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    • 12. 发明授权
    • Removal of naphthenic acids in crude oils and distillates
    • 去除原油和馏出物中的环烷酸
    • US5961821A
    • 1999-10-05
    • US49466
    • 1998-03-27
    • Ramesh VaradarajDavid William SavageWilliam Edward Wales
    • Ramesh VaradarajDavid William SavageWilliam Edward Wales
    • C10G19/02C10G21/20C10G29/20C10G17/00
    • C10G29/20C10G19/02C10G21/20C10G2300/203
    • The instant invention is directed to a process for extracting organic acids including naphthenic acids, heavy metals, and sulfur from a starting crude oil comprising the steps of:(a) treating the starting crude oil containing organic acids, heavy metals, and sulfur with an amount of an ethoxylated amine and water under conditions and for a time and at a temperature sufficient to form a water-in-oil emulsion of amine salt wherein said ethoxylated amine has the following formula: ##STR1## where m=1 to 10 and R=C.sub.3 to C.sub.6 hydrocarbon; (b) separating said emulsion of step (a) into a plurality of layers, wherein one of such layers contains a treated crude oil having decreased amounts of organic acids, heavy metals and sulfur;(c) recovering said layer of step (b) containing said treated crude oil having decreased amounts of organic acids, heavy metal and sulfur and layers containing water and ethoxylated amine salt.
    • 本发明涉及从起始原油中提取包括环烷酸,重金属和硫的有机酸的方法,包括以下步骤:(a)用含有机酸,重金属和硫的起始原油用 乙氧基化胺和水的量在足以形成胺盐的油包水乳液的条件和时间和温度下进行,其中所述乙氧基化胺具有下式:其中m = 1〜10,R = C3〜 C6烃; (b)将步骤(a)的所述乳液分离成多个层,其中这些层之一含有具有降低量的有机酸,重金属和硫的经处理的原油; (c)回收含有所述经处理的原油的所述含有有机酸,重金属和硫的量减少的步骤(b)层,以及含有水和乙氧基化胺盐的层。