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11. 发明授权

US07060829B2 Colorant compounds containing copolymerizable vinyl groups 失效
公开(公告)号：US07060829B2
公开(公告)日：2006-06-13
申请号：US10654175
申请日：2003-09-03
申请人： Michael John Cyr , Max Allen Weaver , Gerry Foust Rhodes , Jason Clay Pearson , Phillip Michael Cook
发明人： Michael John Cyr , Max Allen Weaver , Gerry Foust Rhodes , Jason Clay Pearson , Phillip Michael Cook
IPC分类号： C07D401/12 , C07D249/12
CPC分类号： C09B69/109 , C08F246/00 , C08F290/06 , C08F290/14 , C09B69/101 , C09B69/105 , C09B69/106
摘要： Disclosed are novel colorant compounds which contain one or more ethylenically-unsaturated (vinyl), photopolymerizable radicals which may be copolymewrized (or cured) with ethylenically-unsaturated monomers to produce colored compositions such as colored acrylic coatings and polymers, e.g., coatings and polymers produced from acrylate and methacrylate esters, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The present invention also pertains to processes for the preparation of certain of the photopolymerizable colorant compounds.

12. 发明授权

US06727372B2 Colorant compounds containing copolymerizable vinyl groups 失效
公开(公告)号：US06727372B2
公开(公告)日：2004-04-27
申请号：US09920904
申请日：2001-08-02
申请人： Michael John Cyr , Max Allen Weaver , Gerry Foust Rhodes , Jason Clay Pearson , Phillip Michael Cook
发明人： Michael John Cyr , Max Allen Weaver , Gerry Foust Rhodes , Jason Clay Pearson , Phillip Michael Cook
IPC分类号： C09B116
CPC分类号： C09B69/109 , C08F246/00 , C08F290/06 , C08F290/14 , C09B69/101 , C09B69/105 , C09B69/106
摘要： Disclosed are novel colorant compounds which contain one or more ethylenically-unsaturated (vinyl), photopolymerizable radicals which may be copolymewrized (or cured) with ethylenically-unsaturated monomers to produce colored compositions such as colored acrylic coatings and polymers, e.g., coatings and polymers produced from acrylate and methacrylate esters, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The present invention also pertains to processes for the preparation of certain of the photopolymerizable colorant compounds.

13. 发明授权

US06174400B1 Near infrared fluorescent security thermal transfer printing and marking ribbons 失效
标题翻译：近红外荧光安全热转印和标记丝带
公开(公告)号：US06174400B1
公开(公告)日：2001-01-16
申请号：US08811311
申请日：1997-03-04
申请人： James John Krutak, Sr. , Michael John Cyr , Nelson Zamora Escano , Horst Clauberg , Barbara Crawford Jackson , Tony Wayne Helton
发明人： James John Krutak, Sr. , Michael John Cyr , Nelson Zamora Escano , Horst Clauberg , Barbara Crawford Jackson , Tony Wayne Helton
IPC分类号： B41M526
CPC分类号： B41M5/465 , B41M3/14 , B41M3/144 , B41M5/385 , G06K1/121 , G07D7/00 , Y10S428/913 , Y10S428/914
摘要： The present invention relates to thermal transfer ribbons comprising a ribbon backing element and at least one printing media layer comprising at least one near infrared fluorescent compound in a concentration which provides detectable fluorescence without imparting color to a mark made from said printing media layer. Methods for printing marks containing said at least one near infrared fluorescent compounds via thermal transfer and methods for reading said marks are also disclosed.
摘要翻译：本发明涉及包含带状背衬元件的热转印带和至少一种包含至少一种近红外荧光化合物的印刷介质层，其浓度可提供可检测的荧光，而不会对由所述印刷介质层制成的标记赋予颜色。还公开了通过热转印印刷含有所述至少一种近红外荧光化合物的标记的方法和用于读取所述标记的方法。

