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11. 发明授权

US08852750B2 Method for the coating of a cellulose material by using a glucan 有权
标题翻译：通过使用葡聚糖涂覆纤维素材料的方法
公开(公告)号：US08852750B2
公开(公告)日：2014-10-07
申请号：US13432760
申请日：2012-03-28
申请人： Mari Granström , Stephan Freyer , Rajan Hollmann , Julia Kristiane Schmidt , Alois Kindler
发明人： Mari Granström , Stephan Freyer , Rajan Hollmann , Julia Kristiane Schmidt , Alois Kindler
IPC分类号： B32B23/04
CPC分类号： C08B37/0024 , C08B37/0003 , C09D105/00 , D21H19/10 , Y02P20/542 , Y10T428/26 , Y10T428/31971 , Y10T428/31975 , Y10T428/31978 , Y10T428/31993
摘要： The present invention is directed to a method for coating a sheet-like cellulose containing material by applying a composition comprising at least one glucan (G), which has a β(beta)-1,3-glycosidically linked main chain and at least one side group having a β(beta)-1,6-glycosidic bond to the main chain, particularly Schizophyllan, and at least one solvent (S), particularly a ionic liquid, on the surface of the sheet-like material.
摘要翻译：本发明涉及一种通过将包含至少一种具有β-（β）-1,3-糖苷连接的主链的至少一种葡聚糖（G）的组合物施用至少包含片状含纤维素材料的方法，在该片状材料的表面上具有与主链特别是裂枝菌烯（β）-1,6-糖苷键（β）-1,6-糖苷键的至少一个溶剂（S），特别是离子液体。

12. 发明授权

US08785154B2 Method for manufacturing an aqueous glucose solution from plants of the Triticeae species 失效
标题翻译：从Triticeae种植物制造葡萄糖水溶液的方法
公开(公告)号：US08785154B2
公开(公告)日：2014-07-22
申请号：US12937554
申请日：2009-04-09
申请人： Matthias Boy , Stephan Freyer , Julia Brodersen
发明人： Matthias Boy , Stephan Freyer , Julia Brodersen
IPC分类号： C12P21/02
CPC分类号： C12P19/02 , A23K10/12 , A23K20/147 , C12P21/00 , C13K1/06
摘要： The present invention relates to a method for manufacturing an aqueous glucose solution from the starch components of Triticeae grains, for example from rye, triticale or in particular wheat grains. The invention also relates to a glucose-based fermentation method for manufacturing organic compounds in which the glucose manufactured for fermentation is produced from the starch components of Triticeae grains by way of a method according to the invention.
摘要翻译：本发明涉及一种由Triticeae颗粒的淀粉组分制备葡萄糖水溶液的方法，例如来自黑麦，黑小麦或特别是小麦籽粒。本发明还涉及一种用于制造有机化合物的葡萄糖基发酵方法，其中通过根据本发明的方法由Triticeae颗粒的淀粉组分制备用于发酵的葡萄糖。

13. 发明申请

US20080318287A1 Fermentative Production of Organic Compounds Using Substances Containing Dextrin 有权
标题翻译：使用含有糊精的物质发酵生产有机化合物
公开(公告)号：US20080318287A1
公开(公告)日：2008-12-25
申请号：US12094646
申请日：2006-11-27
申请人： Matthias Boy , Stephan Freyer
发明人： Matthias Boy , Stephan Freyer
IPC分类号： C12P13/08
CPC分类号： C12P7/26 , C12P7/42 , C12P7/62 , C12P7/6418 , C12P7/6427 , C12P7/6463 , C12P13/00 , C12P13/005 , C12P13/04 , C12P19/14 , C12P19/30 , C12P19/38
摘要： A process for the production of at least one organic compound having at least 3 C atoms or having at least 2 C atoms and at least 1N atom by means of fermentation, comprises the following steps: a1) milling a starch feedstock, thus obtaining a millbase which comprises at least part of the nonstarchy solid constituents of the starch feedstock; a2) suspending the millbase in an aqueous liquid and liquefying the millbase present in the aqueous liquid in the presence of at least one starch-liquefying enzyme, obtaining an aqueous dextrin-containing medium (1) which comprises at least a part of the nonstarchy solid constituents of the starch feedstock; and b) using the aqueous dextrin-containing medium (1) in a fermentation for culturing a microorganism which is capable of overproducing the organic compound; enzymes which hydrolyze the dextrins to monosaccharides being added in an amount of less than 0.001% by weight based on the total weight of the starch feedstock employed, or not at all.
摘要翻译：通过发酵生产具有至少3个C原子或具有至少2个C原子和至少1N原子的至少一种有机化合物的方法包括以下步骤：a1）研磨淀粉原料，从而得到碾磨基其包括淀粉原料的至少部分非淀粉样固体成分; a2）在至少一种淀粉 - 液化酶的存在下，将磨粒悬浮在水性液体中并液化存在于水性液体中的研磨液，得到含有糊精的培养基（1），其含有至少一部分非淀粉样固体淀粉原料成分; 和b）在含有糊精的培养基（1）中用于培养能够过量产生有机化合物的微生物的发酵中; 基于所使用的淀粉原料的总重量，或者根本不加入将糊精水解成单糖的酶的加入量小于0.001重量％。

