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11. 发明专利

FR2825709A1 Silicone composition crosslinkable by hydrosilylation of an ethylenically or acetylenically unsaturated polyorganosiloxane with a polyorganohydrogenosiloxane in the presence of a carbene complex catalyst 未知
公开(公告)号：FR2825709A1
公开(公告)日：2002-12-13
申请号：FR0107473
申请日：2001-06-07
申请人： RHODIA CHIMIE SA
发明人： GEORGE CATHERINE , BLANC MAGNARD DELPHINE , POUCHELON ALAIN , STERIN SEBASTIEN
IPC分类号： C07F15/00 , C08L83/04 , C08G77/08 , C07F7/08 , B01J31/22
摘要： Silicone composition crosslinkable by hydrosilylation of an ethylenically or acetylenically unsaturated polyorganosiloxane with a polyorganohydrogenosiloxane in the presence of a catalyst comprises a Group VIII metal carbene complex (I) as the catalyst. Silicone composition crosslinkable by hydrosilylation of an ethylenically or acetylenically unsaturated polyorganosiloxane with a polyorganohydrogenosiloxane in the presence of a catalyst and optionally a silylation inhibitor comprises a compound of formula (I) as the catalyst: M = a Group VIII metal; L3 = a carbene of formula (II): A, B = C or N; T3, T4 = H; alkyl; cycloalkyl optionally substituted by alkyl or alkoxy; aryl optionally substituted by alkyl or alkoxy; alkenyl; alkynyl; or aralkyl optionally ring-substituted by alkyl or alkoxy; or T3+T4 forms an aryl ring; T1, T2 = alkyl; perfluoroalkyl; perfluoroalkyl-substituted alkyl; cycloalkyl optionally substituted by alkyl or alkoxy; aryl optionally substituted by alkyl or alkoxy; alkenyl; alkynyl; aralkyl optionally ring-substituted by alkyl or alkoxy; -V1-V2; or -W1-W-W2; V1 = a divalent hydrocarbon group; V2 = OH, alkoxy, aryloxy or amine; W1 = a divalent hydrocarbon group; W = CR1=CR1 or ethynylene; R1 = H or alkyl; W2 = H, alkyl, alkylsilyl, alkoxysilyl or an alcohol, ketone, carboxylate ester, amide or acyloxy group; L1, L2 = ligands of formula (III.1) or (III.2) or together form a ligand of formula (IV): Z1-Z6 = H, halogen, CN or electron-withdrawing hydrocarbon groups, or two vicinal Z1-Z6 groups can form an electron-withdrawing ring; or Z1+Z2 can form an alkenyl group with at least one electron-withdrawing substituent; or pairs of Z3-Z6 can form an alkenyl group with at least one electron-withdrawing substituent; Y1, Y2 = CRaRb or SiRcRd; X = O, NRe or CRfRg; R10, R11, R13, R14 = H, alkyl, aryl or alkaryl; R9, R12, Ra, Rb, Rc, Rd = H, alkyl, acyl, aryl,alkaryl, cycloalkyl, alkylcycloalkyl, aralkyl or alkaralkyl; or two Rc groups attached to different Si atoms can form a -X-(SiRR'-X)n- chain; or two Rc groups attached to different Si atoms can form a saturated hydrocarbon group forming a 6- to 10-membered ring; or two Ra groups attached to different C atoms can form a saturated hydrocarbon group forming a 6- to 10-membered ring; n = 1-3; R, R' = groups as defined for Re (not defined); Rf, Rg = H, alkyl, acyl, aryl, alkaryl, cycloalkyl, alkylcycloalkyl, aralkyl, alkaralkyl, halogen, alkenyl, alkynyl or SiG1G2G3; G1-G3 = alkyl; alkoxy; aryl optionally substituted by alkyl or alkoxy; or aralkyl optionally ring-substituted by alkyl or alkoxy; alternatively, adjacent pairs of T1-T4 can form a hydrocarbon chain; provided that T4 is absent when A is N and T3 is absent when B is N. Independent claims are also included for the following: (1) metal complexes of formula (I) in which T3+T4 can form an aryl ring and/or T1 and T2 -V1-V2 or -W1-W-W2 groups or adjacent pairs of T1-T4 groups can form a hydrocarbon chain; (2) metal complexes of formula (I) in which L1 and L2 are ligands of formula (II), (III.1) or (III.2); (3) a catalytic composition comprising one or more metal complexes as defined in (1) or (2); (4) a process for hydrosilylating olefins or acetylenic derivatives, comprising using the above silicone composition and/or the catalytic composition of (3).