14. 发明授权

US06777479B1 Polyamide nanocomposites with oxygen scavenging capability 失效
标题翻译：具有除氧能力的聚酰胺纳米复合材料
公开(公告)号：US06777479B1
公开(公告)日：2004-08-17
申请号：US09630517
申请日：2000-08-02
申请人： Linda Gail Bernard , Horst Clauberg , Michael John Cyr , John Walker Gilmer , Jeffrey Todd Owens , Mark Edward Stewart , Sam Richard Turner , Shriram Bagrodia , James Christopher Matayabas, Jr.
发明人： Linda Gail Bernard , Horst Clauberg , Michael John Cyr , John Walker Gilmer , Jeffrey Todd Owens , Mark Edward Stewart , Sam Richard Turner , Shriram Bagrodia , James Christopher Matayabas, Jr.
IPC分类号： C08K334
CPC分类号： B82Y30/00 , C08J5/005 , C08J2377/00 , C08K3/34 , C08K7/00 , C08K2201/008 , C08L77/00
摘要： Polymer composite materials comprising of least one polymer resin and platelet particles from at least one layered silicate material uniformly dispersed in the resin and articles prepared from the polymer composite materials. The polymer composite contains at least one polyamide resin, at least one oxygen scavenging system, and at least one layered silicate material. These polymer composite materials are especially useful for manufacturing clear polyester bottles and polyester film that are recyclable have improved active gas barrier properties to oxygen, and have improved passive barrier properties to carbon dioxide and other gases. The polymer composite materials can be used in relatively minor amounts as either a blend or a coextruded thin layer with virgin or post consumer recycled polyesters and related copolymners.
摘要翻译：包含至少一种聚合物树脂的聚合物复合材料和均匀分散在树脂中的至少一种层状硅酸盐材料的片晶颗粒和由聚合物复合材料制备的制品。聚合物复合材料含有至少一种聚酰胺树脂，至少一种除氧系统和至少一种层状硅酸盐材料。这些聚合物复合材料特别可用于制造可再循环的透明聚酯瓶和聚酯膜，其具有改善的对氧的活性气体阻隔性能，并且具有改善的对二氧化碳和其它气体的被动阻挡性能。聚合物复合材料可以以相对小的量用作共混物或共挤出的薄层，其具有原始或消费后的再生聚酯和相关共聚物。

15. 发明授权

US6138913A Security document and method using invisible coded markings 失效
标题翻译：安全文件和使用隐形编码标记的方法
公开(公告)号：US6138913A
公开(公告)日：2000-10-31
申请号：US981859
申请日：1998-01-05
申请人： Michael John Cyr , James John Krutak, Sr. , Horst Clauberg , Tony Wayne Helton
发明人： Michael John Cyr , James John Krutak, Sr. , Horst Clauberg , Tony Wayne Helton
IPC分类号： G06K19/14 , G06K7/10
CPC分类号： G06K19/14
摘要： An invisible indicia or encoded information is imprinted on a substrate using a compound which produces a fluorescence at a wavelength greater than about 650 nm when exposed to near infrared radiation. The information covered by a layer of material that reflects or absorbs a substantial amount of the visible and UV radiation illuminating its surface.
摘要翻译： PCT No.PCT / US97 / 20342 Sec。 371日期：1998年1月5日 102（e）日期1998年1月5日PCT 1997年11月5日PCT公布。第WO98 / 22291号公报日期1998年5月28日当暴露于近红外辐射时，使用产生大于约650nm的波长的荧光的化合物将无形标记或编码信息印在底物上。由材料层覆盖的信息，其反射或吸收大量可见光和UV辐射照射其表面。

