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11. 发明授权

US4904779A Heterocycles based on piperazinopiperazine 失效
标题翻译：基于哌嗪哌嗪的杂环
公开(公告)号：US4904779A
公开(公告)日：1990-02-27
申请号：US299423
申请日：1989-01-23
申请人： Peter Neumann , Alexander Aumueller , Hubert Trauth
发明人： Peter Neumann , Alexander Aumueller , Hubert Trauth
IPC分类号： C07D487/22 , C08G63/685 , C08K5/34 , C08K5/3432 , C08K5/3435 , C08K5/3477 , C08L77/00 , C09K15/30
CPC分类号： C07D487/22 , C08K5/3477
摘要： Heterocyclic compounds of the formula (I) ##STR1## where n is an integer from 1 to 70,R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each independently of the others hydrogen, C.sub.1 -C.sub.22 -alkyl or C.sub.5 - or C.sub.6 -cycloalkyl orR.sup.1 and R.sup.2 and also R.sup.3 and R.sup.4 are each pairwise trimethylene or tetramethylene,A is a direct bond, C.sub.1 - C.sub.22 -alkylene, cycloalkylene, ##STR2## where m and o are each from 1 to 20 andR.sup.6 is C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.7 -C.sub.18 -phenylalkyl, unsubstituted or substituted phenyl or C.sub.2 -C.sub.22 -cyanoalkyl,M is a group of the formula ##STR3## which may be bonded to A not only via the nitrogen but also via the carbon, and whereR.sup.7, R.sup.8, and R.sup.10 are each independently of the others C.sub.1 -C.sub.4 -alkyl orR.sup.7 and R.sup.8 and/or R.sup.9 and R.sup.10 are each pairwise tetramethylene or pentamethylene andR.sup.11 is hydrogen or C.sub.1 -C.sub.4 -alkyl,B is a direct bond, C.sub.1 -C.sub.22 - alkylene, C.sub.7 -C.sub.16 -phenylalkylene or carbonyl-, carboxamido- or carboxylato-interrupted C.sub.3 -C.sub.22 -alkylene andR.sup.5 is hydrogen, cyano, hydroxyl, ##STR4## R.sup.12 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.7 -C.sub.16 -phenylalkyl, unsubstituted or substituted phenyl or 5- or 6- membered heterocyclyl or, when n is 1, M--B--R.sup.5 is a group of the formula ##STR5## R.sup.13 is C.sub.1 -C.sub.4 -alkyl, R.sup.14 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy andR.sup.15 is C.sub.1 -C.sub.12 -alkyl, have very good stabilizing properties, no self-color, good compatibility with polymers, a low vapor pressure and stability to thermal decomposition.
摘要翻译：式（I）的杂环化合物其中n为1至70的整数，R 1，R 2，R 3和R 4各自独立地为氢，C 1 -C 22 - 烷基或C 5 - 或C 6 - 环烷基或R 1和R 2，并且R 3和R 4各自为一对三亚甲基或四亚甲基，A为直接键，C 1 -C 22 - 亚烷基，亚环烷基，其中m和o各自为1〜20， R 6是C 1 -C 22 - 烷基，C 5 -C 12 - 环烷基，C 7 -C 18 - 苯基烷基，未取代或取代的苯基或C 2 -C 22 - 氰基烷基，M是可以与A键合的基团，氮，但也经由碳，并且其中R 7，R 8和R 10各自独立地为C 1 -C 4 - 烷基或者R 7和R 8和/或R 9和R 10各自为成对四亚甲基或五亚甲基，R 11为氢或C 1 -C 4 - C 4 - 烷基，B是直接键，C 1 -C 22 - 亚烷基，C 7 -C 16 - 苯基亚烷基或羰基 - ，甲酰胺基或羧基 - 中断的C 3 -C 22亚烷基，R 5是氢，氰基，羟基， > + TR R12是氢，C1-C22-烷基，C5-C12-环烷基，C7-C16-苯基烷基，未取代或取代的苯基或5-或6-元杂环基，或当n是1时，MB-R5是 R 13是C + HD 1 -C 4烷基，R 14是氢，C 1 -C 4烷基或C 1 -C 4烷氧基，R 15是C 1 -C 12烷基，具有非常好的稳定性，无自色，与聚合物相容性好，蒸气压低，热分解稳定。

