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11. 发明授权

US06670085B2 Electrophotographic organophotoreceptors with novel charge transport compounds 失效
标题翻译：具有新型电荷传输化合物的电子照相有机光感受器
公开(公告)号：US06670085B2
公开(公告)日：2003-12-30
申请号：US09963141
申请日：2001-09-24
申请人： Nusrallah Jubran , Hwan Koo Lee , Kam W. Law
发明人： Nusrallah Jubran , Hwan Koo Lee , Kam W. Law
IPC分类号： G03G1502
CPC分类号： C07D455/04 , G03G5/0614 , G03G5/0616 , G03G5/0625 , G03G5/0629 , G03G5/0637 , G03G5/0642 , G03G5/0646 , G03G5/065 , G03G5/0661
摘要： Charge transport compounds are described that have a multiple number of hydrazone-bridged heterocyclic groups (especially julolidine, carbazole and/or triarylmethane groups) connected by a central bridging group. An example of charge transport compounds are those having the following generic formula: (R—Q)n-Y Formula I wherein R is selected from the group consisting of julolidine ring groups, carbazole ring groups, and triarylmethane ring groups; Q comprises an aromatic hydrazone linking group, such as Y comprises a bridging group between R—Q— groups, such as a bond, carbon atom, nitrogen atom, oxygen atom, sulfur atom, a methylene group; Z is an aryl group, preferably a phenyl group or naphthyl group; X is a linking group, preferably amethylene group, and for example having the formula —(CH2)m-(branched or linear), where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups is optionally replaced by an oxygen atom, a carbonyl group, urethane, urea, an ester group, a —NR6 group, a CHR7 group, or a CR8R9 group where R6, R7, R8, and R9 are, independently, H, an alkyl group, or aryl group; and n is an integer between 2 and 6, inclusive. An organic photoreceptor includes that compound and (b) a charge generating compound; and (c) an electrically conductive substrate.
摘要翻译：描述了具有通过中心桥连基团连接的多个腙桥连杂环基（特别是久洛尼牌，咔唑和/或三芳基甲烷基团）的电荷转运化合物。电荷输送化合物的实例是具有以下通式的那些：其中R选自高洛兰环，咔唑环和三芳基甲烷环; Q包括芳族腙连接基团，例如Y包括桥连基团 RQ-基团之间，如键，碳原子，氮原子，氧原子，硫原子，亚甲基; Z是芳基，优选苯基或萘基; X是连接基团，优选亚甲基基团，并且例如具有式 - （CH 2）m - （支链或直链），其中m是0和20之间的整数，包括端值在内，并且一个或多个亚甲基是任选的由氧原子，羰基，氨基甲酸酯，脲，酯基，-NR6基，CHR7基或CR8R9基团取代，其中R6，R7，R8和R9独立地为H，烷基，或芳基; n为2〜6的整数。有机感光体包括该化合物和（b）电荷产生化合物; 和（c）导电基板。

12. 发明授权

US06887634B2 Electrophotographic organophotoreceptors with novel charge transport compounds 失效
标题翻译：具有新型电荷传输化合物的电子照相有机光感受器
公开(公告)号：US06887634B2
公开(公告)日：2005-05-03
申请号：US10748496
申请日：2003-12-30
申请人： Nusrallah Jubran , Hwan Koo Lee , Kam W. Law
发明人： Nusrallah Jubran , Hwan Koo Lee , Kam W. Law
IPC分类号： C07D209/86 , C07D455/04 , G03G5/06 , G03G5/10 , G03G15/02
CPC分类号： G03G5/0648 , C07D209/86 , C07D455/04 , G03G5/0614 , G03G5/0616 , G03G5/0625 , G03G5/0629 , G03G5/0637 , G03G5/0642 , G03G5/0646 , G03G5/065 , G03G5/0661
摘要： Charge transport compounds are described that have a multiple number of hydrazone-bridged (N,N-disubstituted)arylamine groups connected by a central bridging group. Examples of charge transport compounds of this invention are those having the following generic formula: (R-Q)n-Y where R is an (N,N-disubstituted)arylamine group; Q comprises an aromatic hydrazone linking group; Y comprises a bridging group between R-Q- groups; and n is an integer between 2 and 6. An organic photoreceptor includes (a) that compound and (b) a charge generating compound; and (c) an electrically conductive substrate.
摘要翻译：描述了具有通过中心桥连基团连接的多个腙桥连（N，N-二取代的）芳胺基团的电荷转运化合物。本发明的电荷输送化合物的实例是具有以下通式的那些：<？in-line-formula description =“In-line formula”end =“lead”？>（RQ）nY <？in-line-formula description =“在线式”末端=“尾”→其中R是（N，N-二取代的）芳基胺基团; Q包括芳族腙连接基团; Y包含R-Q-基团之间的桥连基团; n为2〜6的整数。有机感光体包括（a）该化合物和（b）产生电荷的化合物; 和（c）导电基板。

