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    • 13. 发明申请
    • AQUEOUS POLYMER DISPERSION AND PROCESS
    • 水性聚合物分散体和工艺
    • WO2004069879A1
    • 2004-08-19
    • PCT/EP2004/000999
    • 2004-02-04
    • UCB, S.A.DO AMARAL MARTINS, MarceloASUA, José, M.DE BROUWER, HansVAN ES, Steven
    • DO AMARAL MARTINS, MarceloASUA, José, M.DE BROUWER, HansVAN ES, Steven
    • C08F2/22
    • C08F2/24
    • The invention relates to a process for the preparation of an aqueous polymer dispersion by mini-emulsion polymerisation comprising the steps of (a) forming a mixture comprising (optionally formed as a first aqueous pre-mixture) water and at least one amphiphilic stabilising polymer having a number average molecular weight M n of 800 to 100,000 and an acid number of 50 to 400 mg KOH/g and (optionally formed as a second organic pre-mixture) at least one hydrophobic co-stabiliser and at least one a,ß-ethylenically unsaturated monomer; (b) subjecting this mixture to high stress to form a mini-emulsion comprising stabilised droplets of average diameter from about 10 to about 1000 nm and polymerising the monomer within the droplets. Preferably the mixtures are substantially free of surfactant other than the amphiphilic polymer. Aqueous polymer dispersions so obtained and uses thereof in coatings, films, adhesives and inks are also described.
    • 本发明涉及通过微乳液聚合制备含水聚合物分散体的方法,包括以下步骤:(a)形成包含(任选地形成为第一含水预混合物)水和至少一种两亲稳定化聚合物的混合物,其具有 数均分子量Mn为800至100,000,酸值为50至400mg KOH / g,(任选地形成为第二有机预混合物)至少一种疏水性共稳定剂和至少一种α,β-烯属 不饱和单体; (b)使该混合物经受高应力以形成包含平均直径为约10至约1000nm的稳定液滴的微型乳液,并使单体在液滴内聚合。 优选地,混合物基本上不含两亲性聚合物以外的表面活性剂。 还描述了如此获得的水性聚合物分散体及其在涂料,膜,粘合剂和油墨中的用途。