12. 发明授权

US4835273A Glycoluril derivatives 失效
标题翻译：乙二醇衍生物
公开(公告)号：US4835273A
公开(公告)日：1989-05-30
申请号：US133625
申请日：1987-12-16
申请人： Alexander Aumueller , Peter Neumann , Hubert Trauth
发明人： Alexander Aumueller , Peter Neumann , Hubert Trauth
IPC分类号： C07D487/22 , C07D519/00 , C08G69/26 , C08K5/34 , C08K5/3477 , C09D7/12 , C09K15/30
CPC分类号： C07D487/22 , C07D519/00 , C08K5/3477
摘要： Compounds useful for stabilizing organic material have the general formula (I) ##STR1## where the substituents are as defined in claim 1.
摘要翻译：可用于稳定有机材料的化合物具有通式（I）其中取代基如权利要求1中所定义。

13. 发明授权

US4820757A Polymers photostabilized by novel imidazole-2-carboxanilides 失效
标题翻译：聚合物通过新的咪唑-2-羧酰苯胺光稳定化
公开(公告)号：US4820757A
公开(公告)日：1989-04-11
申请号：US167726
申请日：1988-03-14
申请人： Peter Spang , Peter Neumann , Gerhard Wagenblast , Hubert Trauth
发明人： Peter Spang , Peter Neumann , Gerhard Wagenblast , Hubert Trauth
IPC分类号： C07D233/90 , C07D235/20 , C07D235/24 , C08G18/30 , C08G18/38 , C08K5/34 , C08K5/3442 , C08K5/3445 , C08K5/3447 , C08L75/00 , C08L75/04 , C08L101/00
CPC分类号： C07D235/24 , C08K5/3445 , C08K5/3447
摘要： Photostabilized polymers, including polyurethanes and plastics coatings, contain as photostabilizer one or more compounds of the formula ##STR1## or a novel imidazole-2-carboxanilide of the formula ##STR2##
摘要翻译：包含聚氨酯和塑料涂料的光稳定化聚合物包含作为光稳定剂的一种或多种式（I）化合物或式（III）的新型咪唑-2-甲酰苯胺，

14. 发明授权

US5008312A 2,6-polyalkylpiperidine-substituted bislactams and their use for the stabilization of organic material, in particular of plastics, and materials stabilized therewith 失效
标题翻译： 2,6-二烷基哌啶取代的双内酰胺及其用于稳定有机材料，特别是塑料的材料和稳定化材料
公开(公告)号：US5008312A
公开(公告)日：1991-04-16
申请号：US390216
申请日：1989-08-07
申请人： Alexander Aumueller , Peter Neumann , Hubert Trauth
发明人： Alexander Aumueller , Peter Neumann , Hubert Trauth
IPC分类号： C07D487/04 , C08K5/34 , C08K5/3412 , C08K5/3432 , C08K5/3435 , C08L23/02 , C09D7/12 , C09K15/30
CPC分类号： C07D487/04 , C08K5/3435
摘要： Bislactams of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently of one another are each C.sub.1 -C.sub.4 -alkyl, or R.sup.1 and R.sup.2 and/or R.sup.3 and R.sup.4 form a tetra- or pentamethylene radical, and R.sup.5 is hydrogen, carbonyl-C.sub.1 -C.sub.8 -alkyl, benzoyl, C.sub.1 -C.sub.8 -alkyl, C.sub.7 -C.sub.10 -phenylalkyl, the phenyl nucleus being unsubstituted or substituted by one or two C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkyoxy, fluorine, chlorine or bromine radicals, or is C.sub.1 -C.sub.3 -cyanoalkyl, C.sub.2 -C.sub.4 -hydroxyalkyl or C.sub.2 - or C.sub.3 -aminoalkyl, and the acid addition salts and hydrates of these compounds.The compounds (I) are stabilizers for organic materials.
摘要翻译：其中R 1，R 2，R 3和R 4彼此独立地为通式I（I）的双内酰胺各自为C 1 -C 4 - 烷基，或者R 1和R 2和/或R 3和R 4形成四 - 或五亚甲基，并且R 5是氢，羰基-C 1 -C 8 - 烷基，苯甲酰基，C 1 -C 8 - 烷基，C 7 -C 10 - 苯基烷基，所述苯基核是未取代的或被一个或两个C 1 -C 4烷基，C 1 -C 4烷氧基，氟，氯或溴基，或者是C 1 -C 3 - 氰基烷基，C 2 -C 4羟基烷基或C 2 - 或C 3 - 氨基烷基，以及这些化合物的酸加成盐和水合物。化合物（I）是有机材料的稳定剂。

