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11. 发明授权

US07335804B2 Direct conversion of HCFC 225ca/cb mixture 有权
标题翻译：直接转化HCFC 225ca / cb混合物
公开(公告)号：US07335804B2
公开(公告)日：2008-02-26
申请号：US11265949
申请日：2005-11-03
申请人： Haridasan Nair , Sudip Mukhopadhyay , Michael Van Der Puy
发明人： Haridasan Nair , Sudip Mukhopadhyay , Michael Van Der Puy
IPC分类号： C07C19/08
CPC分类号： C07C17/23 , C07C17/00 , C07C17/21 , C07C21/18 , C07C19/08 , C07C19/10
摘要： Provided are methods for producing hydrofluorocarbons via the selective reduction of a halocarbon blend comprising 1,3-dichloro-1,1,2,2,3-pentafluoropropane.
摘要翻译：提供了通过选择性还原包含1,3-二氯-1,1,2,2,3-五氟丙烷的卤代烃共混物制备氢氟烃的方法。

12. 发明申请

US20060030744A1 Processes for synthesis of 1,3,3,3-tetrafluoropropene 有权
标题翻译：合成1,3,3,3-四氟丙烯的方法
公开(公告)号：US20060030744A1
公开(公告)日：2006-02-09
申请号：US11118530
申请日：2005-04-29
申请人： Sudip Mukhopadhyay , Haridasan Nair , HsuehSung Tung , Michael Van Der Puy
发明人： Sudip Mukhopadhyay , Haridasan Nair , HsuehSung Tung , Michael Van Der Puy
IPC分类号： C07C17/087
CPC分类号： C07C17/06 , C07C17/04 , C07C17/206 , C07C17/21 , C07C17/25 , C07C21/18 , C07C19/14 , C07C19/16 , C07C19/01 , C07C19/10
摘要： Disclosed in one embodiment is a process for the synthesis of 1,3,3,3-tetrafluoropropene that comprises (a) reacting a compound of formula (I) X1X2 with a compound of formula (II) CF3CH═CH2 to produce a reaction product comprising a compound of formula (III) CF3CHX1CH2X2, wherein X1 and X2 are each independently selected from the group consisting of hydrogen, chlorine, bromine and iodine, provided that X1 and X2 are not both hydrogen; (b) when X2 in formula (III) is not fluorine, fluorinating the compound of formula (III) to produce a reaction product comprising a compound of formula (III) wherein X1 is as described above and X2 is fluorine; and (c) exposing said compound of formula (III) to reaction conditions effective to convert said compound to 1,3,3,3-tetrafluoropropene. In another embodiment, the process comprises (a) reacting chlorine with a compound of formula (I) CH3CH═CH2 to produce a reaction product comprising a compound of formula (II) CCl3CHC1CH2C1; (b) fluorinating the compound of formula (II) to produce a reaction product comprising a compound of formula (III) CF3CHC1CH2F; and (c) exposing said compound of said formula (III) to reaction conditions effective to convert said compound to 1,3,3,3-tetrafluoropropene.
摘要翻译：在一个实施方案中公开了一种用于合成1,3,3,3-四氟丙烯的方法，其包括（a）使式（I）化合物X 1，X 2，与式（II）化合物CF 3 CH-CH 2取代，生成包含式（III）化合物的反应产物CF 3 其中X 1和X 2都是（CH 2）2 CH 2，其中X 1和X 2都是各自独立地选自氢，氯，溴和碘，条件是X 1和X 2都不是氢; （b）当式（III）中的X 2不是氟时，氟化式（III）化合物以产生包含式（III）化合物的反应产物，其中X 1， / SUP>如上所述，X 2是氟; 和（c）将所述式（III）化合物暴露于有效将所述化合物转化为1,3,3,3-四氟丙烯的反应条件。在另一个实施方案中，该方法包括（a）使氯与式（I）CH 3 CH-CH 2 2的化合物反应以产生包含式（II）CCl 3 CHClCH 2 C 1; （b）氟化式（II）化合物以产生包含式（III）化合物的反应产物：CF 3 CHClCH 2 F; 和（c）将所述式（III）的所述化合物暴露于有效将所述化合物转化为1,3,3,3-四氟丙烯的反应条件。

