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    • 11. 发明授权
    • MOS transistor having shallow source/drain junctions and low leakage current
    • MOS晶体管具有较浅的源/漏结和低漏电流
    • US06218249B1
    • 2001-04-17
    • US09455588
    • 1999-12-06
    • Jer-Shen MaaSheng Teng HsuChien-Hsiung Peng
    • Jer-Shen MaaSheng Teng HsuChien-Hsiung Peng
    • H01L21336
    • H01L21/28518H01L21/28052H01L29/665H01L29/6659
    • A process of forming silicide at uniform rates across the entire source/drain region is provided. A two-step annealing method permits the thickness of the silicide formed on the edge of a silicon electrode to be substantially the same as it is in the center of the electrode. A first, low temperature anneal begins the salicidation process across the source/drain electrode surface. The time and temperature are controlled so that the metal is only partially consumed. The annealing is interrupted to remove excess silicidation metal, especially the unreacted metal overlying oxide areas neighboring the silicon electrode. Then, the silicidation is completed at a higher temperature anneal. Because the excess metal has been removed, the resulting silicide layer is uniformly flat, permitting the transistor to be fabricated with shallow junction areas and low leakage currents. In one embodiment of the invention, the crystalline structure of source and drain surfaces is annihilated before the deposition of metal, to lower annealing temperatures and add precise control to the silicidation process. A transistor having a uniformly thick silicide layer, fabricated in accordance with the above-mentioned method, is also provided.
    • 提供了在整个源极/漏极区域以均匀的速率形成硅化物的工艺。 两步退火方法允许形成在硅电极边缘上的硅化物的厚度与电极中心基本相同。 首先,低温退火开始跨越源/漏电极表面的盐析过程。 控制时间和温度,使得金属仅被部分消耗。 中断退火以去除过量的硅化金属,特别是覆盖与硅电极相邻的氧化物区域的未反应的金属。 然后,在较高温度的退火下完成硅化。 由于去除了多余的金属,所得到的硅化物层是均匀平坦的,从而允许晶体管被制造成具有浅结的区域和低的漏电流。 在本发明的一个实施例中,源极和漏极表面的晶体结构在金属沉积之前被消除,以降低退火温度并且增加对硅化工艺的精确控制。 还提供了具有根据上述方法制造的均匀厚的硅化物层的晶体管。
    • 13. 发明授权
    • Metalorganic chemical vapor deposition of ferroelectric thin films
    • 铁电薄膜的金属有机化学气相沉积
    • US5431958A
    • 1995-07-11
    • US999738
    • 1992-12-31
    • Seshu B. DesuChien-Hsiung Peng
    • Seshu B. DesuChien-Hsiung Peng
    • C23C16/40
    • C23C16/409
    • A method to produce high quality doped and undoped lead zirconate titanate (PZT) thin films by metalorganic chemical vapor deposition is disclosed. The PZT thin films with the perovskite structure were deposited on sapphire disks, Pt/Ti/SiO.sub.2 /Si wafers, and RuO.sub.x /SiO.sub.2 /Si wafers by both hot-wall and cold-wall CVD reactors at deposition temperature as low as 550.degree. C. and a reduced pressure 6 torr. The source materials include metalorganic precursors and oxidizing agent. The metalorganic precursors can be metal alkoxides, metal acetylacetonates, or metal .beta.-diketonates. Preferably, the precursors are lead tetramethylheptadione for Pb component, zirconium tetramethylheptadione for Zr component, and titanium ethoxide for Ti component and the oxidizing agent is oxygen. The stoichiometry of the films can be easily controlled by varying the individual precursor temperature and/or the flow rate of the carrier gas. The Pb(Zr.sub.0.82 Ti.sub.0.18)O.sub.3 film produced by the present invention shows a spontaneous polarization of 23.3 .mu.C/cm.sup.2, a remanent polarization of 12.3 .mu.C/cm.sup.2, and coercive field of 64.5 kV/cm.
    • 公开了通过金属有机化学气相沉积生产高质量掺杂和未掺杂的锆钛酸铅(PZT)薄膜的方法。 具有钙钛矿结构的PZT薄膜通过热壁和冷壁CVD反应器在低至550℃的沉积温度下沉积在蓝宝石盘,Pt / Ti / SiO 2 / Si晶片和RuO x / SiO 2 / Si晶片上 并减压6乇。 源材料包括金属有机前体和氧化剂。 金属有机前体可以是金属醇盐,金属乙酰丙酮化物或金属β-二酮化物。 优选地,前体是Pb组分的铅四甲基庚二酮,Zr组分的四甲基庚二酸锆和Ti组分的乙醇钛,氧化剂是氧。 可以通过改变载体气体的各个前体温度和/或流速来容易地控制膜的化学计量。 本发明生产的Pb(Zr0.82Ti0.18)O3膜的自发极化为23.3μC/ cm2,剩余极化为12.3μC/ cm 2,矫顽磁场为64.5kV / cm。