15. 发明授权

US4981969A Polyalkylpiperidine-substituted tetrahydropyridones and use thereof 失效
标题翻译：聚烷基哌啶取代的四氢吡啶酮及其用途
公开(公告)号：US4981969A
公开(公告)日：1991-01-01
申请号：US443478
申请日：1989-11-30
申请人： Alexander Aumueller , Peter Neumann , Hubert Trauth
发明人： Alexander Aumueller , Peter Neumann , Hubert Trauth
IPC分类号： C07D211/78 , C07D211/90 , C07D401/14 , C08K5/3412 , C08K5/3435 , C09D7/12
CPC分类号： C07D401/14 , C07D211/90 , C08K5/3435
摘要： Tetrahydropyridones which in one of their tautomeric forms conform to the general formula (I) ##STR1## where R.sup.1 and R.sup.2 are each independently of the other C.sub.1 -C.sub.12 -alkyl, which may be oxygen-interrupted, C.sub.5 -C.sub.6 -cycloalkyl or C.sub.7 -C.sub.12 -phenylalkyl where the phenyl is unsubstituted or monosubstituted, disubstituted or trisubstitued by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, fluorine, chlorine or bromine, or ##STR2## is a from 5- to 12-membered cycloaliphatic ring which may be monosubstituted, disubstituted, trisubstituted or tetrasubstituted by C.sub.1 -C.sub.4 -alkyl, andR.sup.3 is hydrogen, substituted or unsubstituted alkyl or phenyl alkyl or alkanoyl, are effective stabilizers for plastics and coatings.
摘要翻译：以其互变异构形式之一的四氢吡啶酮符合通式（I）其中R 1和R 2各自独立地为可被氧中断的C 1 -C 12 - 烷基，C 5 -C 6 - 环烷基或C 7 -C 12 - 苯基烷基，其中苯基是未取代的或被C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，氟，氯或溴单取代，二取代或三取代，或者是＆lt; IMAGE＆gt;是5至12元环脂族环可以被C1-C4-烷基单取代，三取代或四取代，R3是氢，取代或未取代的烷基或苯基烷基或烷酰基，是塑料和涂料的有效稳定剂。

