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11. 发明申请

WO2008015435A1 AN EROSION AND WEAR RESISTANT SONOELECTROCHEMICAL PROBE 审中-公开
标题翻译：耐腐蚀和耐磨耗的电化学探针
公开(公告)号：WO2008015435A1
公开(公告)日：2008-02-07
申请号：PCT/GB2007/002933
申请日：2007-08-01
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT N.V. , HALL, Clive , JIANG, Li , JONES, Timothy , MEREDITH, Andrew , LAWRENCE, Nathan , PAGELS, Markus
发明人： HALL, Clive , JIANG, Li , JONES, Timothy , MEREDITH, Andrew , LAWRENCE, Nathan , PAGELS, Markus
IPC分类号： G01N27/30 , G01N27/38
CPC分类号： G01N27/308 , G01N27/26 , G01N27/38
摘要： The present invention provides methods and systems incorporating conducting diamond electrodes into a high power acoustic resonator. More specifically in certain embodiments of the present invention, diamond electrodes may be integrated into a high power acoustic resonator to provide a robust sensing device that may provide for acoustic cleaning of the electrodes and increasing the rate of mass transport to the diamond electrodes. The diamond electrodes may be used as working, reference or counter electrodes or a combination of two or more of such electrodes. In certain aspects, the high power acoustic resonator may include an acoustic horn for focusing acoustic energy and the diamond electrodes may be coupled with the acoustic horn.
摘要翻译：本发明提供了将导电金刚石电极结合到高功率声谐振器中的方法和系统。更具体地，在本发明的某些实施例中，金刚石电极可以集成到高功率声谐振器中，以提供鲁棒的感测装置，其可以提供对电极的声学清洁并且提高质量传输到金刚石电极的速率。金刚石电极可以用作工作电极，参考电极或对电极，或两个或多个这样的电极的组合。在某些方面，高功率声谐振器可以包括用于聚焦声能的声喇叭，并且金刚石电极可以与声喇叭耦合。

12. 发明申请

WO2005066618A1 ELECTRO-CHEMICAL SENSOR 审中-公开
标题翻译：电化学传感器
公开(公告)号：WO2005066618A1
公开(公告)日：2005-07-21
申请号：PCT/GB2004/005397
申请日：2004-12-22
申请人： SCHLUMBERGER TECHNOLOGY B.V. , PRAD RESEARCH AND DEVELOPMENT N.V. , SCHLUMBERGER CANADA LIMITED , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER OILFIELD ASSISTANCE LIMITED , SCHLUMBERGER OVERSEAS S.A. , SCHLUMBERGER SEACO INC. , SCHLUMBERGER SURENCO S.A. , SERVICES PETROLIERS SCHLUMBERGER , JIANG, Li , JONES, Timothy, Gareth, John , COMPTON, Richard , LAWRENCE, Nathan , WILDGOOSE, Gregory, George , PANDURANGAPPA, Malingappagari , MULLINS, Oliver, Clinton , MEREDITH, Andrew
发明人： JIANG, Li , JONES, Timothy, Gareth, John , COMPTON, Richard , LAWRENCE, Nathan , WILDGOOSE, Gregory, George , PANDURANGAPPA, Malingappagari , MULLINS, Oliver, Clinton , MEREDITH, Andrew
IPC分类号： G01N27/416
CPC分类号： G01N27/308 , E21B47/10 , G01N27/302 , G01N27/3335
摘要： An electro-chemical sensor is described having two molecular redox systems sensitive to the same species and having an detector to detect relative shifts in the voltammograms of the two redox systems.
摘要翻译：描述了一种电化学传感器，其具有对相同物质敏感的两个分子氧化还原系统，并且具有检测器以检测两个氧化还原体系的伏安图的相对位移。

