专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

11. 发明授权

US07297806B2 Manufacture of alpha-olefins 有权
标题翻译： α-烯烃的制造
公开(公告)号：US07297806B2
公开(公告)日：2007-11-20
申请号：US10235443
申请日：2002-09-05
申请人： Maurice S. Brookhart, III , Brooke L. Small
发明人： Maurice S. Brookhart, III , Brooke L. Small
IPC分类号： B01J31/00 , B01J37/00
CPC分类号： C07D213/53 , C07C2/32 , C07C2531/22 , C07F15/02 , C07F15/025 , C08F10/00 , C08F4/7042
摘要： Alpha-olefin are manufactured in high yield and with very high selectivity by contacting ethylene with an iron complex of a selected 2,6-pyridinedicarboxaldehyde bisimine or a selected 2,6-diacylpyridine bisimine, and in some cases a selected activator compound such as an alkyl aluminum compound. Novel bisimines and their iron complexes are also disclosed. The α-olefin are useful as monomers and chemical intermediates.
摘要翻译：通过使乙烯与选择的2,6-吡啶二甲醛双亚胺或选择的2,6-二酰基吡啶双亚胺的铁络合物接触，以高产率和非常高的选择性制备α-烯烃，并且在一些情况下选择的活化剂化合物例如烷基铝化合物。还公开了新型双亚胺及其铁络合物。 α-烯烃可用作单体和化学中间体。

12. 发明授权

US07223893B2 Linear alpha-olefin dimers possessing substantial linearity 有权
标题翻译：线性α-烯烃二聚体具有很大的线性
公开(公告)号：US07223893B2
公开(公告)日：2007-05-29
申请号：US10056137
申请日：2002-01-24
申请人： Brooke L. Small , Eduardo J Baralt
发明人： Brooke L. Small , Eduardo J Baralt
IPC分类号： C07C13/00
CPC分类号： C07C2/32 , C07C11/02 , C07C2531/22 , C07C2531/26
摘要： Linear 1-butene dimers and other linear alpha-olefin dimers are manufactured in high yield and with high selectivity by coupling of alpha-olefins. The coupling is accomplished by contacting alpha olefins with an iron-based catalyst activated with an aluminum-based co-catalyst. The catalyst is structured to preclude formation of multiple dimer products, and the byproducts of the olefin coupling consist almost exclusively of methyl branched olefin dimers. The dimers have potentially diverse use in areas stretching form pharmaceuticals to plastics. Linear 1-butene dimers may be particularly useful in the production of plasticizer alcohols which may in turn be used to manufacture high quality plastics with reduced leaching.
摘要翻译：线性1-丁烯二聚体和其它直链α-烯烃二聚体以高产率和高选择性通过α-烯烃的偶联制备。通过使α-烯烃与用铝基助催化剂活化的铁基催化剂接触来实现偶合。该催化剂被构造成排除多个二聚体产物的形成，并且烯烃偶联的副产物几乎完全由甲基支链烯烃二聚体组成。二聚体在从药物到塑料中拉伸的领域中具有潜在的多种用途。线性1-丁烯二聚体可以特别用于生产增塑剂醇，其可以用于制造具有减少浸出的高质量塑料。

13. 发明授权

US06911505B2 Selective isomerization and linear dimerization of olefins using cobalt catalysts 失效
标题翻译：使用钴催化剂选择性异构化和烯烃线性二聚
公开(公告)号：US06911505B2
公开(公告)日：2005-06-28
申请号：US10264730
申请日：2002-10-04
申请人： Brooke L. Small
发明人： Brooke L. Small
IPC分类号： C07C11/02 , C07C11/107 , C10G50/00 , C08F4/44
CPC分类号： C10G50/00 , C07C11/02 , C07C11/107 , Y10S526/901
摘要： Processes for the production of alpha-olefins, including dimerization and isomerization of olefins using a cobalt catalyst complex are provided herein. The olefins so produced are useful as monomers in further polymerization reactions and are useful as chemical intermediates.
摘要翻译：本文提供了使用钴催化剂复合物生产α-烯烃的方法，包括烯烃的二聚和异构化。如此生产的烯烃可用作进一步聚合反应中的单体，并且可用作化学中间体。

