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11. 发明授权

US4770692A 4-cyano(nitro)-5-oxy(thio)-pyrazole derivatives, composition containing them, and herbicidal and plant growth regulating methods of using them 失效
标题翻译： 4-氰基（硝基）-5-氧（硫代） - 吡唑衍生物，含有它们的组合物，以及使用它们的除草和植物生长调节方法
公开(公告)号：US4770692A
公开(公告)日：1988-09-13
申请号：US73555
申请日：1987-07-14
申请人： Jorg Stetter , Reinhold Gehring , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
发明人： Jorg Stetter , Reinhold Gehring , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
IPC分类号： A01N43/56 , C07D231/18 , C07D231/20 , C07D231/22 , C07D231/26 , C07D401/04 , C07D401/12 , A01N43/40
CPC分类号： C07D401/12 , C07D231/18 , C07D231/20 , C07D231/22 , C07D231/26
摘要： Novel herbicidal and plant-growth regulating pyrazoles of the formula ##STR1## in which R.sup.1 represents hydrogen, alkyl or halogenoalkyl,R.sup.2 represents nitro or cyano,R.sup.3 represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkinyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl or optionally substituted aryl,Ar represents phenyl which is substituted twice or more, or optionally substituted pyridyl, andY represents O, S, SO or SO.sub.2.Several intermediates therefor are also new.
摘要翻译：新颖的除草和植物生长调节式为“IMAGE”的吡唑，其中R 1表示氢，烷基或卤代烷基，R 2表示硝基或氰基，R 3表示任选取代的烷基，任选取代的烯基，任选取代的炔基，任选取代的环烷基，环烷基烷基，任选取代的芳烷基或任选取代的芳基，Ar表示被取代两次或更多个或任选取代的吡啶基的苯基，Y表示O，S，SO或SO 2。其中的几个也是新的。

12. 发明授权

US4740231A 1-aryl-5-alkoximinoalkylamino-pyrazoles, composition containing them, herbicidal and plant-growth regulating method of using them, and intermediates in the preparation of them 失效
标题翻译： 1-芳基-5-肟基烷基氨基 - 吡唑，含有它们的组合物，除草剂和植物生长调节方法及其制备中间体
公开(公告)号：US4740231A
公开(公告)日：1988-04-26
申请号：US866510
申请日：1986-05-22
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
IPC分类号： A01N43/56 , A01N47/02 , C07D231/38 , C07D401/04 , C07D521/00 , C07D401/14
CPC分类号： C07D231/38 , A01N43/56 , A01N47/02 , C07D231/12 , C07D233/56 , C07D249/08 , C07D401/04
摘要： 1-Aryl-5-alkoximinoalkylamino-pyrazoles of the formula ##STR1## in which R represents cyano or nitro, or represents an optionally substituted heterocyclic radical,R.sup.1 represents hydrogen or alkyl,R.sup.2 represents hydrogen or alkyl, or represents optionally substituted aryl,R.sup.3 represents hydrogen, alkyl or alkenyl, or represents in each case optionally substituted aralkyl or aryl andAr represents optionally substituted phenyl or pyridyl,are active as herbicides and plant growth regulants. Compounds of the formula ##STR2## in which R" has the same definition as R other than cyano, are also active and useful as intermediates as well.
摘要翻译：其中R表示氰基或硝基，或表示任选取代的杂环基，R 1表示氢或烷基，R 2表示氢或烷基，或表示任选取代的芳基，R 3表示任选取代的芳基，或代表任意取代的芳烷基或芳基，Ar表示任意取代的苯基或吡啶基，作为除草剂和植物生长调节剂是有活性的。 R“具有与R不同于氰基的定义相同的式”IMAGE“的化合物也是有活性的并且也用作中间体。