12. 发明专利

TR200003428T2 未知
公开(公告)号：TR200003428T2
公开(公告)日：2001-06-21
申请号：TR200003428
申请日：1999-03-10
申请人： RHODIA CHIMIE SA
发明人： GEORGE CATHERINE , POUCHELON ALAIN , SAC JACQUES
IPC分类号： C08K3/00 , C08K3/22 , C08K5/00

13. 发明专利

PL220596B1 Nadająca się do sieciowania na drodze hydrosililowania kompozycja silikonowa, kompleks metaliczny i zastosowanie kompleksu metalicznego 未知
公开(公告)号：PL220596B1
公开(公告)日：2015-11-30
申请号：PL36697902
申请日：2002-06-03
申请人： RHODIA CHIMIE SA
发明人： GEORGE CATHERINE , BLANC-MAGNARD DELPHINE , POUCHELON ALAIN , STERIN SÉBASTIEN
IPC分类号： C08L83/04 , B01J31/22 , C07F7/08 , C07F15/00

14. 发明专利

ES2379926T3 Composición reticulable para electrolito de batería 未知
公开(公告)号：ES2379926T3
公开(公告)日：2012-05-07
申请号：ES04742319
申请日：2004-03-23
申请人： RHODIA CHIMIE SA
发明人： GAMBUT-GAREL LUCILE , GEORGE CATHERINE , VERGELATI CARROLL , PUJOL JEAN-MARC
IPC分类号： C08L83/04 , C08G77/20 , C08G77/42 , C08K3/00 , C08L83/07 , C08L83/12 , H01B1/04 , H01B1/12 , H01M6/18 , H01M8/10 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0567 , H01M10/22 , H01M10/36
摘要： Composición polimerizable y/o reticulable mediante poliadición para electrolito de batería, que comprende: a) al menos un poliorganosiloxano (POS) (A) que presenta, por molécula, al menos dos grupos alquenilos de C2-C6 unidos al silicio y al menos un grupo directamente unido a un átomo de silicio que comprende una función de éter de polioxialquileno (Poa); b) al menos un poliorganosiloxano (POS) (B) que presenta, por molécula, al menos dos átomos de hidrógeno unidos al silicio; c) una cantidad catalíticamente eficaz de al menos un catalizador de hidrosililación (C); y d) al menos una sal electrolito (D); el POS (A) es un copolímero esencialmente lineal, estático, secuenciado o en bloques, de fórmula general media (II) siguiente: y que puede comprender eventualmente restos de fórmula RSiO3/2 (T); fórmula en la cual: - los símbolos R, iguales o diferentes, representan cada uno un grupo hidrocarbonado monovalente escogido entre un radical alquilo, lineal o ramificado, que tiene de 1 a 6 átomos de carbono, un radical cicloalquilo que tiene de 5 a 8 átomos de carbono, un radical alcoxilo y un radical fenilo; - los símbolos Y, iguales o diferentes, representan cada uno un grupo R1-Poa en el que el símbolo R1 representa un radical que comprende de 2 a 50 átomos de carbono y el símbolo Poa representa un grupo de tipo éter de polioxialquileno, preferentemente éter de polioxietileno y/o éter de polioxipropileno; - los símbolos X, iguales o diferentes, representan cada uno una función alquenilo de C2-C6 unidos al silicio, preferentemente vinilo o alilo; - los símbolos A, iguales o diferentes, representan cada uno un símbolo R, un símbolo X o un símbolo Y, y dichos símbolos tienen las mismas definiciones que las antecedentes; - m es un número entero o fraccionario superior o igual a 0; - n es un número entero o fraccionario superior o igual a 1; y - o es un número entero o fraccionario superior o igual a 2.

