷基的（甲基）丙烯酸酯; 单体（c）是不具有Rf基且具有封端异氰酸酯基的单体（c1）或不具有Rf基且具有至少两个可聚合不饱和基团的单体（c2）。

16. 发明申请

US20100331479A1 COPOLYMER AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：共聚物及其制造方法
公开(公告)号：US20100331479A1
公开(公告)日：2010-12-30
申请号：US12878045
申请日：2010-09-09
申请人： Kazunori Sugiyama , Toyomichi Shimada , Nobuyuki Otozawa , Yuuichi Oomori
发明人： Kazunori Sugiyama , Toyomichi Shimada , Nobuyuki Otozawa , Yuuichi Oomori
IPC分类号： C08F16/24 , C08F214/18 , C08F220/22 , C08L33/12 , C08F214/06 , C08F214/08
CPC分类号： C08F214/00 , C08F214/06 , C08F214/08 , C08F220/18 , C08F220/24 , C08F220/26 , Y10T428/3154
摘要： To provide a copolymer which can impart sufficient dynamic water repellency, after air-drying water repellency and friction durability to a surface of an article, and which has low impact on the environment, a method for producing the same, a water repellent composition and an article excellent in dynamic water repellency, after air-drying water repellency and friction durability.A copolymer which is characterized in that it has structural units based on the following monomer (a) and structural units based on the following monomer (b), wherein the content of structural units based on the monomer (a) is from 5 to 95 mass % in the total structural units (100 mass %), the content of structural units based on the monomer (b) is from 5 to 60 mass % in the total structural units (100 mass %) and the sum of the contents of structural units based on the monomer (a) and structural units based on the monomer (b) is at least 65 mass % in the total structural units (100 mass %), and a water repellent composition which comprises the copolymer: Monomer (a): a (meth)acrylate having no Rf group and having a C20-30 alkyl group; Monomer (b): a halogenated olefin.
摘要翻译：为了提供赋予足够的动态防水性的共聚物，对制品表面的空气干燥防水性和摩擦耐久性，对环境的影响较小的共聚物，其制造方法，防水组合物和具有优异的动态防水性，空气干燥防水性和摩擦耐久性。一种共聚物，其特征在于其具有基于以下单体（a）的结构单元和基于以下单体（b）的结构单元，其中基于单体（a）的结构单元的含量为5至95质量份（100质量％），基于单体（b）的结构单元的含量在总结构单位（100质量％）中为5〜60质量％，结构单元的含量之和基于单体（a）和基于单体（b）的结构单元在总结构单元（100质量％）中为至少65质量％，以及包含共聚物的防水组合物：单体（a）：a （甲基）丙烯酸酯，不具有Rf基且具有C20-30烷基; 单体（b）：卤代烯烃。

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