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11. 发明申请

US20090062560A1 Electroluminescent Metal Complexes With Triazoles 有权
标题翻译：电子发光金属配合物与三唑
公开(公告)号：US20090062560A1
公开(公告)日：2009-03-05
申请号：US12086646
申请日：2006-12-18
申请人： Roger Pretot , Roman Kolly , Thomas Schafer , Paul Adriaan Van Der Schaaf
发明人： Roger Pretot , Roman Kolly , Thomas Schafer , Paul Adriaan Van Der Schaaf
IPC分类号： C07F17/02
CPC分类号： C09K11/06 , C07F15/0033 , C09K2211/1059 , C09K2211/185 , H01L51/0085 , H01L51/5016 , H05B33/14
摘要： Disclosed are electroluminescent metal complexes with triazoles of the formula (I), where n1 is an integer of 1 to 3, m1 and m2 each are an integer 0, 1 or 2, M1 is a metal with an atomic weight of greater than 40, L1 is a monodentate ligand or a bidentate ligand, L2 is a monodentate ligand, Q2 stands for an organic bridging group completing, together with the bonding carbon atoms of the triazole ring, an annellated, carbocyclic or heterocyclic, non-aromatic ring, which optionally may be substituted, Q3 represents a group of forming a condensed aromatic, or heteroaromatic ring, which can optionally be substituted, as well as new intermediates for the preparation of these complexes, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays, and as catalysts.
摘要翻译：公开了具有式（I）的三唑的电致发光金属络合物，其中n1为1〜3的整数，m1和m2各自为整数0,1或2，M1为原子量大于40的金属， L1是单齿配体或二齿配体，L2是单齿配体，Q2表示完全有机桥基，连同三唑环的键合碳原子，环状的，碳环或杂环的非芳香环，其任选地可以被取代，Q3表示形成稠合芳族或可以任意被取代的杂芳环的基团，以及用于制备这些络合物的新中间体，包含金属络合物的电子器件及其在电子器件中的用途，特别是有机发光二极管（OLED）作为氧敏感指标，作为生物测定中的磷光指示剂，以及作为催化剂。

12. 发明授权

US07928242B2 Electroluminescent metal complexes with triazoles 有权
标题翻译：电致发光金属络合物与三唑
公开(公告)号：US07928242B2
公开(公告)日：2011-04-19
申请号：US12086646
申请日：2006-12-18
申请人： Roger Prétôt , Roman Kolly , Thomas Schäfer , Paul Adriaan Van Der Schaaf
发明人： Roger Prétôt , Roman Kolly , Thomas Schäfer , Paul Adriaan Van Der Schaaf
IPC分类号： C07F15/00 , C07F3/00 , B32B9/00 , H01J1/62
CPC分类号： C09K11/06 , C07F15/0033 , C09K2211/1059 , C09K2211/185 , H01L51/0085 , H01L51/5016 , H05B33/14
摘要： Disclosed are electroluminescent metal complexes with triazoles of the formula (I), where n1 is an integer of 1 to 3, m1 and m2 each are an integer 0, 1 or 2, M1 is a metal with an atomic weight of greater than 40, L1 is a monodentate ligand or a bidentate ligand, L2 is a monodentate ligand, Q2 stands for an organic bridging group completing, together with the bonding carbon atoms of the triazole ring, an annellated, carbocyclic or heterocyclic, non-aromatic ring, which optionally may be substituted, Q3 represents a group of forming a condensed aromatic, or heteroaromatic ring, which can optionally be substituted, as well as new intermediates for the preparation of these complexes, electronic devices comprising the metal complexes and their use in electronic devices, especially organic light emitting diodes (OLEDs), as oxygen sensitive indicators, as phosphorescent indicators in bioassays, and as catalysts.
摘要翻译：公开了具有式（I）的三唑的电致发光金属络合物，其中n1为1〜3的整数，m1和m2各自为整数0,1或2，M1为原子量大于40的金属， L1是单齿配体或二齿配体，L2是单齿配体，Q2表示完全有机桥基，连同三唑环的键合碳原子，环状的，碳环或杂环的非芳香环，其任选地可以被取代，Q3表示形成稠合芳族或可以任意被取代的杂芳环的基团，以及用于制备这些络合物的新中间体，包含金属络合物的电子器件及其在电子器件中的用途，特别是有机发光二极管（OLED）作为氧敏感指标，作为生物测定中的磷光指示剂，以及作为催化剂。