13. 发明授权

US4810283A Novel 1-aryl-4-nitro-pyrazole herbicides and plant growth regulators, compositions and use 失效
标题翻译：新型1-芳基-4-硝基 - 吡唑除草剂和植物生长调节剂，组合物和用途
公开(公告)号：US4810283A
公开(公告)日：1989-03-07
申请号：US925639
申请日：1986-10-30
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
IPC分类号： A01N43/56 , C07D231/38 , C07D231/40 , C07D401/04 , C07D231/16
CPC分类号： C07D231/38 , A01N43/56 , C07D401/04
摘要： Novel 1-aryl-4-nitro-pyrazoles which exhibit herbicidal and plant growth-regulating activity of the formula ##STR1## in which R.sup.1 represents in each case optionally substituted alkyl, alkenyl, alkinyl or cycloalkyl andR.sup.2 represents hydrogen, or represents in each case optionally substituted alkyl, alkenyl, alkinyl or cycloalkyl, or represents a radical ##STR2## or R.sup.1 and R.sup.2, together with the nitrogen atom to which they are bonded, represent a saturated heterocyclic radical, which can optionally contain further hetero atoms, andAr represents in each case optionally substituted phenyl or pyridyl,whereinX represents oxygen or sulphur andR.sup.3 represents hydrogen, alkyl, alkoxy, alkoxy-alkyl, alkylthio, alkylthioalkyl, alkylamino, di-alkylamino, halogenoalkyl, alkenyl or alkinyl, or represents optionally substituted cycloalkyl, or represents optionally substituted aryl, or represents optionally substituted aryloxy, or represents optionally substituted arylthio, or represents optionally substituted arylamino,but wherein R.sup.2 only represents hydrogen or a radical ##STR3## if R.sup.1 does not simultaneously represent unsubstituted alkyl or represent alkyl which is substituted by an alkoximino radical.
摘要翻译：表现出式（IMAGE）的除草和植物生长调节活性的新型1-芳基-4-硝基 - 吡唑，其中R 1在每种情况下表示任选取代的烷基，烯基，炔基或环烷基，R 2表示氢，或每个或任选取代的烷基，烯基，炔基或环烷基，或者表示基团，或者R 1和R 2与它们所键合的氮原子一起代表饱和杂环基团，其可以任选地含有其它杂原子，Ar 在每种情况下表示任选取代的苯基或吡啶基，其中X表示氧或硫，R 3表示氢，烷基，烷氧基，烷氧基 - 烷基，烷硫基，烷硫基烷基，烷基氨基，二烷基氨基，卤代烷基，烯基或炔基，或表示任选取代的环烷基或表示任选取代的芳基，或表示任选取代的芳氧基，或表示任选取代的芳硫基，或表示任选的亚芳基取代的芳基氨基，但其中R 2仅代表氢或基团，如果R 1不同时表示未取代的烷基或代表被烷基肟基取代的烷基。

14. 发明授权

US4772309A 5-acylamino-pyrazoles, composition containing them, and herbicidal and plant growth regulating method of using them 失效
标题翻译： 5-酰基氨基 - 吡唑，含有它们的组合物，以及使用它们的除草和植物生长调节方法
公开(公告)号：US4772309A
公开(公告)日：1988-09-20
申请号：US27756
申请日：1987-03-19
申请人： Jorg Stetter , Reinhold Gehring , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
发明人： Jorg Stetter , Reinhold Gehring , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
IPC分类号： C07D317/00 , A01N43/56 , A01N43/80 , A01N47/02 , C07D333/00 , C07D401/12 , C07D403/12 , C07D405/12 , C07D405/14 , C07D409/12 , C07D411/12 , C07D413/12 , C07D417/12 , C07D419/12
CPC分类号： C07D401/12 , A01N43/56 , A01N43/80 , A01N47/02 , C07D403/12 , C07D405/12 , C07D405/14 , C07D409/12 , C07D411/12 , C07D413/12 , C07D417/12
摘要： A 5-Acylamino-pyrazole derivatives of the formula ##STR1## in which R.sup.1 represents hydrogen, halogen or nitro,R.sup.2 represents hydrogen, alkyl, alkenyl, alkinyl or optionally substituted cycloalkyl,R.sup.3 represents hydrogen or alkyl,R.sup.4 represents hydrogen or alkyl,X represents oxygen or sulphur,n represents the integer 0, 1 or 2,Ar represents in each case optionally substituted phenyl or pyridyl andHet represents an optionally substituted 5- or 6- membered heterocyclic radical linked via a carbon atom,which exhibit herbicidal and plant growth regulating activity.
摘要翻译：其中R 1表示氢，卤素或硝基，R 2表示氢，烷基，烯基，炔基或任意取代的环烷基，R 3表示氢或烷基，R 4表示氢或烷基，X 表示氧或硫，n表示整数0,1或2，Ar表示各自为任意取代的苯基或吡啶基，Het表示经由碳原子连接的任选取代的5-或6-元杂环基，其表现出除草和植物生长调节活性。

