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    • 14. 发明授权
    • Process for producing polycarbonate
    • 生产聚碳酸酯的方法
    • US06703473B2
    • 2004-03-09
    • US10038953
    • 2002-01-02
    • Uwe HucksKaspar HallenbergerSilke KratschmerMichael PreinSteffen Kühling
    • Uwe HucksKaspar HallenbergerSilke KratschmerMichael PreinSteffen Kühling
    • C08G6400
    • C08G64/406C08G64/307
    • An improvement to the melt transesterification reaction of diaryl carbonate with dihydroxy aryl compound is disclosed. The improvement entails the following steps (i) introducing the resulting vapor stream at the mid-height of a first distillation column, and (ii) separating the vapor stream into a top product containing high purity monohydroxy aryl compound and a first bottom product, and (iii) recycling the high purity monohydroxy aryl compound of (ii) to the reaction, and (iv) introducing the first bottom product at mid-height of a second distillation column, and (v) separating said first bottom product into high boiling bottom by-product and overhead remaining constituents, and (vi) introducing the overhead remaining constituents at mid-height of a third distillation column, and (vii) separating said overhead remaining constituents into overhead low-boiling fractions and bottom or product side stream that contains diaryl carbonate product, and (viii) recycling the diaryl carbonate product directly to the transesterification reaction.
    • 公开了碳酸二芳酯与二羟基芳基化合物的熔融酯交换反应的改进。 改进需要以下步骤:(i)将所得蒸汽流引入第一蒸馏塔的中间高度,和(ii)将蒸汽流分离成含有高纯度单羟基芳基化合物和第一底部产物的顶部产物,以及 (iii)将(ii)的高纯度单羟基芳基化合物再循环到反应中,和(iv)在第二蒸馏塔的中间部分引入第一底部产物,和(v)将所述第一底部产物分离成高沸点底部 副产物和塔顶残留组分,和(vi)在第三蒸馏塔的中间高度引入塔顶剩余成分,和(vii)将塔顶剩余组分分离成塔顶低沸点馏分和底部或产物侧流,其含有 碳酸二芳基酯产物,和(viii)将碳酸二芳基酯产物直接再循环到酯交换反应中。
    • 19. 发明授权
    • Process for the recycling of polycarbonates
    • 聚碳酸酯回收工艺
    • US06887968B2
    • 2005-05-03
    • US10229787
    • 2002-08-28
    • Heinrich HähnsenUwe HucksSilke KratschmerManfred Schraut
    • Heinrich HähnsenUwe HucksSilke KratschmerManfred Schraut
    • C08G64/40C08G64/42C08G64/00
    • C08G64/42
    • A process for making a high molecular weight (co)polycarbonate resin is disclosed. The process entails (i) obtaining at least one member selected from the group low molecular weight residue (weight average molecular weight 15,000 to 30,000) of aromatic (co)polycarbonate production, waste of (co)polycarbonate production, remainders of (co)polycarbonate production and (co)polycarbonate recyclate (ii) melting the said member in a suitable vessel to obtain a melt and (iii) feeding the melt into a reactor optionally along with at least one bisphenol or oligocarbonate having terminal OH groups and further optionally with a transesterification catalyst, and (iv) subjecting the melt to transesterification reaction at a temperature of 250 to 350° C., at a pressure below 5 mbar and residence time of 0.02-4 hours.
    • 公开了制备高分子量(共)聚碳酸酯树脂的方法。 该方法包括:(i)获得选自芳族(共)聚碳酸酯生产的低分子量残余物(重均分子量为15,000至30,000)中的至少一种,(共)聚碳酸酯生产的废弃物,(共)聚碳酸酯的剩余物 生产和(共)聚碳酸酯回收(ii)在合适的容器中熔化所述构件以获得熔体,和(iii)将熔体任选地与至少一种具有末端OH基的双酚或低聚碳酸酯一起进料到反应器中, 酯交换催化剂,和(iv)在250-350℃的温度,低于5mbar的压力和0.02-4小时的停留时间下对熔体进行酯交换反应。