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    • 14. 发明申请
    • LEAD-FREE LOW-TEMPERATURE SOLDER
    • 无铅低温焊接机
    • US20100015004A1
    • 2010-01-21
    • US11990518
    • 2006-08-18
    • Minoru Ueshima
    • Minoru Ueshima
    • C22C28/00C22C12/00C22C30/00
    • C22C28/00B23K35/26B23K35/264C22C12/00H05K3/3463
    • A conventional low-temperature solder containing Pb or Cd had problems with respect to environmental pollution. A conventional low-temperature lead-free solder had a liquidus temperature which was too high for low heat resistance parts having a heat resistance temperature of 130° C., or it was brittle or had low mechanical strength. A lead-free low-temperature solder according to the present invention comprises 48-52.5 mass % of In and a balance of Bi, and most of the structure is constituted by a BiIn2 intermetallic compound which is not brittle. Zn or La can be added in order to further improve solderability, and a small amount of P can be added to prevent corrosion at high temperatures and high humidities.
    • 含有Pb或Cd的常规低温焊料在环境污染方面存在问题。 常规的低温无铅焊料的液相线温度对于耐热温度为130℃的低耐热部件而言太高,或者是脆性或机械强度低的。 根据本发明的无铅低温焊料包含48-52.5质量%的In和余量的Bi,并且大部分结构由不脆的BiIn2金属间化合物构成。 可以添加Zn或La以进一步提高可焊性,并且可以加入少量的P以防止在高温和高湿度下的腐蚀。
    • 15. 发明申请
    • Lead-free solder paste
    • 无铅锡膏
    • US20090301606A1
    • 2009-12-10
    • US11920962
    • 2006-05-24
    • Minoru Ueshima
    • Minoru Ueshima
    • B23K35/22
    • H05K3/3484B23K35/0244B23K35/025B23K35/22B23K35/262B23K35/362H05K2201/0215H05K2201/0257
    • In a conventional Sn—Zn based lead-free solder, Zn crystallized to a large size of several tens of micrometers, and it was difficult to suppress the formation of coarse crystallizates and to increase the bonding strength without changing the soldering temperature. There were alloys which improved strength by the addition of a minute amount of a Group 1B metal, but the alloys had an increased melting temperature so that reflow could not be performed with the same temperature profile as for Sn—Pb, so the alloys had advantages and disadvantages.By using a solder paste formed by mixing an ethanol solution containing nanoparticles having a particle diameter of 5-300 nm and containing at least one of Ag, Au, and Cu with a flux and solder powder for an Sn—Zn based lead-free solder paste, the formation of an alloy of Au, Au, or Cu with Zn occurs during soldering, thereby forming fine clusters in the resulting liquid phase of molten solder, and a fine solder structure is obtained following melting.
    • 在常规的Sn-Zn基无铅焊料中,Zn结晶到几十微米的大尺寸,并且难以抑制粗结晶的形成,并且在不改变焊接温度的情况下提高接合强度。 存在通过添加少量1B族金属来提高强度的合金,但是合金具有增加的熔融温度,使得不能以与Sn-Pb相同的温度分布进行回流,因此合金具有优点 和缺点。 通过使用通过将含有粒径为5-300nm并含有Ag,Au和Cu中的至少一种的纳米颗粒的乙醇溶液与用于Sn-Zn基无铅焊料的助焊剂和焊料粉末混合而形成的焊膏 在焊接中发生Au,Au或Cu与Zn的合金的形成,从而在熔融焊料的液相中形成微细的簇,熔融后得到细小的焊料结构。