14. 发明授权

US6103946A Manufacture of .alpha.-olefins 失效
标题翻译： α-烯烃的制造
公开(公告)号：US6103946A
公开(公告)日：2000-08-15
申请号：US005965
申请日：1998-01-12
申请人： Maurice S. Brookhart, III , Brooke L. Small
发明人： Maurice S. Brookhart, III , Brooke L. Small
IPC分类号： C07B61/00 , C07C2/32 , C07C11/02 , C07D213/53 , C07F15/02 , C08F4/44 , C08F10/00 , C07C2/02
CPC分类号： C07D213/53 , C07C2/32 , C07F15/02 , C07F15/025 , C08F10/00 , C07C2531/22
摘要： Alpha-olefins are manufactured in high yield and with very high selectivity by contacting ethylene with an iron complex of a selected 2,6-pyridinedicarboxaldehyde bisimine or a selected 2,6-diacylpyridine bisimine, and in some cases a selected activator compound such as an alkyl aluminum compound. Novel bisimines and their iron complexes are also disclosed. The .alpha.-olefins are useful as monomers and chemical intermediates.
摘要翻译：通过使乙烯与选择的2,6-吡啶二甲醛双亚胺或选择的2,6-二酰基吡啶双亚胺的铁络合物接触，以高产率和非常高的选择性制备α-烯烃，并且在一些情况下选择的活化剂化合物如烷基铝化合物。还公开了新型双亚胺及其铁络合物。 α-烯烃可用作单体和化学中间体。

15. 发明授权

US08791217B2 Catalyst systems for production of alpha olefin oligomers and polymers 有权
标题翻译：用于生产α-烯烃低聚物和聚合物的催化剂体系
公开(公告)号：US08791217B2
公开(公告)日：2014-07-29
申请号：US13338362
申请日：2011-12-28
申请人： Mark L. Hlavinka , Qing Yang , Brooke L. Small , Youlu Yu
发明人： Mark L. Hlavinka , Qing Yang , Brooke L. Small , Youlu Yu
IPC分类号： C08F4/52 , C08F4/64 , C08F4/76
CPC分类号： C08F4/65912 , B01J31/2243 , B01J2231/10 , B01J2531/0258 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2540/10 , B01J2540/30 , B01J2540/40 , B01J2540/50 , C08F4/60158 , C08F4/659 , C08F4/76 , C08F110/14 , C08F4/64158 , C08F4/025
摘要： Catalyst compositions containing N,N-bis[2-hydroxidebenzyl]amine transition metal compounds are disclosed. Methods for making these transition metal compounds and for using such compounds in catalyst compositions for the polymerization or oligomerization of alpha olefins also are provided.
摘要翻译：公开了含有N，N-双[2-氢氧基苄基]胺过渡金属化合物的催化剂组合物。还提供了制备这些过渡金属化合物和在催化剂组合物中用于α-烯烃聚合或低聚的这些化合物的方法。

16. 发明授权

US08536391B2 Oligomerization of alpha olefins using metallocene-SSA catalyst systems and use of the resultant polyalphaolefins to prepare lubricant blends 有权
标题翻译：使用茂金属-SSA催化剂体系低聚α烯烃，并使用得到的聚α-烯烃制备润滑剂共混物
公开(公告)号：US08536391B2
公开(公告)日：2013-09-17
申请号：US12816077
申请日：2010-06-15
申请人： Brooke L. Small , Kenneth D. Hope , Qing Yang , Albert P. Masino , Max P. McDaniel , Richard M. Buck , William B. Beaulieu , Eduardo J. Baralt , Eric J. Netemeyer , Bruce Kreischer
发明人： Brooke L. Small , Kenneth D. Hope , Qing Yang , Albert P. Masino , Max P. McDaniel , Richard M. Buck , William B. Beaulieu , Eduardo J. Baralt , Eric J. Netemeyer , Bruce Kreischer
IPC分类号： C07C2/74
CPC分类号： C07C2/32 , B01J21/04 , B01J21/12 , B01J27/053 , B01J27/08 , B01J31/143 , B01J37/24 , B01J37/26 , B01J2231/20 , B01J2531/48 , C07C2/30 , C07C5/05 , C07C2531/14 , C07C2531/22 , C08F4/65912 , C08F4/65916 , C08F10/14 , C08F110/14 , C08F2410/01 , C10G2300/1088 , C10G2300/302 , C10G2300/304 , C10G2300/703 , C10G2400/22 , C10M105/04 , C10M107/08 , C10M107/10 , C10M143/08 , C10M2203/024 , C10M2205/026 , C10M2205/0265 , C10M2205/028 , C10M2205/0285 , C10N2220/021 , C10N2220/022 , C10N2220/023 , C10N2220/028 , C10N2220/032 , C10N2230/02 , C10N2230/10 , C10N2230/34 , C10N2230/74 , C10N2270/00 , Y02P20/52 , C08F4/65922 , C08F2500/02 , C08F2500/17
摘要： This disclosure provides for alpha olefin oligomers and polyalphaolefins (or PAOs) and methods of making the alpha olefin oligomers and PAOs. This disclosure encompasses metallocene-based alpha olefin oligomerization catalyst systems, including those that include at least one metallocene and an activator comprising a solid oxide chemically-treated with an electron withdrawing anion. The alpha olefin oligomers and PAOs prepared with these catalyst systems can have a high viscosity index combined with a low pour point, making them particularly useful in lubricant compositions and as viscosity modifiers.
摘要翻译：本公开提供了α-烯烃低聚物和聚α-烯烃（或PAO）以及制备α-烯烃低聚物和PAO的方法。本公开内容包括基于茂金属的α-烯烃低聚催化剂体系，包括至少一种茂金属和包含用吸电子阴离子化学处理的固体氧化物的活化剂的催化剂体系。用这些催化剂体系制备的α-烯烃低聚物和PAO可以具有与低倾点相结合的高粘度指数，使得它们在润滑剂组合物和粘度调节剂中特别有用。