13. 发明申请

US20070197842A1 METHOD FOR PRODUCING FLUORINATED ORGANIC COMPOUNDS 有权
标题翻译：生产氟化有机化合物的方法
公开(公告)号：US20070197842A1
公开(公告)日：2007-08-23
申请号：US11619592
申请日：2007-01-03
申请人： Sudip Mukhopadhyay , Hsueh Tung , Barbara Light , Steven Phillips , Jing Ma , Cheryl Bortz , Michael Van Der Puy , Daniel Merkel , Rajesh Dubey
发明人： Sudip Mukhopadhyay , Hsueh Tung , Barbara Light , Steven Phillips , Jing Ma , Cheryl Bortz , Michael Van Der Puy , Daniel Merkel , Rajesh Dubey
IPC分类号： C07C21/18 , C07C17/25
CPC分类号： C07C17/25 , C07C17/00 , C07C17/04 , C07C17/087 , C07C17/10 , C07C17/20 , C07C17/204 , C07C17/206 , C07C17/21 , C07C17/26 , C07C17/269 , C07C17/272 , C07C17/278 , C07C21/18 , C07C19/01 , C07C19/10 , C07C19/08 , C07C21/073 , C07C21/04
摘要： Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF3CF═CH2 (1234yf). Three steps may be used in preferred embodiments in which a feedstock such as CCl2═CClCH2Cl (which may be purchased or synthesized from 1,2,3-trichloropropane) is fluorinated (preferably with HF in gas-phase in the presence of a catalyst) to synthesize a compound such as CF3CCl═CH2, preferably in a 80-96% selectivity. The CF3CCl═CH2 is preferably converted to CF3CFClCH3 (244-isomer) using a SbCl5 as the catalyst which is then transformed selectively to 1234yf, preferably in a gas-phase catalytic reaction using activated carbon as the catalyst. For the first step, a mixture of Cr2O3 and FeCl3/C is preferably used as the catalyst to achieve high selectivity to CF3CCl═CH2 (96%). In the second step, SbCl5/C is preferably used as the selective catalyst for transforming 1233xf to 244-isomer, CF3CFClCH3. The intermediates are preferably isolated and purified by distillation and used in the next step without further purification, preferably to a purity level of greater than about 95%.
摘要翻译：公开了用于生产氟化烯烃的方法，优选适于CF 3 CH 2 CH 2（1234yf）的商业化。在优选实施方案中可以使用三个步骤，其中原料如CCl 2 -CClCH 2 Cl（其可以从1,2,3-三氯丙烷购买或合成）被氟化（优选在催化剂存在下在气相中用HF）合成化合物如CF 3 CCl-CH 2，优选在80-96 ％选择性。 CF 3 CCl-CH 2 2优选使用以下化合物转化为CF 3 CFClCH 3（244-异构体） SbCl 5作为催化剂，然后将其选择性地转化为1234yf，优选在使用活性炭作为催化剂的气相催化反应中进行。对于第一步，优选使用Cr 2 O 3 O 3和FeCl 3 / C的混合物作为催化剂以实现对CF的高选择性 3 CCl-CH 2（96％）。在第二步中，优选使用SbCl 5 / C作为将1233xf转化为244-异构体CF 3 CFClCH 3的选择性催化剂。中间体优选通过蒸馏分离和纯化，并用于下一步骤而不进一步纯化，优选纯度高于约95％。

14. 发明申请

US20070197841A1 METHOD FOR PRODUCING FLUORINATED ORGANIC COMPOUNDS 有权
标题翻译：生产氟化有机化合物的方法
公开(公告)号：US20070197841A1
公开(公告)日：2007-08-23
申请号：US11619589
申请日：2007-01-03
申请人： Sudip Mukhopadhyay , Hsueh Tung , Michael Van Der Puy , Daniel Merkel , Jing Ji Ma , Cheryl Bortz , Barbara Light , Steven Phillips , Kim Fleming , Susan Ferguson
发明人： Sudip Mukhopadhyay , Hsueh Tung , Michael Van Der Puy , Daniel Merkel , Jing Ji Ma , Cheryl Bortz , Barbara Light , Steven Phillips , Kim Fleming , Susan Ferguson
IPC分类号： C07C21/18 , C07C17/25
CPC分类号： C07C17/23 , C07C17/087 , C07C17/10 , C07C17/206 , C07C17/21 , C07C17/25 , C07C19/08 , C07C19/10 , C07C21/18
摘要： Disclosed is a process for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of Formula (I): C(X)3CF2C(X)3 (I) to at least one compound of Formula (II) CF3CF═CHZ (II) where each X and Z is independently H, F, Cl, I or Br, said process preferably not including any substantial amount of oxygen-containing catalyst in certain embodiments. Preferably Z is H.
摘要翻译：公开了一种生产含氟有机化合物的方法，包括氢氟丙烯，其优选包括转化至少一种式（I）的化合物：<？在线式描述=“在线式”末端=“铅”→> （X）3 C（X）3（I）<？in-line-formula description =“In-line Formulas” 结束=“尾”→至少一种式（II）的化合物<？在线公式描述=“在线公式”end =“lead”？> CF 3 CF- CHZ（II）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中每个X和Z独立地为H，F，Cl，I或Br，所述方法优选不包括任何实质在某些实施方案中含氧催化剂的量。 Z优选为

