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11. 发明授权

US4585617A Amorphous metal alloy compositions and synthesis of same by solid state incorporation/reduction reactions 失效
标题翻译：无定形金属合金组成及其通过固态掺入/还原反应的合成
公开(公告)号：US4585617A
公开(公告)日：1986-04-29
申请号：US751704
申请日：1985-07-03
申请人： Michael A. Tenhover , Richard S. Henderson , Robert K. Grasselli
发明人： Michael A. Tenhover , Richard S. Henderson , Robert K. Grasselli
IPC分类号： B22F9/20 , B22F9/00 , B22F9/16 , C22C1/00 , C22C33/00 , C22C45/00 , B22F7/00
CPC分类号： B22F9/004 , C22C45/00
摘要： Amorphous metal alloy compositions are synthesized by solid state incorporation/reduction reactions wherein a high-surface area support is brought in contact with a precursor metal-bearing compound in such a manner that the compound is incorporated into the support or caused to deposit metal onto the surface of the support. The composition obtained is an amorphous alloy composition or can be made so by heat treating at a temperature below the crystallization temperature of the amorphous metal alloy desired to be formed.
摘要翻译：无定形金属合金组合物通过固态掺入/还原反应合成，其中高表面积载体与含前体金属的化合物接触，使得化合物被引入载体中或使金属沉积到表面的支撑。获得的组合物是非晶合金组合物，或者可以通过在低于期望形成的非晶态金属合金的结晶温度的温度下进行热处理而制成。

12. 发明授权

US4537624A Amorphous metal alloy powders and synthesis of same by solid state decomposition reactions 失效
标题翻译：无定形金属合金粉末并通过固相分解反应合成
公开(公告)号：US4537624A
公开(公告)日：1985-08-27
申请号：US586380
申请日：1984-03-05
申请人： Michael A. Tenhover , Richard S. Henderson , Robert K. Grasselli
发明人： Michael A. Tenhover , Richard S. Henderson , Robert K. Grasselli
IPC分类号： B22F3/00 , B22F9/00 , B22F9/30 , C22C1/00 , C22C1/04 , B22F3/24
CPC分类号： B22F3/007 , B22F9/004 , B22F9/30 , C22C1/04 , Y10S505/804 , Y10S505/807
摘要： Amorphous metal alloy powders are synthesized by solid state decomposition reactions. At least one precursor compound is thermally decomposed at a temperature below the crystallization temperature of the amorphous metal alloy to be formed. The decomposition product comprises an intimate mixture of the elements of the alloy and, after heat-treating if necessary, exhibits amorphous characteristics.
摘要翻译：无定形金属合金粉末通过固相分解反应合成。至少一种前体化合物在低于要形成的非晶态金属合金的结晶温度的温度下热分解。分解产物包括合金元素的紧密混合物，并且如果需要进行热处理后，其表现出无定形特性。

13. 发明授权

US4851296A Process for the production of multi-metallic amorphous alloy coatings on a substrate and product 失效
标题翻译：在基材和产品上生产多金属非晶态合金涂层的方法
公开(公告)号：US4851296A
公开(公告)日：1989-07-25
申请号：US931494
申请日：1986-11-17
申请人： Michael A. Tenhover , Richard S. Henderson , Robert K. Grasselli
发明人： Michael A. Tenhover , Richard S. Henderson , Robert K. Grasselli
IPC分类号： C22C38/48 , C22C1/00 , C22C45/00 , C22C45/04 , C23C16/06 , C23C16/08 , C23C16/16 , C23C16/30
CPC分类号： C23C16/30 , C23C16/06 , Y10T428/12576 , Y10T428/12903 , Y10T428/12944 , Y10T428/12951 , Y10T428/31678
摘要： A process is disclosed for the formation of amorphous multi-metallic alloy coatings. More specifically, a chemical vapor deposition process is described wherein precursor compounds are induced to decompose upon a substrate under controlled parameters so as to form a coating on the substrate that is a substantially amorphous multi-metallic alloy. Preferred amorphous alloy compositions are also taught that are ideally synthesized by the claimed process.
摘要翻译：公开了用于形成非晶多金属合金涂层的方法。更具体地，描述了一种化学气相沉积方法，其中在受控参数下在衬底上诱导前体化合物分解，从而在基材上形成基本上为非晶态的多金属合金的涂层。还教导了理想地通过所要求保护的方法合成的优选的非晶合金组合物。

