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    • 13. 发明授权
    • Ion-exchangeable phosphate glass compositions and strengthened optical
quality glass articles
    • 可离子交换的磷酸盐玻璃组合物和增强的光学质量玻璃制品
    • US5164343A
    • 1992-11-17
    • US703962
    • 1991-05-22
    • John D. Myers
    • John D. Myers
    • C03C3/17
    • C03C3/17
    • Ion-exchangeable phosphate glass compositions containing in mole percent from about 50 to 70% P.sub.2 O.sub.5, from about 5 to 30% Li.sub.2 O, from about 5 to 25% MO, where M is selected from the group consisting of Be, Mg, Ca, Sr, Ba, and Zn, and about 5 to 30% X.sub.2 O.sub.3, where X is selected from the group consisting of Al, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu are provided. In another aspect, the phosphate glass compositions of the present invention also contain in mole percent up to 10% R.sub.2 O, where R is selected from the group consisting of Na, K, Rb and Cs. Solarization inhibitors and minor amounts of anhydrous fluorides and chlorides are also included in some embodiments. Optical quality phosphate glass articles formed of the phosphate glass compositions of the present invention are readily ion- exchangeable when contacted with certain salts. Optical quality phosphate glass articles are also provided having good thermal shock resistance. These glass articles have an inner tension region and an outer compressive surface layer formed using an ion exchange process. In some embodiments, laser rods and similar active optical elements are formed from the strengthened phosphate glass articles of the present invention where the optical elements are doped with an amount of a suitable dopant effective for laser activity.
    • 可离子交换的磷酸盐玻璃组合物,其含有摩尔百分数为约50至70%的P2O5,约5至30%的Li2O,约5至25%的MO,其中M选自Be,Mg,Ca,Sr ,Ba和Zn以及约5〜30%的X2O3,其中X选自Al,Y,La,Ce,Pr,Nd,Pm,Sm,Eu,Gd,Tb,Dy,Ho,Er ,Tm,Yb和Lu。 另一方面,本发明的磷酸盐玻璃组合物还含有多至10%的R 2 O,其中R选自Na,K,Rb和Cs。 在一些实施方案中还包括减光剂和少量的无水氟化物和氯化物。 由本发明的磷酸盐玻璃组合物形成的光学质量磷酸盐玻璃制品在与某些盐接触时容易离子交换。 还提供具有良好耐热冲击性的光学品质磷酸盐玻璃制品。 这些玻璃制品具有内部张力区域和使用离子交换工艺形成的外部压缩表面层。 在一些实施例中,激光棒和类似的有源光学元件由本发明的加强的磷酸盐玻璃制品形成,其中光学元件掺杂一定量的适合于激光活性的掺杂剂。
    • 14. 发明授权
    • Sensitized laser glass
    • 敏化激光玻璃
    • US4770811A
    • 1988-09-13
    • US714737
    • 1985-03-22
    • John D. Myers
    • John D. Myers
    • C03C3/17C03C4/00C03C3/16
    • C03C4/0071C03C3/17
    • A sensitized laser glass which includes a primary lasing dopant and auxiliary dopants which absorb in regions of the flashlamp emission spectrum away from the absorption bans of the primary dopant and transfer the energy absorbed to the primary dopant, thus improving the efficiency and sensitivity of the laser glass. The auxiliary dopant comprises the combination of cerium and chromium as Ce.sub.2 O.sub.3 and Cr.sub.2 O.sub.3 and the primary dopant is a rare earth metal, preferably neodymium or erbium as Nd.sub.2 O.sub.3 or Er.sub.2 O.sub.3. Th auxiliary dopant consists essentially of 0.1 to 5% by weight Ce.sub.2 O.sub.3 and 0.025 to 0.1% by weight Cr.sub.2 O.sub.3, however the preferred concentration of the auxiliary dopant is 2 to 4% by weight Ce.sub.2 O.sub.3 plus 0.03 to 0.07% by weight Cr.sub.2 O.sub.3. The experimental data establishes that such auxiliary dopants are particularly suitable for phosphate laser glasses.