15. 发明授权

US07189884B2 Processes for synthesis of tetrafluoropropene 有权
标题翻译：合成四氟丙烯的方法
公开(公告)号：US07189884B2
公开(公告)日：2007-03-13
申请号：US11118530
申请日：2005-04-29
申请人： Sudip Mukhopadhyay , Haridasan K. Nair , HsuehSung Tung , Michael Van Der Puy
发明人： Sudip Mukhopadhyay , Haridasan K. Nair , HsuehSung Tung , Michael Van Der Puy
IPC分类号： C07C21/18
CPC分类号： C07C17/06 , C07C17/04 , C07C17/206 , C07C17/21 , C07C17/25 , C07C21/18 , C07C19/14 , C07C19/16 , C07C19/01 , C07C19/10
摘要： Disclosed in one embodiment is a process for the synthesis of 1,3,3,3-tetrafluoropropene that comprises (a) reacting a compound of formula (I) X1X2 with a compound of formula (II) CF3CH═CH2 to produce a reaction product comprising a compound of formula (III) CF3CHX1CH2X2, wherein X1 and X2 are each independently selected from the group consisting of hydrogen, chlorine, bromine and iodine, provided that X1 and X2 are not both hydrogen; (b) when X2 in formula (III) is not fluorine, fluorinating the compound of formula (III) to produce a reaction product comprising a compound of formula (III) wherein X1 is as described above and X2 is fluorine; and (c) exposing said compound of formula (III) to reaction conditions effective to convert said compound to 1,3,3,3-tetrafluoropropene.
摘要翻译：在一个实施方案中公开了一种用于合成1,3,3,3-四氟丙烯的方法，其包括（a）使式（I）化合物X 1，X 2，与式（II）化合物CF 3 CH-CH 2取代，生成包含式（III）化合物的反应产物CF 3 其中X 1和X 2都是（CH 2）2 CH 2，其中X 1和X 2都是各自独立地选自氢，氯，溴和碘，条件是X 1和X 2都不是氢; （b）当式（III）中的X 2不是氟时，氟化式（III）化合物以产生包含式（III）化合物的反应产物，其中X 1， / SUP>如上所述，X 2是氟; 和（c）将所述式（III）化合物暴露于有效将所述化合物转化为1,3,3,3-四氟丙烯的反应条件。

16. 发明授权

US10059647B2 Method for producing fluorinated organic compounds 有权
公开(公告)号：US10059647B2
公开(公告)日：2018-08-28
申请号：US14269251
申请日：2014-05-05
申请人： Sudip Mukhopadhyay , Hsueh S. Tung , Michael Van Der Puy , Daniel C. Merkel , Jing Ji Ma , Cheryl L. Bortz , Barbara A. Light , Steven D. Phillips , Rajesh K. Dubey
发明人： Sudip Mukhopadhyay , Hsueh S. Tung , Michael Van Der Puy , Daniel C. Merkel , Jing Ji Ma , Cheryl L. Bortz , Barbara A. Light , Steven D. Phillips , Rajesh K. Dubey
IPC分类号： C07C17/25 , C07C17/10 , C07C17/087 , C07C17/20 , C07C17/21
CPC分类号： C07C17/25 , C07C17/00 , C07C17/04 , C07C17/087 , C07C17/10 , C07C17/20 , C07C17/204 , C07C17/206 , C07C17/21 , C07C17/26 , C07C17/269 , C07C17/272 , C07C17/278 , C07C21/18 , C07C19/01 , C07C19/10 , C07C19/08 , C07C21/073 , C07C21/04
摘要： Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF3CF═CH2 (1234yf). Three steps may be used in preferred embodiments in which a feedstock such as CCl2═CClCH2Cl (which may be purchased or synthesized from 1,2,3-trichloropropane) is fluorinated (preferably with HF in gas-phase in the presence of a catalyst) to synthesize a compound such as CF3CCl═CH2, preferably in a 80-96% selectivity. The CF3CCl═CH2 is preferably converted to CF3CFClCH3 (244-isomer) using a SbCl5 as the catalyst which is then transformed selectively to 1234yf, preferably in a gas-phase catalytic reaction using activated carbon as the catalyst. For the first step, a mixture of Cr2O3 and FeCl3/C is preferably used as the catalyst to achieve high selectivity to CF3CCl═CH2 (96%). In the second step, SbCl5/C is preferably used as the selective catalyst for transforming 1233xf to 244-isomer, CF3CFClCH3. The intermediates are preferably isolated and purified by distillation and used in the next step without further purification, preferably to a purity level of greater than about 95%.