14. 发明授权

US4557766A Bulk amorphous metal alloy objects and process for making the same 失效
标题翻译：块状非晶金属合金物体及其制造方法
公开(公告)号：US4557766A
公开(公告)日：1985-12-10
申请号：US586467
申请日：1984-03-05
申请人： Michael A. Tenhover , Richard S. Henderson , Robert K. Grasselli
发明人： Michael A. Tenhover , Richard S. Henderson , Robert K. Grasselli
IPC分类号： B22F3/00 , B22F9/00 , B22F9/30 , C22C1/04 , B22F3/24
CPC分类号： B22F9/004 , B22F3/007 , B22F9/30 , C22C1/04
摘要： Amorphous metal alloy shapes are synthesized by providing an intimate mixture of the components of the amorphous alloy, which mixture includes at least one ductile component. The mixture may be subjected to well-known forming techniques at a temperature below the crystallization temperature of the amorphous metal alloy to be formed. The ductile component of the mixture acts as a binder matrix to provide strength and uniform properties to the formed object.
摘要翻译：无定形金属合金形状通过提供非晶合金的组分的紧密混合而合成，该混合物包括至少一种延性组分。可以在低于要形成的非晶态金属合金的结晶温度的温度下对混合物进行公知的成形技术。混合物的延性组分用作粘合剂基质，以向成形物体提供强度和均匀的性质。

15. 发明授权

US4746584A Novel amorphous metal alloys as electrodes for hydrogen formation and oxidation 失效
标题翻译：新型非晶态金属合金作为氢形成和氧化的电极
公开(公告)号：US4746584A
公开(公告)日：1988-05-24
申请号：US747985
申请日：1985-06-24
申请人： Michael A. Tenhover , Robert K. Grasselli
发明人： Michael A. Tenhover , Robert K. Grasselli
IPC分类号： C22C45/00 , C22C45/04 , C25B11/04 , H01M4/90 , B32B15/01 , C22C19/05
CPC分类号： C22C45/04 , C22C45/003 , C25B11/0478 , H01M4/90 , Y10T428/12806 , Y10T428/12875
摘要： Novel amorphous metal alloy electrodes have the formulaePt.sub.p A.sub.a D.sub.dwhereA is Ir, Pd, Rh, Ru and mixtures thereof;D is B, Al, As, P, Sb, Ge, Sn, Si and mixtures thereof;p is from about 40 to 92 percent;a is from about 1 to 40 percent;d is from about 8 to 40 percent; and p+a+d=100; andNi.sub.n E.sub.e F.sub.f G.sub.g whereE is Mo, W and mixtures thereof;F is Pt, Pd, Rh, Ir, Cr and mixtures thereof;G is Al, Ga and mixtures thereof;n is from about 30 to 90 percent;e is from about 10 to 50 percent;f is from about 0 to 25 percent;g is from about 10 to 40 percent; and n+e+f+g=100.These electrodes are useful for hydrogen formation and oxidation and operate at lower potentials than existing electrodes.
摘要翻译：新型无定形金属合金电极具有式PtpAaDd，其中A为Ir，Pd，Rh，Ru及其混合物; D是B，Al，As，P，Sb，Ge，Sn，Si及其混合物; p为约40％至92％; a为约1％至40％; d为约8％至40％; 和p + a + d = 100; 和NinEeFfGg，其中E是Mo，W及其混合物; F是Pt，Pd，Rh，Ir，Cr及其混合物; G是Al，Ga及其混合物; n为约30至90％; e为约10％至50％; f为约0至25％; g为约10％至40％; 并且n + e + f + g = 100。这些电极可用于氢形成和氧化，并在比现有电极更低的电位下工作。

