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11. 发明专利

AU2014343715A1 Process for converting oxygenates to olefins 未知
公开(公告)号：AU2014343715A1
公开(公告)日：2016-05-12
申请号：AU2014343715
申请日：2014-10-31
申请人： SHELL INT RESEARCH
发明人： SANBORN RICHARD ADDISON , SADASIVAN VIJAYAKUMARI SIVAKUMAR , CHEWTER LESLIE ANDREW , CHEN YE MON
IPC分类号： C07C1/20 , B01J4/00 , B01J8/44
摘要： A process for converting oxygenates to olefins comprising: a) providing an oxygenate containing stream to an oxygenate to olefins conversion reactor; b) passing the oxygenate containing stream through a feed introduction system comprising one or more nozzles and one or more corresponding caps; c) contacting the oxygenate containing stream with a molecular sieve catalyst in the oxygenate to olefins conversion reactor to form an olefin containing product stream; and d) removing the product stream from the reactor.

12. 发明专利

AU2013341078B2 Processes for the preparation of an olefinic product 未知
公开(公告)号：AU2013341078B2
公开(公告)日：2016-04-21
申请号：AU2013341078
申请日：2013-10-29
申请人： SHELL INT RESEARCH
发明人： KLOTH ANTONIUS GIJSBERTUS JOHANNES , SADASIVAN VIJAYAKUMARI SIVAKUMAR , VAN WESTRENEN JEROEN
IPC分类号： C07C1/20 , B01D3/14 , C07C11/02
摘要： The invention provides a process for the preparation of an olefinic product, the process comprising the steps of: (a)reacting an oxygenate feedstock, comprising oxygenate, in an oxygenate reaction zone in the presence of a catalyst comprising a molecular sieve, at a temperature in the range of from 350 to 1000°C, to produce a reaction effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b)cooling the reaction effluent stream by means of an indirect heat exchange to a temperature greater than the dew point temperature of reaction effluent stream; (c)further rapidly cooling the reaction effluent stream to a temperature lower than the dew point temperature of the reaction effluent stream by direct injection of an aqueous liquid into the reaction effluent stream, to form a first quench effluent stream; and (d)separating the first quench effluent stream into a first liquid quench effluent stream and a first gaseous quench effluent stream, comprising the olefinic product.

13. 发明专利

ZA201402881B METHOD FOR PROCESSING FISCHER-TROPSCH OFF-GAS 未知
公开(公告)号：ZA201402881B
公开(公告)日：2015-12-23
申请号：ZA201402881
申请日：2014-04-22
申请人： SHELL INT RESEARCH
发明人： SADASIVAN VIJAYAKUMARI SIVAKUMAR , LINDERS XANDER , VAN DE GRAAF WOUTER DAVID , TE BRAAKE JUSTUS THEODORUS GERARDUS , BUNGKU DESMOND ANDREW , BRACHT MAARTEN

14. 发明专利

SG11201503328SA PROCESSES FOR THE PREPARATION OF AN OLEFINIC PRODUCT 未知
公开(公告)号：SG11201503328SA
公开(公告)日：2015-05-28
申请号：SG11201503328S
申请日：2013-10-29
申请人： SHELL INT RESEARCH
发明人： KLOTH ANTONIUS GIJSBERTUS JOHANNES , SADASIVAN VIJAYAKUMARI SIVAKUMAR , VAN WESTRENEN JEROEN
IPC分类号： C07C1/20 , C07C11/02
摘要： The invention provides a process for the preparation of an olefinic product, the comprising: (a) reacting an oxygenate to produce an effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the effluent stream by means of an indirect heat exchange to a temperature greater than the dew point temperature of effluent stream; (c) further rapidly cooling the effluent stream to a temperature at or lower than the dew point temperature of the reaction effluent stream by direct injection of a first aqueous liquid into the effluent stream, to form a quench effluent stream; (d) separating the first quench effluent stream into a liquid quench stream and a gaseous quench stream; and passing the gaseous quench stream into a quench tower and contacting the gaseous quench stream with a second aqueous liquid, to produce a quench tower gaseous stream comprising the olefinic product.