13. 发明申请

US20100003520A1 POROUS INORGANIC MATERIALS OF SILCON AND OXYGEN 失效
标题翻译： SILCON和OXYGEN的多孔无机材料
公开(公告)号：US20100003520A1
公开(公告)日：2010-01-07
申请号：US12536522
申请日：2009-08-06
申请人： PATRICE BUJARD , Andreas Mühlebach , Paul Adriaan Van Der Schaaf
发明人： PATRICE BUJARD , Andreas Mühlebach , Paul Adriaan Van Der Schaaf
IPC分类号： B32B3/26
CPC分类号： C09C1/0015 , C01P2006/12 , C01P2006/16 , C09C1/0018 , C09C2200/102 , C09C2200/1037 , C09C2200/502 , C09C2200/505 , C09C2220/20 , C23C14/0005 , C23C14/10 , C23C14/24 , Y10T428/2982 , Y10T428/2993
摘要： The present invention relates to a process for the production of porous inorganic materials or a matrix material containing nanoparticles with high uniformity of thickness and/or high effective surface area and to the materials obtainable by this process. By the above-mentioned process materials with a defined thickness in the region of ±10%, preferably ±5% of the average thickness are available.
摘要翻译：本发明涉及一种生产多孔无机材料的方法或含有高均匀度厚度和/或高有效表面积的纳米颗粒的基体材料以及可通过该方法获得的材料。通过上述方法，具有在平均厚度的±10％，优选±5％的范围内的限定厚度的材料是可用的。

14. 发明授权

US08177901B2 Porous inorganic materials of silcon and oxygen 失效
标题翻译：硅氧烷和氧气的多孔无机材料
公开(公告)号：US08177901B2
公开(公告)日：2012-05-15
申请号：US12536522
申请日：2009-08-06
申请人： Patrice Bujard , Andreas Mühlebach , Paul Adriaan Van Der Schaaf
发明人： Patrice Bujard , Andreas Mühlebach , Paul Adriaan Van Der Schaaf
IPC分类号： C04B14/00 , C04B14/04 , C23C16/00 , B01F3/12 , C01B33/14
CPC分类号： C09C1/0015 , C01P2006/12 , C01P2006/16 , C09C1/0018 , C09C2200/102 , C09C2200/1037 , C09C2200/502 , C09C2200/505 , C09C2220/20 , C23C14/0005 , C23C14/10 , C23C14/24 , Y10T428/2982 , Y10T428/2993
摘要： The present invention relates to a process for the production of porous inorganic materials or a matrix material containing nanoparticles with high uniformity of thickness and/or high effective surface area and to the materials obtainable by this process. By the above-mentioned process materials with a defined thickness in the region of ±10%, preferably ±5% of the average thickness are available.
摘要翻译：本发明涉及一种生产多孔无机材料的方法或含有高均匀度厚度和/或高有效表面积的纳米颗粒的基体材料以及可通过该方法获得的材料。通过上述方法，具有在平均厚度的±10％，优选±5％的范围内的限定厚度的材料是可用的。

15. 发明授权

US07594962B2 Process for the production of porous inorganic materials or a matrix material containing nanoparticles 失效
标题翻译：用于生产多孔无机材料或含有纳米颗粒的基体材料的方法
公开(公告)号：US07594962B2
公开(公告)日：2009-09-29
申请号：US10542035
申请日：2004-01-12
申请人： Patrice Bujard , Andreas Mühlebach , Paul Adriaan Van Der Schaaf
发明人： Patrice Bujard , Andreas Mühlebach , Paul Adriaan Van Der Schaaf
IPC分类号： C04B14/04 , C09C1/62 , C09C1/36
CPC分类号： C09C1/0015 , C01P2006/12 , C01P2006/16 , C09C1/0018 , C09C2200/102 , C09C2200/1037 , C09C2200/502 , C09C2200/505 , C09C2220/20 , C23C14/0005 , C23C14/10 , C23C14/24 , Y10T428/2982 , Y10T428/2993
摘要： The present invention relates to a process for the production of porous inorganic materials or a matrix material containing nanoparticles with high uniformity of thickness and/or high effective surface area and to the materials obtainable by this process. By the abovementioned process materials with a defined thickness in the region of ±10%, preferably ±5%, of the average thickness are available.
摘要翻译：本发明涉及一种生产多孔无机材料的方法或含有高均匀度厚度和/或高有效表面积的纳米颗粒的基体材料以及可通过该方法获得的材料。通过上述方法可以获得在平均厚度的±10％，优选±5％范围内具有规定厚度的材料。

