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    • 17. 发明授权
    • Crosslinked cellulose products and method for their preparation
    • 交联纤维素产品及其制备方法
    • US5225047A
    • 1993-07-06
    • US395208
    • 1989-08-17
    • Peter A. GraefFrank R. Hunter
    • Peter A. GraefFrank R. Hunter
    • A61F13/15D21H11/20D21H17/06D21H17/07D21H17/09D21H17/10D21H17/15D21H21/06D21H21/14D21H21/24D21H23/14D21H23/18D21H23/28
    • D21H21/06D21H11/20D21H17/06D21H17/07D21H17/09D21H17/10D21H17/15D21H21/14D21H21/24D21H23/14D21H23/18D21H23/28A61F2013/530007A61F2013/530474
    • The invention is a method of making a wet formed, sheeted, readily reslurriable sheeted crosslinked cellulose and the products made by the method. Crosslinked wood pulp fibers tend to be quite brittle. If crosslinked while in sheeted form, the sheets cannot be readily defibered, either in a wet or dry state, without serious fiber degradation. The sheet products of the present invention can be easily redispersed or repulped in water without significant fiber breakage. The present products are made by including within the sheet, while still in wet form, a debonding or softening agent which is preferably added before the latent crosslinking reactant. Most preferably the debonder is added prior to the headbox of a paper machine and the crosslinking reactant is applied near the end of the forming wire or at the press section. The treated sheet is dried conventionally. Crosslinking may occur entirely during drying or during a period of additional heating, usually at a temperature in excess of 100.degree. C. for a short period of time. Conventional debonding agents and crosslinking reactants are suitable. The softening agent apparently reduces or prevents adhesive bonding between adjacent fibers caused by polymer formation external to the fiber under reaction conditions.
    • 本发明是一种制成湿成型,片状,易于再生的片状交联纤维素和通过该方法制备的产品的方法。 交联的木浆纤维往往是相当脆的。 如果以片状形式交联,则在湿或干的状态下,片材不能容易地脱纤维,而不会严重的纤维降解。 本发明的片状产品可以容易地再分散或重新分配在水中而不会明显的纤维断裂。 本产品通过在片状物中包含湿态形式,优选在潜在交联反应剂之前加入的脱粘剂或软化剂制成。 最优选地,脱纸器在造纸机的流浆箱之前添加,并且交联反应物被施加在成形丝的端部附近或在压榨部分处。 经处理的片材是常规干燥的。 交联可能在干燥期间或在额外加热期间完全发生,通常在超过100℃的温度下短时间内完成。 常规脱粘剂和交联反应物是合适的。 在反应条件下,柔软剂明显降低或防止由纤维外部的聚合物形成引起的相邻纤维之间的粘结。
    • 20. 发明授权
    • Hydrophilic cellulose product and method of its manufacture
    • 亲水纤维素产品及其制造方法
    • US4853086A
    • 1989-08-01
    • US941461
    • 1986-12-15
    • Peter A. Graef
    • Peter A. Graef
    • A61L15/28D21C9/00D21H17/06D21H23/28
    • D21H23/28A61L15/28D21C9/005D21H17/06
    • The present invention is a method of making a resilient hydrophilic cellulosic pulp particularly suitable for conversion into an absorbent fluff for products such as disposable diapers. The process involves treating a wet or partially dried cellulosic fiber web with an aqueous solution of a glycol and dialdehyde. Glyoxal and propylene glycol are preferred materials. These are desirable sprayed on a wet or only partially dried sheet at some convenient location on a conventional paper machine. This location is not critical, but a point about midway through the press section has given excellent results. The treated sheet is then dried conventionally. There is no need for the use of any catalysts or for a prolonged curing step at elevated temperatures. The products of the invention are characterized by a much increased absorbency rate and by a somewhat higher water holding capacity. The sheets also require less power for milling into a fibrous fluff. Knots or fiber clumps are reduced and there is no significant increase in fiber fines due to embrittlement of the treated pulp product. The invention further includes the products made using the present method.
    • 本发明是一种制备弹性亲水性纤维素纸浆的方法,特别适用于将产品如一次性尿布转化成吸收性绒毛。 该方法包括用二醇和二醛的水溶液处理湿的或部分干燥的纤维素纤维网。 乙二醛和丙二醇是优选的材料。 这些需要在常规造纸机上的一些方便的位置喷涂在湿的或仅部分干燥的片材上。 这个位置并不重要,但通过新闻部分的中间点已经取得了很好的成果。 然后将经处理的片材经常干燥。 在升高的温度下不需要使用任何催化剂或延长固化步骤。 本发明的产品的特征在于吸收速率大大提高,保水能力更高。 片材也需要更少的功率来铣削成纤维绒毛。 结节或纤维团被减少,并且由于处理过的纸浆产品的脆化,纤维细粉没有显着增加。 本发明还包括使用本方法制造的产品。