17. 发明授权

US07902415B2 Processes for dimerizing or isomerizing olefins 失效
标题翻译：烯烃二聚或异构化的方法
公开(公告)号：US07902415B2
公开(公告)日：2011-03-08
申请号：US11963252
申请日：2007-12-21
申请人： Brooke L. Small
发明人： Brooke L. Small
IPC分类号： C07C2/24
CPC分类号： C07C2/32 , C07C5/2581 , C07C11/02
摘要： A process for dimerizing alpha olefins comprising contacting (i) an alpha olefin having at least 3 carbon atoms, (ii) a hexadentate bimetallic catalyst, and (iii) a cocatalyst, and dimerizing the alpha olefin in a reaction zone at conditions effective to dimerize an alpha olefin to form a reaction zone effluent comprising alpha olefin oligomers including alpha olefin dimers. A process for dimerizing olefins comprising contacting (i) an alpha olefin having at least 3 carbon atoms, (ii) a hexadentate bimetallic complex comprising a cobalt compound, and (iii) a cocatalyst, and dimerizing the alpha olefin in a reaction zone at conditions effective to dimerize an alpha olefin to form a reaction zone effluent comprising oligomers including dimmers, wherein greater than 20 weight percent of the alpha olefin has been converted to oligomers, greater than 30 weight percent of the oligomers are dimers, and greater than 85 mole percent of the dimers are linear.
摘要翻译：一种使α-烯烃二聚的方法，包括使（i）具有至少3个碳原子的α-烯烃，（ii）六齿双金属催化剂和（iii）助催化剂，和在有效二聚的条件下在反应区中使α-烯烃二聚 α-烯烃以形成包含α-烯烃低聚物（包括α-烯烃二聚体）的反应区流出物。一种使烯烃二聚的方法，包括使（i）具有至少3个碳原子的α-烯烃，（ii）包含钴化合物的六齿双金属络合物和（iii）助催化剂，并在条件下将α烯烃在反应区中二聚有效地使α-烯烃二聚以形成包含低聚物（包括二聚体）的反应区流出物，其中大于20重量％的α-烯烃已经转化为低聚物，大于30重量％的低聚物是二聚体，并且大于85摩尔％的二聚体是线性的。

18. 发明申请

US20100222577A1 Diimine Metal Complexes, Methods of Synthesis, and Methods of Using in Oligomerization and Polymerization 有权
标题翻译：二亚胺金属络合物，合成方法和在低聚和聚合中使用的方法
公开(公告)号：US20100222577A1
公开(公告)日：2010-09-02
申请号：US12775596
申请日：2010-05-07
申请人： Brooke L. Small , Michael Carney
发明人： Brooke L. Small , Michael Carney
IPC分类号： C07F15/02 , C07F13/00 , C07F15/06
CPC分类号： B01J31/1805 , B01J31/00 , B01J31/143 , B01J2231/10 , C07F13/005 , C07F15/02 , C07F15/025 , C07F15/06 , C07F15/065 , C08F10/00 , C08F110/02 , C08F2500/02 , C08F4/695 , C08F4/7042 , C08F4/7006 , C08F4/7045 , C08F4/7049 , C08F4/7044
摘要： Novel α-diimine metal complexes, particularly iron complexes, having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are disclosed. The α-diimine metal complexes having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are produced by forming one of the α-diimine metal complex imine bonds in the presence of a metal salt or an α-acylimine metal complex. The α-diimine metal complexes having phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are useful for polymerizing or oligomerizing olefins.
摘要翻译：公开了具有苯基硫代基或取代的苯基硫代金属络合基团的新型α-二亚胺金属络合物，特别是铁络合物。通过在金属盐或α-酰亚胺金属络合物的存在下形成α-二亚氨基金属络合物亚胺键之一来制备具有苯基硫基或取代的苯基硫基金属络合基团的α-二亚胺金属络合物。具有苯基硫代基或取代的苯基硫代金属络合基团的α-二亚胺金属络合物可用于烯烃的聚合或低聚。

