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11. 发明授权

US07220698B2 Catalyst for catalytic gas phase oxidation of acrolein and process for producing acrylic acid by catalytic gas phase oxidation using said catalyst 失效
标题翻译：用于丙烯醛催化气相氧化的催化剂和使用所述催化剂通过催化气相氧化制备丙烯酸的方法
公开(公告)号：US07220698B2
公开(公告)日：2007-05-22
申请号：US11052897
申请日：2005-02-09
申请人： Hiromi Yunoki , Michio Tanimoto
发明人： Hiromi Yunoki , Michio Tanimoto
IPC分类号： B01J23/00 , C01C51/235
CPC分类号： C07C51/252 , B01J23/002 , B01J23/22 , B01J23/28 , B01J23/8876 , B01J23/8877 , B01J23/8885 , B01J37/0236 , B01J2523/00 , C07C57/04 , B01J2523/13 , B01J2523/17 , B01J2523/53 , B01J2523/55 , B01J2523/68 , B01J2523/69
摘要： There are provided a catalyst for catalytic gas phase oxidation of acrolein with molecular oxygen to produce acrylic acid, the catalyst including molybdenum and vanadium and further including at least one volatile catalyst poison ingredient in an amount of 10 to 100 ppb by mass as measured by ion chromatography; and a process for producing acrylic acid, including a step of carrying out catalytic gas phase oxidation of acrolein with molecular oxygen using the catalyst. The catalyst of the present invention can lower a hot spot temperature and suppress reduction in a reaction efficacy accompanied with thermal degradation, so that the acrolein conversion can stably be kept higher over a long term.
摘要翻译：提供了一种用分子氧催化气相氧化丙烯醛产生丙烯酸的催化剂，该催化剂包括钼和钒，还包括至少一种挥发性催化剂毒成分，其用量为离子浓度为10-100ppb 色谱以及丙烯酸的制造方法，包括使用催化剂进行丙烯醛与分子氧的催化气相氧化的工序。本发明的催化剂可以降低热点温度并抑制伴随热降解的反应效率的降低，使得丙烯醛转化率可以长期稳定地保持较高。

12. 发明授权

US07045657B2 Catalytic gas phase oxidation process 有权
公开(公告)号：US07045657B2
公开(公告)日：2006-05-16
申请号：US10387244
申请日：2003-03-12
申请人： Hiromi Yunoki , Michio Tanimoto
发明人： Hiromi Yunoki , Michio Tanimoto
IPC分类号： C07C51/235 , C07C51/16
CPC分类号： C07C45/37 , B01J23/002 , B01J23/8876 , B01J23/8877 , B01J23/8885 , B01J35/023 , B01J37/0009 , B01J37/0236 , C07C45/32 , C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： The object of the present invention is to provide a process in which, when the unsaturated carboxylic acid is produced, or when the unsaturated aldehyde and/or the unsaturated carboxylic acid are produced by carrying out the catalytic gas phase oxidation reaction by using the fixed-bed multitubular reactor which is packed with the molybdenum-containing catalyst, the reaction can be continued for a long time while a high yield is maintained, regardless of where the hot spot portion occurs and also even if the concentration of the raw gas is high. To solve this object, the present invention production process for an unsaturated carboxylic acid is characterized in: a particulate catalysts including, as catalytic components, an oxide and/or a complex oxide including Mo and V, or Mo, Fe and Bi as essential components, and having a hole are used; and a catalyst-packed layer of each reaction tube of the fixed-bed multitubular reactor is divided into at least two reaction zones in a tubular axial direction, wherein the packing of the catalysts is such that the diameters of the holes of the catalysts differ between at least two of the reaction zones.

