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    • 11. 发明授权
    • Trisazo compound, ink composition, recording method and colored body
    • 三唑类化合物,油墨组合物,记录方法和着色体
    • US08080100B2
    • 2011-12-20
    • US12989784
    • 2009-04-28
    • Takashi YoshimotoYoshiaki KawaidaTakahiko Matsui
    • Takashi YoshimotoYoshiaki KawaidaTakahiko Matsui
    • C09D11/02C09B31/16
    • B41M5/0023C09B31/28C09D11/328
    • Disclosed is a dye compound for black ink which has high solubility in media composed mainly of water and which is stable even when a high-concentration aqueous solution and ink are stored over a long term. The density of printed images is very high, and even if a high-concentration solution is used for printing, no bronzing occurs in the images, and black recorded images are provided with which all aspects of printed image durability, particularly light resistance and ozone gas resistance, are excellent. Also disclosed is an ink composition thereof. Trisazo compounds represented by general formula (1) or tautomers thereof or salts thereof are used as said dye compound for black ink. In formula (1), group A represents a 2-naphthothiazolyl group, R1 represents a substitutable C1 to C4 alkyl group or the like, R2 represents a cyano group or the like, R3 and R4 independently represent a hydrogen atom, a sulfo group, or the like, R5 to R7 independently represent a hydrogen atom, a substitutable C1 to C4 alkyl group, or a substitutable C1 to C4 alkoxy group, or the like, and R8 to R10 independently represent a hydrogen atom, a substitutable C1 to C4 alkyl group, a substitutable C1 to C4 alkxy group, a substitutable C1 to C4 alkylthio group, or the like.
    • 公开了一种黑色油墨用染料化合物,其在主要由水组成的介质中的溶解度高,即使长期储存高浓度水溶液和油墨也是稳定的。 印刷图像的浓度非常高,即使使用高浓度溶液进行印刷,也不会在图像中发生烫伤,并且黑色记录图像具有印刷图像耐久性,特别是耐光性和臭氧气体的所有方面 阻力很好。 还公开了其油墨组合物。 作为黑色油墨的染料化合物,使用由通式(1)表示的三唑并
      化合物或其互变异构体或其盐。 式(1)中,A组表示2-萘并噻唑基,R 1表示可取代的C 1〜C 4烷基等,R 2表示氰基等,R 3和R 4分别表示氢原子, R 5〜R 7独立地表示氢原子,可取代的C 1〜C 4烷基或可取代的C 1至C 4烷氧基等,R 8至R 10独立地表示氢原子,可取代的C 1至C 4烷基 基团,可取代的C1至C4烷氧基,可取代的C1-C4烷硫基等。
    • 15. 发明申请
    • Trisazo compound, ink composition, and colored object
    • 三唑烷化合物,油墨组合物和有色物体
    • US20070107628A1
    • 2007-05-17
    • US10581469
    • 2004-11-26
    • Takahiko MatsuiHiroaki OhnoTakashi YonedaYoshiaki KawaidaYasuo Shirasaki
    • Takahiko MatsuiHiroaki OhnoTakashi YonedaYoshiaki KawaidaYasuo Shirasaki
    • C09D11/00C09D11/02C07C245/02
    • C09D11/328C09B33/22
    • [PROBLEMS] To provide: a black compound which is for use in ink-jet recording or writing utensils, is excellent in ozone resistance, light resistance, moisture resistance, and color rendering, and gives a recording fluid having satisfactory storage stability; and an ink composition containing the compound. [MEANS FOR SOLVING PROBLEMS] The black compound is a trisazo compound represented by the following formula (1) or a salt thereof. (1) [In the formula (1), R1 and R2 each independently represents hydrogen, carboxy, sulfo, hydroxy, a C1-4 alkyl, C1-4 alkoxy, or sulfo group optionally substituted by C1-4 alkoxy, an optionally carboxylated C1-4 alkoxy group, etc.; and A represents phenyl or naphthyl (provided that the phenyl and naphthyl groups may be substituted by halogeno, carboxy, sulfo, sulfamonyl optionally substituted by alkyl or phenyl, nitro, etc.).]