19. 发明授权

US07727926B2 Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization 有权
标题翻译：二亚胺金属配合物，合成方法，以及在低聚反应中使用的方法
公开(公告)号：US07727926B2
公开(公告)日：2010-06-01
申请号：US11590435
申请日：2006-10-31
申请人： Brooke L. Small , Michael Carney
发明人： Brooke L. Small , Michael Carney
IPC分类号： B01J31/00 , C07F15/02 , C07F15/06
CPC分类号： B01J31/1805 , B01J31/00 , B01J31/143 , B01J2231/10 , C07F13/005 , C07F15/02 , C07F15/025 , C07F15/06 , C07F15/065 , C08F10/00 , C08F110/02 , C08F2500/02 , C08F4/695 , C08F4/7042 , C08F4/7006 , C08F4/7045 , C08F4/7049 , C08F4/7044
摘要： Novel α-diimine metal complexes, particularly iron complexes, having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are disclosed. The α-diimine metal complexes having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are produced by forming one of the α-diimine metal complex imine bonds in the presence of a metal salt or an α-acylimine metal complex. The α-diimine metal complexes having phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are useful for polymerizing or oligomerizing olefins.
摘要翻译：公开了具有苯基硫代基或取代的苯基硫代金属络合基团的新型α-二亚胺金属络合物，特别是铁络合物。通过在金属盐或α-酰亚胺金属络合物的存在下形成α-二亚氨基金属络合物亚胺键之一来制备具有苯基硫基或取代的苯基硫基金属络合基团的α-二亚胺金属络合物。具有苯基硫代基或取代的苯基硫代金属络合基团的α-二亚胺金属络合物可用于烯烃的聚合或低聚。

20. 发明授权

US07378537B2 Olefin oligomerization catalysts and methods of using same 有权
标题翻译：烯烃低聚催化剂及其使用方法
公开(公告)号：US07378537B2
公开(公告)日：2008-05-27
申请号：US11459795
申请日：2006-07-25
申请人： Brooke L. Small , Jeffery C. Gee
发明人： Brooke L. Small , Jeffery C. Gee
IPC分类号： C07C2/32 , C07C2/08 , C07F9/28 , B01J31/00
CPC分类号： C07F9/46 , B01J31/143 , B01J31/188 , B01J2231/20 , B01J2531/62 , C07C2/36 , C07C2531/24 , C07F11/00 , C07C11/02
摘要： A metal complex comprising a metal compound complexed to a heteroatomic ligand, the metal complex having Structure X: wherein R1, R2, R3, and R4 are each independently an alkyl group, a cycloalkyl group, a substituted cycloalkyl group, an aromatic group, or a substituted aromatic group, R1c, R2c, R3c, R4c, and R5c are each independently hydrogen or an alkyl group, and MXp comprises a group IVB, VB, or VIB metal. A metal complex comprising a metal compound complexed to a diphosphino aminyl ligand comprising at least two diphosphino aminyl moieties and a linking group linking each aminyl nitrogen atom of the diphosphino aminyl moieties.
摘要翻译：包含与杂原子配位体配位的金属化合物的金属络合物，具有结构X的金属络合物：其中R 1，R 2，R 3， R 4和R 4各自独立地为烷基，环烷基，取代的环烷基，芳族基团或取代的芳族基团，R 1c，R“ > 2c，R 3c，R 4c和R 5c各自独立地为氢或烷基，MX _{p 包括IVB族，VB族或VIB族金属。一种金属络合物，其包含与二膦基乙炔基配体络合的金属化合物，其包含至少两个二膦酰乙烯基部分和连接二膦酰乙烯基部分的每个亚氨基氮原子的连接基团。}

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式