17. 发明授权

US08084653B2 Method for producing fluorinated organic compounds 有权
标题翻译：氟化有机化合物的制备方法
公开(公告)号：US08084653B2
公开(公告)日：2011-12-27
申请号：US11619592
申请日：2007-01-03
申请人： Hsueh S. Tung , Sudip Mukhopadhyay , Michael Van Der Puy , Daniel C. Merkel , Jing Ji Ma , Cheryl L. Bortz , Barbara A. Light , Steven D. Phillips , Rajesh K. Dubey
发明人： Hsueh S. Tung , Sudip Mukhopadhyay , Michael Van Der Puy , Daniel C. Merkel , Jing Ji Ma , Cheryl L. Bortz , Barbara A. Light , Steven D. Phillips , Rajesh K. Dubey
IPC分类号： C07C17/00 , C07C19/08 , C07C21/18 , C07C23/00 , C07C25/13
CPC分类号： C07C17/25 , C07C17/00 , C07C17/04 , C07C17/087 , C07C17/10 , C07C17/20 , C07C17/204 , C07C17/206 , C07C17/21 , C07C17/26 , C07C17/269 , C07C17/272 , C07C17/278 , C07C21/18 , C07C19/01 , C07C19/10 , C07C19/08 , C07C21/073 , C07C21/04
摘要： Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF3CF═CH2 (1234yf). Three steps may be used in preferred embodiments in which a feedstock such as CCl2═CClCH2Cl (which may be purchased or synthesized from 1,2,3-trichloropropane) is fluorinated (preferably with HF in gas-phase in the presence of a catalyst) to synthesize a compound such as CF3CCl═CH2, preferably in a 80-96% selectivity. The CF3CCl═CH2 is preferably converted to CF3CFClCH3 (244-isomer) using a SbCl5 as the catalyst which is then transformed selectively to 1234yf, preferably in a gas-phase catalytic reaction using activated carbon as the catalyst. For the first step, a mixture of Cr2O3 and FeCl3/C is preferably used as the catalyst to achieve high selectivity to CF3CCl═CH2 (96%). In the second step, SbCl5/C is preferably used as the selective catalyst for transforming 1233xf to 244-isomer, CF3CFClCH3. The intermediates are preferably isolated and purified by distillation and used in the next step without further purification, preferably to a purity level of greater than about 95%.
摘要翻译：公开了用于生产氟化烯烃的方法，优选适于CF 3CF≡CH2（1234yf）的商业化。在优选实施方案中可以使用三个步骤，其中诸如CCl 2 = CClCH 2 Cl（其可以从1,2,3-三氯丙烷购买或合成）的原料被氟化（优选在气相存在下在HF的情况下为催化剂）合成化合物如CF 3 CCl = CH 2，优选选择性为80-96％。 CF 3 CCl = CH 2优选使用SbCl 5作为催化剂转化为CF 3 CFClCH 3（244-异构体），然后将其选择性地转化为1234yf，优选在使用活性炭作为催化剂的气相催化反应中。对于第一步，优选使用Cr 2 O 3和FeCl 3 / C的混合物作为催化剂以实现对CF 3 CCl = CH 2（96％）的高选择性。在第二步中，SbCl 5 / C优选用作用于将1233xf转化为244-异构体CF 3 CFClCH 3的选择性催化剂。中间体优选通过蒸馏分离和纯化，并用于下一步骤而不进一步纯化，优选纯度高于约95％。