15. 发明授权

US4711658A 5-perfluoroacylamino-4-nitro-1-arylpyrazole salts, plant growth regulating and herbicidal composition containing them, and plant growth regulating and herbicidal method of using them 失效
标题翻译： 5-全氟酰基氨基-4-硝基-1-芳基吡唑盐，含有它们的植物生长调节和除草组合物，以及使用它们的植物生长调节和除草方法
公开(公告)号：US4711658A
公开(公告)日：1987-12-08
申请号：US934047
申请日：1986-11-24
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
IPC分类号： A01N43/56 , C07D231/40 , C07D401/04
CPC分类号： C07D401/04 , A01N43/56 , C07D231/40
摘要： 5-perfluoroacylamino-4-nitro-1-arylpyrazole salts of the formula ##STR1## in which R represents a perfluoroalkyl radical,M.sup..sym. represents one equivalent of a metal cation, or represents an optionally substituted ammonium ion andAr represents in each case optionally substituted phenyl or pyridyl,exhibit herbicidal and plant growth-regulating activity.
摘要翻译：其中R表示全氟烷基，M（+）表示1当量的金属阳离子，或表示任选取代的铵离子，Ar表示各自的全氟酰基氨基-4-硝基-1-芳基吡唑盐任选取代的苯基或吡啶基的情况，表现出除草和植物生长调节活性。

16. 发明授权

US4685957A 1-aryl-5-iminoaminopyrazoles, compositions containing them, and herbicidal method of using them 失效
标题翻译： 1-芳基-5-亚氨基氨基吡唑，含有它们的组合物和使用它们的除草方法
公开(公告)号：US4685957A
公开(公告)日：1987-08-11
申请号：US885064
申请日：1986-07-14
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Klaus Lurssen , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Klaus Lurssen , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/40 , A01N43/56 , C07D231/16 , C07D231/38 , C07D401/04
CPC分类号： C07D231/38 , A01N43/56 , C07D231/16 , C07D401/04
摘要： Plant growth regulants and herbicides of the formula ##STR1## in which R.sup.1 represents hydrogen or alkyl,R.sup.2 represents cyano or nitro,R.sup.3 and R.sup.4 independently of one another each represent hydrogen, alkyl, alkoxyalkyl, alkylthioalkyl or halogenoalkyl or represent optionally substituted aryl, orR.sup.3 and R.sup.4 together represent a divalent alkylene radical,R.sup.5 represents hydrogen or alkyl andAr represents optionally substituted phenyl, or represented optionally substituted pyridyl.
摘要翻译：其中R 1表示氢或烷基，R 2表示氰基或硝基，R 3和R 4各自独立地表示氢，烷基，烷氧基烷基，烷硫基烷基或卤代烷基，或表示任意取代的芳基，或 R3和R4一起表示二价亚烷基，R 5表示氢或烷基，Ar表示任选取代的苯基，或表示任选取代的吡啶基。

17. 发明授权

US4808209A 5-Fluoroacylamino-4-nitro-1-aryl-pyrazoles 失效
标题翻译： 5-氟酰氨基-4-硝基-1-芳基 - 吡唑
公开(公告)号：US4808209A
公开(公告)日：1989-02-28
申请号：US934075
申请日：1986-11-24
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert F. Schmidt , Klaus Lurssen
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert F. Schmidt , Klaus Lurssen
IPC分类号： A01N43/56 , A01N47/02 , C07D231/40 , C07D401/04 , C07D231/16
CPC分类号： C07D401/04 , A01N43/56 , A01N47/02 , C07D231/40
摘要： Novel 5-fluoroacylamino-4-nitro-1-aryl-pyrazoles of the formula ##STR1## in which R represents alkyl which is substituted by fluorine andAr represents in each case optionally substituted phenyl or pyridyl,exhibit herbicidal and plant growth-regulating activity. The nitro-free corresponding intermediates are also novel.
摘要翻译：其中R表示被氟取代的烷基，Ar表示任意取代的苯基或吡啶基的新颖的5-氟酰基氨基-4-硝基-1-芳基 - 吡唑，其表示除草和植物生长调节活性。无硝基对应的中间体也是新的。