14. 发明授权

US09206348B2 Process for mineral oil production from mineral oil deposits with high deposit temperature 有权
标题翻译：具有高沉积温度的矿物油矿床生产矿物油的工艺
公开(公告)号：US09206348B2
公开(公告)日：2015-12-08
申请号：US13371880
申请日：2012-02-13
申请人： Sebastian Briechle , Tillmann Faust , Stephan Freyer , Rajan Hollmann , Tobias Käppler , Bernd Leonhardt , Julia Kristiane Schmidt , Benjamin Wenzke , Foppe Visser
发明人： Sebastian Briechle , Tillmann Faust , Stephan Freyer , Rajan Hollmann , Tobias Käppler , Bernd Leonhardt , Julia Kristiane Schmidt , Benjamin Wenzke , Foppe Visser
IPC分类号： C09K8/588
CPC分类号： C09K8/588
摘要： A two-stage process for mineral oil production from mineral oil deposits with a deposit temperature of more than 70° C. and a salinity of 20 000 ppm to 350 000 ppm, in which an aqueous formulation comprising at least one glucan with a β-1,3-glycosidically linked main chain, and side groups β-1,6-glycosidically bonded thereto and having a weight-average molecular weight Mw of 1.5*106 to 25*106 g/mol, are injected into a mineral oil deposit through at least one injection borehole and crude oil is withdrawn from the deposit through at least one production borehole. The aqueous formulation is prepared in two stages, by first preparing an aqueous concentrate of the glucan, and diluting the concentrate on site with water to the use concentration.
摘要翻译：矿物油沉积物的矿物油生产的两阶段工艺，矿物油沉积物的沉积温度高于70℃，盐度为20 000ppm至350 000ppm，其中含有至少一种具有β-葡聚糖的葡聚糖的水性制剂 -1,3糖苷键连接的主链以及重量平均分子量为1.5 * 106〜25 * 106g / mol的重量平均分子量Mw与-1,6-糖基结合的侧基与bgr- 通过至少一个注入井眼沉积，原油通过至少一个生产钻孔从沉积物中排出。通过首先制备葡聚糖的水性浓缩物，并将水浓缩物在水中稀释至使用浓度，分两步制备水性制剂。

15. 发明授权

US08586794B2 5-isopropyl-3-aminomethyl-2-methyl-1-amino-cyclohexane (carvone diamine), and method for the production thereof 失效
标题翻译： 5-异丙基-3-氨基甲基-2-甲基-1-氨基 - 环己烷（葡萄糖酮二胺）及其制备方法
公开(公告)号：US08586794B2
公开(公告)日：2013-11-19
申请号：US13055604
申请日：2009-07-13
申请人： Martin Ernst , Alfred Oftring , Kathrin Wissel-Stoll , Oemer Uensal , Stephan Freyer , Ansgar Gereon Altenhoff , Wolfgang Staffel
发明人： Martin Ernst , Alfred Oftring , Kathrin Wissel-Stoll , Oemer Uensal , Stephan Freyer , Ansgar Gereon Altenhoff , Wolfgang Staffel
IPC分类号： C07C209/00 , C07C211/00 , C08G63/48 , C08G63/91 , C08L67/00 , C08L67/02
CPC分类号： C07C211/36
摘要： The present invention relates to 5-isopropyl-3-aminomethyl-2-methyl-1-aminocyclohexane (carvonediamine) and to a process for preparation thereof by a) reacting carvone with hydrogen cyanide, b) then reacting the carvonenitrile obtained in stage a) with ammonia in the presence of an imine formation catalyst and c) then reacting the carvonenitrile imine-containing reaction mixture obtained in stage b) with hydrogen and ammonia over hydrogenation catalysts.The present invention further relates to the use of carvonediamine as a hardener for epoxy resins, as an intermediate in the preparation of diisocyanates, as a starter in the preparation of polyetherols and/or as a monomer for polyamide preparation.
摘要翻译：本发明涉及5-异丙基-3-氨基甲基-2-甲基-1-氨基环己烷（carvonediamine）及其制备方法，其通过以下步骤：a）使香芹酮与氰化氢反应，b）然后使得a）与氨在亚胺形成催化剂存在下反应，c）然后使步骤b）中得到的含氰腈亚胺的反应混合物与氢气和氨在氢化催化剂上反应。本发明还涉及作为制备二异氰酸酯的中间体，作为制备聚醚类和/或作为聚酰胺制备用单体的起始剂的环氧树脂用硬化剂的用途。