16. 发明授权

US08003565B2 Platinum-ruthenium containing catalyst formulations for hydrogen generation 有权
标题翻译：含铂 - 钌的催化剂配方用于氢气生成
公开(公告)号：US08003565B2
公开(公告)日：2011-08-23
申请号：US11412918
申请日：2006-04-28
申请人： Alfred Hagemeyer , Raymond E. Carhart , Karin Yaccato , Peter Strasser , Robert K. Grasselli , Christopher James Brooks , Cory Bernard Phillips
发明人： Alfred Hagemeyer , Raymond E. Carhart , Karin Yaccato , Peter Strasser , Robert K. Grasselli , Christopher James Brooks , Cory Bernard Phillips
IPC分类号： B01J23/00 , B01J21/00 , B01J20/00
CPC分类号： C01B3/16 , B01J23/40 , B01J23/462 , B01J23/56 , B01J23/58 , B01J23/622 , B01J23/63 , B01J23/6482 , B01J23/6525 , B01J23/6562 , B01J23/89 , B01J23/8933 , B01J23/894 , B01J23/8946 , B01J23/8993 , B01J37/024 , B01J2219/00585 , B01J2219/00596 , B01J2219/00605 , B01J2219/00612 , B01J2219/00637 , B01J2219/00641 , B01J2219/00659 , B01J2219/00662 , B01J2219/00691 , B01J2219/00702 , B01J2219/00707 , B01J2219/00745 , B01J2219/00747 , C01B2203/00 , C01B2203/0283 , C01B2203/1011 , C01B2203/1023 , C01B2203/1041 , C01B2203/1052 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/1094 , C01B2203/1614 , C40B30/08 , C40B40/18 , H01M8/0618 , H01M8/0668 , Y02P20/52
摘要： A method and catalysts for producing a hydrogen-rich syngas are disclosed. According to the method a CO-containing gas contacts a water gas shift (WGS) catalyst, optionally in the presence of water, preferably at a temperature of less than about 450° C. to produce a hydrogen-rich gas, such as a hydrogen-rich syngas. Also disclosed is a water gas shift catalyst formulated from: a) Pt, its oxides or mixtures thereof; b) Ru, its oxides or mixtures thereof; and c) at least one of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Co, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu. Another disclosed catalyst formulation comprises Pt, its oxides or mixtures thereof; Ru, its oxides or mixtures thereof; Co, its oxides or mixtures thereof; and at least one of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu, their oxides and mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, zeolite, perovskite, silica clay, yttria and iron oxide. Fuel processors containing such water gas shift catalysts are also disclosed.
摘要翻译：公开了一种用于生产富氢合成气的方法和催化剂。根据该方法，含CO气体任选地在水存在下，优选在低于约450℃的温度下接触水煤气变换（WGS）催化剂，以产生富氢气体，例如氢气富含合成气。还公开了一种由以下物质配制的水煤气变换催化剂：a）Pt，其氧化物或其混合物; b）Ru，其氧化物或其混合物; 和c）Li，Na，K，Rb，Cs，Mg，Ca，Sr，Ba，Sc，Y，Ti，Zr，V，Mo，Mn，Fe，Co，Rh，Ir，Ge，Sn中的至少一种，Sb，La，Ce，Pr，Sm和Eu。另一种公开的催化剂配方包括Pt，其氧化物或其混合物; Ru，其氧化物或其混合物; Co，其氧化物或其混合物; 以及Li，Na，K，Rb，Cs，Mg，Ca，Sr，Ba，Sc，Y，Ti，Zr，V，Mo，Mn，Fe，Rh，Ir，Ge，Sn，Sb，La中的至少一种，Ce，Pr，Sm和Eu，它们的氧化物及其混合物。 WGS催化剂可以负载在载体上，例如氧化铝，氧化锆，二氧化钛，二氧化铈，氧化镁，镧系，氧化铌，沸石，钙钛矿，硅土，氧化钇和氧化铁中的任一种或其组合。还公开了含有这种水煤气变换催化剂的燃料加工机。