13. 发明申请

WO2016044017A1 MID-INFRARED ACID SENSOR 审中-公开
标题翻译：中红外传感器
公开(公告)号：WO2016044017A1
公开(公告)日：2016-03-24
申请号：PCT/US2015/049086
申请日：2015-09-09
申请人： SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER TECHNOLOGY B.V. , PRAD RESEARCH AND DEVELOPMENT LIMITED , SCHLUMBERGER TECHNOLOGY CORPORATION
发明人： JONES, Timothy , LAWRENCE, Nathan , FUJISAWA, Go , CHAO, Sheng , LI, Jiang
IPC分类号： G01N21/3577 , G01N21/05
CPC分类号： G01N21/3577 , G01N21/552
摘要： A sensor is provided for monitoring a mineral acid dissolved in a liquid. The sensor includes an internal reflection window which, in use, is in direct contact with the liquid. The sensor further includes a mid-infrared light source which directs a beam of mid-infrared radiation into said window for attenuated internal reflection at an interface between the window and the liquid. The sensor further includes a first narrow bandpass filter which preferentially transmits mid-infrared radiation over a band of wavelengths corresponding to an absorbance peak of the dissolved mineral acid to filter internally reflected mid-infrared radiation received from the window. The sensor further includes an infrared detector which detects filtered mid-infrared radiation transmitted through the first filter. The sensor further includes a processor arrangement, operably coupled to the infrared detector, which measures the intensity of the detected mid-infrared radiation transmitted through the first filter, and determines therefrom an amount of the mineral acid dissolved in the liquid.
摘要翻译：提供了一种用于监测溶解在液体中的无机酸的传感器。传感器包括在使用中与液体直接接触的内部反射窗口。该传感器还包括一个中红外光源，它将一束中红外辐射引导到所述窗口中以在窗口和液体之间的界面处衰减内反射。传感器还包括第一窄带通滤波器，其优先在对应于溶解的无机酸的吸收峰的波长带上传输中红外辐射，以过滤从窗口接收的内部反射的中红外辐射。传感器还包括红外检测器，其检测经过第一过滤器传输的过滤的中红外辐射。传感器还包括可操作地耦合到红外检测器的处理器装置，其测量通过第一过滤器传输的检测到的中红外辐射的强度，并从其确定溶解在液体中的无机酸的量。

14. 发明申请

WO2013093899A1 ELECTROCHEMICAL SENSOR FOR PH MEASUREMENT 审中-公开
标题翻译：电化学传感器用于PH测量
公开(公告)号：WO2013093899A1
公开(公告)日：2013-06-27
申请号：PCT/IB2012/057695
申请日：2012-12-24
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT LIMITED , SCHLUMBERGER TECHNOLOGY CORPORATION
发明人： LAWRENCE, Nathan , MEREDITH, Andrew
IPC分类号： G01N27/30 , G01N27/416
CPC分类号： G01N27/302
摘要： A method of determining the pH of an aqueous liquid which contains little or no buffer, such as does not contain more than 0.01 moles per litre of pH-buffering partially dissociated acid, base and/or salt, uses an electrode with at least one redox active compound immobilized thereon convertible electrochemically between reduced and oxidized forms with transfer of at least one proton between the compound and the aqueous liquid. Varying potential is applied to the electrode, observing current flow as potential is varied, determining the applied potential at a maximum current for redox reaction of the compound, and determining pH from the potential at maximum current. The electrode has a covering layer which separates the redox active compound from the aqueous liquid but selectively allows the passage of hydrogen ions between the redox active compound and the aqueous liquid. The presence of the covering layer enhances accuracy of the measurement of pH of the aqueous liquid.
摘要翻译：确定含有很少或没有缓冲液的水性液体的pH值的方法，例如不超过0.01摩尔每升pH缓冲部分解离的酸，碱和/或盐，使用具有至少一种氧化还原电极固定在其上的活性化合物在还原和氧化形式之间电化学转化，同时在化合物和含水液体之间转移至少一个质子。对电极施加不同的电位，随着电位的变化观察电流，确定化合物的氧化还原反应的最大电流下的施加电位，并从最大电流的电位测定pH。电极具有将氧化还原活性化合物与水性液体分离的覆盖层，但是选择性地允许氢氧离子在氧化还原活性化合物和含水液体之间通过。覆盖层的存在提高了水性液体的pH的测量的准确性。

15. 发明申请

WO2016048655A1 TEMPERATURE INVARIANT INFRARED FILTER 审中-公开
标题翻译：温度不变的红外滤波器
公开(公告)号：WO2016048655A1
公开(公告)日：2016-03-31
申请号：PCT/US2015/049094
申请日：2015-09-09
申请人： SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER TECHNOLOGY B.V. , PRAD RESEARCH AND DEVELOPMENT LIMITED , SCHLUMBERGER TECHNOLOGY CORPORATION , READING UNIVERSITY
发明人： JONES, Timothy , LAWRENCE, Nathan , HAWKINS, Gary
IPC分类号： G02B5/20
CPC分类号： G02B5/285 , G01N33/2823
摘要： A narrow bandpass filter that may be used in a mid-infrared sensor for monitoring a species, which may be a component of a fluid or a solid material. The filter comprises a cavity comprising a low refractive index material. By providing a high ratio of low refractive index material in the filter with respective to high refractive index material, the filter is configured so that wavelength transmission remains constant with varying temperature. Materials used for the low and/or high refractive index provide a temperature invariant filter that transmits mid-infrared spectra without serious degradation.
摘要翻译：可用于中红外传感器的窄带通滤波器，用于监测物种，其可以是流体或固体材料的组分。该滤光器包括一个包含低折射率材料的空腔。通过在滤光器中提供高折射率材料与高折射率材料的高比率，滤光器被配置为使得波长透射在温度变化时保持恒定。用于低和/或高折射率的材料提供了传递中红外光谱而不严重退化的温度不变滤波器。