13. 发明授权

US5442108A Process for removal of solid organic matters 失效
标题翻译：去除固体有机物的方法
公开(公告)号：US5442108A
公开(公告)日：1995-08-15
申请号：US208667
申请日：1994-03-11
申请人： Tatsuya Kawajiri , Hideyuki Hironaka , Kazuyuki Uekawa , Michio Tanimoto , Hiromi Yunoki , Tsuyoshi Kudoh
发明人： Tatsuya Kawajiri , Hideyuki Hironaka , Kazuyuki Uekawa , Michio Tanimoto , Hiromi Yunoki , Tsuyoshi Kudoh
IPC分类号： B01J23/88 , B01J23/92 , B01J23/94 , B01J38/06 , B01J38/12 , C07B61/00 , C07C51/21 , C07C51/487 , C07C57/05 , C07C57/055 , C07C57/07 , C07C51/16
CPC分类号： C07C51/487 , B01J23/94 , B01J38/06 , B01J38/12 , Y02P20/584
摘要： A process for removal of solid organic matters formed and deposited in the reaction system when an unsaturated aldehyde or an unsaturated aidehyde-containing gas is subjected to catalytic gaseous oxidation in the presence of an oxidizing catalyst to prepare an unsaturated carboxylic acid corresponding thereto, which process comprises contacting the solid organic matters with a mixed gas containing at least 3 volume % of molecular oxygen and at least 0.1 volume % of steam at a temperature of 260.degree. to 450.degree. C.
摘要翻译：当在氧化催化剂存在下使不饱和醛或不饱和含酐气体进行催化气体氧化以制备与其相对应的不饱和羧酸时，去除在反应体系中形成和沉积的固体有机物质的方法，包括在260-450℃的温度下使固体有机物质与含有至少3体积％分子氧和至少0.1体积％蒸汽的混合气体接触。

14. 发明申请

US20050176995A1 Catalyst for catalytic gas phase oxidation of acrolein and process for producing acrylic acid by catalytic gas phase oxidation using said catalyst 失效
标题翻译：用于丙烯醛催化气相氧化的催化剂和使用所述催化剂通过催化气相氧化制备丙烯酸的方法
公开(公告)号：US20050176995A1
公开(公告)日：2005-08-11
申请号：US11052897
申请日：2005-02-09
申请人： Hiromi Yunoki , Michio Tanimoto
发明人： Hiromi Yunoki , Michio Tanimoto
IPC分类号： B01J33/00 , B01J23/00 , B01J23/22 , B01J23/28 , B01J23/88 , B01J23/887 , B01J23/888 , B01J27/24 , B01J35/00 , B01J37/02 , C07B61/00 , C07C51/235 , C07C51/25 , C07C57/04 , C07C57/055
CPC分类号： C07C51/252 , B01J23/002 , B01J23/22 , B01J23/28 , B01J23/8876 , B01J23/8877 , B01J23/8885 , B01J37/0236 , B01J2523/00 , C07C57/04 , B01J2523/13 , B01J2523/17 , B01J2523/53 , B01J2523/55 , B01J2523/68 , B01J2523/69
摘要： There are provided a catalyst for catalytic gas phase oxidation of acrolein with molecular oxygen to produce acrylic acid, the catalyst including molybdenum and vanadium and further including at least one volatile catalyst poison ingredient in an amount of 10 to 100 ppb by mass as measured by ion chromatography; and a process for producing acrylic acid, including a step of carrying out catalytic gas phase oxidation of acrolein with molecular oxygen using the catalyst. The catalyst of the present invention can lower a hot spot temperature and suppress reduction in a reaction efficacy accompanied with thermal degradation, so that the acrolein conversion can stably be kept higher over a long term.
摘要翻译：提供了一种用分子氧催化气相氧化丙烯醛产生丙烯酸的催化剂，该催化剂包括钼和钒，还包括至少一种挥发性催化剂毒成分，其用量为离子浓度为10-100ppb 色谱以及丙烯酸的制造方法，包括使用催化剂进行丙烯醛与分子氧的催化气相氧化的工序。本发明的催化剂可以降低热点温度并抑制伴随热降解的反应效率的降低，使得丙烯醛转化率可以长期稳定地保持较高。