17. 发明授权

US4960921A Multiply promoted MN-SB oxide catalysts 失效
标题翻译：多重促进的MN-SB氧化物催化剂
公开(公告)号：US4960921A
公开(公告)日：1990-10-02
申请号：US478382
申请日：1990-02-12
申请人： Dev. D. Suresh , Robert K. Grasselli , Frances I. Ratka , James F. Brazdil
发明人： Dev. D. Suresh , Robert K. Grasselli , Frances I. Ratka , James F. Brazdil
IPC分类号： B01J23/34 , B01J23/889 , C07C45/34 , C07C45/35 , C07C253/26
CPC分类号： C07C253/26 , B01J23/34 , B01J23/8892 , C07C45/34 , C07C45/35 , Y02P20/52
摘要： Certain novel multiply promoted Mn-Sb oxides are superior catalysts for the ammoxidation of olefins to the corresponding unsaturated nitriles, the selective oxidation of olefins to unsaturated aldehydes and acids, and the oxydehydrogenation of olefins to diolefins.
摘要翻译：某些新型多重促进的Mn-Sb氧化物是用于将烯烃氨氧化成相应的不饱和腈的优良催化剂，将烯烃选择性氧化成不饱和醛和酸，并将烯烃氧化脱氢成二烯烃。

18. 发明授权

US4855275A Catalyst performance improvement via separate boron addition 失效
标题翻译：催化剂性能改善通过单独的硼添加
公开(公告)号：US4855275A
公开(公告)日：1989-08-08
申请号：US157428
申请日：1988-02-18
申请人： Dev D. Suresh , Michael J. Seely , James F. Brazdil , Robert K. Grasselli
发明人： Dev D. Suresh , Michael J. Seely , James F. Brazdil , Robert K. Grasselli
IPC分类号： B01J21/02 , B01J23/18 , B01J27/188 , C07C253/26
CPC分类号： B01J23/18 , B01J21/02 , B01J27/188 , C07C253/26 , Y02P20/52
摘要： A process for improving the performance of an ammoxidation catalyst comprising contacting said catalyst with a boron containing or heat decomposable boron compound to deposit boron on the catalyst.
摘要翻译：一种用于改善氨氧化催化剂性能的方法，包括使所述催化剂与含硼或可热分解的硼化合物接触以在催化剂上沉积硼。

19. 发明授权

US4816243A Preparation of vanadium III oxidic compounds, and dehydrogenation of paraffins 失效
标题翻译：钒III氧化物的制备和链烷烃脱氢
公开(公告)号：US4816243A
公开(公告)日：1989-03-28
申请号：US113957
申请日：1987-10-29
申请人： Andrew T. Guttmann , James F. Brazdil , Robert K. Grasselli
发明人： Andrew T. Guttmann , James F. Brazdil , Robert K. Grasselli
IPC分类号： B01J23/22 , B01J23/847 , C01G31/00 , C01G37/00 , C01G45/00 , C01G49/00 , C01G51/00 , C01G53/00 , C07C5/333 , C01F1/00
CPC分类号： C07C5/3332 , B01J23/22 , B01J23/8472 , C01G31/00 , C01G33/006 , C01G35/006 , C01G37/006 , C01G49/009 , C01P2002/32 , C01P2002/34 , C01P2002/82 , C01P2006/60 , C01P2006/80 , Y02P20/52 , Y10S502/524 , Y10S502/525
摘要： Disclosed is making a particular inorganic crystalline vanadium III oxidic compound from a pentavalent vanadium compound and at least one other or more metal cations, which process comprises (1) reducing a pentavalent vanadium oxidic compound to the V.sup.III state by heating at 100.degree. C. or less an aqueous medium slurry or solution of said pentavalent compound containing a reducing agent selected from hydrazine and hydrocarbylhydrazine, (2) providing in said aqueous medium, either before, during or after said reducing step, said other metal cation(s) in solution in the ratio called for by said particular crystalline compound, (3) removing the liquid aqueous medium, and (4) calcining the resulting dry solid at a temperature in the range from 400.degree. to 800.degree. C. in an inert atmosphere.Also disclosed is the vapor phase catalytic dehydrogenation of paraffins using certain spinels and perovskites as catalysts.
摘要翻译：公开了从五价钒化合物和至少一种其它或多种金属阳离子制备特定的无机结晶钒III氧化物，该方法包括（1）通过在100℃下加热将五价钒氧化化合物还原成VIII态，或少量含有选自肼和烃基肼的还原剂的所述五价化合物的水性介质浆液或溶液，（2）在所述还原步骤之前，期间或之后在所述水性介质中提供溶液中的所述其它金属阳离子所述特定结晶化合物所要求的比例，（3）除去液体水性介质，和（4）在惰性气氛中在400-800℃的温度下煅烧所得干燥固体。还公开了使用某些尖晶石和钙钛矿作为催化剂的石蜡的气相催化脱氢。