18. 发明授权

US4758673A 1-aryl-5-halopyrazoles 失效
标题翻译： 1-芳基-5- halopyrazoles
公开(公告)号：US4758673A
公开(公告)日：1988-07-19
申请号：US16599
申请日：1987-02-19
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , C07D231/14 , C07D231/16 , C07D231/22 , C07D231/32 , C07D231/38
CPC分类号： C07D231/16
摘要： 1-Aryl-pyrazoles of the general formula ##STR1## in which Hal represents halogen,R.sup.1 and R.sup.3 independently of one another represent cyano, nitro, halogen, alkyl, alkoxy, alkoxycarbonyl, halogenoalkyl, halogenoalkoxy or a radical --S(O).sub.n --R.sup.6 andR.sup.2, R.sup.4 and R.sup.5 independently of one another and independently of R.sup.1 and R.sup.3 represent the same radicals as R.sup.1 and R.sup.3, and additionally represent hydrogen,and whereinR.sup.6 represents alkyl, halogenoalkyl, amino, alkylamino or dialkylamino and n-represents the number 0, 1 or 2 are disclosed.These compounds can be nitrated to form herbicially effective 1-aryl-4-nitropyrazoles.
摘要翻译：通式其中Hal表示卤素，R 1和R 3独立地为1芳基吡唑类另一个代表氰基，硝基，卤素，烷基，烷氧基，烷氧基羰基，卤代烷基，卤代烷氧基或基团-S（O）N -R 6和R2，R4和R5彼此独立地且独立的R1和R3代表相同的基团作为R 1和R 3，并另外代表氢，且其中R 6代表烷基，卤代烷基，氨基，烷基氨基或二烷基氨基和n表示号0，1或2。这些化合物可以被硝化以形成herbicially有效的1-芳基-4-硝基吡唑。

19. 发明授权

US4746354A 4-nitro-1-phenylpyrazoles, composition containing them, and method of using them to combat unwanted vegetation 失效
标题翻译： 4-硝基-1-苯基吡唑，含有它们的组合物，以及使用它们来对付不需要的植被的方法
公开(公告)号：US4746354A
公开(公告)日：1988-05-24
申请号：US836268
申请日：1986-03-04
申请人： Reinhold Gehring , Uta Jensen-Korte , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Wolfgang Behrenz
发明人： Reinhold Gehring , Uta Jensen-Korte , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Wolfgang Behrenz
IPC分类号： A01N43/56 , C07D231/12 , C07D231/16
CPC分类号： C07D231/16
摘要： Herbicidally and insecticidally active 4-nitro-1-phenylpyrazoles of the formula ##STR1## in which R.sup.1 and R.sup.2 each independently is hydrogen, alkyl, cycloalkyl, hydroxyalkyl, alkoxyalkyl, alkylthioalkyl or halogenoalkyl,R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 each independently is hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, alkoxycarbonyl, or --(X).sub.n --R.sup.8,X is oxygen, sulphur, sulphinyl or sulphonyl,n is 0 or 1, andR.sup.8 is halogenoalkyl.
摘要翻译： R1和R2各自独立地为氢，烷基，环烷基，羟基烷基，烷氧基烷基，烷硫基烷基或卤代烷基，R3，R4，R5，R6和R7各自独立地为除草和杀虫活性的4-硝基-1-苯基吡唑，或 - （X）n -R 8，X为氧，硫，亚磺酰基或磺酰基，n为0或1，并且R 8为卤代烷基，卤素，氰基，硝基，烷基，烷氧基，烷硫基，烷基亚磺酰基，烷基磺酰基，。

20. 发明授权

US4734125A 5-acylamido-1-aryl-pyrazoles, composition containing them and herbicidal method of using them 失效
标题翻译： 5-酰基酰氨基-1-芳基吡唑，含有它们的组合物和使用它们的除草方法
公开(公告)号：US4734125A
公开(公告)日：1988-03-29
申请号：US1471
申请日：1987-01-08
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , A01N47/02 , C07D231/40 , C07D401/04 , C07D231/38
CPC分类号： C07D401/04 , A01N43/56 , A01N47/02 , C07D231/40
摘要： Herbicidally active 5-acylamido-1-aryl-pyrazoles of the formula ##STR1## in which R.sup.1 represents hydrogen, halogen or nitro,R.sup.2 represents hydrogen or alkyl,X represents oxygen or sulphur,Y represents oxygen, sulphur, a sulphinyl group or a sulphonyl group,A represents a straight-chain or branched, optionally substituted alkylene bridge,Ar.sup.1 represents in each case optionally substituted aryl or heteroaryl, andAr.sup.2 represents in each case optionally substituted phenyl or pyridyl.
摘要翻译：式“IMAGE”的除草活性5-酰基酰氨基-1-芳基 - 吡唑，其中R1表示氢，卤素或硝基，R2表示氢或烷基，X表示氧或硫，Y表示氧，硫，亚磺酰基或磺酰基，A表示直链或支链的任选取代的亚烷基桥，Ar 1在每种情况下表示任选取代的芳基或杂芳基，Ar 2表示各自为任选取代的苯基或吡啶基。

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