16. 发明授权

US08486669B2 Enzymatic hydrolysis of a cellulose material treated with an ionic liquid 失效
标题翻译：用离子液体处理的纤维素材料的酶水解
公开(公告)号：US08486669B2
公开(公告)日：2013-07-16
申请号：US12523327
申请日：2008-01-22
申请人： Tim Balensiefer , Julia Brodersen , Giovanni D'Andola , Klemens Massonne , Stephan Freyer , Veit Stegmann
发明人： Tim Balensiefer , Julia Brodersen , Giovanni D'Andola , Klemens Massonne , Stephan Freyer , Veit Stegmann
IPC分类号： C12P19/02
CPC分类号： C12P19/02 , Y02E50/16
摘要： A process for preparing glucose from a cellulose material, in which a cellulose-comprising starting material is provided and treated with a liquid treatment medium comprising an ionic liquid whose anions are selected from among polyatomic anions and the cellulose-comprising material which has been treated with the ionic liquid is subjected to an enzymatic hydrolysis, is described.
摘要翻译：一种从纤维素材料制备葡萄糖的方法，其中提供含纤维素原料并用含有离子液体的液体处理介质进行处理，所述液体处理介质的阴离子选自多原子阴离子和已经用对离子液体进行酶水解。

17. 发明申请

US20110033896A1 METHOD FOR MANUFACTURING AN AQUEOUS GLUCOSE SOLUTION FROM PLANTS OF THE TRITICEAE SPECIES 失效
标题翻译：从三叉树种植物制造水果葡萄糖溶液的方法
公开(公告)号：US20110033896A1
公开(公告)日：2011-02-10
申请号：US12937554
申请日：2009-04-09
申请人： Matthias Boy , Stephan Freyer , Julia Brodersen
发明人： Matthias Boy , Stephan Freyer , Julia Brodersen
IPC分类号： C12P21/02 , A23K1/00 , C12P1/00 , C12P19/00 , C12P19/38 , C12P19/30 , C12P19/12 , C12P19/04 , C12P13/04 , C12P13/14 , C12P13/12 , C12P13/08 , C12P17/18 , C12P17/12 , C12P17/02 , C12P13/00 , C12P7/64 , C12P7/40 , C12P7/44 , C12P7/48 , C12P7/46 , C12P7/42 , C12P7/26 , C12P7/02 , C12P5/00 , C07K14/415
CPC分类号： C12P19/02 , A23K10/12 , A23K20/147 , C12P21/00 , C13K1/06
摘要： The present invention relates to a method for manufacturing an aqueous glucose solution from the starch components of Triticeae grains, for example from rye, triticale or in particular wheat grains. The invention also relates to a glucose-based fermentation method for manufacturing organic compounds in which the glucose manufactured for fermentation is produced from the starch components of Triticeae grains by way of a method according to the invention.
摘要翻译：本发明涉及一种由Triticeae颗粒的淀粉组分制备葡萄糖水溶液的方法，例如来自黑麦，黑小麦或特别是小麦籽粒。本发明还涉及一种用于制造有机化合物的葡萄糖基发酵方法，其中通过根据本发明的方法由Triticeae颗粒的淀粉组分制备用于发酵的葡萄糖。

18. 发明申请

US20100081798A1 METHOD FOR PRODUCING GLUCOSE BY ENZYMATIC HYDROLYSIS OF CELLULOSE THAT IS OBTAINED FROM MATERIAL CONTAINING LIGNO-CELLULOSE USING AN IONIC LIQUID THAT COMPRISES A POLYATOMIC ANION 审中-公开
标题翻译：通过使用包含聚阴离子的离子液体从含有LIGNO-纤维素的材料中获得的纤维素的酶促水解产生葡萄糖的方法
公开(公告)号：US20100081798A1
公开(公告)日：2010-04-01
申请号：US12523740
申请日：2008-01-22
申请人： Tim Balensiefer , Hartwig Schroeder , Stephan Freyer , Giovanni D'Andola , Klemens Massonne
发明人： Tim Balensiefer , Hartwig Schroeder , Stephan Freyer , Giovanni D'Andola , Klemens Massonne
IPC分类号： C12P19/02 , C07H3/02 , C07G1/00
CPC分类号： C12P19/02 , Y02E50/16
摘要： The present invention relates to a process for preparing glucose from a lignocellulose-comprising starting material, in which this is firstly treated with an ionic liquid and subsequently subjected to an enzymatic hydrolysis. The invention further relates to a process for preparing microbial metabolites, especially ethanol, in which the glucose obtained is additionally subjected to a fermentation.
摘要翻译：本发明涉及一种由含木素纤维素的原料制备葡萄糖的方法，其中首先用离子液体处理，然后进行酶水解。本发明还涉及一种制备微生物代谢物，特别是乙醇的方法，其中获得的葡萄糖另外进行发酵。

