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    • 12. 发明授权
    • Rubber composition, method of formulating and blending the same and article and tires made therefrom
    • 橡胶组合物,配制和混合方法以及由其制成的制品和轮胎
    • US06242534B1
    • 2001-06-05
    • US09365226
    • 1999-07-30
    • Werner ObrechtThomas SchollPeter WendlingMichael WellVictor Monroy
    • Werner ObrechtThomas SchollPeter WendlingMichael WellVictor Monroy
    • C08F800
    • C08L7/02B60C1/0016C08L7/00C08L19/00C08L21/00Y02T10/862Y10T152/10Y10T152/10495Y10T152/10855C08L2666/08
    • A rubber mixture containing at least one rubber component, at least one filler, and conventional additives that it contain at least one first gel as a filler, which is essentially comprised of a rubber, has a particle size of 3×10−9 to 1×10−6 m, and has a swelling index in toluene of 1 to 15, and at least the surface of this gel has acid or base groups, where these groups have not been produced by means of reaction with dithiophosphoric acid, and comprises: a) at least one second gel as an additional filler, which is essentially comprised of a rubber, has a particle size of 3×10−9 to 1×10−6 m, and has a swelling index in toluene of 1 to 15, which is in a position to undergo a neutralization reaction with the acid or base groups of the first gel and/or b) contains at least one substance as an additional additive, which is capable of undergoing a neutralization reaction with the acid or base groups of at least one gel. The rubber mixture demonstrates an improved hysteresis behavior in the vulcanized state so that, with the use of this rubber mixture in tires, for example, the rolling resistance is reduced and the wet slippage behavior is improved in relation to the conventional rubber mixture. Methods of formulating such rubber mixtures are also provided.
    • 包含至少一种橡胶组分,至少一种填料和常规添加剂的橡胶混合物,其含有至少一种基本上由橡胶组成的填料的第一凝胶具有3×10 -9至1×10 -6 并且在甲苯中的溶胀指数为1至15,并且至少该凝胶的表面具有酸或碱基,其中这些基团未通过与二硫代磷酸反应产生,并且包括:a)至少 基本上由橡胶组成的附加填料的一秒钟凝胶的粒径为3×10 -9〜1×10 -6 m,甲苯中的溶胀指数为1〜15,其处于 与第一凝胶和/ orb的酸或碱基的中和反应)含有至少一种作为另外的添加剂的物质,其能够与至少一种凝胶的酸或碱基进行中和反应。橡胶混合物显示 v。改进的滞后行为 硫化状态使得通过使用轮胎中的这种橡胶混合物,例如,相对于常规的橡胶混合物,滚动阻力降低,并且湿滑滑动性能得到改善。还提供了配制这种橡胶混合物的方法。