    • 敏化激光玻璃,其包括初级激光掺杂剂和辅助掺杂剂,其在闪光发射光谱的区域中吸收远离主要掺杂剂的吸收抑制并将吸收的能量转移到主要掺杂剂,从而提高激光器的效率和灵敏度 玻璃。 辅助掺杂剂包括作为Ce 2 O 3和Cr 2 O 3的铈和铬的组合,并且主要掺杂剂是稀土金属,优选作为Nd 2 O 3或Er 2 O 3的钕或铒。 辅助掺杂剂基本上由0.1至5重量%的Ce 2 O 3和0.025至0.1重量%的Cr 2 O 3组成,然而辅助掺杂剂的优选浓度为2至4重量%的Ce 2 O 3加0.03至0.07重量%的Cr 2 O 3。 实验数据表明,这种辅助掺杂剂特别适用于磷酸盐激光眼镜。
    • 15. 发明授权
    • Laser device and method
    • 激光装置及方法
    • US4601288A
    • 1986-07-22
    • US703963
    • 1985-02-21
    • John D. Myers
    • John D. Myers
    • A61B18/00A61F9/007A61F9/011A61F9/02H01S3/02H01S3/092H01S3/113A61B17/36
    • H01S3/025A61F9/00736A61F9/00825H01S3/093H01S3/113A61B2018/00083A61F2009/0087A61F2009/00887A61F9/022
    • A simplified, relatively inexpensive laser device, wherein the laser elements are fixed in a body exoskeleton of electrical insulating material having a low coefficient of thermal expansion. The preferred embodiment includes a shotgun type laser filter having parallel bores which receive the laser flashlamp and laser rod in fixed relation in a body chamber. The reflector surrounds the laser filter and retains the filter within the body chamber. In the preferred method of this invention, several controlled lasing pulses are generated with each illumination pulse of the flashlamp, substantially increasing the efficiency of the laser device. The number of pulses is generally controlled by increasing the voltage to the flashlamp. The rapid multiple lasing pulses generate an elongated plasma in a fluid medium, such as the vitreous fluid body of an eye which makes the laser device extremely efficient for treating glaucoma and other medical treatments.
    • 一种简化的,相对便宜的激光装置,其中激光元件被固定在具有低热膨胀系数的电绝缘材料的身体外骨骼中。 优选实施例包括具有平行孔的霰弹枪型激光滤光器,其在体腔中接收固定关系的激光闪光灯和激光棒。 反射器围绕激光过滤器并将过滤器保持在体腔内。 在本发明的优选方法中,利用闪光灯的每个照明脉冲产生几个受控的激光脉冲,从而大大提高了激光装置的效率。 脉冲数通常通过增加闪光灯的电压来控制。 快速多重激光脉冲在流体介质(例如眼睛的玻璃体液体)中产生细长的等离子体,这使得激光装置对于治疗青光眼和其它医疗治疗非常有效。
    • 16. 发明申请
    • Non-Invasive In-Situ Detection Of Malignant Skin Tissue And Other Abnormalities Using Laser Plasma Spectroscopy
    • 使用激光等离子体光谱法对恶性皮肤组织和其他异常的非侵入性原位检测
    • US20080269618A1
    • 2008-10-30
    • US12110528
    • 2008-04-28
    • Michael J. MyersJohn D. MyersJeffrey A. MyersAbbey G. Myers
    • Michael J. MyersJohn D. MyersJeffrey A. MyersAbbey G. Myers
    • A61B6/00A61B10/02
    • A61B5/0062A61B5/0075A61B5/444
    • Disclosed is a system and method for a non-invasive method for determining the presence or absence of cancerous cells in the skin and deeper tissue levels. The system includes a portable handheld laser coupled with a spectroscopy system to produce real-time material analysis of the presence of cancerous cells without sample preparation. The system focuses a high peak power laser pulse onto a targeted material to produce a laser spark or micro-plasma. Elemental line spectra emission is created, collected and analyzed by a spectrophotometer. The line spectra emission data is quickly displayed on a laptop computer. “Eye-safe” Class I lasers provide for practical in-situ laser plasma spectroscopy applications such as detection of cancerous skin tissues. The emission data can be used to detect changes in the levels of a series of elements that are associated with cancerous cells versus normal skin cells. The system also finds use during excisional biopsy procedures to ensure that all cancerous cells have been removed.