16. 发明授权

US07402675B2 Process for the synthesis of amine ethers from secondary amino oxides 有权
公开(公告)号：US07402675B2
公开(公告)日：2008-07-22
申请号：US10919776
申请日：2004-08-17
申请人： Andreas Hafner , Hans Jürg Kirner , Franz Schwarzenbach , Paul Adriaan Van Der Schaaf , Peter Nesvadba
发明人： Andreas Hafner , Hans Jürg Kirner , Franz Schwarzenbach , Paul Adriaan Van Der Schaaf , Peter Nesvadba
IPC分类号： C07D211/54
CPC分类号： C07D401/14 , C04B35/632 , C07D209/44 , C07D211/94 , C07D217/26 , C07D241/08 , C07D401/12 , C07D405/12 , C08K5/3412
摘要： An amine ether of formula A wherein a is 1 or 2; and when a is 1, E is E′; when a is 2, E is L; E′ is C1-C36 alkyl; C3-C18 alkenyl; C2-C18 alkinyl; C5-C18 cycloalkyl; C5-C18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C2-C7alkyl or C3-C7alkenyl substituted by halogen; C7-C15 aralkyl or C7-C15 aralkyl substituted by C1-C4 alkyl or phenyl; or E′ is a radical of formula (VII) as explained in claim 1; T′ is tertiary C4-C18alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR21 or C(O)—R22; or T′ is C5-C12cycloalkyl; C5-C12cycloalkyl which is interrupted by at least one O or —NR18—; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or —NR18—; or T′ is —C(G1)(G2)-T″; or C1-C18alkyl or C5-C12cycloalkyl substituted by T″ is hydrogen, halogen, NO2, cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; or T″ and T′ together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G1 and G2, an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E1-H or H-L-H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. The products of present process find utility as polymerization regulators and/or light stabilizers for organic material.

17. 发明授权

US06900328B2 Process for the synthesis of amine ethers from secondary amino oxides 有权
公开(公告)号：US06900328B2
公开(公告)日：2005-05-31
申请号：US10296107
申请日：2001-05-17
申请人： Andreas Hafner , Hans Jürg Kirner , Franz Schwarzenbach , Paul Adriaan Van Der Schaaf , Peter Nesvadba
发明人： Andreas Hafner , Hans Jürg Kirner , Franz Schwarzenbach , Paul Adriaan Van Der Schaaf , Peter Nesvadba
IPC分类号： B01J27/122 , C07B61/00 , C07D209/44 , C07D211/94 , C07D217/26 , C07D241/08 , C07D401/12 , C07D401/14 , C07D405/12 , C08F4/00 , C08K5/3412 , C08K5/3435 , C08L101/00 , C09K15/30 , C09K21/10 , C07D211/54
CPC分类号： C07D401/14 , C04B35/632 , C07D209/44 , C07D211/94 , C07D217/26 , C07D241/08 , C07D401/12 , C07D405/12 , C08K5/3412
摘要： An amine ether of formula (A) wherein a is 1 or 2; and when a is 1, E is E′; when a is 2, E is L; E′ is C1-C36 alkyl; C3-C18 alkenyl; C2-C18 alkinyl; C5-C18 cycloalkyl; C5-C18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C2-C7alkyl or C3-C7alkenyl substituted by halogen; C7-C15aralkyl or C7-C15 aralkyl substituted by C1-C4 alkyl or phenyl; or E′ is a radical of formula (VII) as explained in claim 1; T′ is tertiary C4-C18alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR21 or C(O)—R22; or T′ is C5-C12cycloalkyl; C5-C12cacloalkyl which is interrupted by at least one O or —NR18—; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or —NR18—; or T′ is —C(G1)(G2)—T″; or C1-C18alkyl or C5-C12cycloalkyl substituted by F(I)T″ is hydrogen, halogen, NO2, cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; or T″ and T′ together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G1 and G2, an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E1—H or H—L—H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. The products of present process find utility as polymerization regulators and/or light stabilizers for organic material