15. 发明专利

FR2880029B1 未知
公开(公告)号：FR2880029B1
公开(公告)日：2007-02-16
申请号：FR0413808
申请日：2004-12-23
申请人： RHODIA CHIMIE SA
发明人： GEORGE CATHERINE , BLANC MAGNARD DELPHINE , BARRANDON GEORGES
IPC分类号： C08L83/04 , A61K6/896 , C08L83/07
摘要： Use of polyorganosiloxane resin (P1) to reduce the yellowing of a silicone crosslinked elastomer composition (I) (optionally comprises a filler) by hydrosilylation of (P1) silicon-alkenyl unit (preferably silicon-vinyl) comprises a functionalized siloxyl unit, a non-functionalized siloxyl unit and a siloxyl unit (where silanol groups are present at 2.5 (preferably less than 0.5) M%, which is added to (I) prior to cross linking). Use of polyorganosiloxane resin (P1) to reduce the yellowing of a silicone crosslinked elastomer composition (I) (optionally comprises a filler) by hydrosilylation of (P1) (silicon-alkenyl unit (preferably silicon-vinyl) comprises a functionalized siloxyl unit of formula (Y1R aSiO ( 3 - a ) / 2), a non-functionalized siloxyl unit of formula (R bSiO ( 4 - b ) / 2) and a siloxyl unit of formula SiO 4 / 2 (where silanol groups are present at 2.5 (preferably less than 0.5) M%, which is added to (I) prior to cross linking). Y1 : 2-12C alkenyl (preferably vinyl); R : 1-8C alkyl (methyl, ethyl, propyl, 3,3,3-trifluoropropyl, xylyl, tolyl or phenyl); a : 0-2; and b : 1-3. An independent claim is also included for a silicone elastomer composition (I) polyorganosiloxane (having 2 alkenyl groups bonded to silicon), a polyorganosiloxane (having 3H atoms bonded to silicon), a metallic catalyst (preferably containing platinum), (P2) and optionally (a cross linking inhibitor, a coupling agent, (P1) (which is non-reactive by polyaddition), a filler and a reinforcing agent).

16. 发明专利

DE602004003569D1 未知
公开(公告)号：DE602004003569D1
公开(公告)日：2007-01-18
申请号：DE602004003569
申请日：2004-03-23
申请人： RHODIA CHIMIE SA
发明人： BARRANDON GEORGES , GEORGE CATHERINE , VERGELATI CARROLL , GIRAUD YVES
IPC分类号： C08L83/04 , C08L83/06 , H01B1/12 , H01M6/18 , H01M10/0525 , H01M10/0565 , H01M10/26 , H01M10/36
摘要： The field of the present invention relates to the field of batteries and of polymer electrolytes for batteries and more particularly to the field of lithium batteries. The invention relates to a composition which can be polymerized and/or crosslinked by dehydrocondensation for a battery electrolyte comprising: a) at least one organohydropolysiloxane (POS) (A) having, per molecule, at least 2 hydrogen atoms directly bonded to silicon atoms; b) at least one organohydroxypolysiloxane (POS) (B) having, per molecule, at least 2 —OH groups directly bonded to silicon atoms; c) an effective amount of a dehydrocondensation catalyst (C); and d) at least one electrolyte salt (D); with the condition that the POS (A) and/or the POS (B) comprise(s), per molecule, at least one siloxyl unit comprising at least one group directly bonded to a silicon atom comprising a polyoxyalkylene (Poa) ether functional group.