15. 发明授权

US06429332B1 Catalyst for production of acrylic acid and method for production of acrylic acid by the use of the catalyst 失效
标题翻译：用于生产丙烯酸的催化剂和通过使用催化剂生产丙烯酸的方法
公开(公告)号：US06429332B1
公开(公告)日：2002-08-06
申请号：US08456085
申请日：1995-05-31
申请人： Michio Tanimoto , Tatsuya Kawajiri , Hiromi Yunoki , Yukio Aoki
发明人： Michio Tanimoto , Tatsuya Kawajiri , Hiromi Yunoki , Yukio Aoki
IPC分类号： C07C5116
CPC分类号： B01J35/0006 , B01J23/8877 , B01J23/8885 , B01J27/053 , B01J27/188
摘要： A catalyst for the production of acrylic acid by the vapor-phase catalytic oxidation of acrolein or acrolein-containing gas and a method for the production of acrylic acid by the use of this catalyst are provided. The catalyst of this invention comprises (A) a catalyst having Mo and V as essential components and used for the production of acrylic acid by vapor-phase catalytic oxidation of acrolein and (B) a solid acid having acid strength (Ho) of not more than −11.93. Since this catalyst excels in catalytic activity and service life, it allows acrylic acid to be produced stably at a high yield for a long time.
摘要翻译：提供了通过气相催化氧化丙烯醛或含丙烯醛的气体生产丙烯酸的催化剂和通过使用该催化剂生产丙烯酸的方法。本发明的催化剂包括（A）具有Mo和V作为必要成分的催化剂，用于通过丙烯醛的气相催化氧化制备丙烯酸和（B）酸强度（Ho）不大于的固体酸比-11.93。由于该催化剂在催化活性和使用寿命方面优异，因此能够以高产率长时间稳定地制备丙烯酸。

16. 发明申请

US20090005593A1 Catalyst for production of acrylic acid and process for production of acrylic acid using this catalyst 审中-公开
标题翻译：用于生产丙烯酸的催化剂和使用该催化剂生产丙烯酸的方法
公开(公告)号：US20090005593A1
公开(公告)日：2009-01-01
申请号：US12080503
申请日：2008-04-02
申请人： Hiromi Yunoki , Michio Tanimoto
发明人： Hiromi Yunoki , Michio Tanimoto
IPC分类号： C07C57/05 , C01G39/02 , C01G41/02 , C01G31/02 , B01J23/22 , B01J23/28 , B01J23/30 , B01J23/72
CPC分类号： B01J23/002 , B01J23/30 , B01J23/885 , B01J23/8877 , B01J23/8885 , B01J35/0006 , B01J35/002 , B01J35/0073 , B01J35/023 , B01J37/0018 , B01J37/0219 , B01J37/0223 , B01J37/0228 , B01J37/0236 , B01J37/0244 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/17 , B01J2523/55 , B01J2523/68 , B01J2523/69
摘要： An object of the present invention is to provide: a catalyst for production of acrylic acid which catalyst is so high active as to give a still higher selectivity of acrylic acid (which is the objective product) or a long-catalytic-life-time catalyst for production of acrylic acid which catalyst is so high active as to be able to give a high acrylic acid yield while suppressing the temperature rise of the oxidation reaction to a low one; and processes for production of acrylic acid using these catalysts. As a means of achieving this object, a catalyst according to the present invention for production of acrylic acid comprises an oxide and/or a composite oxide as an essential catalytic component, wherein the oxide and/or the composite oxide has a metal element composition shown by general formula (1): MoaVbWcCudOx (1) (wherein: when a=12, then 1≦b≦14, 0≦c≦12, 0≦d≦10, and 0
摘要翻译：本发明的目的是提供：用于制备丙烯酸的催化剂，该催化剂具有如此高的活性，以产生更高的丙烯酸（目标产物）的选择性或长催化寿命催化剂为了生产丙烯酸，该催化剂具有如此高的活性，能够在将氧化反应的温度上升抑制在低温的同时产生高的丙烯酸收率; 以及使用这些催化剂生产丙烯酸的方法。作为实现该目的的手段，根据本发明的用于生产丙烯酸的催化剂包含氧化物和/或复合氧化物作为必需催化组分，其中氧化物和/或复合氧化物具有所示的金属元素组成通过通式（1）：<？in-line-formula description =“In-line Formulas”end =“lead”？> MoaVbWcCudOx（1）<？in-line-formula description =“In-line Formulas”end = “tail”？>（其中：当a = 12时，则1 <= b <= 14,0 <= c <= 12,0 <= d <= 10和0