16. 发明授权

US4980476A Polyalkylpiperidine-substituted lactams and use thereof as stabilizers for plastics 失效
标题翻译：聚烷基哌啶取代的内酰胺及其作为塑料稳定剂的用途
公开(公告)号：US4980476A
公开(公告)日：1990-12-25
申请号：US438795
申请日：1989-11-20
申请人： Alexander Aumueller , Peter Neumann , Hubert Trauth
发明人： Alexander Aumueller , Peter Neumann , Hubert Trauth
IPC分类号： C07D401/14 , C08K5/3432 , C08K5/3435 , C09K15/22
CPC分类号： C07D401/14 , C08K5/3435
摘要： Compound of the formula (I) ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each alkyl or R.sup.1 and R.sup.2 or R.sup.3 and R.sup.4 are together tetra- or pentamethylene and R.sup.5 is hydrogen, alkanoyl, alkyl, cyanoalkyl, hydroxyalkyl, aminoalkyl or phenylalkyl, in which the phenyl nucleus may be substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or halogen, and the acid addition salts and hydrates of these compounds are useful stabilizers for organic materials, in particular plastics.
摘要翻译：式（I）的化合物其中R 1，R 2，R 3和R 4各自为烷基或R 1，R 2或R 3和R 4一起为四或五亚甲基，R 5为氢，烷酰基，烷基，氰基烷基，羟基烷基，氨基烷基或苯基烷基，其中苯基核可以被C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基或卤素取代，并且这些化合物的酸加成盐和水合物是有机材料，特别是塑料的有用的稳定剂。

17. 发明授权

US4976889A 4-formylaminopiperidine derivatives, their use as stabilizers and organic material stabilized with the said derivatives 失效
标题翻译： 4-甲酰氨基哌啶衍生物，它们用作稳定剂和用所述衍生物稳定的有机物质
公开(公告)号：US4976889A
公开(公告)日：1990-12-11
申请号：US270806
申请日：1988-11-14
申请人： Alexander Aumueller , Peter Neumann , Hubert Trauth
发明人： Alexander Aumueller , Peter Neumann , Hubert Trauth
IPC分类号： C07D211/58 , C07D221/20 , C07D401/12 , C07D405/12 , C07D409/12 , C08K5/3435
CPC分类号： C07D401/12 , C07D211/58 , C07D405/12
摘要： 4-Formylaminopiperidine derivatives of the formula (I) ##STR1## where n is 1 or 2, R.sup.1 to R.sup.4 are each alkyl or R.sup.1 and R.sup.2 or R.sup.3 and R.sup.4 are tetra- or pentamethylene, R.sup.5 is hydrogen or alkyl, R.sup.6 is hydrogen, unsubstituted or substituted alkyl, alkenyl, aralkyl or acyl, and, when n is 1, Y is hydrogen, unsubstituted or substituted alkyl, alkenyl, cycloalkyl, bicycloalkyl, aralkyl, aryl, alkyl containing heterocyclic radicals, or ##STR2## or, when n is 2, Y is alkylene, cycloalkylene, aralkylene or arylene or is alkylene which is interrupted by oxygen, nitrogen, sulfur or a 5-membered or 6-membered heterocyclic structure, and their acid addition salts have very good stabilizing properties in plastics.
摘要翻译：式（I）的4-甲酰氨基哌啶衍生物其中n为1或2，R 1至R 4各自为烷基或R 1，R 2或R 3和R 4为四或五亚甲基，R 5为氢或烷基，R 6为当n为1时，Y为氢，未取代或取代的烷基，链烯基，环烷基，双环烷基，芳烷基，芳基，含烷基的杂环基，或当n为2时，Y为亚烷基，亚环烷基，亚芳基或亚芳基，或为被氧，氮，硫或5元或6元杂环结构中断的亚烷基，其酸加成盐具有非常好的稳定性塑料。