    • 公开了用于确定皮肤和深层组织水平中癌细胞存在或不存在的非侵入性方法的系统和方法。 该系统包括与光谱系统耦合的便携式手持式激光器,以在没有样品制备的情况下产生癌细胞的存在的实时材料分析。 该系统将高峰值功率激光脉冲聚焦到目标材料上以产生激光火花或微等离子体。 通过分光光度计产生,收集和分析元素线谱发射。 线谱发射数据快速显示在笔记本电脑上。 “眼睛安全”I类激光器提供实际的原位激光等离子体光谱应用,例如检测癌性皮肤组织。 发射数据可用于检测与癌细胞相对于正常皮肤细胞相关的一系列元件的水平的变化。 该系统还可以在切除活检过程中使用,以确保所有的癌细胞已被去除。
    • 17. 发明授权
    • Fiber laser with cladding-to-core energy migration
    • 具有包层到核心能量迁移的光纤激光器
    • US07042915B2
    • 2006-05-09
    • US10433024
    • 2001-12-07
    • John D. MyersMichael J. Myers
    • John D. MyersMichael J. Myers
    • H01S3/30
    • H01S3/06708H01S3/067H01S3/06716H01S3/1698
    • A method of transferring energy in an optical fiber (12) from the fiber's cladding element (16) of the fiber's core element (14) is disclosed. The core element (14) includes an active gain component and an energy migration component, and the cladding element (16), which surrounds the core element (14), includes the energy migration component. The method includes the steps of providing a pump (22) for producting energy and optically coupling the pump with the cladding element (16), such that the energy is absorbed and stored in the cladding element (16) by its energy migration component. A further step includes the active gain component in the core element (14) lasing or providing gain, when the transferring of energy from the cladding element's energy migration component to the core element's energy migration component takes place.
    • 公开了一种从光纤的芯元件(14)的光纤包层元件(16)向光纤(12)传输能量的方法。 核心元件(14)包括有源增益分量和能量迁移组件,并且围绕核心元件(14)的包层元件(16)包括能量迁移组件。 该方法包括以下步骤:提供用于产生能量并将泵与包层元件(16)光学耦合的泵(22),使得能量通过其能量迁移部件被吸收并存储在包层元件(16)中。 当能量从包层元件的能量迁移组件转移到核心元件的能量迁移组件时,另一步骤包括激励或提供增益的核心元件(14)中的有源增益分量。
    • 18. 发明授权
    • Optical fiber laser structure and system based on ASE pumping of cladding element
    • 光纤激光器结构和基于ASE泵浦包层元件的系统
    • US06693924B2
    • 2004-02-17
    • US10070036
    • 2002-06-07
    • John D. MyersMichael J. Myers
    • John D. MyersMichael J. Myers
    • H01S330
    • H01S3/06716H01S3/06708H01S3/06729H01S3/06737H01S3/094007H01S3/094023H01S3/1608H01S3/1611H01S3/1618H01S2301/02H01S2302/00
    • An optical fiber laser structure and system are disclosed. The fiber laser structure includes a core, an inner cladding, and an outer cladding. The core has a first and second end and includes a combination of ytterbium and erbium as a first active gain component. The inner cladding, having a length defined between the first and second ends, surrounds the core. The inner cladding includes neodymium as a second active gain component that is different from the first active gain component. The system includes a pumping source coupled to the inner cladding to provide energy to the neodymium in the inner cladding. Upon being pumped, the neodymium achieves amplified spontaneous emission in the inner cladding along the length between the first and second ends. As a result, energy is efficiently transferred from the neodymium to the combination of the ytterbium and erbium in the core thereby providing laser activity at an eye-safe laser wavelength of 1535 nanometers.