17. 发明授权

US06632965B1 Process for producing acrolein and acrylic acid 有权
标题翻译：制备丙烯醛和丙烯酸的方法
公开(公告)号：US06632965B1
公开(公告)日：2003-10-14
申请号：US09633292
申请日：2000-08-04
申请人： Michio Tanimoto , Hiromi Yunoki , Hideyuki Hironaka , Naomasa Kimura
发明人： Michio Tanimoto , Hiromi Yunoki , Hideyuki Hironaka , Naomasa Kimura
IPC分类号： C07C5116
CPC分类号： C07C51/252 , B01J23/002 , B01J23/8876 , B01J23/8885 , B01J2523/00 , C07C45/35 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/847
摘要： The present invention provides a process for producing acrolein and acrylic acid by the vapor-phase oxidation of propylene in the presence of Mo—Bi—Fe-based compound oxide catalysts packed in a fixed-bed multitubular reactor wherein acrolein and acrylic acid can be stably produced in high yield for a long period of time. This process is characterized in that each reaction tube having two or more reaction zones disposed along the axis of the tube is packed with catalysts having different ratios of the Bi and/or Fe content to the Mo content in such a way that the ratio decreases from the gas inlet side toward the gas outlet side.
摘要翻译：本发明提供了一种在填充在固定床多管反应器中的Mo-Bi-Fe系复合氧化物催化剂存在下丙烯气相氧化制备丙烯醛和丙烯酸的方法，其中丙烯醛和丙烯酸可以稳定地长期以高产量生产。该方法的特征在于，具有沿着管轴设置的两个或更多反应区的每个反应管装填有具有不同比例的Bi和/或Fe含量与Mo含量的催化剂，使得该比例从气体入口侧朝向气体出口侧

18. 发明授权

US07378367B2 Catalyst for production of acrylic acid and process for production of acrylic acid using the catalyst 有权
标题翻译：用于生产丙烯酸的催化剂和使用催化剂生产丙烯酸的方法
公开(公告)号：US07378367B2
公开(公告)日：2008-05-27
申请号：US11078680
申请日：2005-03-11
申请人： Hiromi Yunoki , Michio Tanimoto
发明人： Hiromi Yunoki , Michio Tanimoto
IPC分类号： B01J23/00 , C07C51/235
CPC分类号： B01J23/002 , B01J23/30 , B01J23/885 , B01J23/8877 , B01J23/8885 , B01J35/0006 , B01J35/002 , B01J35/0073 , B01J35/023 , B01J37/0018 , B01J37/0219 , B01J37/0223 , B01J37/0228 , B01J37/0236 , B01J37/0244 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/17 , B01J2523/55 , B01J2523/68 , B01J2523/69
摘要： A catalyst for production of acrylic acid which catalyst is so high in activity as to give a still higher selectivity of acrylic acid or a long-catalytic-life-time catalyst for production of acrylic acid which catalyst is so high in activity as to be able to give a high acrylic acid yield while suppressing the temperature rise of the oxidation reaction to a low one; and processes for production of acrylic acid using these catalysts. The catalyst includes an oxide and/or a composite oxide as an essential catalytic component, wherein the oxide and/or the composite oxide has a metal element composition shown by general formula (1): MoaVbWcCudOx (1) (wherein: when a=12, then 1≦b≦14, 0≦c≦12, 0 ≦d≦10, and 0
摘要翻译：用于生产丙烯酸的催化剂，其催化剂具有如此高的活性以提供丙烯酸的更高选择性或用于生产丙烯酸的长催化寿命催化剂，该催化剂的活性如此高得到高的丙烯酸收率，同时将氧化反应的温度升高抑制到较低的一个; 以及使用这些催化剂生产丙烯酸的方法。催化剂包括作为必需催化组分的氧化物和/或复合氧化物，其中氧化物和/或复合氧化物具有通式（1）所示的金属元素组成：<？在线配方说明=“In 线公式“end =”lead“？> Mo _{a （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>（其中：当a = 12时，则1 <= b <= 14,0 < = c <= 12,0 <= d <= 10，0}