16. 发明授权

US6099930A Methods for marking digital compact discs as a means to determine its authenticity 失效
标题翻译：将数字光盘标记为确定其真实性的方法
公开(公告)号：US6099930A
公开(公告)日：2000-08-08
申请号：US11805
申请日：1998-07-20
申请人： Michael John Cyr , Horst Clauberg , Tony Wayne Helton , Gregory W. Nelson , Randy B. Meade , James E. Moore , G. Russell Owens , Barbara C. Jackson , James John Krutak, Sr.
发明人： Michael John Cyr , Horst Clauberg , Tony Wayne Helton , Gregory W. Nelson , Randy B. Meade , James E. Moore , G. Russell Owens , Barbara C. Jackson , James John Krutak, Sr.
IPC分类号： G11B7/24 , G11B7/244 , G11B7/246 , G11B7/248 , G11B7/253 , G11B7/2531 , G11B7/2533 , G11B7/2534 , G11B7/2535 , G11B7/2542 , G11B7/2585 , G11B7/26 , G11B23/28 , G11B23/40 , B32B3/00
CPC分类号： G11B23/281 , G11B23/40 , G11B7/24 , G11B7/244 , G11B7/245 , G11B7/248 , G11B7/253 , G11B7/2542 , G11B7/2585 , G11B7/26 , G11B2007/24624 , G11B7/2531 , G11B7/2533 , G11B7/2534 , G11B7/2535 , Y10S428/913 , Y10S430/146 , Y10T428/21
摘要： A digital recording medium, such as a compact disc, having a substrate, a reflective layer and a protective layer includes a near infrared fluorophore in one of the layers. The near infrared fluorophore can be incorporated into the CD by coating, admixing, blending or copolymerization and in an amount to impart a detectable fluorescence from the fluorophore when exposed to electromagnetic radiation having a wavelength ranging from about 670 nanometers (nm) to about 1100 nm. A method of marking a CD with an invisible marking and an apparatus for detecting the fluorophore is further provided.
摘要翻译： PCT No.PCT / US97 / 23265 Sec。 371日期：1998年7月20日 102（e）1998年7月20日PCT PCT 1997年12月15日PCT公布。公开号WO98 / 29238 日期1998年7月9日具有基板，反射层和保护层的诸如光盘的数字记录介质包括一层中的近红外荧光团。通过涂布，混合，共混或共聚，可以将近红外荧光团掺入到CD中，并且当暴露于波长范围为约670纳米（nm）至约1100nm）的电磁辐射时，能够使荧光团发出可检测的荧光。还提供了用不可见标记标记CD的方法和用于检测荧光团的装置。

17. 发明授权

US5959296A Scanners for reading near infrared fluorescent marks 失效
标题翻译：用于阅读近红外荧光标记的扫描仪
公开(公告)号：US5959296A
公开(公告)日：1999-09-28
申请号：US880037
申请日：1997-06-20
申请人： Michael John Cyr , James John Krutak, Sr. , Horst Clauberg , Randy Barnett Meade , James Edward Moore , Gabor Patonay
发明人： Michael John Cyr , James John Krutak, Sr. , Horst Clauberg , Randy Barnett Meade , James Edward Moore , Gabor Patonay
IPC分类号： G02B6/38 , G06K7/12 , G06K7/10
CPC分类号： G06K7/12 , G02B6/3861 , G02B6/3862 , G02B6/3887
摘要： An apparatus for detecting an invisible, near infrared fluorescing mark disposed on a background comprises: includes an excitation source for exciting the mark, having sufficient power to excite the mark and provide a fluorescent signal the mark from a; a signal detector for detecting the fluorescent signal from the mark; a and power modulator means for varying the power if the excitation source between zero and the maximum power level to produce a decodable fluorescent signal from the mark disposed on the background. A process for decoding an invisible mark having a near infrared fluorescing material includes the steps of: providing at least one invisible, near infrared fluorescing mark disposed on at least one portion of a background; exciting the mark with a laser having a maximum power level sufficient to provide a fluorescent signal from the mark; detecting the fluorescent signal and concurrently varying the power of the laser between zero and its maximum power, to obtain a decodable fluorescent signal.
摘要翻译：用于检测设置在背景上的不可见的近红外荧光标记的装置包括：包括用于激发标记的激励源，具有足够的功率来激发标记并从a提供标记的荧光信号; 用于从标记检测荧光信号的信号检测器; a和功率调制器装置，用于如果激励源在零和最大功率水平之间改变功率，以从设置在背景上的标记产生可解码的荧光信号。用于解码具有近红外荧光材料的不可见标记的方法包括以下步骤：提供设置在背景的至少一部分上的至少一个不可见的近红外荧光标记; 使用具有足以提供来自标记的荧光信号的最大功率电平的激光器来激发标记; 检测荧光信号并同时改变激光器在0和最大功率之间的功率，以获得可解码的荧光信号。