13. 发明授权

US07351508B2 Organophotoreceptors with a charge transport material having multiple vinyl-containing hydrazone groups 失效
标题翻译：具有多个含乙烯基腙基团的电荷传输材料的有机光感受器
公开(公告)号：US07351508B2
公开(公告)日：2008-04-01
申请号：US10962926
申请日：2004-10-12
申请人： Juozas V. Grazulevicius , Gintaras Buika , Vygintas Jankauskas , Valentas Gaidelis , Ruta Budreckiene , Zbigniew Tokarski , Nusrallah Jubran
发明人： Juozas V. Grazulevicius , Gintaras Buika , Vygintas Jankauskas , Valentas Gaidelis , Ruta Budreckiene , Zbigniew Tokarski , Nusrallah Jubran
IPC分类号： G03G5/04
CPC分类号： C07D209/86 , C07D207/335 , C07D241/48 , C07D265/38 , C07D279/22 , C07D279/26 , C07D307/52 , C07D333/22 , C07D495/04 , G03G5/0605 , G03G5/0614 , G03G5/0616 , G03G5/0629 , G03G5/0631 , G03G5/0635 , G03G5/0638 , G03G5/0644 , G03G5/0648 , G03G5/065 , G03G5/0655 , G03G5/0661 , G03G5/071 , G03G5/073
摘要： Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Y comprises an aromatic group; V1 and V2 comprise, each independently, a vinyl containing group; and R1, R2, R3, and R4 comprise, each independently, H, an alkyl group, an acyl group, an ether group, an ester group, an alkenyl group, an alkynyl group, a heterocyclic group, an aromatic group, or a part of a ring group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, electrophotographic imaging methods, and charge transport materials are also described.
摘要翻译：改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件，光电导元件包括：（a）具有下式的电荷传输材料，其中Y包含芳族基团; V 1和V 2 2各自独立地包含含乙烯基的基团; 且R 1，R 2，R 3和R 4各自独立地包含H，烷基基团，酰基，醚基，酯基，烯基，炔基，杂环基，芳族基或环基的一部分; 和（b）电荷产生化合物。还描述了相应的电子照相设备，电子照相成像方法和电荷传输材料。