20. 发明授权

US4788317A Ammoxidation of paraffins and catalysts therefor 失效
标题翻译：石蜡及其催化剂的氨氧化
公开(公告)号：US4788317A
公开(公告)日：1988-11-29
申请号：US47949
申请日：1987-05-08
申请人： Andrew T. Guttmann , Robert K. Grasselli , James F. Brazdil, Jr.
发明人： Andrew T. Guttmann , Robert K. Grasselli , James F. Brazdil, Jr.
IPC分类号： B01J23/30 , B01J23/88 , B01J23/888 , B01J27/057 , C07C120/14
CPC分类号： B01J23/8898 , B01J23/30 , B01J23/888 , B01J27/057 , C07C253/24 , B01J2523/00 , Y02P20/52
摘要： Disclosed is a process for ammoxidation of paraffins containing 3-5 C atoms using a complex metal oxide catalyst which is essentially free of bismuth, and has the elements and the proportions which are represented by the following empirical formula:VSb.sub.m P.sub.n A.sub.a D.sub.b C.sub.c O.sub.xwhereA is one of more of W, Sn, B, Mo and As;D is one or more of Fe, Co, Ni, Cr, Mn, Cu, Pb, Zn, Se, Te and As;C is one or more of an alkali metal, Ca, Sr, Ba, T1 and where m is greater than 1 and up to 20; n is 0-10; a is 0.2-10; b is 0-5; c is 0-1; a is equal to or less than m; b is equal to or less than m; wherein x is determined by oxidation state of the other elements present, and wherein the antimony has an average valency higher than +3 and the vanadium has an average valency lower than +5, wherein A includes at least 0.2 atoms of W, crystalline Sb.sub.2 O.sub.4 is present in said catalyst, and wherein the foregoing catalyst is on a specified inorganic oxide support material.
摘要翻译：公开了使用基本上不含铋的复合金属氧化物催化剂使含有3-5个C原子的链烷烃进行氨氧化的方法，并且具有由以下经验式表示的元素和比例：VSbmPnAaDbCcOx其中A是更多的一种的W，Sn，B，Mo和As; D是Fe，Co，Ni，Cr，Mn，Cu，Pb，Zn，Se，Te和As中的一种或多种; C是碱金属，Ca，Sr，Ba，T1中的一种或多种，其中m大于1且高达20; n为0-10; a为0.2-10; b为0-5; c为0-1; a等于或小于m; b等于或小于m; 其中x由存在的其它元素的氧化态决定，其中锑的平均价高于+3，钒的平均价低于+5，其中A包含至少0.2个W原子，结晶Sb 2 O 4为存在于所述催化剂中，并且其中上述催化剂在特定的无机氧化物载体材料上。

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