18. 发明授权

US6077805A Hexacoordinated ruthenium or osmium carbene catalysts 失效
标题翻译：六配位的钌或镉卡因催化剂
公开(公告)号：US6077805A
公开(公告)日：2000-06-20
申请号：US33265
申请日：1998-03-02
申请人： Paul Adriaan Van Der Schaaf , Andreas Hafner , Andreas Muhlebach
发明人： Paul Adriaan Van Der Schaaf , Andreas Hafner , Andreas Muhlebach
IPC分类号： B01J31/22 , B01J31/24 , C07F15/00 , C08G61/02 , C08G61/08 , B01J31/00 , C07D231/00 , C07D233/00 , C07F17/02
CPC分类号： B01J31/1815 , B01J31/181 , B01J31/183 , B01J31/2265 , B01J31/24 , B01J31/2404 , C07F15/002 , C07F15/0046 , C08G61/02 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825
摘要： Hexacoordinated ruthenium and osmium catalysts of the formulae ##STR1## in which M and M' independently of one another are ruthenium or osmium;X, X', Y and Y' independently of one another are anionic ligands, or X and Y and X' and Y' in each case together are bis-anionic ligandsL.sup.1 and L.sup.1' independently of one another are tertiary phosphine;L.sup.2 and L.sup.3 independently of one another are a monodentate ligand, or L.sup.2 and L.sup.3 together are bidentate, neutral electron donor ligands;L.sup.4 is tetradentate, neutral electron donor ligand;L.sup.5 is a bidentate, neutral electron donor ligand; andT and T' indepedently of one another are H or organic substituents, are useful for the synthesis of custom-tailored polymers and for the ring-closing metathesis of olefins.
摘要翻译：其中M和M'彼此独立的下式的六配位钌和锇催化剂是钌或锇; X，X'，Y和Y'彼此独立的是阴离子配体，或者X和Y以及X'和Y'各自在一起是双阴离子配体，L1和L1'彼此独立地是叔膦; L2和L3彼此独立是单齿配体，或L2和L3一起是双齿中性电子给体配体; L4是四齿中性电子给体配体; L5是二齿中性电子给体配体; 且T和T'彼此独立地是H或有机取代基，可用于合成定制聚合物和烯烃的闭环复分解。

19. 发明申请

US20110159050A1 AMPHIPHILIC PROTEINS AS MORPHOLOGY MODIFIERS 审中-公开
标题翻译：大分子蛋白作为形态修饰剂
公开(公告)号：US20110159050A1
公开(公告)日：2011-06-30
申请号：US13002777
申请日：2009-06-23
申请人： Andreas Hafner , Andreas Buthe , Paul Adriaan Van Der Schaaf , Franz Kaufmann , Gordon Bradley
发明人： Andreas Hafner , Andreas Buthe , Paul Adriaan Van Der Schaaf , Franz Kaufmann , Gordon Bradley
IPC分类号： A61K9/14 , C07C233/25 , A61K31/167 , C07C233/65 , A61K31/166 , C07D207/34 , A61K31/40 , C07C215/64 , A61K31/137
CPC分类号： B01D9/005 , A61K9/1688 , C07K14/37
摘要： Disclosed is a process for modifying the morphology and/or polymorphism of an organic substance, which process comprises treating the solid substance, or a solution or dispersion thereof, with one or more amphiphilic proteins.
摘要翻译：公开了一种用于改变有机物质的形态和/或多态性的方法，该方法包括用一种或多种两亲性蛋白质处理固体物质或其溶液或分散体。

20. 发明授权

US6162883A Catalyst mixture and polymerizable composition 失效
标题翻译：催化剂混合物和可聚合组合物
公开(公告)号：US6162883A
公开(公告)日：2000-12-19
申请号：US155561
申请日：1998-09-30
申请人： Andreas Muhlebach , Paul Adriaan Van Der Schaaf , Andreas Hafner
发明人： Andreas Muhlebach , Paul Adriaan Van Der Schaaf , Andreas Hafner
IPC分类号： B01J31/24 , C08G61/08 , C08G61/12 , C09D145/00
CPC分类号： C08G61/12 , C08G61/08 , Y10T428/2991 , Y10T428/2993 , Y10T428/31678
摘要： A mixture of at least one thermal carbene-free ruthenium catalyst A and at least one thermal ruthenium carbene catalyst B, both of which initiate the ring-opening metathesis polymerization on their own, said catalysts being present in a weight ratio of A to B from 10:1 to 1:10. By adding this mixture even in small amounts, the ring-opening metathesis polymerization of strained cycloolefins can be effectively catalyzed.
摘要翻译： PCT No.PCT / EP97 / 01579 Sec。 371日期：1998年9月30日 102（e）1998年9月30日PCT PCT 1997年3月27日PCT公布。公开号WO97 / 38036 日期1997年10月16日将至少一种不含热不卡宾的钌催化剂A和至少一种热钌卡宾催化剂B的混合物二者自身引发开环易位聚合，所述催化剂以重量比存在的A到B从10：1到1:10。通过少量加入该混合物，可以有效催化应变环烯烃的开环易位聚合。

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