18. 发明授权

US4925888A Mixture for stabilizing polyurethanes 失效
标题翻译：用于稳定聚氨酯的混合物
公开(公告)号：US4925888A
公开(公告)日：1990-05-15
申请号：US260612
申请日：1988-10-21
申请人： Alexander Aumueller , Peter Neumann , Peter Spang , Guenter Matzke , Hubert Trauth
发明人： Alexander Aumueller , Peter Neumann , Peter Spang , Guenter Matzke , Hubert Trauth
IPC分类号： C08G18/38 , C08G18/30 , C08G65/32 , C08K5/1545 , C08K5/34 , C08K5/3435 , C08K5/3475 , C08L71/02 , C08L75/00 , C08L75/04
CPC分类号： C08K5/3435 , C08K5/3475
摘要： A mixture for stabilizing polyurethanes contains(a) an amine of the formula I ##STR1## (b) a mixture of the benzotriazoles II and III ##STR2## in which n is chosen so that the mean molecular weight of the mixture is greater than 600, and(c) .alpha.-tocopherol, if necessary mixed with tris-(nonylphenyl) phosphite, and polyurethanes contain from 0.005 to 5.0% by weight, based on the material to be stabilized, of this mixture.
摘要翻译：用于稳定聚氨酯的混合物包含（a）式I的胺（I）（b）苯并三唑II和III的混合物（II）图像（III）图像，其中n 被选择使得混合物的平均分子量大于600，和（c）如果需要，与三（壬基苯基）亚磷酸酯混合的α-生育酚和基于该材料的聚氨酯含有0.005-5.0重量％要稳定的混合物。

19. 发明授权

US5017702A 2,6-polyalkyl-4-piperidylamides, use thereof as stabilizers, in particular for plastics, and organic material containing same 失效
标题翻译： 2,6-聚烷基-4-哌啶酰胺，其用作稳定剂，特别是塑料的稳定剂，以及含有它们的有机材料
公开(公告)号：US5017702A
公开(公告)日：1991-05-21
申请号：US375874
申请日：1989-07-06
申请人： Alexander Aumueller , Peter Neumann , Hubert Trauth
发明人： Alexander Aumueller , Peter Neumann , Hubert Trauth
IPC分类号： C07D211/58 , C07D401/12 , C07D405/12 , C08K5/34 , C08K5/3412 , C08K5/3435 , C08K5/43 , C08L23/02 , C08L75/00 , C08L75/04 , C08L77/00 , C09D7/12 , C09K3/00
CPC分类号： C07D401/12 , C07D211/58 , C07D405/12 , C08K5/3435
摘要： Useful stabilizers for organic material, in particular plastics and paints, and metal ion deactivators are amides of the formula ##STR1## where R.sup.1 and R.sup.2 are singly methyl or together tetramethylene or pentamethylene, R.sup.3 is hydrogen, alkyl, alkoxycarbonyl, alkanoyl, benzyl, hydroxyethyl, cyanomethyl or aminomethyl, n is 1, 2 or 3 and--when n is 1--R.sup.4 is hydrogen and R.sup.5 is --CO--R.sup.6 is H, alkyl, cycloalkyl, aralkyl, phenoxyalkyl, aryl, a 5- or 6-membered heterocycle, alkoxy, aryloxy, cycloalkyloxy, phenylalkoxy, carbamoyl or --SO.sub.2 --R.sup.8 where R.sup.8 is alkyl or phenyl or ##STR2## is a phthalimide group or--when n is 2--R.sup.4 is H and R.sup.5 is --CO--Z--CO-- where Z is a chemical bond, C.sub.1 -C.sub.8 -alkylene, oxaalkylene, phenylene, cyclohexylene, biphenylene, biphenylene oxide, dioxyphenylene, diaminophenylene, diaminocyclohexylene, 1-.OMEGA.-diiminoalkylene or a 2-valent heterocycle or ##STR3## is a pyromellimide group or--when n is 3--R.sup.4 is H and R.sup.5 is ##STR4## where R.sup.10 is a trivalent alkyl or 3-valent aryl, or acid addition salts and hydrates thereof.
摘要翻译：有机材料，特别是塑料和涂料以及金属离子失活剂的有用的稳定剂是式（I）的酰胺，其中R 1和R 2是单甲基或四亚甲基或五亚甲基，R 3是氢，烷基，烷氧基羰基，烷酰基，苄基，羟乙基，氰甲基或氨基甲基，n为1,2或3，当n为1-R4为氢且R5为-CO-R6时，为H，烷基，环烷基，芳烷基，苯氧基烷基，芳基，5-或6 芳基氧基，环烷氧基，苯基烷氧基，氨基甲酰基或-SO2-R8，其中R8是烷基或苯基，或者是“邻苯二甲酰亚胺基”，或者当n是2-R 4是H且R 5是-CO-Z- CO-，其中Z是化学键，C1-C8-亚烷基，氧杂亚烷基，亚苯基，亚环己基，亚联苯基，亚联苯氧基，二氧亚苯基，二氨基亚苯基，二氨基环己烯，1-OMEGA-二亚氨基亚烷基或2价杂环或基团或 - 当n是3-R 4是H且R 5是时，其中R 10是三价烷基或3价芳基或酸性其盐及其水合物。