14. 发明授权

US07108948B2 Organophotoreceptor with charge transport compositions 有权
标题翻译：有机光感受器与电荷输送组合物
公开(公告)号：US07108948B2
公开(公告)日：2006-09-19
申请号：US10789077
申请日：2004-02-27
申请人： Zbigniew Tokarski , Nusrallah Jubran , Vytautas Getautis , Juozas V. Grazulevicius , Tadas Malinauskas , Edmundas Montrimas , Valentas Gaidelis
发明人： Zbigniew Tokarski , Nusrallah Jubran , Vytautas Getautis , Juozas V. Grazulevicius , Tadas Malinauskas , Edmundas Montrimas , Valentas Gaidelis
IPC分类号： G03G5/04
CPC分类号： G03G5/0614 , C07C323/48 , C07D209/86 , C07D285/125 , C07D417/14 , C08G61/122 , C08G61/123 , C08G61/126 , C08G73/0253 , C08G73/0273 , G03G5/0616 , G03G5/062 , G03G5/0629 , G03G5/0633 , G03G5/075 , G03G5/076
摘要： An organophotoreceptor comprises an electrically conductive substrate and photoconductive element on the electrically conductive substrate, the photoconductive element having a) a charge transport composition with the formula where Y1 and Y2 are, each independently, an arylamine group; X1 and X2 are, each independently, a linking group; R1 and R2 are, each independently, a hydrogen, an alkyl group, an alkenyl group, a heterocyclic group, an aromatic group; Z is a bridging group; and n is a distribution of integers between 1 and 100,000 with an average value greater than 1; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
摘要翻译：有机光感受器包括导电衬底上的导电衬底和光电导元件，光电导元件具有a）具有下式的电荷传输组合物，其中Y 1和Y 2是，各自独立地为芳基胺基; X 1和X 2各自独立地为连接基团; R 1和R 2各自独立地为氢，烷基，烯基，杂环基，芳族基团; Z是桥接组; n是1和100,000之间的平均值大于1的整数分布; 和（b）电荷产生化合物。描述相应的电子照相设备和成像方法。

15. 发明授权

US07326506B2 Bridged charge transport materials having a central sulfur atom linkage 失效
标题翻译：具有中心硫原子键的桥接电荷传输材料
公开(公告)号：US07326506B2
公开(公告)日：2008-02-05
申请号：US10857267
申请日：2004-05-28
申请人： Nusrallah Jubran , Zbigniew Tokarski , Vytautas Getautis , Juozas V. Grazulevicius , Vygintas Jankauskas , Ingrida Paulauskaite , Jurate Simokaitiene , Albina Stanisauskaite , Valentas Gaidelis
发明人： Nusrallah Jubran , Zbigniew Tokarski , Vytautas Getautis , Juozas V. Grazulevicius , Vygintas Jankauskas , Ingrida Paulauskaite , Jurate Simokaitiene , Albina Stanisauskaite , Valentas Gaidelis
IPC分类号： G03G15/02 , G03G15/00 , C07C251/00 , C07C259/00
CPC分类号： G03G5/0616 , C07C323/12 , C07C323/48 , C07D209/86 , C07D279/28 , G03G5/0614 , G03G5/062 , G03G5/0627 , G03G5/0629 , G03G5/0638
摘要： Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Z1 and Z2 comprise, each independently, a bond, a vinyl group, a —CR1═N—NR2— group, or a —CR3═N—N═CR4— group; Y1 and Y2 comprise, each independently, an aromatic group; X1 and X2 are, each independently, a linking group; W1 and W2 are, each independently, a —(CH2)n— group or a —(CH2)n-1—C(═O)— group, where n is an integer between 1 and 10, inclusive; Q1 and Q2 are, each independently, O, S, or NR; and R1, R2, R3, R4, R, R′, and R″ comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an acyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
摘要翻译：改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件，光电导元件包括：（a）具有下式的电荷传输材料：其中Z 1和Z 2，各自独立地包含键，乙烯基，-CR 1 -N-NR 2 - 基或-CR 3 - 基团; -NN-CR 4 - 基团; Y 1和Y 2 2各自独立地包含芳族基团; X 1和X 2各自独立地为连接基团; W 1和W 2各自独立地为 - （CH 2）n - n - 或 - （CH 2）n - （CH 2）n-1 -C（-O） - 基，其中n是1和10之间的整数，包括1和10; Q 1和Q 2各自独立地为O，S或NR; 和R 1，R 2，R 3，R 4，R，R'和R“ 各自独立地包含H，烷基，烯基，炔基，酰基，杂环基或芳族基; 和（b）电荷产生化合物。描述相应的电子照相设备和成像方法。