16. 发明申请

WO2016044005A1 MID-INFRARED CARBON DIOXIDE SENSOR 审中-公开
标题翻译：中红外二氧化碳传感器
公开(公告)号：WO2016044005A1
公开(公告)日：2016-03-24
申请号：PCT/US2015/049058
申请日：2015-09-09
申请人： SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER TECHNOLOGY B.V. , PRAD RESEARCH AND DEVELOPMENT LIMITED , SCHLUMBERGER TECHNOLOGY CORPORATION
发明人： FUJISAWA, Go , CHAO, Sheng , JONES, Timothy , LAWRENCE, Nathan , RUSTAD, Rolf , JIANG, Li , GAHLINGS, Steven
IPC分类号： G01N21/3504
CPC分类号： G01V8/10 , E21B49/08 , E21B2049/085 , G01N21/15 , G01N21/3504 , G01N21/3577 , G01N21/552 , G01N33/004 , G01N2021/152 , G01N2021/154 , G01N2201/068 , G01N2201/0696 , G01N2201/12 , Y02A50/244
摘要： A sensor for monitoring CO 2 in a fluid regardless of the phase properties of the fluid, i.e ., regardless of whether the fluid contacting the window is a liquid water-based phase, a liquid oil-based phase, a mixture of liquid water and liquid oil-based phases, or a gas phase. The sensor includes an internal reflection window for contacting with the fluid. A mid-infrared light source directs a beam of mid-infrared radiation into the window and the beam is internal reflected at an interface between the window and the fluid. The reflected beam is passed through three narrow bandpass filters which preferentially transmit mid-infrared radiation over bands of wavelengths corresponding to absorbance peaks of water, oil and CO 2 . The amount of CO 2 is determined from the intensities of the mid-infrared radiation passing through the three filters
摘要翻译：无论流体的相位特性如何，监测流体中CO 2的传感器，而不管流体是否接触流体窗口是液体水基相，液体油基相，液体水和液体油基相的混合物，或气相。传感器包括用于与流体接触的内部反射窗口。中红外光源将中红外辐射光束引导到窗口中，并且光束在窗口和流体之间的界面处被内部反射。反射光束通过三个窄带通滤波器，其优先在与水，油和CO 2的吸收峰对应的波长带上传输中红外辐射。 CO 2的量由通过三个过滤器的中红外辐射的强度来确定

17. 发明申请

WO2013093888A1 ELECTROCHEMICAL SENSORS 审中-公开
标题翻译：电化学传感器
公开(公告)号：WO2013093888A1
公开(公告)日：2013-06-27
申请号：PCT/IB2012/057638
申请日：2012-12-21
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT LIMITED , SCHLUMBERGER TECHNOLOGY CORPORATION
发明人： CRAWFORD, Lynne , MEREDITH, Andrew , LAWRENCE, Nathan , JONES, Timothy
IPC分类号： G01N27/26 , G01N33/18
CPC分类号： G01N27/28 , E21B47/00 , G01N27/302 , G01N27/308 , G01N27/48 , G01N33/1886
摘要： An electrochemical sensor incorporates a ferrocenophane which is a compound with at least one bridging group covalently attached to and connecting the two cyclopentadiene rings associated with the same iron atom. This bridging group maybe tetramethylene. As compared to an equivalent sensor with ferrocene, the tolerance of elevated temperature is improved and so is the working life at ambient temperature.
摘要翻译：电化学传感器包含二茂铁根，其是与至少一个共价连接并连接与相同铁原子相连的两个环戊二烯环的桥连基团的化合物。该桥连基团可以是四亚甲基。与具有二茂铁的等效传感器相比，提高温度的公差提高，并且在环境温度下的工作寿命也得到改善。

18. 发明申请

WO2013093884A2 DERIVATIZATION OF CARBON 审中-公开
标题翻译：碳的衍生物
公开(公告)号：WO2013093884A2
公开(公告)日：2013-06-27
申请号：PCT/IB2012/057619
申请日：2012-12-21
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT LIMITED , SCHLUMBERGER TECHNOLOGY CORPORATION
发明人： CRAWFORD, Lynne , LAWRENCE, Nathan , JONES, Timothy
IPC分类号： C01B31/02 , C01B31/04 , C07C243/16 , B01J19/24
CPC分类号： C07C201/12 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B32/194 , C01B32/20 , G01N27/302 , G01N27/308 , H01G11/32 , H01M4/583 , H01M4/96 , Y02E60/13
摘要： Derivatization of an elemental carbon surface is accomplished by exposing the carbon surface to an aprotic solvent containing a hydrazone molecule of formula or the corresponding salt of formula wherein R 1 is an organic group, and R2 is an organic group or hydrogen and decomposing the hydrazone in the presence of elemental carbon to create a carbene moiety of formula: which attaches to the carbon surface. The attached groups may be redox active so that the derivatized carbon may be used in an electrochemical sensor.
摘要翻译：元素碳表面的衍生是通过将碳表面暴露于含有下式的腙分子的非质子溶剂或相应的式的盐，其中R 1是有机基团，R 2是有机基团或氢，并将腙分解成存在的元素碳以产生下式的卡宾部分：其附着在碳表面上。所连接的基团可以是氧化还原活性的，使得衍生的碳可以用在电化学传感器中。

