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    • 12. 发明申请
    • HYDROCARBON COMPOSITION
    • 碳氢化合物
    • WO2011091200A2
    • 2011-07-28
    • PCT/US2011021965
    • 2011-01-21
    • SHELL OIL COSHELL INT RESEARCHMILAM STANLEY NEMECREYNOLDS MICHAEL ANTHONYWELLINGTON SCOTT LEE
    • MILAM STANLEY NEMECREYNOLDS MICHAEL ANTHONYWELLINGTON SCOTT LEE
    • C10G47/00
    • C10L1/00C10G47/00C10G47/02C10G47/06C10G2300/202C10G2300/301C10G2400/30
    • A hydrocarbon composition is provided containing: at least 0.05 grams of hydrocarbons having boiling point in the range from an initial boiling point of the composition up to 204°C (400°F) per gram of the composition; at least 0.1 gram of hydrocarbons having a boiling point in the range from 204°C up to 260°C (500°F) per gram of the composition; at least 0.25 gram of hydrocarbons having a boiling point in the range from 260°C up to 343°C per gram of the composition; at least 0.3 gram of hydrocarbons having a boiling point in the range from 343°C to 538°C per gram of the composition; and at most 0.03 gram of hydrocarbons having a boiling point of greater than 538°C per gram of the composition; at least 0.0005 gram of sulfur per gram of the composition, wherein at least 40 wt.% of the sulfur is contained in hydrocarbon compounds having a carbon number of 17 or less as determined by GC-GC sulfur chemiluminscence, where at least 60 wt. % of the sulfur in the sulfur-containing hydrocarbon compounds having a carbon number of 17 or less is contained in benzothiophenic compounds as determined by GC-GC sulfur chemiluminscence.
    • 提供了一种烃组合物,其含有:至少0.05克沸点在组合物的初沸点至204℃(400°F)范围内的烃/克组合物; 至少0.1克沸点为每克组合物的204℃至260℃(500华氏度)的烃类; 至少0.25克沸点为每克组合物的260℃至343℃的烃; 至少0.3克沸点在每克组合物343℃至538℃范围内的烃; 和至多0.03克每克组合物沸点大于538℃的烃; 每克组合物至少含有0.0005克硫,其中通过GC-GC硫化学发光测定,碳原子数为17以下的烃化合物中至少含有40重量%的硫,其中至少60重量% 通过GC-GC硫化学发光测定,苯并噻吩类化合物中含有碳数为17以下的含硫烃化合物中的硫的%。
    • 19. 发明申请
    • PROCESS FOR CRACKING A HYDROCARBON-CONTAINING FEED
    • 破碎含油料进料的方法
    • WO2011091201A3
    • 2012-04-19
    • PCT/US2011021966
    • 2011-01-21
    • SHELL OIL COSHELL INT RESEARCHMILAM STANLEY NEMECREYNOLDS MICHAEL ANTHONYWELLINGTON SCOTT LEE
    • MILAM STANLEY NEMECREYNOLDS MICHAEL ANTHONYWELLINGTON SCOTT LEE
    • C10G47/06B01J27/02B01J27/04B01J27/047B01J27/051B01J27/057B01J35/02C01G3/12C01G39/06C10G47/26
    • C10G47/06B01J27/04B01J27/047B01J27/051B01J35/002B01J35/023B01J35/1014B01J35/1019B01J35/1038B01J35/1061B01J37/031B82Y30/00C01G39/006C01P2004/61C01P2004/62C01P2004/64C01P2006/12C01P2006/14C01P2006/16C10G47/26C10G2300/202C10G2300/206C10G2300/207C10G2300/301C10G2300/4006C10G2300/4012
    • A process for treating a hydrocarbon-containing feed is provided in which a hydrocarbon-containing feed comprising at least 20 wt.% of heavy hydrocarbons is mixed with hydrogen, hydrogen sulfide, and a catalyst to produce a hydrocarbon-containing product, where hydrogen sulfide is provided at a mole ratio relative to hydrogen of at least 0.5:9.5. The catalyst is comprised of a material comprised of a first metal and a second metal, where the first metal is selected from the group consisting of Cu, Fe, Ni, Co, Bi, Ag, Mn, Zn, Sn, Ru, La, Ce, Pr, Sm, Eu, Yb, Lu, Dy, Pb, and Sb and the second metal is Mo, W, V, Sn, and Sb. The material of the catalyst may have a structure according to formula (I), formula (II), formula (III), or formula (IV): where M is either the first metal or the second metal, and at least one M is the first metal and at least one M is the second metal; where M is either the first metal or the second metal, and at least one M is the first metal and at least one M is the second metal, and X is selected from the group consisting of SO4, PO4, oxalate (C2O4), acetylacetonate, acetate, citrate, tartrate, Cl, Br, I, ClO4, and NO3; where M is either the first metal or the second metal, and at least one M is the first metal and at least one M is the second metal, and X is selected from the group consisting of SO4, PO4, oxalate (C2O4), acetylacetonate, acetate, citrate, tartrate, Cl, Br, I, ClO4, and NO3; where M is either the first metal or the second metal, and at least one M is the first metal and at least one M is the second metal, and X is selected from the group consisting of SO4, PO4, oxalate (C2O4), acetylacetonate, acetate, citrate, tartrate, Cl, Br, I, ClO4, and NO3.
    • 提供了一种处理含烃进料的方法,其中将包含至少20重量%重烃的含烃进料与氢气,硫化氢和催化剂混合以产生含烃产物,其中硫化氢 以相对于氢的摩尔比提供至少0.5:9.5。 催化剂由包含第一金属和第二金属的材料组成,其中第一金属选自Cu,Fe,Ni,Co,Bi,Ag,Mn,Zn,Sn,Ru,La, Ce,Pr,Sm,Eu,Yb,Lu,Dy,Pb和Sb,第二金属是Mo,W,V,Sn和Sb。 催化剂的材料可以具有根据式(I),式(II),式(III)或式(IV)的结构:其中M是第一种金属或第二种金属,至少一种M是 第一金属和至少一个M是第二金属; 其中M是第一金属或第二金属,并且至少一个M是第一金属,并且至少一个M是第二金属,X选自SO 4,PO 4,草酸盐(C 2 O 4),乙酰丙酮化物 ,乙酸盐,柠檬酸盐,酒石酸盐,Cl,Br,I,ClO4和NO3; 其中M是第一金属或第二金属,并且至少一个M是第一金属,并且至少一个M是第二金属,X选自SO 4,PO 4,草酸盐(C 2 O 4),乙酰丙酮化物 ,乙酸盐,柠檬酸盐,酒石酸盐,Cl,Br,I,ClO4和NO3; 其中M是第一金属或第二金属,并且至少一个M是第一金属,并且至少一个M是第二金属,X选自SO 4,PO 4,草酸盐(C 2 O 4),乙酰丙酮化物 ,乙酸盐,柠檬酸盐,酒石酸盐,Cl,Br,I,ClO4和NO3。