19. 发明授权

US08728773B2 Fermentative production of organic compounds using substances containing dextrin 有权
标题翻译：使用含有糊精的物质发酵生产有机化合物
公开(公告)号：US08728773B2
公开(公告)日：2014-05-20
申请号：US12094646
申请日：2006-11-27
申请人： Matthias Boy , Stephan Freyer
发明人： Matthias Boy , Stephan Freyer
IPC分类号： C12P13/08 , C12P13/04 , C12P7/26
CPC分类号： C12P7/26 , C12P7/42 , C12P7/62 , C12P7/6418 , C12P7/6427 , C12P7/6463 , C12P13/00 , C12P13/005 , C12P13/04 , C12P19/14 , C12P19/30 , C12P19/38
摘要： Process for the production of at least one organic compound having at least 3 C atoms or having at least 2 C atoms and at least 1 N atom by fermentation. In particular, the process comprises milling a starch feedstock, thus obtaining a millbase which comprises at least part of the nonstarchy solid constituents of the starch feedstock; suspending the millbase in an aqueous liquid and liquefying the millbase present in the aqueous liquid in the presence of at least one starch-liquefying enzyme, obtaining an aqueous dextrin-containing medium (1) which comprises at least a part of the nonstarchy solid constituents of the starch feedstock; and using the aqueous dextrin-containing medium (1) in a fermentation for culturing a microorganism which is capable of overproducing the organic compound; wherein enzymes which hydrolyze the dextrins to monosaccharides are being added in an amount of less than 0.001% by weight based on the total weight of the starch feedstock employed, or not at all.
摘要翻译：通过发酵生产具有至少3个C原子或具有至少2个C原子和至少1个N原子的至少一种有机化合物的方法。特别地，该方法包括研磨淀粉原料，从而获得包含至少部分淀粉原料的非淀粉状固体成分的研磨料; 在至少一种淀粉 - 液化酶的存在下使磨浆液悬浮在水性液体中并液化存在于水性液体中的研磨液，得到含水性糊精的培养基（1），其含有至少一部分非淀粉样固体成分淀粉原料; 以及使用含水糊精的培养基（1）进行发酵，培养能够过量生成有机化合物的微生物; 其中将糊精水解成单糖的酶的加入量相对于所用淀粉原料的总重量小于0.001重量％，或根本不加入。

20. 发明申请

US20120205099A1 PROCESS FOR MINERAL OIL PRODUCTION FROM MINERAL OIL DEPOSITS WITH HIGH DEPOSIT TEMPERATURE 有权
标题翻译：矿物油沉积物矿物油生产过程与高储量温度
公开(公告)号：US20120205099A1
公开(公告)日：2012-08-16
申请号：US13371880
申请日：2012-02-13
申请人： Sebastian Briechle , Tillmann Faust , Stephan Freyer , Rajan Hollmann , Tobias Käppler , Bernd Leonhardt , Julia Kristiane Schmidt , Benjamin Wenzke , Foppe Visser
发明人： Sebastian Briechle , Tillmann Faust , Stephan Freyer , Rajan Hollmann , Tobias Käppler , Bernd Leonhardt , Julia Kristiane Schmidt , Benjamin Wenzke , Foppe Visser
IPC分类号： E21B43/22
CPC分类号： C09K8/588
摘要： A two-stage process for mineral oil production from mineral oil deposits with a deposit temperature of more than 70° C. and a salinity of 20 000 ppm to 350 000 ppm, in which an aqueous formulation comprising at least one glucan with a β-1,3-glycosidically linked main chain, and side groups β-1,6-glycosidcally bonded thereto and having a weight-average molecular weight Mw of 1.5*106 to 25*106 g/mol, are injected into a mineral oil deposit through at least one injection borehole and crude oil is withdrawn from the deposit through at least one production borehole. The aqueous formulation is prepared in two stages, by first preparing an aqueous concentrate of the glucan, and diluting the concentrate on site with water to the use concentration.
摘要翻译：矿物油沉积物的矿物油生产的两阶段工艺，矿物油沉积物的沉积温度高于70℃，盐度为20 000ppm至350 000ppm，其中含有至少一种具有β-葡聚糖的葡聚糖的水性制剂 -1,3糖苷键连接的主链以及重量平均分子量Mw为1.5×10 -6〜25×10 6 g / mol的侧链基团与-1,6-糖基结合的基团被注入到矿物油通过至少一个注入井眼沉积，原油通过至少一个生产钻孔从沉积物中排出。通过首先制备葡聚糖的水性浓缩物，并将水浓缩物在水中稀释至使用浓度，分两步制备水性制剂。

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