19. 发明申请

WO2013093883A2 DERIVATIZATION OF CARBON 审中-公开
标题翻译：碳的衍生物
公开(公告)号：WO2013093883A2
公开(公告)日：2013-06-27
申请号：PCT/IB2012/057617
申请日：2012-12-21
申请人： SCHLUMBERGER TECHNOLOGY B.V. , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , PRAD RESEARCH AND DEVELOPMENT LIMITED , SCHLUMBERGER TECHNOLOGY CORPORATION
发明人： CRAWFORD, Lynne , LAWRENCE, Nathan , JONES, Timothy
IPC分类号： C01B31/02 , B82B1/00 , B82B3/00
CPC分类号： C01B31/02 , B82Y30/00 , B82Y40/00 , C01B31/0273 , C01B31/04 , C01B31/0484 , C01B32/05 , C01B32/174 , C01B32/194 , C01B32/20 , G01N27/302 , G01N27/308 , G01N27/48
摘要： A process for derivatization of an elemental carbon surface comprising exposing the carbon surface to a reaction mixture containing a thiol and a free radical initiator, and inducing decomposition of the initiator to free radicals so that moieties from the thiol become covalently attached to the carbon surface. The process can derivatize carbon with a redox active compound having a functional group which can be converted electrochemically between reduced and oxidized forms. Such derivatized carbon may be used in an electrode of an electrochemical sensor.
摘要翻译：包括将碳表面暴露于含有硫醇和自由基引发剂的反应混合物，并引发引发剂分解成自由基的方法，使得来自硫醇的部分共价连接到碳表面。该方法可以用具有官能团的氧化还原活性化合物衍生碳，其可以在还原和氧化形式之间电化学转化。这种衍生的碳可以用在电化学传感器的电极中。

20. 发明申请

WO2016044008A1 MID-INFRARED SENSOR 审中-公开
标题翻译：中红外传感器
公开(公告)号：WO2016044008A1
公开(公告)日：2016-03-24
申请号：PCT/US2015/049065
申请日：2015-09-09
申请人： SCHLUMBERGER CANADA LIMITED , SERVICES PETROLIERS SCHLUMBERGER , SCHLUMBERGER HOLDINGS LIMITED , SCHLUMBERGER TECHNOLOGY B.V. , PRAD RESEARCH AND DEVELOPMENT LIMITED , SCHLUMBERGER TECHNOLOGY CORPORATION
发明人： JONES, Timothy , LAWRENCE, Nathan , FUJISAWA, Go , CHAO, Sheng
IPC分类号： E21B49/08 , G01N21/35 , G01N33/24
CPC分类号： E21B47/123 , E21B47/0002 , G01N21/552 , G01N33/24
摘要： A sensor for monitoring a species which is a component of a fluid. The sensor includes an internal reflection window which, in use, is in direct contact with the fluid. The sensor further includes a mid-infrared light source which directs a beam of mid-infrared radiation into said window for attenuated internal reflection at an interface between the window and the fluid. The sensor further includes a first narrow bandpass filter which preferentially transmits mid-infrared radiation over a band of wavelengths corresponding to an absorbance peak of the species. The sensor further includes an infrared detector which detects filtered mid-infrared radiation transmitted through the first filter and a processor for measuring the intensity of the detected mid-infrared radiation transmitted through the first filter, and determines therefrom an amount of the species in the fluid.
摘要翻译：用于监测作为流体成分的物种的传感器。传感器包括在使用中与流体直接接触的内部反射窗口。传感器还包括一个中红外光源，它将一束中红外辐射引导到所述窗口中，用于在窗口和流体之间的界面处进行衰减的内部反射。传感器还包括第一窄带通滤波器，其优先地在与物种的吸收峰对应的波长带上传输中红外辐射。传感器还包括红外检测器，其检测透过第一过滤器的过滤的中红外辐射，以及处理器，用于测量通过第一过滤器传输的检测到的中红外辐射的强度，并由此确定流体中物质的量。

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