16. 发明授权

US07189483B2 Charge transport materials having heteroaromatic hydrazone groups 失效
标题翻译：具有杂芳族腙基团的电荷输送材料
公开(公告)号：US07189483B2
公开(公告)日：2007-03-13
申请号：US10789094
申请日：2004-02-27
申请人： Almantas Danilevicius , Gintaras Buika , Ramunas Lygaitis , Juozas V. Grazulevicius , Robertas Maldzius , Edmundas Montrimas , Zbigniew Tokarski , Nusrallah Jubran
发明人： Almantas Danilevicius , Gintaras Buika , Ramunas Lygaitis , Juozas V. Grazulevicius , Robertas Maldzius , Edmundas Montrimas , Zbigniew Tokarski , Nusrallah Jubran
IPC分类号： G03G5/047
CPC分类号： C07D279/28 , C07D241/48 , C07D265/38 , G03G5/0616 , G03G5/0637 , G03G5/0638 , G03G5/0642
摘要： An improved organophotoreceptor includes an electrically conductive substrate and a photoconductive element on the electrically conductive substrate where the photoconductive element comprises: a) a charge transport material having the following formula: where X is a linking group; Y1 and Y2 are, each independently, a phenothiazine group, a phenoxazine group, or a phenazine group; R1, R2, R3, and R4 are, each independently, an alkyl group, an alkenyl group, a heterocyclic group, or an aromatic group; and R5 and R6 are, each independently, a hydrogen, an alkyl group, an alkenyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
摘要翻译：改进的有机光感受器包括在导电基底上的导电基底和光电导元件，其中光电导元件包括：a）具有下式的电荷传输材料：其中X是连接基团; Y 1和Y 2各自独立地是吩噻嗪基，吩恶嗪基或吩嗪基; R 1，R 2，R 3和R 4各自独立地为烷基，烯基，杂环基或芳基; R 5和R 6分别独立地为氢，烷基，烯基，杂环基或芳族基; 和（b）电荷产生化合物。描述相应的电子照相设备和成像方法。

17. 发明授权

US07348116B2 Aromatic heterocyclic-based charge transport materials having two amino groups 失效
标题翻译：具有两个氨基的芳族杂环基电荷传输材料
公开(公告)号：US07348116B2
公开(公告)日：2008-03-25
申请号：US10933934
申请日：2004-09-03
申请人： Ausra Matoliukstyte , Valentas Gaidelis , Juozas V. Grazulevicius , Vygintas Jankauskas , Beata Klejevskaja , Nusrallah Jubran , Zbigniew Tokarski
发明人： Ausra Matoliukstyte , Valentas Gaidelis , Juozas V. Grazulevicius , Vygintas Jankauskas , Beata Klejevskaja , Nusrallah Jubran , Zbigniew Tokarski
IPC分类号： G03G5/06
CPC分类号： G03G5/0698 , C07D209/88 , C07D401/14 , C07D405/06 , C07D405/12 , C07D409/12 , C07D417/06 , G03G5/0625 , G03G5/0629 , G03G5/0661
摘要： Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Y comprises an aromatic heterocyclic group; X is a bond or a linking group; E comprises a reactive ring group or a reactive functional group; and R1, R2, R3, and R4 comprise, each independently, H, an alkyl group, an acyl group, an ether group, an alkenyl group, an alkynyl group, a heterocyclic group, an aromatic group, or a part of a ring group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, electrophotographic imaging methods, and bridged charge transport materials derived form the charge transport material above are also described.
摘要翻译：改进的有机光感受器包括导电衬底和导电衬底上的光电导元件，光电导元件包括：（a）具有下式的电荷传输材料，其中Y包含芳族杂环基; X是键或连接基团; E包含反应性环基或反应性官能团; 且R 1，R 2，R 3和R 4各自独立地包含H，烷基基团，酰基，醚基，烯基，炔基，杂环基，芳族基或环基的一部分; 和（b）电荷产生化合物。还描述了相应的电子照相设备，电子照相成像方法以及由上述电荷传输材料得到的桥接电荷传输材料。