20. 发明授权

US5008397A N-substituted benzimidazole-2-carboxanilides 失效
标题翻译： N-取代的苯并咪唑-2-甲酰苯胺
公开(公告)号：US5008397A
公开(公告)日：1991-04-16
申请号：US393962
申请日：1989-08-15
申请人： Peter Spang , Peter Neumann , Gerhard Wagenblast , Hubert Trauth
发明人： Peter Spang , Peter Neumann , Gerhard Wagenblast , Hubert Trauth
IPC分类号： C07D235/20 , C07D235/24 , C08K5/34 , C08K5/3442 , C08K5/3447 , C08L33/04 , C08L55/00 , C08L55/02 , C08L67/00 , C08L67/02 , C08L75/00 , C08L75/04 , C09D7/12
CPC分类号： C07D235/24 , C07D235/20 , C08K5/3447
摘要： Compounds of the general formula (I) ##STR1## where R.sup.1 and R.sup.2 are each H, Cl, alkyl, alkoxy, substituted or unsubstituted phenyl or phenylalkyl, R.sup.3 and R.sup.4 are each H, alkyl, oxaalkyl, alkoxy, oxaalkoxy, substituted or unsubstituted phenyl, phenylalkyl, phenoxy, phenylalkoxy, alkylcarbonylamino, benzoylamino, alkanoyloxy or benzoyloxy, n is 1 or 2 and R.sup.5 is -- when n is 1-alkyl, hydroxyalkyl, cycloalkyl, alkenyl, oxaalkyl, phenylalkyl or ##STR2## or -- when n is 2-akylene, cycloalkylene, alkenylene, oxaalkylene or ##STR3## where m is from 2 to 4, R.sup.6 is alkyl, alkenyl, cycloalkyl, phenylalkyl, substituted or unsubstituted phenyl or naphthyl, and R.sup.7 is alkylene, alkenylene, cycloalkylene, substituted or unsubstituted phenylene, naphthylene, diphenylene, ##STR4## are effective light stabilizers for organic materials, in particular for polymers.
摘要翻译：通式（I）的化合物其中R 1和R 2各自为H，Cl，烷基，烷氧基，取代或未取代的苯基或苯基烷基，R 3和R 4各自为H，烷基，氧杂烷基，烷氧基，氧杂烷氧基，取代或未取代的苯基，苯基烷基，苯氧基，苯基烷氧基，烷基羰基氨基，苯甲酰氨基，烷酰氧基或苯甲酰氧基，n为1或2，R5为 - 当n为1-烷基，羟基烷基，环烷基，烯基，氧杂烷基，苯基烷基或或者 - 当n是2-亚烷基，亚环烷基，亚烯基，氧杂亚烷基或其中m为2至4时，R 6为烷基，烯基，环烷基，苯基烷基，取代或未取代的苯基或萘基，R 7是亚烷基，亚烯基，亚环烷基，取代或未取代的亚苯基，亚萘基，亚苯基，有机材料的光稳定剂，特别是聚合物。

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