15. 发明专利

AU2013285980A1 Process for preparing ethylene and/or propylene 未知
公开(公告)号：AU2013285980A1
公开(公告)日：2015-01-22
申请号：AU2013285980
申请日：2013-07-01
申请人： SHELL INT RESEARCH
发明人： CHEWTER LESLIE ANDREW , CHEN YE-MON , NISBET TIMOTHY MICHAEL , SADASIVAN VIJAYAKUMARI SIVAKUMAR , VAN WESTRENEN JEROEN
IPC分类号： B01J29/40 , B01J29/90 , B01J31/12 , C07C1/20 , C10G3/00
摘要： The present invention provides a process for preparing ethylene and/or propylene, wherein oxygenates and olefins are converted to ethylene and/or propylene over a zeolite-comprising catalyst, comprising the steps of: a) reacting in a first reactor an oxygenate feed over the zeolite-comprising catalyst at a temperature in the range of from 350 to 1000 °C and retrieving from the first reactor a first reactor effluent stream comprising gaseous products, including ethylene and/or propylene, and zeolite-comprising catalyst; b) reacting in a second reactor an olefin feed over the zeolite-comprising catalyst at a temperature in the range of from 500 to 700 °C and retrieving from the second reactor a second reactor effluent stream comprising gaseous products, including ethylene and/or propylene, and zeolite-comprising catalyst; c) providing the first and second reactor effluent stream to one or more gas/solid separators to retrieve zeolite-comprising catalyst from the first and second reactor effluent; d) providing part of the zeolite-comprising catalyst retrieved in step (c) to the first reactor; e) regenerating another part of the zeolite-comprising catalyst retrieved in step (c) by contacting the zeolite-comprising catalyst with oxygen at elevated temperatures to provide a hot regenerated zeolite-comprising catalyst; and f) providing part of the hot regenerated zeolite-comprising catalyst to the first reactor and another part of the hot regenerated zeolite-comprising catalyst to the second reactor. The invention further provides a system suitable for preparing ethylene and propylene and the use thereof.

16. 发明专利

AU2012360938A1 Process for preparing ethylene and/or propylene 未知
公开(公告)号：AU2012360938A1
公开(公告)日：2014-07-10
申请号：AU2012360938
申请日：2012-12-21
申请人： SHELL INT RESEARCH
发明人： CHEN YE MON , CHEWTER LESLIE ANDREW , NISBET TIMOTHY MICHAEL , SADASIVAN VIJAYAKUMARI SIVAKUMAR , VAN WESTRENEN JEROEN
IPC分类号： C07C1/20 , C07C11/04 , C07C11/06
摘要： The present invention provides a process for preparing ethylene and/or propylene, comprising the steps of providing an oxygenate feed comprising oxygenate and C4 olefins to a first reaction zone; contacting the oxygenate feed with a first zeolite-comprising catalyst and retrieving from the first reaction zone a first effluent stream comprising at least C2 to C5 olefins; separating the first effluent stream into at least: a first product stream comprising C2 and/or C3 olefins; a second fraction comprising C4 olefins; a third fraction comprising C5 olefins; and recycling at least part of the second fraction to the first reaction zone as part of the oxygenate feed; providing an olefinic feed comprising C5 olefins to a second reaction zone, wherein the olefinic feed comprises at least part of the third fraction; and contacting in the second reaction zone the olefinic feed with a second zeolite-comprising catalyst at a temperature in the range of from 500 to 700°C and retrieving from the second reaction zone a second effluent stream comprising at least C2 to C3 olefins.

17. 发明专利

AU2012330384A1 Method for processing Fischer-Tropsch off-gas 未知
公开(公告)号：AU2012330384A1
公开(公告)日：2014-05-22
申请号：AU2012330384
申请日：2012-10-25
申请人： SHELL INT RESEARCH
发明人： BRACHT MAARTEN , BUNGKU DESMOND ANDREW , TE BRAAKE JUSTUS THEODORUS GERARDUS , VAN DE GRAAF WOUTER DAVID , LINDERS XANDER , SADASIVAN VIJAYAKUMARI SIVAKUMAR
IPC分类号： B01D53/04 , B01D53/047 , C10K1/32
摘要： This invention concerns a method for producing a gas comprising at least 80 vol% carbon monoxide from a Fischer- Tropsch off-gas. The method comprises the following steps: (1) feeding Fischer-Tropsch off-gas through a column comprising an adsorbent bed at high pressure and discharging effluent; (2) reducing the pressure in the column and the bed slightly; (3) rinsing the column and the adsorbent bed with methane or a mixture of methane and carbon dioxide; (4) reducing the pressure of the column and adsorbent bed to a low pressure; (5) rinsing the column and adsorbent bed with a mixture of hydrogen and nitrogen; (6) pressurizing the column and adsorbent bed to a high pressure again using a mixture of hydrogen and nitrogen. The product stream obtained in step (3) which comprises at least 80 vol% carbon monoxide can be sent as feed to a Fischer-Tropsch reaction.In a preferred embodiment a gas comprising at least 80 vol% hydrogen is produced as well.

