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    • 11. 发明授权
    • Rare earth bonded magnet, rare earth magnetic composition, and method
for manufacturing rare earth bonded magnet
    • 稀土粘结磁铁,稀土磁性组合物,稀土类粘结磁铁制造方法
    • US6143193A
    • 2000-11-07
    • US744014
    • 1996-11-05
    • Koji AkiokaHayato ShiraiKen IkumaMitsuru TakeiYoshiki Nakamura
    • Koji AkiokaHayato ShiraiKen IkumaMitsuru TakeiYoshiki Nakamura
    • H01F1/055H01F1/057H01F1/059B22F3/00
    • H01F1/0578H01F1/0558H01F1/059
    • A rare earth bonded magnet comprising a rare earth magnet powder bonded with a binder resin is manufactured by extrusion or injection molding. A rare earth bonded magnet manufactured by extrusion molding has a rare earth magnet powder content of 78.1 to 83.0 percent by volume. A rare earth bonded magnet manufactured by injection molding has a rare earth magnet powder content of 68.0 to 76.0 percent by volume. Preferably, the rare earth metal powder is at least one of Sm--Co alloys, R--Fe--B alloys wherein R is at least one of rare earth elements including Y, and Sm--Fe--N alloys. Preferably, the thermoplastic resin include polyamide, liquid crystal polymer, and Polyphenylene sulfide. Preferably, the rare earth bonded metal has a void ratio of 2 percent by volume or less. A rare earth bonded magnet is manufactured by kneading a rare earth magnetic composition comprising a rare earth magnet powder and a thermoplastic resin, and by extruding or injecting the mixture after kneading. A rare earth magnetic composition used for extrusion molding contains a rare earth metal powder of 77.6 to 82.5 percent by volume, and a rare earth magnetic composition used for injection molding contains a rare earth metal powder of 67.6 to 75.5 percent by volume. Preferably, such rare earth magnetic compositions further comprise an antioxidant, such as a chelating agent. Thus, a rare earth bonded magnet showing excellent moldability and magnetic properties and high mechanical strength at a minimum binding resin can be obtained.
    • 包括用粘合剂树脂粘合的稀土磁体粉末的稀土粘结磁体通过挤出或注射成型制造。 通过挤出成型制造的稀土类粘结磁体的稀土类磁体粉末的含量为78.1〜83.0体积%。 通过注射成型制造的稀土类粘结磁体的稀土类磁体粉末含量为68.0〜76.0体积%。 优选地,稀土金属粉末是Sm-Co合金,R-Fe-B合金中的至少一种,其中R是包括Y的稀土元素和Sm-Fe-N合金中的至少一种。 优选地,热塑性树脂包括聚酰胺,液晶聚合物和聚苯硫醚。 优选稀土键合金属的空隙率为2体积%以下。 通过将包含稀土类磁铁粉末和热塑性树脂的稀土类磁性组合物进行混炼,捏合后将混合物挤出或注入,制造稀土类粘结磁铁。 用于挤出成型的稀土类磁性组合物含有77.6〜82.5体积%的稀土类金属粉末,注射成型用的稀土类磁性组合物含有67.6〜75.5体积%的稀土类金属粉末。 优选地,这种稀土磁性组合物还包含抗氧化剂,例如螯合剂。 因此,可以获得在最小粘合树脂下显示优异的成型性和磁性能以及高机械强度的稀土粘结磁体。
    • 12. 发明授权
    • Dies for extrusion moulding
    • 模具用于挤出成型
    • US5733580A
    • 1998-03-31
    • US608035
    • 1996-02-28
    • Ken IkumaMasaaki SakataKoji AkiokaTatsuya Smimoda
    • Ken IkumaMasaaki SakataKoji AkiokaTatsuya Smimoda
    • B29C47/20H01F41/02
    • H01F41/0273B29C47/20B29C47/0016B29C47/0019B29C47/0023Y10S264/58Y10S425/033
    • A die for extrusion molding a resin bonding magnet. In the production of the magnet, a molten mixture of a magnetic powder and a resin are introduced into a cavity between an outer die and a mandril to which a magnetic field is applied. A steep temperature gradient along the die axis direction of the molten mixture and the cavity is achieved by making the outer die of a multiple layer structure along the die axis direction, utilizing two or more axially adjacent blocks or sheets made of the same or different materials whereby fluidity of the molten mixture is sufficiently high at the inlet of the cavity to enable the magnetic powder in the molten mixture to be sufficiently orientated in the direction of the magnetic field and then the molten mixture is cooled to a solidified state so that the orientation of the magnetic powder is not disturbed, thereby producing a magnetic having high magnetic properties.