19. 发明授权

US07030269B2 Catalyst and process for production of acrylic acid 失效
标题翻译：用于生产丙烯酸的催化剂和方法
公开(公告)号：US07030269B2
公开(公告)日：2006-04-18
申请号：US10684285
申请日：2003-10-13
申请人： Hiromi Yunoki , Michio Tanimoto
发明人： Hiromi Yunoki , Michio Tanimoto
IPC分类号： C07C51/232
CPC分类号： C07C51/252 , B01J21/12 , B01J23/002 , B01J23/8877 , B01J37/0018 , B01J37/0223 , B01J2523/00 , C07C57/04 , B01J2523/17 , B01J2523/55 , B01J2523/68 , B01J2523/69
摘要： There are disclosed: a catalyst which can be used for production of acrylic acid and is excellent in the catalytic performances (e.g. conversion of starting material, selectivity of aimed product) and further has very high physical strength; and a process for production of acrylic acid using this catalyst. The above catalyst for production of acrylic acid is a catalyst which is obtained by a process including the steps of: heating a mixed liquid of starting materials including molybdenum and vanadium as essential components; and then molding the resultant dried material with a liquid binder; and then calcining the resultant molding; with the catalyst being characterized in that the liquid binder is an aqueous liquid of 7.0 to 10.0 in pH. The above process for production of acrylic acid is a process which comprises the step of carrying out catalytic gas phase oxidation of acrolein in the presence of molecular oxygen, thereby producing the acrylic acid; with the process being characterized by using the above catalyst for production of acrylic acid according to the present invention.
摘要翻译：公开了可用于生产丙烯酸的催化剂，催化性能（例如起始原料的转化，目标产物的选择性）优异，并且还具有非常高的物理强度; 以及使用该催化剂生产丙烯酸的方法。上述用于制备丙烯酸的催化剂是通过包括以下步骤的方法获得的催化剂：将包含钼和钒的原料的混合液作为必要成分加热; 然后用液体粘合剂将得到的干燥材料成型; 然后煅烧所得成型品; 催化剂的特征在于液体粘合剂是pH为7.0至10.0的水性液体。上述丙烯酸的制造方法是在分子氧的存在下进行丙烯醛的催化气相氧化的工序，由此生成丙烯酸; 该方法的特征在于使用上述催化剂制备本发明的丙烯酸。

20. 发明申请

US20050215818A1 Catalyst for production of acrylic acid and process for production of acrylic acid using this catalyst 有权
标题翻译：用于生产丙烯酸的催化剂和使用该催化剂生产丙烯酸的方法
公开(公告)号：US20050215818A1
公开(公告)日：2005-09-29
申请号：US11078680
申请日：2005-03-11
申请人： Hiromi Yunoki , Michio Tanimoto
发明人： Hiromi Yunoki , Michio Tanimoto
IPC分类号： B01J23/00 , B01J23/30 , B01J23/885 , B01J23/887 , B01J23/888 , B01J35/00 , B01J35/02 , B01J37/00 , B01J37/02 , C07C51/25 , C07C51/16 , C08F2/00
CPC分类号： B01J23/002 , B01J23/30 , B01J23/885 , B01J23/8877 , B01J23/8885 , B01J35/0006 , B01J35/002 , B01J35/0073 , B01J35/023 , B01J37/0018 , B01J37/0219 , B01J37/0223 , B01J37/0228 , B01J37/0236 , B01J37/0244 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/17 , B01J2523/55 , B01J2523/68 , B01J2523/69
摘要： An object of the present invention is to provide: a catalyst for production of acrylic acid which catalyst is so high active as to give a still higher selectivity of acrylic acid (which is the objective product) or a long-catalytic-life-time catalyst for production of acrylic acid which catalyst is so high active as to be able to give a high acrylic acid yield while suppressing the temperature rise of the oxidation reaction to a low one; and processes for production of acrylic acid using these catalysts. As a means of achieving this object, a catalyst according to the present invention for production of acrylic acid comprises an oxide and/or a composite oxide as an essential catalytic component, wherein the oxide and/or the composite oxide has a metal element composition shown by general formula (1): MoaVbWcCudOx (1) (wherein: when a=12, then 1≦b≦14, 0≦c≦12, 0≦d≦10, and 0
摘要翻译：本发明的目的是提供：用于制备丙烯酸的催化剂，该催化剂具有如此高的活性，以产生更高的丙烯酸（目标产物）的选择性或长催化寿命催化剂为了生产丙烯酸，该催化剂具有如此高的活性，能够在将氧化反应的温度上升抑制在低温的同时产生高的丙烯酸收率; 以及使用这些催化剂生产丙烯酸的方法。作为实现该目的的手段，根据本发明的用于生产丙烯酸的催化剂包含氧化物和/或复合氧化物作为必需催化组分，其中氧化物和/或复合氧化物具有所示的金属元素组成通过通式（1）：<？in-line-formula description =“In-line formula”end =“lead”？> Mo _{a （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>（其中：当a = 12时，则1 <= b <= 14,0 <= c <= 12,0 <= d <= 10和0}

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