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    • 12. 发明授权
    • Process for coating metal strip by the coil coating process for the
production of components exposed to high temperatures
    • 用于生产暴露于高温组件的线圈涂层工艺涂覆金属条的工艺
    • US5084304A
    • 1992-01-28
    • US490641
    • 1990-06-13
    • Klaus-Wilhelm LienertArno Schmitz
    • Klaus-Wilhelm LienertArno Schmitz
    • B05D7/00B05D7/16C08L79/08C09D179/08
    • B05D7/52B05D7/16C08L79/08C09D179/08B05D2252/02B05D2505/50B05D2701/00
    • The invention relates to a process for coating metal strip by the coil coating process using coating materials consisting of high temperature resistant systems (polyesterimides, polyamidocarboxylic acids, polyamidimides, polyhydantoins and polybismaleimides), pigments and/or fillers, suitable auxiliary substances and additives as well as solvents or solvent mixtures. The coating material is used in a one-coat or two-coat application, only polyesterimides and polyhydantoins being used for the primers as high temperatures resistant systems, while any of the high temperature resistant systems listed are used in the topcoat.The metal strip coated in this manner possesses good formability, good hardness, outstanding anticorrosion characteristics, outstanding resistance to chemicals, solvents, water, oil, shock and prolonged high temperatures, outstanding adhesion and resistance to stone impact, and is particularly suitable for the production of exhausts, silencers, exhaust air ducts, furnace and radiator claddings, grill utensils and other components exposed to high temperatures.
    • 本发明涉及一种使用由耐高温系统(聚酯酰亚胺,聚酰胺羧酸,聚酰胺酰亚胺,聚乙内酰脲和聚双马来酰亚胺),颜料和/或填料,合适的辅助物质和添加剂组成的涂层材料的卷材涂布方法来涂覆金属条的方法 作为溶剂或溶剂混合物。 涂层材料用于单涂层或双涂层应用中,仅使用聚酰亚胺和聚乙内酰脲作为耐高温系统的底漆,而所列的任何耐高温系统均用于面漆。 以这种方式涂覆的金属带具有良好的成形性,良好的硬度,优异的耐腐蚀特性,优异的耐化学品,溶剂,水,油,冲击和长时间的高温,优异的附着力和耐石料冲击性,特别适用于生产 废气,消声器,废气管道,炉子和散热器包层,烧烤器具和暴露于高温的其他部件。
    • 16. 发明授权
    • Method for the production of polyester imides containing carboxyl- and hydroxyl groups and their usage in wire enamels
    • 生产含羧基和羟基的聚酰亚胺的方法及其在线瓷中的应用
    • US06211326B1
    • 2001-04-03
    • US09308117
    • 1999-07-13
    • Brian W. GlasperGeoffrey C. RixKlaus-Wilhelm Lienert
    • Brian W. GlasperGeoffrey C. RixKlaus-Wilhelm Lienert
    • C08G7316
    • H01B3/306C08G73/16C09D179/08H01B3/308
    • The invention relates to a process for preparing hydroxyl- and carboxyl-containing polyesterimide resins, comprising as monomeric components: (A) imide-forming compounds having at least two primary amino groups and/or at least two isocyanate groups or imide-forming compounds having at least one primary amino group and/or at least one isocyanate group and at least one further functional group selected from hydroxyl, carboxyl and/or carboxylic anhydride, (B) polycarboxylic acids and/or their anhydrides and/or their esters and (C) polyols, characterized in that (I) component (A) is reacted with part of component (B) to form a polyimide, (II) the polyimide obtained in accordance with stage (I) is reacted with component (C) to form a polyesterimide, and finally (III) the polyesterimide obtained in accordance with stage (II) is reacted with the remaining part of component (B) to form the Also embraced by the invention is the use of the polyesterimides prepared by the process according to the invention as binders, and wire enamels comprising hydroxyl- and carboxyl-containing polyesterimides having an acid number >80 mg of KOH/g which can be prepared by the process according to the invention.
    • 本发明涉及一种制备含羟基和羧基的聚酯酰亚胺树脂的方法,包括作为单体组分:(A)具有至少两个伯氨基和/或至少两个异氰酸酯基的酰亚胺形成化合物或具有酰亚胺形成化合物,其具有 至少一个伯氨基和/或至少一个异氰酸酯基和至少一个选自羟基,羧基和/或羧酸酐的另外的官能团,(B)多元羧酸和/或它们的酸酐和/或它们的酯和(C )多元醇,其特征在于(I)成分(A)与成分(B)的一部分反应形成聚酰亚胺,(II)将按照(I)中得到的聚酰亚胺与组分(C)反应形成 聚酯酰亚胺,最后(III)将根据阶段(II)获得的聚酯酰亚胺与组分(B)的剩余部分反应形成本发明还包括使用通过本发明方法制备的聚酯酰亚胺 作为粘合剂和包含含有羟基和羧基的聚酯酰亚胺的线搪瓷,其酸值> 80mg KOH / g,其可以通过本发明的方法制备。