18. 发明授权

US07951982B2 Method for producing fluorinated organic compounds 有权
标题翻译：氟化有机化合物的制备方法
公开(公告)号：US07951982B2
公开(公告)日：2011-05-31
申请号：US11592842
申请日：2006-11-03
申请人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy , Robert C. Johnson , Daniel C. Merkel
发明人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy , Robert C. Johnson , Daniel C. Merkel
IPC分类号： C07C21/18
CPC分类号： C07C17/25 , B01J23/02 , B01J23/44 , B01J23/755 , B01J23/78 , B01J23/83 , B01J35/06 , C07C17/00 , C07C17/269 , C07C21/18 , C07C19/08
摘要： Disclosed is a process for the preparation of fluorinated olefins. In preferred embodiments C3 olefins are produced by methods comprising contacting a compound of the Formula (I) C(R1aR2bR3c) (I) with a compound of Formula (II) C(R1aR2bR3c)Cn(R1aR2bR3c) II wherein R1a, R2b, and R3c are independently a hydrogen atom or a halogen selected from the group consisting of fluorine; chlorine, bromine and iodine, provided that the compound of formula I has at least three halogen substituents and that said at three halogen substituents comprise at least one fluorine; a, b and c are independently=0, 1, 2 or 3 and (a+b+c)=2 or 3; and n is 0 or 1, under conditions effective to produce at least one C3 fluoroolefin.
摘要翻译：公开了一种制备氟化烯烃的方法。在优选实施方案中，C3烯烃通过以下方法制备：包括使式（I）C（R 1a R 2b b C 3）（I）的化合物与式（II）的化合物C（R1aR2bR3c）Cn（R1aR2bR3c）II的化合物接触，其中R1a，R2b和R3c 独立地为氢原子或选自氟的卤素; 氯，溴和碘，条件是式I化合物具有至少三个卤素取代基，并且在三个卤素取代基上含有至少一个氟; a，b和c独立地为= 0,1,2或3，（a + b + c）= 2或3; 在有效产生至少一种C3氟代烯烃的条件下，n为0或1。

19. 发明授权

US07345209B2 Processes for synthesis of 1,3,3,3-tetrafluoropropene 失效
标题翻译：合成1,3,3,3-四氟丙烯的方法
公开(公告)号：US07345209B2
公开(公告)日：2008-03-18
申请号：US11118503
申请日：2005-04-29
申请人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy
发明人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy
IPC分类号： C07C17/278 , C07C17/10 , C07C17/23 , C07C17/25 , C07C17/04
CPC分类号： C07C17/206 , C07C17/00 , C07C17/25 , C07C17/275 , C07C17/278 , C07C21/18 , C07C19/10 , C07C19/16 , C07C19/14 , C07C19/01
摘要： Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene that comprises, in one preferred embodiment, providing a compound of the formula CF3CH2CHFX, wherein X is a selected from the group consisting of chlorine, bromine and iodine, and exposing said compound to reaction conditions effective to convert said compound to 1,3,3,3-tetrafluoropropene. Other processes for forming 1,3,3,3-tetrafluoropropene are also disclosed.
摘要翻译：公开了一种合成1,3,3,3-四氟丙烯的方法，其在一个优选的实施方案中包括提供式CF 3 CH 2 CHFX的化合物其中X选自氯，溴和碘，并将所述化合物暴露于有效将所述化合物转化为1,3,3,3-四氟丙烯的反应条件下。还公开了形成1,3,3,3-四氟丙烯的其它方法。

20. 发明授权

US08395000B2 Method for producing fluorinated organic compounds 有权
标题翻译：氟化有机化合物的制备方法
公开(公告)号：US08395000B2
公开(公告)日：2013-03-12
申请号：US12702135
申请日：2010-02-08
申请人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy , Daniel C. Merkel , Rajesh K. Dubey , Jing Ji Ma
发明人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy , Daniel C. Merkel , Rajesh K. Dubey , Jing Ji Ma
IPC分类号： C07C17/25 , C07C21/185 , C07C21/18
CPC分类号： C07C17/04 , C07C17/00 , C07C17/06 , C07C17/206 , C07C17/25 , C07C17/26 , C07C17/269 , C07C17/272 , C07C17/278 , C07C21/18 , C07C19/08 , C07C19/10
摘要： Disclosed are methods for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CHXCH2X (I) to at least one compound of formula (II) CF3CZCHZ (II). where X is independently Cl, Br, I or F, and Z independently is H or F. In certain preferred embodiments, each Z is different.
摘要翻译：公开了生产氟化有机化合物的方法，包括氢氟丙烯，其优选包括将至少一种式（I）化合物：CF 3 CHXCH 2 X（I）转化为至少一种式（II）CF 3 CZCHZ（II）化合物。其中X独立地为Cl，Br，I或F，Z独立地为H或F.在某些优选实施方案中，每个Z不同。

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