18. 发明授权

US07329722B2 Polymeric charge transport materials having carbazolyl repeating units 失效
标题翻译：具有咔唑重复单元的聚合电荷输送材料
公开(公告)号：US07329722B2
公开(公告)日：2008-02-12
申请号：US10929912
申请日：2004-08-30
申请人： Violeta Vaitkeviciene , Sauljus Grigalevicius , Juozas V. Grazulevicius , Valentas Gaidelis , Robertas Mald{hacek over (z)}ius , Zbigniew Tokarski , Nusrallah Jubran
发明人： Violeta Vaitkeviciene , Sauljus Grigalevicius , Juozas V. Grazulevicius , Valentas Gaidelis , Robertas Mald{hacek over (z)}ius , Zbigniew Tokarski , Nusrallah Jubran
IPC分类号： C08G73/06 , G03G5/04
CPC分类号： G03G5/073 , G03G5/0629 , G03G5/0661 , G03G5/071 , G03G5/075 , G03G5/076
摘要： Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a polymeric charge transport material having the formula where n is a distribution of integers between 1 and 100,000 with an average value of greater than one; Y comprises an aromatic group; and X is a bond or a linking group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods and methods of making the polymeric charge transport material are described.
摘要翻译：改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件，光电导元件包括：（a）具有下式的聚合物电荷传输材料，其中n是1和100,000之间的整数分布，平均值较大比一个 Y包括芳族基团; X是键或连接基团; 和（b）电荷产生化合物。描述了相应的电子照相设备和制备聚合物电荷传输材料的成像方法和方法。

19. 发明授权

US07202002B2 Hydrazone-based charge transport materials 失效
标题翻译：腙类电荷输送材料
公开(公告)号：US07202002B2
公开(公告)日：2007-04-10
申请号：US10836734
申请日：2004-04-30
申请人： Zbigniew Tokarski , Nusrallah Jubran , Ruta Budreckiene , Gintaras Buika , Valentas Gaidelis , Juozas V. Grazulevicius , Vygintas Jankauskas
发明人： Zbigniew Tokarski , Nusrallah Jubran , Ruta Budreckiene , Gintaras Buika , Valentas Gaidelis , Juozas V. Grazulevicius , Vygintas Jankauskas
IPC分类号： G03G5/06
CPC分类号： G03G5/0614 , C07C323/12 , C07D209/86 , G03G5/0616 , G03G5/0618 , G03G5/062 , G03G5/0648
摘要： Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where R1 and R2 are, each independently, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; R3 and R4 are, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; X1 and X2 are, each independently, a linking group; Y1 and Y2, each independently, comprise an arylamino group; and Z is a bridging group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
摘要翻译：改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件，光导元件包括

20. 发明申请

US20050095519A1 Organophotoreceptor with charge transport material with a hydrazone group linked to a heterocyclic group 失效
公开(公告)号：US20050095519A1
公开(公告)日：2005-05-05
申请号：US10699364
申请日：2003-10-31
申请人： Nusrallah Jubran , Zbigniew Tokarski , Juozas Grazulevicius , Vytautas Getautis , Jolita Ostrauskaite , Jurate Simokaitiene , Vygintas Jankauskas
发明人： Nusrallah Jubran , Zbigniew Tokarski , Juozas Grazulevicius , Vytautas Getautis , Jolita Ostrauskaite , Jurate Simokaitiene , Vygintas Jankauskas
IPC分类号： C07D279/22 , G03G5/047 , G03G5/06 , G03G9/12 , G03G5/05 , C07D265/34 , C07D279/18 , C07D335/08
CPC分类号： C07D279/22
摘要： Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where n is an integer between 2 and 6, inclusive; R1 and R2 are, independently, H, an alkyl group, an alkaryl group, or an aryl group; X is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups is optionally replaced by O, S, C═O, O═S═O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR3 group, a CHR4 group, or a CR5R6 group where R3, R4, R5, and R6 are, independently, H, hydroxyl group, thiol group, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; Y comprises a bond, C, N, O, S, a branched or linear —(CH2)p— group where p is an integer between 0 and 10, an aromatic group, a cycloalkyl group, a heterocyclic group, or a NR7 group where R7 is hydrogen atom, an alkyl group, or aryl group, wherein Y has a multivalent structure selected to form n bonds with the corresponding X groups; and Z comprises a heterocyclic group selected from the group consisting of phenothiazine group, phenoxazine group, phenoxathiin group, dibenzo(1,4)dioxin group, thianthrene group, and phenazine group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.

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