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    • 17. 发明专利
    • DE3803339A1
    • 1989-08-10
    • DE3803339
    • 1988-02-04
    • SUEDZUCKER AG
    • GANDER MICHAELRAPP KNUT M DIPL CHEM DR RER NSCHIWECK HUBERT DR
    • C07H3/10C07H1/08C07H19/01
    • The invention relates to a process for the preparation of 1,6-beta-D-anhydroglucopyranose (levoglucosan) from starch and/or starch-containing or cellulose-containing material by vacuum pyrolysis. … The known processes are too elaborate and/or too costly for preparation of levoglucosan of high purity on the industrial scale. The known pyrolysis of starch forms a large number of by-products so that time-consuming purification processes using organic solvents and slow crystallisation are usual. Low yields and deficient purity characterise the known levoglucosan products. … A process for the preparation of levoglucosan is provided in which the starting material, which has a water content adjusted to not more than 20 %, is depolymerised, the volatile components are condensed and the condensate is, after neutralisation, filtration and, where appropriate, treatment with an adsorbent, subjected to a chromatographic separation on ion exchangers, with water as eluent, and the levoglucosan-containing fractions are concentrated and crystalline levoglucosan is obtained by an evaporation and/or cooling crystallisation from water.