    • 公开了一种光纤激光器结构和系统。 光纤激光器结构包括芯,内包层和外包层。 芯具有第一和第二端,并且包括镱和铒的组合作为第一有源增益分量。 具有限定在第一和第二端之间的长度的内包层围绕芯。 内包层包括钕作为与第一有源增益分量不同的第二有源增益分量。 该系统包括耦合到内包层的泵浦源,以向内包层中的钕提供能量。 在被泵送时,钕在内包层中沿着第一和第二端之间的长度实现放大的自发发射。 结果,能量被有效地从钕转移到核心中的镱和铒的组合中,从而在1535纳米的眼睛安全的激光波长下提供激光活性。
    • 19. 发明授权
    • Ion-exchangeable phosphate glass compositions and strengthened optical
quality glass articles
    • 可离子交换的磷酸盐玻璃组合物和增强的光学质量玻璃制品
    • US4875920A
    • 1989-10-24
    • US128676
    • 1987-12-04
    • John D. Myers
    • John D. Myers
    • C03C3/17
    • C03C3/17
    • Ion-exchangeable phosphate glass compositions containing in mole percent from about 50 to 70% P.sub.2 O.sub.5, from about 5 to 30 % Li.sub.2 O, from about 5 to 25% MO, where M is selected from the group consisting of Be, Mg, Ca, Sr, Ba, and Zn, and about 5 to 30% X.sub.2 O.sub.3, where X is selected from the group consisting of Al, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu are provided. In another aspect, the phosphate glass compositions of the present invention also contain in mole percent up to 10% R.sub.2 O, where R is selected from the group consisting of Na, K, Rb and Cs. Solarization inhibitors and minor amounts of anhydrous fluorides and chlorides are also included in some embodiments. Optical quality phosphate glass articles formed of the phosphate glass compositions of the present invention are readily ion- exchangeable when contacted with certain salts. Optical quality phosphate glass articles are also provided having good thermal shock resistance. These glass articles have an inner tension region and an outer compressive surface layer formed using an ion exchange process. In some embodiments, laser rods and similar active optical elements are formed from the strengthened phosphate glass articles of the present invention where the optical elements are doped with an amount of a suitable dopant effective for laser activity.
    • 可离子交换的磷酸盐玻璃组合物,其含有摩尔百分数为约50至70%的P2O5,约5至30%的Li2O,约5至25%的MO,其中M选自Be,Mg,Ca,Sr ,Ba和Zn以及约5〜30%的X2O3,其中X选自Al,Y,La,Ce,Pr,Nd,Pm,Sm,Eu,Gd,Tb,Dy,Ho,Er ,Tm,Yb和Lu。 另一方面,本发明的磷酸盐玻璃组合物还含有多至10%的R 2 O,其中R选自Na,K,Rb和Cs。 在一些实施方案中还包括减光剂和少量的无水氟化物和氯化物。 由本发明的磷酸盐玻璃组合物形成的光学质量磷酸盐玻璃制品在与某些盐接触时容易离子交换。 还提供具有良好耐热冲击性的光学品质磷酸盐玻璃制品。 这些玻璃制品具有内部张力区域和使用离子交换工艺形成的外部压缩表面层。 在一些实施例中,激光棒和类似的有源光学元件由本发明的加强的磷酸盐玻璃制品形成,其中光学元件掺杂一定量的适合于激光活性的掺杂剂。