18. 发明授权

US06610772B1 Platelet particle polymer composite with oxygen scavenging organic cations 失效
标题翻译：具有清除有机阳离子的血小板聚合物复合物
公开(公告)号：US06610772B1
公开(公告)日：2003-08-26
申请号：US09630518
申请日：2000-08-02
申请人： Horst Clauberg , Michael John Cyr , Robert Boyd Barbee , Tony Wayne Helton
发明人： Horst Clauberg , Michael John Cyr , Robert Boyd Barbee , Tony Wayne Helton
IPC分类号： C08K334
CPC分类号： B82Y30/00 , C08J5/005 , C08K5/0091 , C08K5/098 , C08K9/04
摘要： The present invention relates to oxygen scavenging compositions comprising a) platelet particles having attached thereto at least one oxygen scavenging organic cation and b) at least one oxidation catalyst. The oxygen scavenging compositions of the present invention maybe readily incorporated into a variety of matrix polymers to create polymer composites, which display improved passive barrier and oxygen scavenging capabilities. Articles formed from these composites are also disclosed.
摘要翻译：本发明涉及除氧组合物，其包含a）附着有至少一种除氧有机阳离子的b）至少一种氧化催化剂的血小板颗粒。本发明的除氧组合物可以容易地并入各种基质聚合物中以产生聚合物复合材料，其显示改进的被动屏障和除氧能力。还公开了由这些复合材料形成的制品。

19. 发明授权

US06455620B1 Polyether containing polymers for oxygen scavenging 失效
标题翻译：用于除氧的聚醚聚合物
公开(公告)号：US06455620B1
公开(公告)日：2002-09-24
申请号：US09630519
申请日：2000-08-02
申请人： Michael John Cyr , Horst Clauberg , Mark Edward Stewart , Stephen Neal Falling , Martin Emerson Rogers
发明人： Michael John Cyr , Horst Clauberg , Mark Edward Stewart , Stephen Neal Falling , Martin Emerson Rogers
IPC分类号： C08K506
CPC分类号： C08L71/02 , C08G63/672 , C08K5/098 , C08K2201/012 , C08L67/02
摘要： The present invention relates to oxygen scavenging compositions comprising an oxidation catalyst and at least one polyether selected from the group consisting of unsubstituted poly(alkylene glycol)s having alkylene chains of 1 to 3 carbon atoms, substituted or unsubstituted poly(alkylene glycol)s having alkylene chains of at least 4 carbon atoms, copolymers of poly(alkylene glycol)s, blends containing poly(alkylene glycol)s and mixtures thereof. The invention further relates to polymers containing said oxygen scavenging compounds and articles made therefrom.
摘要翻译：本发明涉及包含氧化催化剂和至少一种选自具有1至3个碳原子的亚烷基链的未取代的聚（亚烷基二醇），取代或未取代的聚（亚烷基二醇）的聚醚的氧清除组合物，其具有至少4个碳原子的亚烷基链，聚（亚烷基二醇）的共聚物，含有聚（亚烷基二醇）的共混物及其混合物。本发明还涉及含有所述除氧化合物和由其制成的制品的聚合物。

20. 发明授权

US06221279B1 Pigment particles for invisible marking applications 失效
标题翻译：用于不可见标记应用的颜料颗粒
公开(公告)号：US06221279B1
公开(公告)日：2001-04-24
申请号：US09339125
申请日：1999-06-24
申请人： Marc Alan Strand , Crystal Leigh Kendrick , Michael John Cyr
发明人： Marc Alan Strand , Crystal Leigh Kendrick , Michael John Cyr
IPC分类号： C09K1106
CPC分类号： C09K11/02 , C09D5/22 , C09K11/06
摘要： A pigment composition includes a crystalline thermoplastic polyester resin having residues of at least one dicarboxylic acid and a near-infrared fluorescing compound having a fluorescence between about 650 nm to about 2500 nm associated with the crystalline thermoplastic polyester, wherein the polyester has an intrinsic viscosity (IV) of less than about 0.37. A preferred polyester is polybutylene terephthalate. Another aspect is a method for providing a detectable or identifiable marking that is invisible to the unaided eye on a surface of a substrate is also provided. The method includes the steps of applying to the surface a marking composition comprising a suitably compatible marking fluid containing the fluorescent pigment composition. The near infrared fluorescing pigment composition is useful in letterpress, flexographic and gravure printing applications.
摘要翻译：颜料组合物包括具有至少一种二羧酸残基的结晶热塑性聚酯树脂和具有与结晶热塑性聚酯相关的约650nm至约2500nm之间的荧光的近红外荧光化合物，其中该聚酯具有特性粘度（ IV）小于约0.37。优选的聚酯是聚对苯二甲酸丁二醇酯。还提供了一种用于提供在基底表面上对肉眼不可见的可检测或可识别标记的方法。该方法包括以下步骤：向表面施加包含含有荧光颜料组合物的适当兼容的标记液的标记组合物。近红外荧光颜料组合物可用于凸版，柔版印刷和凹版印刷应用。

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