    • 用于挤出成型树脂粘合磁体的模具。 在制造磁体时,将磁性粉末和树脂的熔融混合物引入到外部管芯和施加有磁场的心轴之间的空腔中。 通过使用由相同或不同材料制成的两个或更多个轴向相邻的块或片,通过沿着模具轴线方向制造多层结构的外模具来实现沿着熔融混合物和模腔的模具轴线方向的陡峭的温度梯度 由此在空腔的入口处熔融混合物的流动性足够高,使得熔融混合物中的磁粉能够在磁场方向上被充分取向,然后将熔融混合物冷却至凝固状态,使得取向 的磁粉不会受到干扰,从而产生具有高磁性的磁性。
    • 17. 发明授权
    • Rare earth bonded magnet and composition therefor
    • 稀土粘结磁铁及其组成
    • US5888417A
    • 1999-03-30
    • US732967
    • 1996-10-16
    • Koji AkiokaHayato ShiraiKen Ikuma
    • Koji AkiokaHayato ShiraiKen Ikuma
    • H01F1/053H01F1/08H01F1/055H01F1/057H01F1/059
    • H01F1/0533Y10S977/838
    • A rare earth bonded magnet formed by bonding a rare earth magnet powder with a binding resin contains the rare earth magnet powder, and a thermoplastic resin serving as the binding resin in an amount within a range of from 1 to 5 wt. %, and preferably further contains an oxidation inhibitor. As the rare earth magnet powder, for example, at least one of an Sm--Co alloy, an R--Fe--B alloy (where, R represents at least a kind of rare earth elements including Y) and an Sm--Fe--N alloy can be appropriately used. As the thermoplastic resin, for example, polyamide, a liquid crystal polymer, or a PPS is appropriately employed. As the oxidation inhibitor, a chelating agent is appropriately applicable. In such a rare earth bonded magnet, the thermoplastic resin covers the outer surface of the rare earth magnet powder 2, and is present so as to prevent particles of the magnet powder from coming into contact with each other. Such a rare earth bonded magnet should preferably have a void ratio of no more than 2 vol. %.
    • 通过将稀土类磁体粉末与粘合树脂结合而形成的稀土类粘结磁铁含有稀土类磁体粉末和作为粘合树脂的热塑性树脂,其量为1〜5重量%。 %,优选还含有氧化抑制剂。 作为稀土类磁体粉末,例如可以使用Sm-Co合金,R-Fe-B系合金(其中,R表示至少一种含有Y的稀土元素的种类)和Sm-Fe-N 合金可以适当使用。 作为热塑性树脂,可以适当使用聚酰胺,液晶聚合物,PPS等。 作为氧化抑制剂,螯合剂适用。 在这种稀土类粘结磁体中,热塑性树脂覆盖稀土类磁体粉末2的外表面,并且存在以防止磁铁粉末的粒子彼此接触。 这种稀土类粘结磁体优选具有不大于2体积的空隙率。 %。
    • 18. 发明授权
    • Liquid developer
    • 液体显影剂
    • US07723005B2
    • 2010-05-25
    • US11394370
    • 2006-03-29
    • Koji AkiokaNobuhiro MiyakawaTakashi TeshimaSatoru Miura
    • Koji AkiokaNobuhiro MiyakawaTakashi TeshimaSatoru Miura
    • G03G9/00
    • G03G9/125G03G9/132
    • A liquid developer contains an insulation liquid containing as its main component a glyceride of an unsaturated fatty acid, toner particles dispersed in the insulation liquid; and an oxidation polymerization accelerator for accelerating oxidation polymerization reaction of the glyceride during fixing process of the toner particles. The oxidation polymerization accelerator accelerates the oxidation polymerization reaction by supplying oxygen during the fixing process of the toner particles. The liquid developer may further contain an antioxidizing agent. Preferably, the oxidation polymerization accelerator is contained in the insulation liquid being encapsulated.
    • 液体显影剂包含以不饱和脂肪酸的甘油酯为主要成分的绝缘液,分散在绝缘液中的调色剂颗粒; 以及用于在调色剂颗粒的定影过程中促进甘油酯的氧化聚合反应的氧化聚合促进剂。 氧化聚合促进剂在调色剂颗粒的定影过程中通过供氧来加速氧化聚合反应。 液体显影剂还可以含有抗氧化剂。 优选地,氧化聚合促进剂被包封在被封装的绝缘液体中。