    • 提供:用于喷墨记录或书写用具的黑色化合物,具有优异的耐臭氧性,耐光性,耐湿性和显色性,并且得到具有令人满意的储存稳定性的记录液; 和含有该化合物的油墨组合物。 解决问题的方法黑色化合物是由下式(1)表示的三偶氮化合物或其盐。 (1)[式(1)中,R 1和R 2各自独立地表示氢,羧基,磺基,羟基,C 1-4烷基, C 1-4烷氧基或任选被C 1-4烷氧基取代的磺基,任选羧基化的C 1-4烷基 烷氧基等。 并且A表示苯基或萘基(条件是苯基和萘基可以被卤素,羧基,磺基,任选被烷基或苯基,硝基等取代的磺酰氨基取代)。
    • 16. 发明申请
    • MODIFIED NATURAL RUBBER, PRODUCTION PROCESS FOR THE SAME AND RUBBER COMPOSITION AND TIRE PREPARED BY USING THE SAME
    • 改性天然橡胶,其制造方法和橡胶组合物及使用其制备的轮胎
    • US20110224365A1
    • 2011-09-15
    • US13128429
    • 2009-11-10
    • Takahiko Matsui
    • Takahiko Matsui
    • C08F36/08C08L7/00C08F8/14
    • C08C1/04B60C1/0016C08C1/02C08C19/38C08K3/013C08L15/00
    • After hydrolyzing a phospholipid bonded to a molecular end of a natural rubber, a compound having a polar group reacting with a hydroxyl group is condensed with a hydroxyl group contained in the phospholipid-hydrolyzed natural rubber to thereby obtain a modified natural rubber in which a polar group is present at a molecular end. The modified natural rubber thus obtained in which a polar group is present at a molecular end is used for a rubber component of a rubber composition, whereby a rubber composition in which carbon black and silica as fillers are bonded to the rubber component to enhance a reinforcing effect and which is excellent in a low hysteresis loss property and abrasion resistance to a large extent is obtained. An enzyme or an alkali is used for hydrolyzing the phospholipid, and a condensing agent is used for condensing the polar group-containing compound.
    • 在与天然橡胶的分子末端结合的磷脂水解后,将具有与羟基反应的极性基团的化合物与磷脂水解天然橡胶中所含的羟基缩合,得到极性的改性天然橡胶 基团存在于分子末端。 橡胶组合物的橡胶组分使用由此获得的极性基团在分子末端存在的改性天然橡胶,由此将作为填料的炭黑和二氧化硅作为填料的橡胶组合物结合到橡胶组分以增强强化 并且获得了在很大程度上具有优异的低磁滞损耗特性和耐磨性。 酶或碱用于水解磷脂,并使用缩合剂冷凝含极性基团的化合物。
    • 18. 发明授权
    • Azo compound, ink composition, and colored object
    • 偶氮化合物,油墨组合物和有色物体
    • US07503965B2
    • 2009-03-17
    • US11547302
    • 2005-04-06
    • Takahiko MatsuiHiroaki OhnoTakashi YonedaYasuo Shirasaki
    • Takahiko MatsuiHiroaki OhnoTakashi YonedaYasuo Shirasaki
    • C09D11/00C09D11/02C09B35/50B41J2/01
    • C07D231/46C09B35/58C09D11/17C09D11/328
    • A novel azo compound represented by the following Formula (1) wherein A represents the following Formula (2) and is located preferably in a position meta or para to the azo group; R1 and R2 each independently represents hydrogen, carboxy, sulfo, nitro, C1-4 alkoxy, etc.; R3 and R4 each independently represents hydrogen, halogeno, cyano, carboxy, sulfo, nitro, C1-4 alkyl, hydroxy, or C1-4 alkoxy; and n is 0 or 1. [In the Formula (2), R5 represents cyano, carboxy, C1-4 alky, C1-4 alkoxycarbonyl, or phenyl; and R6, R7, and R8 each independently represents hydrogen, halogeno, cyano, carboxy, sulfo, nitro, C1-4 alkyl, C1-4 alkoxy, or acylamino.] The compound is useful as a black dye, especially one for ink compositions for, e.g., inkjet prints. Also provided are: an ink composition which contains the compound and has excellent storage stability; and a print obtained through recording with the ink. The print is excellent in light resistance, ozone resistance, fastness to moisture, etc.