18. 发明专利

AU2014343715B2 Process for converting oxygenates to olefins 未知
公开(公告)号：AU2014343715B2
公开(公告)日：2017-03-02
申请号：AU2014343715
申请日：2014-10-31
申请人： SHELL INT RESEARCH
发明人： SANBORN RICHARD ADDISON , SADASIVAN VIJAYAKUMARI SIVAKUMAR , CHEWTER LESLIE ANDREW , CHEN YE MON
IPC分类号： C07C1/20 , B01J4/00 , B01J8/44
摘要： A process for converting oxygenates to olefins comprising: a) providing an oxygenate containing stream to an oxygenate to olefins conversion reactor; b) passing the oxygenate containing stream through a feed introduction system comprising one or more nozzles and one or more corresponding caps; c) contacting the oxygenate containing stream with a molecular sieve catalyst in the oxygenate to olefins conversion reactor to form an olefin containing product stream; and d) removing the product stream from the reactor.

19. 发明专利

EA025157B1 СПОСОБ ПЕРЕРАБОТКИ ОТХОДЯЩЕГО ГАЗА СИНТЕЗА ФИШЕРА-ТРОПША 未知
公开(公告)号：EA025157B1
公开(公告)日：2016-11-30
申请号：EA201400499
申请日：2012-10-25
申请人： SHELL INT RESEARCH
发明人： BRACHT MAARTEN , BUNGKU DESMOND ANDREW , TE BRAAKE JUSTUS THEODORUS GERARDUS , VAN DE GRAAF WOUTER DAVID , LINDERS XANDER , SADASIVAN VIJAYAKUMARI SIVAKUMAR
IPC分类号： B01D53/04 , B01D53/047 , C10K1/32
摘要： Настоящееизобретениеотноситсяк способуполучениягаза, содержащегопоменьшеймере 80 об.% монооксидауглерода, изотходящегогазасинтезаФишера-Тропша. Способвключаетв себяследующиестадии: (1) подачуотходящегогазасинтезаФишера-Тропшачерезколонку, котораясодержитслойадсорбента, привысокомдавлениии выпусканияотходящегопотока; (2) незначительноеснижениедавленияв колонкеи слое; (3) продувкуколонкии слояадсорбентаметаномилисмесьюметанаи диоксидауглерода; (4) снижениедавленияв колонкеи слоеадсорбентадонизкогодавления; (5) продувкуколонкии слояадсорбентасмесьюводородаи азота; (6) созданиев колонкеи слоеадсорбентавысокогодавлениясновас использованиемсмесиводородаи азота. Полученныйнастадии (3) потокпродукта, которыйсодержитпоменьшеймере 80 об.% монооксидауглерода, можетподаватьсяв качествесырьясинтезаФишера-Тропша. Впредпочтительномвариантеосуществлениятакжеполучаетсягаз, содержащийпоменьшеймере 80 об.% водорода.

20. 发明专利

AP201609598A0 METHOD FOR PROCESSING A GAS MIXTURE 未知
公开(公告)号：AP201609598A0
公开(公告)日：2016-11-30
申请号：AP201609598
申请日：2015-06-29
申请人： SHELL INT RESEARCH
发明人： SADASIVAN VIJAYAKUMARI SIVAKUMAR , KOTAK PARAG , JONCKERS ARJAN ALLERT , SCHENCK HUBERT WILLEM , DUNCAN JULIE HÉLÈNE EMOND , FESTA PEREIRA RIBEIRO EDUARDO JORGE
IPC分类号： B01D53/047
CPC分类号： C01B3/12 , B01D53/047 , B01D2253/102 , B01D2253/104 , B01D2253/106 , B01D2253/108 , B01D2256/16 , B01D2256/22 , B01D2256/245 , B01D2257/102 , B01D2257/11 , B01D2257/502 , B01D2257/504 , B01D2257/7022 , B01D2257/7025 , B01D2259/40032 , B01D2259/4005 , B01D2259/402 , B01D2259/4062 , C01B2203/0283 , C01B2203/043 , C01B2203/0465 , C01B2203/1205 , C01B2203/146 , Y02C10/08 , Y02C20/20 , Y02P20/582
摘要： The present invention relates to a process for processing a gas mixture comprising methane, carbon dioxide, carbon monoxide, hydrogen, nitrogen, argon and traces of olefins and oxygenates. Methane, carbon dioxide and carbon monoxide, and optionally hydrogen, can be recovered from the gas mixture in a very efficient way.

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