17. 发明专利

FR2856072B1 未知
公开(公告)号：FR2856072B1
公开(公告)日：2005-08-05
申请号：FR0307210
申请日：2003-06-16
申请人： RHODIA CHIMIE SA
发明人： JUNG BERND , DIENEMANN JOERG , GEORGE CATHERINE
IPC分类号： C08L83/04 , C08L83/07 , C09D183/07 , C09J183/04 , H01L23/29 , C08J3/24 , C08J3/075 , C09J183/07 , A61L26/00
摘要： A silicone composition crosslinkable into an adhesive gel by hydrosilylation consisting of three specified (optionally four) polyorganosiloxanes and hydrosilylation catalyst. The first polyorganosiloxane (POS) comprises terminal silyl units of type M ((R) 2(H)SiO 1 / 2, R : optionally substituted 1-6C alkyl or aryl ) and siloxyl units of type D ((R 1>) p(H) qSiO 2 / 2, R 1>R; p : 1-2; q : 0,1; p+q : 2 ). It comprises at least two SiH radicals per molecule. The second POS comprises terminal siloxyl units of type M ((X) s(R 2>) tSiO 1 / 2, R 2>R; X : 2-6C alkenyl and preferably vinyl; s : 0-1; t : 2-3; s+t : 3 ) and siloxyl units of type D ((X) u(R 3>) vZiO 2 / 2, R 3>R,u = 0,1; v : 1-3; u+v : 2 ). It comprises at least two radicals X per molecule. The third POS is monofunctional and essentially linear with less than 2% by moles (mol.%), more preferably less than 1.5 mol.% and most preferably less than 1 mol.% of siloxyl units of type T (RSiO 3 / 2). It comprises an alkenyl group X, preferably vinyl, directly bonded to silicon and comprises terminal siloxyl groups of type M ((X) w(R 4>) xSiO 1 / 2, R 4>R; w : 0-1; x : 2, 3; w+x : 3 ) and at least one siloxyl unit of type D ((X) y(R 5>) zSiO 2 / 2, R 5>R; y : 0,1; z : 1, 2; y+z : 2 ). The optional POS is not functionalized. It comprises terminal groups of type M ((R 6>) 3SiO 1 / 2, R 6>R ) and siloxyl units of type D ((R 7>) 2SiO 2 / 2, R 7>R ). The amount of the constituents is so chosen that the molar ratio (r) of hydrogen atoms bonded to silicon to alkenyl radicals X bonded to silicon is 0.1:1 to 1.5:1. Independent claims are included for a two component system comprising POS 1-3 and optionally 4 and the catalyst separately and for a crosslinked gel adhesive obtainable by crosslinking of the composition or the component system.

18. 发明专利

ES2197622T3 未知
公开(公告)号：ES2197622T3
公开(公告)日：2004-01-01
申请号：ES99907674
申请日：1999-03-10
申请人： RHODIA CHIMIE SA
发明人： GEORGE CATHERINE , POUCHELON ALAIN , SAC JACQUES
IPC分类号： C08K3/00 , C08K3/22 , C08K5/00

19. 发明专利

AU2003255638A8 Porogenic additive for silicone elastomer foam 未知
公开(公告)号：AU2003255638A8
公开(公告)日：2003-12-19
申请号：AU2003255638
申请日：2003-06-04
申请人： RHODIA CHIMIE SA
发明人： POUCHELON ALAIN , LEUCI CHRISTINE , GEORGE CATHERINE , THIRIA REMI , MARTIN NADIA
IPC分类号： C08J9/00 , C08J9/12 , C08L83/04

20. 发明专利

CZ20021597A3 Heat crosslinkable polyorganosiloxane mixtures usable particularly for manufacture of electrical wires or cables 未知
公开(公告)号：CZ20021597A3
公开(公告)日：2002-09-11
申请号：CZ20021597
申请日：2000-11-08
申请人： RHODIA CHIMIE SA
发明人： BRANLARD PAUL , GEORGE CATHERINE , LEUCI CHRISTINE
IPC分类号： C08K3/22 , C08K3/34 , C08K5/00 , C08K5/14 , H01B3/46 , H01B7/295 , C08L83/04 , C08K13/02

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