    • 由下式(1)表示的新型偶氮化合物,其中A表示下式(2),优选位于偶氮基的间位或对位; R 1和R 2各自独立地表示氢,羧基,磺基,硝基,C 1-4烷氧基等。 R 3和R 4各自独立地表示氢,卤素,氰基,羧基,磺基,硝基,C 1-4烷基,羟基或C 1-4烷氧基; 并且n为0或1. [式(2)中,R 5表示氰基,羧基,C 1-4烷基,C 1-4烷氧基羰基或苯基。 并且R 6,R 7和R 8各自独立地表示氢,卤素,氰基,羧基,磺基,硝基,C 1-4烷基,C 1-4烷氧基或酰基氨基。]该化合物可用作黑色染料,特别是用于油墨组合物 例如喷墨打印。 还提供:含有该化合物并具有优异储存稳定性的油墨组合物; 以及通过用墨水记录获得的印刷品。 该印刷品的耐光性,耐臭氧性,耐潮湿性等优异。
    • 20. 发明申请
    • Azo compound, ink composition, recording method and colored article
    • 偶氮化合物,油墨组合物,记录方法和彩色制品
    • US20090118479A1
    • 2009-05-07
    • US11921201
    • 2006-06-08
    • Hiroaki OhnoTakahiko MatsuiShinjirou TakahashiYasuo Shirasaki
    • Hiroaki OhnoTakahiko MatsuiShinjirou TakahashiYasuo Shirasaki
    • C09B35/64B05D5/00
    • C09B33/18C09D11/328
    • The present invention relates to an azo compound represented by the following formula (1) (wherein, each of R1 and R2 independently represents a hydrogen atom, a halogen atom, a cyano group, a carboxyl group, a sulfo group, a sulfamoyl group or the like, each of m and n independently represents 0 or 1, X represents a sulfo group, B represents a substituted p-phenylene group or a substituted p-naphthylene group (these may be substituted by a group selected from the group consisting of a sulfo group, a sulfo C1 to C4 alkoxy group, a C1 to C4 alkyl group and the like), and C represents a substituted phenyl group or a naphthyl group) or a salt thereof, an ink composition containing it, especially a black ink composition. Said pentakis-azo compound is excellent in solubility to medium whose main component is water and suitable for an water-soluble composition (ink composition and the like) for inkjet recording and writing tools; recorded articles recorded using said composition are excellent in fastnesses such as light fastness and ozone gas fastness; bronzing is not generated on the recorded images; and its recording liquids are good in storage stability.
    • 本发明涉及由下式(1)表示的偶氮化合物(其中,R 1和R 2各自独立地表示氢原子,卤素原子,氰基,羧基,磺基,氨磺酰基或 m,n各自独立地表示0或1,X表示磺基,B表示取代的对亚苯基或取代的对亚萘基(它们可以被选自以下的基团取代: 磺基,磺基C1〜C4烷氧基,C1〜C4烷基等),C表示取代苯基或萘基)或其盐,含有它的油墨组合物,特别是黑色油墨组合物 。 所述五烷基偶氮化合物对主要成分为水的介质的溶解性优异,适用于喷墨记录和书写工具的水溶性组合物(油墨组合物等); 使用所述组合物记录的记录物具有优异的耐光性,例如耐光性和耐臭氧气体牢度; 记录图像上不产生烫金; 其记录液体的储存稳定性好。